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Electrostatic interaction-mediated 1:1 complexes for high-contrast mitochondrial-targeted phosphorescence bioimaging

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science China Chemistry 2024年第10期67卷 3406-3413页

作者： Jianshuo Cheng Hao sun Lulu Zhou Glib v.Baryshnikov Mouwei Liu shen shen Hans ?gren Liangliang Zhu state Key Laboratory of Molecular Engineering of Polymers Department of Macromolecular ScienceFudan University Laboratory of Organic Electronics Department of Science and TechnologyLink?ping University Department of Physics and Astronomy Uppsala University

Organelle-targeted imaging can provide information on cellular functions and intracellular interactions, being significant for disease diagnosis. The use of room-temperature phosphorescence(RTP) in organelle-targeted imaging can fully utilize its unique characteristics of long wavelength and deep penetration. However, this technology has long been plagued by insufficient probe targeting and limited luminous intensity. In this work, we prepared a series of complexes composed of multicationic persulfurated arenes and biomacromolecules via electrostatic interactions in 1:1 stoichiometry for high-contrast mitochondrial-targeted RTP imaging. such an electrostatic interaction design effectively prevented the self-aggregation of the probes, which is not conducive to mitochondrial targeting. simultaneously, it suppressed the non-radiative decay to the maximum extent, enabling the probes to exhibit strong RTP signals both in aqueous solution and at the cellular level. Furthermore, the biomacromolecules can serve as carriers for an electrostatic interaction transfer of the persulfurated arenes to mitochondria. This leads to high mitochondrial targeting Pearson's correlation coefficients of the probes and high-contrast RTP imaging effects, as well as the independence of the co-incubated probe concentration. These results provide new insights for the development of targeted imaging technologies.

关键词： room-temperature phosphorescence mitochondrial targeting bioimaging complex electrostatic interaction

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Enhanced solar Water Desalination by CuCo_(2)s_(4)-decorated Carbon Foam Derived from Waste Plastics

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Chemical Research in Chinese Universities 2024年第3期40卷 548-555页

作者： Muzammil HUssAIN Tofik Ahmed sHIFA Pratik v.sHINDE Pankaj KUMAR stefano CENTENARO silvia GROss Elisa MORETTI Alberto vOMIERO Department of Molecular sciences and Nanosystems Ca'Foscari University of VeniceVia Torino 15530172 VeniceItaly Department of Industrial Engineering University of PadovaVia Venezia 135131 PadovaItaly Department of Chemical sciences University of PadovaVia Francesco Marzolo135131 PadovaItaly Division of Materials science Department of Engineering Sciences and MathematicsLulea University of Technology97187 LuleaSweden Center for Cultural Heritage Technologies(CCHT) Istituto Italiano di Tecnologia(IT)Via Torino 15530170 Venezia-MestreItaly

Interfacial solar desalination is an emerging technology for freshwater production,but the finding of novel solar evaporators is still *** the present research,graphitic carbon foam(CF)was synthesized from the upcycling of waste plastic polyethylene terephthalate(PET)waste bottles functionalized with carrollite CuCo_(2)s_(4) as a photothermal *** characterization[X-ray diffraction(XRD),Fourier transform infrared spectroscopy(FTIR),and scanning electron microscopy-energy dispersive spectroscopy(sEM-EDs)]confirms the functionalization of carrollite CuCo_(2)s_(4) on graphitic carbon *** Uv-vis spectroscopy analysis showed an enhanced optical absorption in the Uv-vis-near IR region(>96%)for functionalized CuCo_(2)s_(4)-CF foam compared to carbon foam(67%).The interfacial solar desalination experiment presented a significantly enhanced evaporation rate of 2.4 kg·m^(−2)·h^(−1) for CuCo_(2)s_(4)-CF compared to that of CF(1.60 kg·m^(−2)·h^(−1))and that of CuCo_(2)s_(4)(1.60 kg·m^(−2)·h^(−1)).The obtained results proved that the newly synthesized CuCo_(2)s_(4)-CF from the upcycled plastic into new material for the photothermal desalination process can enhance the practice of a circular economy to produce fresh water.

