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Synthesis and Crystal Structure of a New Glycinato Copper Compound

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Chinese Journal of Structural Chemistry 2006年第5期25卷 631-635页

作者： XIANG sheng-Chang sheng Tian-Lu FU rui-Biao HU sheng-Min WU Xin-Tao State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter The Chinese Academy of Sciences Fuzhou Fujian 350002 China

A glycinato copper compound {Cu（NH2CH2COO）（H2O）ClO4} crystallizes in monoclinic, space group P21/n with a = 7.8299（9）, b = 10.3807（10）, c = 9.4775（12）A, β = 109.659（6）°, V = 725.43（12）A^3, Z = 4, Mr = 255.07, Dc = 2.335 g/cm^3, F（000） = 508,μ = 3.381 mm^-1, R = 0.0270 and wR = 0.0707 for 1677 observed reflections with Ⅰ 〉 2σ（Ⅰ）. The title compound contains a chain in the syn-anti conformation, which is generated by the glide-plane operation. The adjacent layers made up of the chains through the connection of perchlorate are related by inversion center operation, which links with each other through the hydrogen bonds.

关键词： glycinato copper complex chain hydrogen bonds

Dynamic response characteristics of dry and watersaturated schist under impact loading

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Journal of Mountain Science 2020年第12期17卷 3123-3136页

作者： ZHOU Yang SU sheng-rui CHEN Jian-xun School of Geological Engineering and Geomatics Chang’an UniversityXi’an 710064China School of Highway Chang’an UniversityXi’an 710064China

Many geological engineering hazards are closely related to the dynamic mechanical properties of rock ***,most existing studies on the dynamic mechanical properties of rock materials were conducted on the hard rocks such as sandstone,granite,limestone,and marble,whereas soft rocks,such as schist,are less ***,in this study,a series of triaxial impact tests were conducted on dry and saturated schist by employing a modified triaxial split Hopkinson pressure bar system to reveal the coupling effects of water,strain rate,and triaxial confining pressure on the mechanical properties of *** results show that schist is a type of watersensitive rock and the stress-strain curve of saturated schist has apparent *** effects of strain rate on dynamic strain,deformation modulus and peak stress were *** results also show that the dynamic peak stress is affected by the combined softening effect and viscous effect of water under impact ***,it was found that the failure mode of schist belongs to typical axial tensile failure under uniaxial impact tests,and shear failure is the main failure mode under triaxial impact *** the increase in confining pressure,the failure modes of schist change from tensile failure to shear *** research can provide useful parameters for geological engineering hazard prevention in mountain areas.

关键词： Dry and water-saturated schist Triaxial stress constraint Modified triaxial split Hopkinson pressure bar Dynamic mechanical behavior Impact loading

The Multiple Roles of Autophagy in Neural Function and Diseases

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Neuroscience Bulletin 2024年第3期40卷 363-382页

作者： Yan-Yan Li Zheng-Hong Qin rui sheng Department of Pharmacology and Laboratory of Aging and Nervous Diseases Jiangsu Key laboratory of Neuropsychiatric DiseasesCollege of Pharmaceutical Sciences of Soochow UniversitySuzhou 215123China

Autophagy involves the sequestration and delivery of cytoplasmic materials to lysosomes,where proteins,lipids,and organelles are degraded and *** to the way the cytoplasmic components are engulfed,autophagy can be divided into macroautophagy,microautophagy,and chaperone-mediated ***,many studies have found that autophagy plays an important role in neurological diseases,including Alzheimer's disease,Parkinson's disease,Huntington's disease,neuronal excitotoxicity,and cerebral *** maintains cell homeostasis in the nervous system via degradation of misfolded proteins,elimination of damaged organelles,and regulation of apoptosis and ***-mTOR,Beclin 1,TP53,endoplasmic reticulum stress,and other signal pathways are involved in the regulation of autophagy and can be used as potential therapeutic targets for neurological ***,we discuss the role,functions,and signal pathways of autophagy in neurological diseases,which will shed light on the pathogenic mechanisms of neurological diseases and suggest novel targets for therapies.

关键词： Autophagy Neurodegenerative diseases Cerebral ischemia AMPK mTOR Beclin 1 TP53 Endoplasmic reticulum stress

A Weakly-Supervised Crowd Density Estimation Method Based on Two-Stage Linear Feature Calibration

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IEEE/CAA Journal of Automatica Sinica 2024年第4期11卷 965-981页

作者： Yong-Chao Li rui-sheng Jia Ying-Xiang Hu Hong-Mei Sun the College of Computer Science and Engineering Shandong University of Science and TechnologyQingdao 266590 the Faculty of Information Science and Engineering Ocean University of ChinaQingdao 266000China the College of Computer Science and Engineering Shandong University of Science and TechnologyQingdao 266590China the College of Computer Science and Engineering Nanjing University of Science and TechnologyNanjing 210000China

