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A Dielectric Ink Combining Acrylate and Cyanate Moieties for Inkjet 3D Printing with Good Thermal Stability

Chinese Journal of Polymer Science 2024年第6期42卷 766-774页

作者： Yi-Xuan Li Liang-Ying Wu Yan Yang Yao-Zhong Lu Zhong-Ying Ji Yu-Xiong Guo Xiao-Long Wang qiao-sheng pu State Key Laboratory of Applied Organic Chemistry College of Chemistry and Chemical EngineeringLanzhou UniversityLanzhou730000China State Key Laboratory of Solid Lubrication Lanzhou Institute of Chemical PhysicsLanzhou730000China Lanzhou Traditional Chinese Medicine Hospital of Orthopedics and Traumatology Lanzhou730000China Shandong Laboratory of Advanced Materials and Green Manufacturing at Yantai Yantai Zhongke Research Institute of Advanced Materials and Green Chemical EngineeringYantai264006China

Inkjet 3D printing has potential in the additive manufacturing of electronic circuits and ***,inks that can be used for printing layers with T5%>300℃ or hardness>200 MPa have been rarely *** ester(CE)polymers have excellent thermal stability,high strength,and low shrinkage compared to other common dielectric inks for inkjet 3D printing,but cannot be quickly shaped by ultraviolet(UV)irradiation or thermal *** CEs with UV-curable monomers may be a possible way to accelerate crosslinking,but there are challenges from the adverse effects of the dilution of both *** this study,dielectric inks with acrylate and cyanate moieties were *** low viscosity and surface tension of the CE precursor(Bisphenol E cyanate ester)were combined with photocurable acrylate diluent monomers and cross-linker to realize an ink suitable for inkjet 3D *** internal dual three-dimensional cross-linked network structure resin was prepared by a combination of photocuring and thermal curing with T5%up to 326.69℃,hardness up to 431.84 MPa,dielectric constant of 2.70 at 8 GHz,and shrinkage of 1.64%.The developed dielectric inks can be applied to the 3D printing of printed circuit boards and other electronic devices that require dielectric properties.

关键词： Inkjet printing Cyanate ester resin 3D doubly cross-linked network Good thermal stability

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Chiral phosphoramidite ligand-modulated palladium auto-tandem catalysis for asymmetric dehydrogenative dienylation of imines with α-alkenes

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Science China Chemistry 2025年

作者： Zhong-sheng Nong Hao-Fan Qian Ying-Chun Chen pu-sheng Wang Liu-Zhu Gong Hefei National Research Center for Physical Sciences at the Microscale and Department of Chemistry University of Science and Technology of China Key Laboratory of Drug Targeting and Drug Delivery System (Sichuan University) Ministry of Education and Sichuan Research Center for Drug Precision Industrial Technology West China School of Pharmacy Sichuan University School of Materials and Chemistry Southwest University of Science and Technology

The development of efficient processes allowing rapid access to complex chiral molecules from easily available alkenes is a long-term pursuit in the synthetic chemistry community. Transition metal-catalyzed asymmetric functionalization of allylic C–H bond represents a unique alternative toward this goal. However, enantioselective dehydrogenative transformation of olefins to value-added optically enriched molecules remains yet to be discovered. Here, we report a highly enantioselective dehydrogenative dienylation of imines with unactivated α-alkenes driven by the synergistic action of palladium complex and carboxylic acid. Chiral phosphoramidite ligands turned out to be superior in modulating the performance of palladium autotandem catalysis and allowed a broad range of α-alkenes and imines to be transformed into chiral dienylamines. Mechanistic studies suggest that the dienes could be in situ generated from α-alkenes through a palladium(0)-mediated dehydrogenative process in the presence of excess benzoquinone oxidants, and then participated in the Pd-chiral phosphoramidite-catalyzed intermolecular vinylogous-type addition to the imines activated by the carboxylic acid co-catalyst. Notably, the second β-H elimination occurring in the dienylation event might be the turnover-limiting step.

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Small extracellular vesicles derived from human induced pluripotent stem cell-differentiated neural progenitor cells mitigate retinal ganglion cell degeneration in a mouse model of optic nerve injury

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Neural Regeneration Research 2025年第2期20卷 587-597页

作者： Tong Li Hui-Min Xing Hai-Dong Qian qiao Gao sheng-Lan Xu Hua Ma Zai-Long Chi State Key Laboratory of Ophthalmology Optometry and Visual ScienceEye HospitalWenzhou Medical UniversityWenzhouZhejiang ProvinceChina National Clinical Research Center for Ocular Diseases Eye HospitalWenzhou Medical UniversityWenzhouZhejiang ProvinceChina

