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Metal-Organic Frameworks Housing Active Molecules as Bioinspired Catalysts

1979年

作者： clark Roy peter

来源：畅想之星图书光盘版（南... 评论

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CCS Chemistry 2024年第6期6卷 1380-1402页

作者： Yin Zhang peter e.VanNatta Junyu Ren Shengqian Ma Department of Chemistry University of North TexasDentonTexas 76201 Department of Chemical and Biomolecular engineering National University of SingaporeSingapore 117585

Optimization of activity,selectivity,and stability of catalysts for practical application is a long-soughtafter *** progress in the advancement of rational catalyst design routinely takes queues from ***,enzymes are renowned for their high efficiency and selectivity in diverse and significant reactions under mild *** the well-known merits of enzymes,they often remain unsuitable for industrial catalysis due to issues,including limited environment(solvent/temperature/pH)compatibility,considerable structural uncertainty,and highly specific reaction *** the context of bioinspired catalysis design,the development of synthetic heterogeneous catalyst analogs,which may not only mimic enzymes to reproduce or even surpass their performance but also bypass their intrinsic limitations,is thus,desirable and has been extensively studied in the context of porous *** metal-organic framework(MOF)is a superior candidate for porous materials towards this goal,thanks to facile and modular preparation,explicit crystalline composition/structure,tunable pore size/environment,and excellent *** introduction of active molecular species such as bioactive molecules(e.g.,proteins,enzymes,peptides,amino acids,porphyrins)and chemically active molecules(e.g.,frustrated Lewis pairs)into metal-organic frameworks(MOFs)via pore encapsulation,chemical postmodification,or bottom-up construction has been shown to facilitate the cooperative enhancement of catalysis through the enforcement of proximity,enhancement of control/activity,and even inducement of unexpected *** this minireview,we sought to summarize the last 5 years of fruitful progress,exploiting MOFs housing active molecules for substantial catalysis applications,including asymmetric reactions,CO_(2)conversion(reduction,cycloaddition),biocatalytic H_(2)O_(2)/dye degradation,and so on,and discuss challenges and opportunities in the prospective exploration of these system

关键词： metal-organic framework bioinspired catalyst active molecular species

Modified rives-stoppa repair for abdominal incisional hernias

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Health 2010年第2期2卷 162-169页

作者： peter Nau Clancy J. clark Mason Fisher Gregory Walker Bradley J. Needleman e. Christopher ellison peter Muscarella 不详

Incisional hernias are a prevalent problem in abdominal surgery and occur in 11% of patients who undergo laparotomy. Primary suture clo-sure of incisional hernias results in a 31%-58% chance of recurrence. The addition of a pros-thetic mesh implant decreases recurrence rates to 8%-10%. Popularized in europe by Rives and Stoppa, the sublay technique has proven to be very effective, with low recurrence rates (0%-23%) and minimal complications. The pur-pose of the study was to evaluate the experi-ence of a single surgeon at a large tertiary care center performing a modified Rives-Stoppa re-pair for abdominal incisional hernias. To do this, the records of all patients undergoing a modi-fied Rives-Stoppa incisional hernia repair be-tween January 2000 and August 2003 were ret-rospectively reviewed. Outpatient clinic notes, discharge summaries, operative reports, and laboratory data were reviewed for patient demographics, surgical data and postoperative complications. Univariate analysis was per-formed in order to identify predictors for recur-rence. During the study period, 83 patients un-derwent a modified Rives-Stoppa incisional hernia repair. Nineteen patients were excluded due to incomplete medical records. No patients required postoperative exploration for an in-tra-abdominal catastrophe. Twenty-five percent (n=16) of patients had a complication as a result of the hernia repair. Only two patients (3.1%) developed recurrent incisional hernias. History of diabetes (p=0.007) and benign prostatic hy-perplasia (p=0.000) were the only significant predictors for recurrence. The results presented here confirm that the modified Rives-Stoppa retromuscular repair is an effective method for the repair of incisional hernias. The complica-tion and recurrence rates compare favorably to results for currently popular alternative tech-niques.

关键词： Incisional Hernia Repair Mesh Rives-Stoppa Repair Abdominal Wall Defects

An Interview with peter Deadman—Acupuncture Pioneer and Founder of The Journal of Chinese Medicine

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Chinese Medicine and Culture 2024年第1期7卷 19-28页

作者： Ioannis Solos Charles Buck peter Deadman Saint George Clinic and Research Institute Scottsdale 85251the United States of America Northern College of Acupuncture Micklegate YO16LJthe United Kingdom British Acupuncture Council London W129HQthe United Kingdom The Register of Chinese Herbal Medicine London WC1N 3GSthe United Kingdom

This interview was conducted on August 21st, 2022 by Charles Buck and Ioannis Solos. peter Deadman has worked in the field of health promotion for 50 years. He co-founded Infinity Foods(an organic and natural foods workers co-op) in 1971, followed by the Brighton Natural Health Centre-a charity dedicated to teaching ways to improve personal, community and planetary health and wellbeing. He qualified as an acupuncturist in 1978 and in Chinese herbal medicine in 1990. He founded The Journal of Chinese Medicine(UK) in 1979(Fig. 1), and co-authored A Manual of Acupuncture(published in 1998). He is the author of Live Well Live Long: Teachings from the Chinese Nourishment of Life Tradition. He has taught Chinese medicine and health promotion internationally for decades and is a dedicated practitioner and teacher of Qi Gong(气功).

