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Enhanced termination of zinc and cadmium ions from wastewater employing plain and chitosan-modified mxenes: synthesis, characterization,and adsorption performance

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Green Chemical Engineering 2024年第3期5卷 339-347页

作者： njood R.Azeez suhaib s.salih Mohammed Kadhom Harith n.Mohammed Tushar K.Ghosh Department of Chemical Engineering College of Engineering University of Tikrit Department of Environmental science College of Energy and Environmental Science Al-Karkh University of Science Department of nuclear science & Engineering Institute University of Missouri-Columbia

Zinc and cadmium pollutants cause a significant environmental effect that cannot be ignored. Due to their considerable amount in an aqueous environment, industries are seeking suitable adsorbents that are environmentally friendly and inexpensive for removing metals from wastewater before disposing of them in surface waters. This research employed original MXene(MX) and chitosan-modified MXene(CsMX) to extract zinc(Zn(Ⅱ)) and cadmium(Cd(Ⅱ)) metal ions from water-based solutions. The composite material produced was analyzed using techniques such as X-ray Diffraction(XRD), scanning Electron Microscopy(sEM), Fourier Transform Infrared spectroscopy(FTIR), and Brunauer-Emmett-Teller(BET). The effects of contact duration, p H of the solution, and initial concentration of metal ions on the adsorption process of Zn(Ⅱ) and Cd(Ⅱ) onto both MX and CsMX composites were investigated. MX and prepared CsMX composite presented a high adsorption capacity for both studied heavy metals, which were 91.55 and 73.82 mg/g for Zn(Ⅱ) and Cd(Ⅱ) onto MX, 106.84 and 93.07 mg/g for Cd(Ⅱ) and Zn(Ⅱ) onto CsMX composite, respectively. Furthermore, the maximum competitive adsorption capacities for Zn(Ⅱ) onto MX and CsMX composites are 77.29 and 93.47 mg/g, and for are Cd(Ⅱ)60.30 and 79.66 mg/g, respectively. Hence, the removal capacities for both single and competitive metal ions were superior to CsMX composite. However, the adsorption capacities after five successive regeneration sequences were only dropped by 13.2% for Zn(Ⅱ) and 17.4% for Cd(Ⅱ) onto the CsMX composite compared to the first cycle. These results confirm that both metals could be efficiently terminated from wastewater, which makes the prepared CsMX composite a favorable candidate adsorbent in practical applications.

关键词： Adsorption Chitosan MXene Zn(II) Cd(II) Wastewater

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Understanding the corrosion and bio-corrosion behaviour of magnesium composites – a critical review

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Journal of magnesium and Alloys 2024年第3期12卷 890-939页

作者： Prithivirajan sekar s.K.Panigrahi Department of Mechanical Engineering Indian Institute of Technology MadrasChennai600036India Applied magnesium Research Center Center of Excellence in Materials and Manufacturing for Futuristic MobilityIndian Institute of Technology MadrasChennai600036India

Realising the potential of magnesium(Mg),several globally leading ventures have invested in the Mg industry,but their relatively poor corrosion resistance is a never ending saga till *** corrosion and bio-corrosion behaviour of Mg has gained research attention and still remains a hot topic in the application of automobile,aerospace and biomedical *** intrinsic high electrochemical nature of Mg limits their utilization in diverse *** scenario has prompted the development of Mg composites with an aim to achieve superior corrosion and bio-corrosion *** present review enlightens the influence of grain size(Gs),secondary phase,texture,type of matrix and reinforcement on the corrosion and bio-corrosion behaviour of Mg ***,the corrosion and bio-corrosion behaviour of Mg composites manufactured by primary and secondary processing routes are ***,the comprehensive corrosion and bio-corrosion mechanisms of these Mg composites are ***,the individual role of Gs,texture and corrosive medium on corrosion and bio-corrosion behaviour of Mg composites are clarified and *** challenges encountered,unanswered issues in this field are explained in detail and accordingly the scope for future research is *** review is presented from basic concrete background to advanced corrosion mechanisms with an aim of creating interest among the readers like students,researchers and industry experts from various research ***,the corrosion and bio-corrosion behaviour of Mg composites are critically reviewed for the first time to:(i)contribute to the body of knowledge,(ii)foster research and development,(iii)make breakthrough,and(iv)create life changing innovations in the field of Mg composite corrosion.