关键词： Photothermal desalination Cobalt Copper Chalcogenide Waste upcycling Circular economy

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superior comprehensive properties of LaFe_(11.8)si_(1.2)/Ce_(60)Co_(40) magnetocaloric composites

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Journal of Rare Earths 2024年第6期42卷 1073-1086,I0003页

作者： Xichun Zhong Yuanxin Li Yucai Wu Jiaohong Huang Cuilan Liu Jian Liu Zhongwu Liu Minglong Zhong Zhenchen Zhong R.v.Ramanujan school of Materials science and Engineering South China University of TechnologyGuangzhou510640China Baotou Research Institute of Rare Earths Baotou014030China Center for Advanced solidification Technology School of Materials Science and EngineeringShanghai UniversityShanghai200444China Jiangxi KeyLaboratory for Rare Earth Magnetic Materials and Devices&Institute for Rare Earth Magnetic Materials and Devices(IREMMD) Jiangxi University of Science and TechnologyGanzhou341000China school of Materials science and Engineering Nanyang Technological University639798Singapore singapore-HUJ Alliance for Research and Enterprise(sHARE) The Smart Grippers for Soft Robotics(SGSR)ProgrammeCampus for Research Excellence and Technological Enterprise(CREATE)138602Singapor

LaFe_(11.8)si_(1.2)/10 wt%Ce_(60)Co_(40) composites were prepared by spark plasma sintering and subsequent diffusion annealing.A novel core-shell structure is observed with the LaFe11.8si1.2 particles as the core and the(La,Ce)_(2)(Fe,Co,si)_(17)(2:17)phase as the *** diffusion annealing time(t_(a))increases,this core-shell structure is replaced by the formation of the(La,Ce)_(1)(Fe,Co,si)_(13) *** at 1323 K for 12 h results in samples with(-ΔsM)^(max) of 9.30 J/(kg·K)(Δμ0H=2 T),good mechanical properties((σbc)^(max)=402 MPa,ε=4.21%)and thermal conductivity of 8.7 W/(m·K).Thus,bulk composites with excellent comprehensive properties for magnetic refrigeration are obtained in this work.

关键词： LaFe_(11.8)si_(1.2)/Ce_(60)Co_(40)composites spark plasma sintering Diffusion annealing Microstructure evolution Magnetocaloric effect Rareearths

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Anomalies in the short-range local environment and atomic diffusion in single crystalline equiatomic CrMnFeCoNi highentropy alloy

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Nano Research 2024年第6期17卷 5336-5348页

作者： Alevtina smekhova Daniel Gaertner Alexei Kuzmin Ana Guilherme Buzanich Goetz schuck Ivo Zizak Gerhard Wilde Kirill v.Yusenko sergiy Divinski Helmholtz-Zentrum Berlin für Materialien und Energie(HZB) D-12489 BerlinGermany Institute of Materials Physics University of MünsterD-48149 MünsterGermany Institute of solid state Physics University of LatviaLV-1063 RigaLatvia Bundesanstalt für Materialforschung und–prüfung(BAM) D-12489 BerlinGermany

Multi-edge extended X-ray absorption fine structure(EXAFs)spectroscopy combined with reverse Monte Carlo(RMC)simulations was used to probe the details of element-specific local coordinations and component-dependent structure relaxations in single crystalline equiatomic CrMnFeCoNi high-entropy alloy as a function of the annealing *** representative states,namely a high-temperature state,created by annealing at 1373 K,and a low-temperature state,produced by long-term annealing at 993 K,were compared in *** features identified in atomic configurations of particular principal components indicate variations in the local environment distortions connected to different degrees of compositional disorder at the chosen representative *** detected changes provide new atomistic insights and correlate with the existence of kinks previously observed in the Arrhenius dependencies of component diffusion rates in the CrMnFeCoNi high-entropy alloy.