In a crowd density estimation dataset,the annotation of crowd locations is an extremely laborious task,and they are not taken into the evaluation *** this paper,we aim to reduce the annotation cost of crowd datasets,and propose a crowd density estimation method based on weakly-supervised learning,in the absence of crowd position supervision information,which directly reduces the number of crowds by using the number of pedestrians in the image as the supervised *** this purpose,we design a new training method,which exploits the correlation between global and local image features by incremental learning to train the ***,we design a parent-child network(PC-Net)focusing on the global and local image respectively,and propose a linear feature calibration structure to train the PC-Net simultaneously,and the child network learns feature transfer factors and feature bias weights,and uses the transfer factors and bias weights to linearly feature calibrate the features extracted from the Parent network,to improve the convergence of the network by using local features hidden in the crowd *** addition,we use the pyramid vision transformer as the backbone of the PC-Net to extract crowd features at different levels,and design a global-local feature loss function(L2).We combine it with a crowd counting loss(LC)to enhance the sensitivity of the network to crowd features during the training process,which effectively improves the accuracy of crowd density *** experimental results show that the PC-Net significantly reduces the gap between fullysupervised and weakly-supervised crowd density estimation,and outperforms the comparison methods on five datasets of Shanghai Tech Part A,ShanghaiTech Part B,UCF_CC_50,UCF_QNRF and JHU-CROWD++.

关键词： Crowd density estimation linear feature calibration vision transformer weakly-supervision learning

Synthesis,Structure and Luminescence of a Novel 2D Cadmium Coordination Polymer with a Ligand Generated in situ

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Chinese Journal of Structural Chemistry 2007年第3期26卷 333-337页

作者： HUANG Xi-He sheng Tian-Lu XIANG sheng-Chang FU rui-Biao HU sheng-Min LI Ya-Min WU Xin-Tao State Key Laboratory of Structural Chemistry Fujian Institute of Research on theStructure of Matter The Chinese Academy of Sciences Fuzhou Fujian 350002 China

The hydrothermal reaction of 1,2-dicyanobenzene with NaN3 in the presence of Cd（NO3）2 affords a novel 2D cadmium tetrazolyl-benzoate, {Cd（tzbz）（H2O）}n （H2tzbz is 2-（5-tetrazolyl）-benzoate）. The tzbz ligand is generated in situ through the [2＋3] Sharpless cycloaddition reaction and hydrolyzation. Its crystal structure was determined by single-crystal X-ray diffraction method. The crystal crystallizes in the orthorhombic system, space group Pbca with a = 9.6659（19）, b = 7.6366（15）, c = 25.964（5）A, V= 1916.5（7）A^3, Z= 8, Mr = 318.57, Dc = 2.208 g/cm^3, F（000） = 1232 and p = 2.276 mm^-1. The Cd（Ⅱ） atom is coordinated by four tzbz ligands and one water molecule to form a severely distorted pentangle bipyramid. While each tzbz ligand connects to four Cd（Ⅱ） atoms in a μ4-η1, η, η1, η1, η1 coordination mode to construct a 2D architecture of the title complex. Additionally, the title complex exhibits strong fluorescence at room temperature in the solid state.

关键词： hydrothermal synthesis in situ crystal structure cadmium

Synthesis and Structure of a Dinuclear Copper(Ⅱ)-ditetrazolate Involving in situ Ligand Synthesis

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Chinese Journal of Structural Chemistry 2007年第2期26卷 161-164页

作者： HUANG Xi-He sheng Tian-Lu XIANG sheng-Chang FU rui-Biao HU sheng-Min LI Ya-Min WU Xin-Tao State Key Laboratory of Structural Chemistry Fufian Institute of Research on theStructure of Matter The Chinese Academy of Sciences Fuzhou Fufian 350002 China

The hydrothermal reaction of 1,2-dicyanobenzene with NaN3 in the presence of CuC12, 2,2＇-bipyridine and H2O affords a novel dinuclear copper（Ⅱ）-ditetrazolate, [Cu（bpy）- （pdtz）]2 （Hpdtz = 5,5＂-1,2-phenylene-ditetrazole, bpy = 2,2＇-bipyridine）. The pdtz ligand is generated in situ through Sharpless 2＋3 cycloaddition reaction. Its crystal structure was determined by single-crystal X-ray diffraction method. The crystal crystallizes in the monoclinic system, space group P211n with a = 8.2096（16）, b = 18.580（4）, c = 11.838（2） A, β = 103.12（3）°, V = 1758.5（6） A^3, Z = 2, Mr = 863.83, Dc = 1.631 g/cm^3, F（000） = 876 and μ = 1.272 mm^-1. In this novel dinuclear structure, the pdtz ligand adopts a peculiar μ2-η1,η2 coordination mode.