关键词： Acupuncture Medicine herbal

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Neuroimaging of inflammation in alcohol use disorder: a review

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Science China(Information Sciences) 2020年第7期63卷 19-37页

作者： Dana e.FeLDMAN Katherine L.MCPHeRSON Catherine L.BIeSeCKeR Corinde e.WIeRS peter MANZA Nora D.VOLKOW Gene-Jack WANG National Institute on Alcohol Abuse and Alcoholism National Institute on Drug Abuse

Alcohol use disorder(AUD) is a global health concern associated with several *** health problems related to AUD, such as cognitive deficits, have been linked to *** use has been associated with changes in neuroimmune activity, although current literature has yielded mixed results. For example, markers of gliosis, including translocator protein 18-kDa(TSPO), proinflammatory cytokines, glutamate(Glu), and myo-inositol(mI), are disrupted in the alcohol-dependent brain. Further, neuroinflammatory-related phenomena including membrane turnover, blood brain barrier(BBB) permeability, and adenosine release have also shown alterations in AUD. However, current literature remains inconclusive about the directionality of these changes. Both in vivo and in vitro studies have provided insight on the relationship between alcohol use and neuroinflammatory processes, suggesting considerable treatment potential for alcohol use disorder and its inflammatory comorbidities. Here, we review current neuroimaging literature assessing the impacts of alcohol use on neuroimmune activity in the brain.

关键词： acetate adenosine alcohol use disorder blood brain barrier choline gliosis glutamate myoinositol neuroimaging neuroinflammation

Seasonal changes in group size and composition of Arabian sand gazelle Gazella subgutturosa marica Thomas, 1897 during a period of drought in central western Saudi Arabia

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Current Zoology 2011年第1期57卷 36-42页

作者： peter Low CUNNINGHAM King Khalid Wildlife Research Centre Thumamah E O. Box 61681 Riyadh Kingdom of Saudi Arabia Zoological Society of London Conservation Programmes Regent's Park London NW1 4RY United Kingdom

Group size variations of the Arabian sand gazelle Gazella subgutturosa marica were studied during a period of drought at the Mahazat as-Sayd Protected Area in central western Saudi Arabia. Significant differences in median group sizes were observed between all seasons except summer. Single animals were observed mainly during summer while group sizes ex- ceeding 10 individuals were observed mainly during winter. Solitary male and female groups were typically observed during winter and mixed groups mainly during the autumn rutting period. Most mixed groups were two to four times larger during winter than summer. The adult sex ratio （male： female） for all seasons combined was in parity and highest during autumn （1：1.23）, probably as a result of prolonged drought conditions. The variability in group structure related to environmental conditions may be one factor permitting G. s. marica to adapt to hyper-arid habitats and climatic regimes in central western Saudi Arabia. The value of continuous monitoring of the gazelle population is emphasised for this drought prone region

关键词： Group variations Seasonality Sex ratio Desert ungulate Mahazat as-Sayd Protected Area

The presence and partitioning behavior of flame retardants in waste,leachate,and air particles from Norwegian waste-handling facilities

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Journal of environmental Sciences 2017年第12期29卷 115-132页

作者： Nicolas A.O.Morin Patrik L.Andersson Sarah e.Hale Hans peter H.Arp Norwegian Geotechnical Institute(NGI) P.O.Box 3930Ulleval StadionN-0806 OsloNorway environmental and Food Laboratory of Vendee(LeA V) Department of ChemistryRond-point Georges Dural CS 8080285021 La Roche-sur-YonFrance Chemistry Department Umed UniversitySE-901 87 UmeaSweden