关键词： high-entropy alloys diffusion short-range order extended X-ray absorption fine structure(EXAFs) reverse Monte Carlo

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告别米格尔街

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语数外学习(初中版) 2024年第6期 15-16页

作者： v.s.奈保尔

我的母亲说：“你在这个地方变得太野了，我想你该离开了。”“去哪儿，委内瑞拉吗？”我说。“不，去个别的什么地方。”我说：“那好吧，等你想好了再决定吧。”母亲说：“这事我要去和格涅沙·庞迪特商量一下，他是你爸爸的朋友。

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Fluoride contamination in groundwater:A global review of the status,processes,challenges,and remedial measures

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Geoscience Frontiers 2024年第2期15卷 1-29页

作者： E.shaji K.v.sarath M.santosh P.K.Krishnaprasad B.K.Arya Manisha s.Babu Department of Geology University of KeralaKariavattom CampusThiruvananthapuramKerala 695581India school of Earth sciences and Resources China University of Geosciences(Beijing)29 Xueyuan RoadBeijing 100083China Department of Earth science University of AdelaideAdelaideSA 5005Australia Department of Geology Central University of KeralaTejaswini HillsPeriyeKasaragodKerala 671316India

Groundwater pollution by fluoride is one of the prime concerns of the world population due to its toxicity,which results in adverse health *** this paper,we review the current scenario of the fluoride contamination of groundwater in various countries across the globe and its impact on human *** the last decade,several newly affected regions have been reported all over the world,with more than 100 countries affected by fluoride contamination in groundwater(concentration exceeding the acceptable limit of 1.5 mg/L defined by the World Health Organization).Fluoride poisoning is mainly due to the unsupervised ingestion of products for dental and oral hygiene and over-fluoridated drinking *** is estimated that more than 200 million people from different countries are affected by fluoriderelated groundwater issues and health *** highest among these are from the countries in Africa(38),Asia(28),and Europe(24),followed by countries like south America(5),North America(3),and Australia(2).The source of fluoride in drinking water is primarily geogenic,together with forage,grasses and grains,tea,and anthropogenic *** countries affected were correlated with climatic zones and geological factors to gain insights into geospatial *** analyses show that most of the fluoride pollution-prone zones are located in high-grade metamorphic terranes with granitoid or alkaline intrusions,geothermal hot springs,and volcanic regions with arid or semi-arid climatic *** study also finds that children across the globe are more vulnerable than adults to fluoride *** review finds that,although there are efficient fluoride removal techniques,including filters with next-generation nanomaterials,to date,there has not been a single technique developed that can claim to be a practically robust solution for fluoride removal from drinking ***,we suggest developing next-generation filters that can retain essential miner

关键词： Fluoride Groundwater Water contamination WHO standards Climate zones Remediation sustainable Development Goals

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stand dynamics of old-growth hemlock forests in central Bhutan are shaped by natural disturbances

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Forest Ecosystems 2024年第4期11卷 434-447页

作者： Karma Tenzin Craig R.Nitschke Kathryn J.Allen Raphael Trouve Thiet v.Nguyen Patrick J.Baker school of Agriculture Foodand Ecosystem SciencesUniversity of Melbourne500 Yarra BlvdRichmondVictoriaAustralia school of Geography Planningand Spatial SciencesUniversity of TasmaniaSandy BayTasmaniaAustralia Forest science Institute of south vietnam 1 Pham Van Hai StreetTan Binh DistrictHo Chi Minh CityViet Nam