关键词： Corrosion Bio corrosion magnesium alloys magnesium composites magnesium implants.

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Casson hybrid nanofluid flow over a Riga plate for drug deliveryapplications with double diffusion

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Chinese Physics B 2024年第10期33卷 311-320页

作者： Abeer s.Alnahdi Taza Gul Department of mathematics and statistics Faculty of ScienceImam Mohammad Ibn Saud Islamic University(IMSIU)RiyadhSaudi Arabia Department of mathematics City University of Science and Information Technology25000PeshawarPakistan DGosT-Directorate General of science&Technology Khyber PakhtunkhwaPeshawarPakistan

Casson fluid-mediated hybrid nanofluids are more effective at transferring heat than traditional heat transfer fluids in terms of thermal *** exchangers,cooling systems and other thermal management systems are ideal for use with Casson *** control of the flow and release of medication is necessary when using Casson fluids in drug delivery systems because of their unique rheological *** involves the creation of nanoparticles that are loaded with drugs and distributed in Casson fluid-based carriers for targeted *** this study,to create a hybrid nanofluid,both single-walled carbon nanotubes(sWCnTs)and multi-walled carbon nanotubes(MWCnTs)are dispersed in a Casson fluid with Fourier’s and Fick’s laws *** Casson fluid is suitable for various engineering and medical applications due to the enhancement of heat transfer and thermal conductivity by the carbon *** objective is to understand how sWCnTs and MWCnTs impact the flow field by studying the flow behavior of the Casson hybrid nanofluid when it is stretched against a Riga *** Darcy-Forchheimer model is also used to account for the impact of the porous medium near the stretching *** linear and quadratic drag terms are taken into account in this model to accurately predict the flow behavior of the *** addition,the homotopy analysis method is utilized to address the model *** outcomes are discussed and deliberated based on drug delivery *** findings shed valuable light on the flow characteristics of a Casson hybrid nanofluid comprising sWCnTs and *** is observed that the incorporation of carbon nanotubes makes the nanofluid a promising candidate for medical applications due to its improved heat transfer properties.

关键词： carbon nanotubes(CnTs) Riga plate Casson fluid with Fourier’s and Fick’s laws analytical solutions

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Editor-in-Chief articles of choice and comments from January to June 2024

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World Journal of Gastroenterology 2024年第34期30卷 3875-3882页

作者： Andrzej s Tarnawski Department of Gastroenterology Research University of California Irvine and the Veterans Administration Long Beach Healthcare SystemLong BeachCA 90822United States

As the Editor-in-Chief of the World Journal of Gastroenterology,I carefully review all articles every week before a new issue’s online publication,including the title,clinical and research importance,originality,novelty,and ratings by the peer *** on this review,I select the papers of choice and suggest pertinent changes(e.g.,in the title or text)to the company editors responsible for *** process,while time-consuming,is essential for assuring the quality of publications and highlighting important articles that readers may revisit.

关键词： Papers of choice Weekly review suggested changes/revisions Hepatocellular carcinoma Pancreatic cancer Liver cirrhosis Liver injury Gastric cancer Colorectal cancer Inflammatory bowel diseases

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nucleoside modified mRnA-lipid nanoparticles as a new delivery platform for the repair of the injured spinal cord

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neural Regeneration Research 2025年第8期20卷 2311-2312页

作者： Krisztián Pajer Tamás Bellák Antal nógrádi Department of Anatomy Histology and EmbryologyAlbert Szent-Györgyi Medical SchoolUniversity of SzegedSzegedHungary

spinal cord injury and treatment opportunities:The adult mammalian spinal cord has a very limited capacity for spontaneous regeneration due to various intrinsic molecular and cellular *** the spinal cord neurons have the capacity to regenerate their axons,the expression of growth inhibitory factors,lack or suppression of proper guidance cues,and profound inflammatory responses do not permit successful regeneration(Khyeam et al.,2021).

关键词： injured capacity modified

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Imaging and endoscopic tools in pediatric inflammatory bowel disease: What’s new?