Several studies have found that transplantation of neural progenitor cells(NPCs)promotes the survival of injured ***,a poor integration rate and high risk of tumorigenicity after cell transplantation limits their clinical *** extracellular vesicles(sEVs)contain bioactive molecules for neuronal protection and *** studies have shown that stem/progenitor cell-derived sEVs can promote neuronal survival and recovery of neurological function in neurodegenerative eye diseases and other eye *** this study,we intravitreally transplanted sEVs derived from human induced pluripotent stem cells(hiPSCs)and hiPSCs-differentiated NPCs(hiPSC-NPC)in a mouse model of optic nerve *** results show that these intravitreally injected sEVs were ingested by retinal cells,especially those localized in the ganglion cell *** with hiPSC-NPC-derived sEVs mitigated optic nerve crush-induced retinal ganglion cell degeneration,and regulated the retinal microenvironment by inhibiting excessive activation of *** analysis further revealed that hiPSC-NPC derived sEVs transported neuroprotective and anti-inflammatory miRNA cargos to target cells,which had protective effects on RGCs after optic nerve *** findings suggest that sEVs derived from hiPSC-NPC are a promising cell-free therapeutic strategy for optic neuropathy.

关键词： exosome miRNA neural progenitor cell neurodegeneration neuroinflammation neuroprotection optic nerve crush optic neuropathy retinal ganglion cell small extracellular vesicles

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Plasmonic tandem heterojunctions enable high-efficiency charge transfer for broad spectrum photocatalytic hydrogen production

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Journal of Energy Chemistry 2025年第1期100卷 710-720页

作者： Wenxuan Chen Xiu-Qing qiao Guo Hui Bojing Sun Dongfang Hou Meidi Wang Xueqian Wu Tao Wu Dong-sheng Li College of Materials and Chemical Engineering Key Laboratory of Inorganic Nonmetallic Crystalline and Energy Conversion Materials China Three Gorges University Hubei Three Gorges Laboratory College of Chemistry and Materials Science and Guangdong Provincial Key Laboratory of Supramolecular Coordination Chemistry Jinan University

Rational engineering of semiconductor photocatalysts for efficient hydrogen production is of great significance but still challenging,primarily due to the limitations in charge transfer ***,a fascinating plasmonic tandem heterojunction with the hc-CdS/Mo2C@C heterostructure is aimfully prepared for effectively promoting the charge separation kinetics of the CdS photocatalyst via the synergistic strategy of phase junction,Schottky junction,and photothermal *** difference in atomic configuration between cubic-CdS （c-CdS） and hexagonal-CdS （h-CdS） leads to effective charge separation through a typical Ⅱ charge transfer mechanism,and plasmonic Schottky junction further extracts the electrons in the hc-CdS phase junction to realize gradient charge ***,the photothermal effect of Mo2C@C helps to expand the light absorption,accelerate charge transfer kinetics,and reduce the hydrogen evolution energy *** carbon layer provides a fast channel for charge transfer and protects the photocatalyst from *** a result,the optimized hc-CMC photocatalyst exhibits a significantly high photocatalytic H2production activity of 28.63 mmol/g/h and apparent quantum efficiency of 61.8%,surpassing most of the reported *** study provides a feasible strategy to enhance the charge transfer kinetics and photocatalytic activity of CdS by constructing plasmonic tandem heterogeneous junctions.

关键词： Cadmium sulfide

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Renewable Scenario Generation Using Controllable Generative Adversarial Networks with Transparent Latent Space

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CSEE Journal of Power and Energy Systems 2021年第1期7卷 66-77页

作者： Ji qiao Tianjiao pu Xinying Wang the China Electric Power Research Institute Haidian DistrictBeijing 100192China

With the growing penetration of renewable energysources in power systems, it becomes increasingly important tocharacterize their inherent variability and uncertainty. Scenariogeneration is a key approach to provide a series of possible powerscenarios in the future for the system planner and operator tomake decisions. In this paper, a data-driven method is presentedfor renewable scenario generation using stable and controllablegenerative adversarial networks with transparent latent space(ctrl-GANs). The machine learning based algorithm can capturethe nonlinear and dynamic renewable patterns without the needfor modeling assumptions and complicated sampling *** orthogonal regularization and spectral normalization areadopted to improve the training stabilization of the GAN *** control the generation process, a relationship is built betweenfeatures of the generated scenarios and latent vectors on themanifold. Moreover, several new metrics for GANs are used toevaluate the quality of the scenarios. The proposed approachis applied to generate realistic time series data of wind andphotovoltaic power. The results demonstrate that our methodhas a better performance on numerical stabilization and is ableto control the generation process with latent space.

关键词： Renewable scenario generation deep learning generative adversarial networks neural network transparent latent spacer

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Luminescence of samarium doped hydroxyapatite containing strontium:Effects of doping concentration

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Journal of Rare Earths 2022年第3期40卷 398-405,I0002页

作者： pu Chen Fen Wang Yinpo qiao Zhen Zhang Shaanxi Key Laboratory of Green Preparation and Functionalization for Inorganic Materials School of Materials Science and EngineeringShaanxi University of Science and TechnologyXi'an 710021China