Understanding how past disturbances have influenced the development of forests is critical for deciphering their current structure and composition and forecasting future *** this study,dendrochronological methods were applied to uncover the disturbance history of old-growth hemlock-dominated forests in central *** of tree-ring samples from two old-growth hemlock stands,located in two different topographic settings,identified the importance of gap-phase dynamics in facilitating recruitment and growth releases and producing complex,multi-aged structure s over *** site showed evidence of a near stand-replacing disturbance in the late 1700s,while the other showed no evide nce of high-severity disturbance at any time over the last 400 *** both sites low-to medium-severity disturbances,some of which appear to be associated with cyclones originating in the Bay of Bengal,dominated the disturbance *** hemlock stands exhibited a significant positive association between cyclone occurrence and growth release events and between recruitment pulses and growth release *** 1800 to 1970 there was an increase in recruitment of angiosperm tree species at most sites and a corresponding decline in conifer *** the past 50 years there has been little new recruitment;this may be due to light limitation in the understory from shade-tolerant angiosperms and bamboo in the lower strata of these *** variations in disturbance dynamics and recruitment were observed across the study sites,suggesting that other factors,such as topography and climate,may be influencing long-term stand development *** study highlights the complex interplay between historical disturbance regimes and tree recruitment in shaping the age and size structures of old-growth hemlock forests in central *** also provides new insights into the dynamics of these forests that can be used to support effective forest conservation and management i

关键词： Forest structure Hemlock forest Himalaya Natural disturbance

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In vivo measurement of NADH fluorescence lifetime in skeletal muscle via -ber-coupled time-correlated single photon counting

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Journal of Innovative Optical Health sciences 2024年第1期17卷 121-134页

作者： Kathryn M.Priest Jacob v.schluns Nathania Nischal Colton L.Gattis Jeffrey C.Wolchok Timothy J.Muldoon Department of Biomedical Engineering University of Arkansas FayettevilleARUSA

Nicotinamide adenine dinucleotide(NADH)is a cofactor that serves to shuttle electrons during metabolic processes such as glycolysis,the tricarboxylic acid cycle,and oxidative phosphorylation(OXPHOs).NADH is autofluorescent,and itsfluorescence lifetime can be used to infer metabolic dynamics in living ***-coupled time-correlated single photon counting(TCsPC)equipped with an implantable needle probe can be used to measure NADH lifetime in vivo,enabling investigation of changing metabolic demand during muscle contraction or tissue *** study illustrates a proof of concept for point-based,minimally-invasive NADHfluorescence lifetime measurement in *** muscle loss(vML)injuries were created in the left tibialis anterior(TA)muscle of male sprague Dawley *** lifetime measurements were collected before,during,and after a 30 s tetanic contraction in the injured and uninjured TA muscles,which was subsequently-t to a biexponential decay model to yield a metric of NADH utilization(cytoplasmic vs protein-bound NADH,the A11/A22 ratio).On average,this ratio was higher during and after contraction in uninjured muscle compared to muscle at rest,suggesting higher levels of free NADH in contracting and recovering muscle,indicating increased rates of *** injured muscle,this ratio was higher than uninjured muscle overall but decreased over time,which is consistent with current knowledge of inflammatory response to injury,suggesting tissue regeneration has *** data suggest that-ber-coupled TCsPC has the potential to measure changes in NADH binding in vivo in a minimally invasive manner that requires further investigation.

关键词： Glycolysis oxidative phosphorylation energy metabolism volumetric muscle loss

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Phase composition,conductivity,and sensor properties of cerium-doped indium oxide

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Nano Materials science 2024年第2期6卷 193-200页

作者： M.I.Ikim G.N.Gerasimov v.F.Gromov O.J.Ilegbusi L.I.Trakhtenberg N.N.semenov Federal Research Center for Chemical Physics of RAs MoscowRussia University of Central Florida OrlandoFLUSA Moscow Institute of Physics and Technology(state University) DolgoprudnyMoscow RegionRussia Lomonosov Moscow state University MoscowRussia