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World Journal of Clinical Pediatrics 2024年第1期13卷 7-13页

作者： Alexandra s Hudson Ghassan T Wahbeh Hengqi Betty Zheng Department of Pediatrics University of WashingtonSeattleWA 98109United States

Pediatric inflammatory bowel disease(IBD)is a chronic inflammatory disorder,with increasing incidence and prevalence *** have been recent advances in imaging and endoscopic technology for disease diagnosis,treatment,and *** ultrasound,including transabdominal,transperineal,and endoscopic,has been emerging for the assessment of transmural bowel inflammation and disease complications(e.g.,fistula,abscess).Aside from surgery,IBD-related intestinal strictures now have endoscopic treatment options including through-the-scope balloon dilatation,injection,and needle knife stricturotomy and new evaluation tools such as endoscopic functional lumen imaging *** transnasal endoscopy may have a role in patients with upper gastrointestinal Crohn’s disease or those with IBD with new upper gastrointestinal *** to dysplasia screening in pediatric patients with longstanding colonic disease or primary sclerosing cholangitis hold promise with the addition of virtual chromoendoscopy and ongoing research in the field of artificial intelligence-assisted endoscopic *** intelligence and machine learning is a rapidly evolving field,with goals of further personalizing IBD diagnosis and treatment selection as well as *** review summarized these advancements,focusing on pediatric patients with IBD.

关键词： Intestinal ultrasound Endoscopy Inflammatory bowel disease Pediatrics Imaging

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Generalized Hopf Bifurcation in a Delay Model of neutrophil Cells Model

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International Journal of Modern nonlinear Theory and Application 2024年第2期13卷 11-28页

作者： suqi ma s. J. Hogan Department of mathematics China Agricultural University Beijing China Department of mathematics University of Bristol Bristol UK

The DDE-Biftool software is applied to solve the dynamical stability and bifurcation problem of the neutrophil cells model. Based on Hopf point finding with the stability property of the equilibrium solution loss, the continuation of the bifurcating periodical solution starting from Hopf point is exploited. The generalized Hopf point is tracked by seeking for the critical value of free parameter of the switching phenomena of the open loop, which describes the lineup of bifurcating periodical solutions from Hopf point. The normal form near the generalized Hopf point is computed by Lyapunov-schimdt reduction scheme combined with the center manifold analytical technique. The near dynamics is classified by geometrically different topological phase portraits.

关键词： Generalized Hopf Bifurcation DDE-Biftool software norm Form

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Kinetics of dense plasma in the field of short laser pulses:A generalized approach

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matter and Radiation at Extremes 2024年第5期9卷 87-92页

作者： V.A.Astapenko V.s.Lisitsa Moscow Institute of Physics and Technology(national Research University) Institutskii per.9141701 DolgoprudnyiRussia national Research Centre“Kurchatov Institute ”123182 MoscowRussia national Research nuclear University MEPhI 115409 MoscowRussia

A generalized kinetic model of atomic level populations in an optically dense plasma excited by laser pulses of arbitrary duration is formulated and *** model is based on a nonstationary expression for the probability of excitation of an atomic transition and takes into account the effects of laser pulse penetration into an optically dense medium.A universal formula for the excitation probability as a function of time and propagation length is derived and applied to the case of a Lorentzian spectral profile of an atomic transition excited by a laser pulse with a Gaussian *** features of nonstationary excitation probabilities are presented for different optical depths of the plasma,laser pulse durations,and carrier *** formulas derived here will be useful for the description of atomic populations excited by laser pulses under realistic conditions of dense plasmas.

关键词： laser excitation excited

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Engineering of efficient visible light photocatalysts:Ti_(1-x+y)Cu_(x)La_(y)O_(2)(x=0.03;y=0,0.005,0.01) compositions

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Journal of Rare Earths 2024年第3期42卷 497-505,I0003页

作者： s.M.Yakout A.M.Youssef Inorganic Chemistry Department National Research Centre(NRC)El Buhouth StDokkiCairo12622Egypt