关键词： hydrothermal synthesis in situ crystal structure copper ditetrazolate

Homing Guidance Law with Falling Angle and Flying Time Control

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Journal of Harbin Institute of Technology(New Series) 2014年第1期21卷 55-61页

作者： Peng-Yun Liu rui-sheng Sun Wei-Ming Li School of Energy and Power Engineering Nanjing University of Science and Technology

In this paper,a new homing guidance method is used to control the flying time and falling angle for guided missiles. Through this approach,it finds the approximate solution to the quadratic equation of time-togo,which is used for the formula derivation of the flying time control command. In this guidance law design,the acceleration rate control command is adopted. The guidance law is composed of a PN guidance command and a flying time control command. Firstly,it obtains a desired falling angle with accurate guidance. Secondly,it introduces to satisfy the constraint of flying time. The flying time control requires an assumption on the future evolution of missile,which is called time-to-go. To cope with the time-varying speed of missiles,a method of compensating the estimation of time-to-go is presented. The new guidance law is evaluated by using a simulation of typical terminal guidance for rocket-propelled torpedo. The simulation results show that the guidance achieves excellent control performance and exhibits insensitivity to initial trajectory parameter over a widen flight envelope.

关键词： homing guidance law falling angle flying time rocket-propelled torpedo time-to-go

Synthesis and Crystal Structure of a Novel Heptanuclear Ruthenium- and Sodium-containing Polyoxomolybdate [{Na(H_2O)_3}_2{Ru(dmso)_3}_2(MoO_4)_3]·_3H_2O

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Chinese Journal of Structural Chemistry 2006年第7期25卷 783-788页

作者： HUANG Xi-He XIANG sheng-Chang FU rui-Biao sheng Tian-Lu ZHANG Jian-Jun LI Ya-Min WANG Long-sheng WU Xin-Tao State Key Laboratory of Structural Chemistry Fujian Institute of Research on theStructure of Matter The Chinese Academy of Sciences Fuzhou Fujian 350002 China

The title compound, [{Na（H2O）3}2lRu（dmso）3}2（MoO4）3]·3H2O, has been obtained by the reaction of Na2MoO4·2H2O with cis-Ru（dmso）4Cl2 in aqueous solution. Its crystal structure was determined by single-crystal X-ray diffraction method. The crystal crystallizes in the triclinic system, space group PI^- with a = 12.3333（3）, b = 12.6289（3）, c = 32.0284（14） A, α = 79.873（7）, β= 87.549（9）, γ = 64.500（4）°, V = 4429.5（2） A^3, Z = 4, Mr = 1358.85, Dc = 2.038 g/cm^3, F（000） = 2696 and μ = 1.874 mm^-1. The compound contains a novel pentanuclear triangle bipyramidal core, [{ Ru（dmso）3 } 2（MoO4）3]^2-, which consists of two { Ru（dmso）3 } ^2＋ fragments and three {μ2-MoO4}^2- units. Furthermore, the dmso ligands bridge the pentanuclear [Ru2Mo3] core and two [Na（H2O）3]^＋ fragments together, forming a neutral heptanuclear ruthenium- and sodiumcontaining polyoxomolybdate.

关键词： synthesis crystal structure ruthenium sodium polyoxomolybdate

Three New Silver Alkylenediphosphonates with Pillar-like Open-frameworks

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Chinese Journal of Structural Chemistry 2005年第11期24卷 1231-1241页

作者： FU rui-Biao HU sheng-Min ZHANG Hui-Shuang WANG Long-sheng LI Ya-Min HUANG Xi-He WU Xin-Tao State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter The Chinese Academy of Science Fuzhou Fujian 350002 China

Three new silver alkylenediphosphonates, [Ag2（HO3PCH2CH2CH2CH2PO3H）] 1, [Ag4（O3PCH2CH2CH2CH2PO3）] 2 and [Ag4（O3PCH2CH2CH2PO3（H2O）] 3, have been hydrotherreally synthesized and characterized by X-ray single-crystal and powder diffraction, elemental analyses, IR and thermogravimetric analyses （TGA）. The structures of these compounds are all threedimensional pillar-like open-frameworks with 18-membered [Ag2O4P4C8] channels for compound 1 and 2, and 16-member [Ag2O4P4C6] channels for compound 3. Both 2 and 3 contain interesting twodimensional Ag（Ⅰ） networks based on Ag...Ag interactions. 1,4-Butylene- and 1,3-propylene diphosphonate groups of 2 and 3 bond the first and second maximum metal atoms among metal organodiphosphonates with linking sixteen and fifteen silver（Ⅰ） atoms, respectively. In addition, the coordinated water molecules of 3 can be reversibly removed and recovered.

关键词： hydrothermal syntheses silver diphosphonate pillar-like single crystal