The hydrothermal synthesis of In_(2)O_(3)and CeO_(2)–In_(2)O_(3)is investigated as well as the properties of sensor layers based on these *** the synthesis of In_(2)O_(3),intermediate products In(OH)_(3)and InOOH are formed,which are the precursors of stable cubic(c-In_(2)O_(3))and metastable rhombohedral(rh-In_(2)O_(3))phases,respectively.A transition from c-In_(2)O_(3)to rh-In_(2)O_(3)is observed with the addition of CeO_(2).The introduction of cerium into rh-In_(2)O_(3)results in a decrease in the sensor response to hydrogen,while it increases in composites based on c-In_(2)O_(3).The data on the sensor activity of the composites correlate with XPs results in which CeO_(2)causes a decrease in the concentrations of chemisorbed oxygen and oxygen vacancies in rh-In_(2)O_(3).The reverse situation is observed in composites based on c-In_(2)O_(3).Compared to In_(2)O_(3)and CeO_(2)–In_(2)O_(3)obtained by other methods,the synthesized composites demonstrate maximum response to H_(2)at low temperatures by 70–100℃,and have short response time(0.2–0.5 s),short recovery time(6–7 s),and long-term stability.A model is proposed for the dependence of sensitivity on the direction of electron transfer between In_(2)O_(3)and CeO_(2).

关键词： Cerium oxide Indium oxide Nanocomposite Hydrothermal method Cubic phase Rhombohedral phase sensor response Conductivity Hydrogen Response/recovery time

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Rigidity symmetry Line for Thermodynamic Fluid Equations-of-state

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Journal of Modern Physics 2024年第5期15卷 613-633页

作者： Leslie v. Woodcock Department of Physics University of Algarve Faro Portugal

We report progress towards a modern scientific description of thermodynamic properties of fluids following the discovery (in 2012) of a coexisting critical density hiatus and a supercritical mesophase defined by percolation transitions. The state functions density ρ(p,T), and Gibbs energy G(p,T), of fluids, e.g. COsub>2sub>, Hsub>2sub>O and argon exhibit a symmetry characterised by the rigidity, ω = (dp/dρ)sub>Tsub>, between gaseous and liquid states along any isotherm from critical (Tsub>csub>) to Boyle (Tsub>Bsub>) temperatures, on either side of the supercritical mesophase. Here, using experimental data for fluid argon, we investigate the low-density cluster physics description of an ideal dilute gas that obeys Dalton’s partial pressure law. Cluster expansions in powers of density relate to a supercritical liquid-phase rigidity symmetry (Rs) line (ω = ρsub>rssub>(T) = RT) to gas phase virial coefficients. We show that it is continuous in all derivatives, linear within stable fluid phase, and relates analytically to the Boyle-work line (BW) (w = (p/ρ)sub>Tsub> = RT), and to percolation lines of gas (PB) and liquid (PA) phases by: ρsub>BWsub>(T) = 2ρsub>PAsub>(T) = 3ρsub>PBsub>(T) = 3ρsub>Rssub>(T)/2 for T Tsub>Bsub>. These simple relationships arise, because the higher virial coefficients (bsub>nsub>, n ≥ 4) cancel due to clustering equilibria, or become negligible at all temperatures (0 T Tsub>Bsub>)sub> sub>within the gas phase. The Boyle-work line (p/ρsub>BWsub>)sub>Tsub> is related exactly at lower densities as T → Tsub>Bsub>, and accurately for liquid densities, by ρsub>BWsub>(T) = −(bsub>2sub>/bsub>3sub>)sub>Tsub>. The Rs line, ω(T) = RT, defines a new liquid-density ground-state physical constant (ρsub>Rssub>(0) = (2/3)ρsub>BWsub>(0) for argon). Given the gas-liquid rigidity symmetry, the entire thermodynamic state functions below Tsub>Bsub> are obtainable from bsub>2sub>(T). A BW

关键词： Liquid-state Theory Cluster Physics Percolation Lines Fluid Thermodynamics Boyle Line Rigidity-symmetry Line

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