In dye-photocatalysis, widening the wavelengths absorption range of catalysts as well as aborting the recombination of the photoexcited charge carriers(electrons-holes pairs) are of paramount *** the current study, we report the photocatalytic characteristics of four compositions composed of TiO_(2),Ti_(0.97)Cu_(0.03)O_(2), Ti_(0.965)Cu_(0.03)La_(0.005)O_(2)and Ti_(0.96)Cu_(0.03)La_(0.01)O_(2)powders for two harmful dyes(Congo red and methylene blue). The X-ray diffraction technique verified the configuration of mixed anatase and rutile phases in pure TiO_(2)and Ti_(0.97)Cu_(0.03)O_(2)powders while Ti_(0.965)Cu_(0.03)La_(0.005)O_(2)and Ti_(0.96)Cu_(0.03)La_(0.01)O_(2)powders possess anatase phase only. The changes of the band gap structure and dimensions of the unit cell volume of TiO_(2)confirm the substitution of Ti^(4+)sites by Cu^(2+)and La^(3+)ions. Remarkable widening of wavelengths absorption with formation of long absorption tails were found in TiO_(2)(3.13 e V) through insertion of La^(3+)plus Cu^(2+)ions. Ti_(0.965)Cu_(0.03)La_(0.005)O_(2)and Ti_(0.96)Cu_(0.03)La_(0.01)O_(2)samples exhibit a visible light band gap of 2.3 and 2.7 e V, respectively. Based on sEM images, incorporation of Cu^(2+)and La^(3+)ions influences the surface morphology of TiO_(2). The resulting Ti_(0.97)Cu_(0.03)O_(2), Ti_(0.965)Cu_(0.03)La_(0.005)O_(2)and Ti_(0.96)Cu_(0.03)La_(0.01)O_(2)powders present enhanced photocatalytic activity towards Congo red dye degradation compared to pure one under natural solar spectrum. The best Ti_(0.96)Cu_(0.03)La_(0.01)O_(2)catalyst exhibits superior photocatalytic activity of 96% for 10 ppm CR dye in 20 min as well as above average photocatalytic efficiency of 63% for 30 ppm CR dye in 120 min. As well, it showed acceptable photodegradation activity of 52% for 30 ppm MB solution in 140 min of sunlight irradiation. The heightened photodegradation efficiency of Ti_(0.96)Cu_(0.03)La_(0.01)O_(2)catalyst can be clarified in terms of higher ch

关键词： semiconductor TiO_(2) Rare earths Congo red Methylene blue solar spectrum Photodegradation

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nonlinear wave dispersion in monoatomic chains with lumped and distributed masses:discrete and continuum models

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Applied mathematics and Mechanics(English Edition) 2024年第4期45卷 633-648页

作者： E.GHAVAnLOO s.EL-BORGI school of Mechanical Engineering Shiraz UniversityShiraz 71963-16548Iran Mechanical Engineering Program Texas A&M University at QatarDoha 23874Qatar

The main objective of this paper is to investigate the influence of inertia of nonlinear springs on the dispersion behavior of discrete monoatomic chains with lumped and distributed *** developed model can represent the wave propagation problem in a non-homogeneous material consisting of heavy inclusions embedded in a *** inclusions are idealized by lumped masses,and the matrix between adjacent inclusions is modeled by a nonlinear spring with distributed ***,the model is capable of depicting the wave propagation in bi-material bars,wherein the first material is represented by a rigid particle and the second one is represented by a nonlinear spring with distributed *** discrete model of the nonlinear monoatomic chain with lumped and distributed masses is first considered,and a closed-form expression of the dispersion relation is obtained by the second-order Lindstedt-Poincare method(LPM).next,a continuum model for the nonlinear monoatomic chain is derived directly from its discrete lattice model by a suitable continualization *** subsequent use of the second-order method of multiple scales(MMs)facilitates the derivation of the corresponding nonlinear dispersion relation in a closed *** novelties of the present study consist of(i)considering the inertia of nonlinear springs on the dispersion behavior of the discrete mass-spring chains;(ii)developing the second-order LPM for the wave propagation in the discrete chains;and(iii)deriving a continuum model for the nonlinear monoatomic chains with lumped and distributed ***,a parametric study is conducted to examine the effects of the design parameters and the distributed spring mass on the nonlinear dispersion relations and phase velocities obtained from both the discrete and continuum *** parameters include the ratio of the spring mass to the lumped mass,the nonlinear stiffness coefficient of the spring,and the wave amplitude.

关键词： nonlinear mass-spring chain discrete model continuum model LindstedtPoincare method(LPM) method of multiple scales(MMs) dispersion phase velocity

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