A series of samarium(Sm)doped hydroxyapatites containing strontium(Sr)with controllable and adjustable luminescence were designed and prepared via chemical hydrolysis co-precipitation *** effects of doping concentration of Sm on the structure,composition,photoluminescence(PL),energy transfer,substitute site,fluoresce lifetime and luminescence color of samples were *** is shown that the introduction of Sr ions induces the structure and composition change for Sm doped *** typical transitions of Sm^(3+) at 564,601,648 and 707 nm due to^(4)G_(5/2)→^(6)H_(J/2)(J=5,7,9 and 11)transition under the excitation of 404 nm were *** PL intensity is affected by the Sr/Ca ratio and Sm concentration,and the optimal concentration of Sm is 0.8 mol%when Sr/Ca ratio equals 7/*** non-radiative transitions and energy transfer of Sm ions are the main reason for the quenching,and the interactions among ions are ascribed to dipole-dipole type by theoretical ***,the ratio of PL intensity between 601 and 648 nm(r_(O/R)=I_(601nm)/I_(648nm))indicates the symmetry and substitution process of Sm ions to Ca/Sr *** fluorescence lifetime(τ)decreases with the concentration of Sm increasing,which is the result of the decrease of distance and the enhanced interaction between Sm *** CIE chromaticity coordinates and luminescence color of samples are in the orange-red region and have close relation with the concentration of ***,the cytotoxicity evaluation and confocal laser scanning microscopy(CLSM)observation of samples via cells indicate the good biocompatibility and safe use of this kind of bio-based luminescent materials for their potential efficient fluorescence labeling and detection.

关键词： Samarium Strontium Hydroxyapatite Photo-luminescence Energy transfer Cytotoxicity evaluation

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Ordering polygonal chains with respect to Hosoya index

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Applied Mathematics(A Journal of Chinese Universities) 2012年第3期27卷 305-319页

作者： qiao You-fu ZHAN pu-qin Department of Mathematics Hechi UniversityYizhou 546300China

The Hosoya index of a graph is defined as the total number of the matching of the graph. In this paper, the ordering of polygonal chains with respect to Hosoya index is characterized.

关键词： Hosoya index matching polygonal chain

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Pd-Catalyzed Asymmetric Allylic C—H Functionalization

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Chinese Journal of Chemistry 2023年第15期41卷 1841-1848页

作者： pu-sheng Wang Liu-Zhu Gong Department of Chemistry University of Science and Technology of ChinaHefeiAnhui 230026China Center for Excellence in Molecular Synthesis of CAS University of Science and Technology of ChinaHefeiAnhui 230026China

Comprehensive Summary Pd-catalyzed asymmetric allylic C—H functionalization has emerged as a powerful tool to access chiral,densely functionalized molecules from easily accessible alkenes,enabling the increase of the step-or atom-economy by minimizing functional group manipulations for preparing allylating *** to the inadequacy of stereoselection strategies,the asymmetric allylic C—H functionalization is still in the early *** this essay,we will describe our journey to identification of asymmetric catalytic systems,mechanism of allylic C—H activation,control of stereo-and regioselectivity,and applications in asymmetric synthesis.

关键词： C-H activation Asymmetric catalysis Allylation Palladium Allylic compounds Regioselectivity Alkenes

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Analytical Blowup Solutions to the Compressible Euler Equations with Time-depending Damping

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Acta Mathematicae Applicatae Sinica 2022年第3期38卷 568-578页

作者： Jian-wei DONG Guang-pu LOU qiao ZHANG Zhengzhou University of Aeronautics Zhengzhou 450015China

In this paper,the analytical blowup solutions of the N-dimensional radial symmetric compressible Euler equations are *** previous results of the blowup solutions for the compressible Euler equations with constant damping are generalized to the time-depending damping *** generalization is untrivial because that the damp coefficient is a nonlinear function of time t.

关键词： compressible Euler equations time-depending damping blowup

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Load Shedding Control Strategy in Power Grid Emergency State Based on Deep Reinforcement Learning

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CSEE Journal of Power and Energy Systems 2022年第4期8卷 1175-1182页

作者： Jian Li sheng Chen Xinying Wang Tianjiao pu China Electric Power Research Institute Haidian DistrictBeijing 100192China

In viewing the power grid for large-scale new energy integration and power electrification of power grid equipment,the impact of power system faults is increased,and the ability of anti-disturbance is decreased,which makes the power system fault clearance more *** this paper,a load shedding control strategy based on artificial intelligence is proposed,this action strategy of load shedding,which is selected by deep reinforcement learning,can support autonomous voltage ***,the power system operation data is used as the basic data to construct the network training dataset,and then a novel reward function for voltage is *** value function,which conforms to the power grid operation characteristics,will act as the reward value for deep reinforcement learning,and the Deep Deterministic Policy Gradient algorithm(DDPG)algorithm,with the continuous action strategy,will be ***,the deep reinforcement learning network is continuously trained,and the load shedding strategy concerning the grid voltage control problem will be obtained in the power system emergency control situation,and this strategy action is input into the Pypower module for simulation verification,thereby realizing the joint drive of data and *** to the numerical simulation analysis,it shows that this method can effectively determine the accurate action selection of load shedding,and improve the stable operational ability of the power system.

关键词： Artificial intelligence deep reinforcement learning load shedding control power system emergency state

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