Flame retardants in commercial products eventually make their way into the waste *** the presence of flame retardants in Norwegian landfills, incineration facilities and recycling sorting/defragmenting facilities is investigated. These facilities handled waste electrical and electronic equipment（Weee）, vehicles, digestate, glass, combustibles, bottom ash and fly ash. The flame retardants considered included polybrominated diphenyl ethers（∑BDe-10） as well as dechlorane plus, polybrominated biphenyls, hexabromobenzene,pentabromotoluene and pentabromoethylbenzene（collectively referred to as ∑FR-7）. Plastic,Weee and vehicles contained the largest amount of flame retardants（∑BDe-10： 45,000–210,000 μg/kg; ∑FR-7： 300–13,000 μg/kg）. It was hypothesized leachate and air concentrations from facilities that sort/defragment Weee and vehicles would be the highest. This was supported for total air phase concentrations（∑BDe-10： 9000–195,000 pg/m^3 Weee/vehicle facilities, 80–900 pg/m^3 in incineration/sorting and landfill sites）, but not for water leachate concentrations（e.g., ∑BDe-10： 15–3500 ng/L in Weee/Vehicle facilities and 1–250 ng/L in landfill sites）. Landfill leachate exhibited similar concentrations as Weee/vehicle sorting and defragmenting facility leachate. To better account for concentrations in leachates at the different facilities, waste-water partitioning coefficients, Kwastewere measured（for the first time to our knowledge for flame retardants）. Weee and plastic waste had elevated Kwastecompared to other wastes, likely because flame retardants are directly added to these materials. The results of this study have implications for the development of strategies to reduce exposure and environmental emissions of flame retardants in waste and recycled products through improved waste management practices.

关键词： Brominated flame retardants Waste management environmental emissions Atmospheric emissions Partitioning Leachate

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Surface integral analogy approaches for predicting noise from 3D high-lift low-noise wings

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Acta Mechanica Sinica 2014年第3期30卷 326-338页

作者： Hua-Dong Yao Lars Davidson Lars-erik eriksson Shia-Hui Peng Olof Grundestam peter e.eliasson Department of Applied Mechanics Chalmers University of Technology Department of Aeronautics and Systems Technology Swedish Defence Research Agency (FOI)

Three surface integral approaches of the acoustic analogies are studied to predict the noise from three concep- tual configurations of three-dimensional high-lift low-noise wings. The approaches refer to the Kirchhoff method, the Ffowcs Williams and Hawkings （FW-H） method of the permeable integral surface and the Curle method that is known as a special case of the FW-H method. The first two approaches are used to compute the noise generated by the core flow region where the energetic structures exist. The last approach is adopted to predict the noise specially from the pressure perturbation on the wall. A new way to con- struct the integral surface that encloses the core region is proposed for the first two methods. Considering the local properties of the flow around the complex object-the actual wing with high-lift devices-the integral surface based on the vorticity is constructed to follow the flow structures. The surface location is discussed for the Kirchhoff method and the FW-H method because a common surface is used for them. The noise from the core flow region is studied on the basis of the dependent integral quantities, which are indicated by the Kirchhoff formulation and by the FW-H formulation. The role of each wall component on noise contribution is analyzed using the Curle formulation. effects of the volume integral terms of Lighthill＇s stress tensors on the noise pre-diction are then evaluated by comparing the results of the Curle method with the other two methods.

关键词： Aero-acoustics High-lift facilities Surface integral approaches of acoustic analogy

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Optimization of residence time distribution in RCDG and an assessment of its applicability in continuous manufacturing

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Particuology 2021年第3期19卷 43-49页

作者： Annika Wilms peter Kleinebudde Heinrich Heine University Düsseldorf Institute of Pharmaceutics and BiopharmaceuticsUniversitätsstraße 140225 DüsseldorfGermany INVITe GmbH Drug Delivery Innovation Center(DDIC)Chempark Building W3251368 LeverkusenGermany

Knowledge of residence time is a critical aspect in developing control and material diversion strategies for continuous manufacturing processes in pharmaceutical *** granulation is a promising continuous granulation technique as it is fast and *** this study,a step-change method to determine residence time in roll compaction/dry granulation is *** factors roll speed and rotational speed of the impeller in the powder inlet unit of the compactor were evaluated using a central composite circumscribed statistical design of experiments in order to optimize the residence *** fill volume in the compactor was varied *** was found that high roll speed,low rotational speed of the impeller and low fill volume in the compactor are beneficial to generate fast transition through the *** impact of roll speed increase was *** can be concluded that despite fast residence time in the process,high roll speed and its subsequent high material throughput can generate a large amount of material that has to be discarded if material diversion is required.

关键词： Roll compaction/dry granulation Residence time distribution Continuous manufacturing Digital image analysis Response surface optimization

experimental investigation on slip conditions during thread rolling with flat dies

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Friction 2024年第1期12卷 136-143页

作者： Stefan VOLZ peter GROCHe Institute for Production engineering and Forming Machines Technical University DarmstadtOtto-Berndt Straße 2Darmstadt 64287Germany

The process design of flat die rolling operations can be a tedious and costly process due to the challenges posed by small process *** this work,an effort is made to closely investigate and understand the process limits caused by excessive slippage of the *** measurements are carried out to capture the characteristics of excessive slippage and the influence of the stroke rate and the tribological system on this process *** differences in slippage were observed,depending on the tribological *** systems with polymer based lubricants showed excessive slippage at low stroke rates,systems using oil or no lubricant endured higher stroke rates before process limits were *** optical measurements revealed three major forms of slippage:successful rolling without slippage,failure due to excessive slippage at process start,and failure due to excessive slippage at around one workpiece rotation.

关键词： rolling incremental forming thread rolling slippage profile rolling