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A simple catalyst for aqueous phase Suzuki reactions based on palladium nanoparticles immobilized on an ionic polymer

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Science China Chemistry 2016年第4期59卷 482-486页

作者： Saeideh Ghazali-Esfahani Emilia Paunescu Mojtaba Bagherzadeh Zhaofu Fei Gabor Laurenczy paul j.dyson Institut des Sciences et Ingénierie Chimiques Ecole Polytechnique Fédérale de LausanneLausanne CH-I O15Switzerland Chemistry Department Sharif University of TechnologyTehran 11155-3615lran

Palladium nanoparticles immobilized on a cross-linked imidazolium-containing polymer were evaluated as a catalyst for Suzuki carbon-carbon cross-coupling reactions using water as the solvent. The nanocatalysts show good catalytic activities for aryl iodides and aryl bromides and moderate activity with aryl chloride substrates. Coupling of sterically hindered substrates could also be achieved in reasonable yields. The heterogeneous catalyst is stable, can be stored without precautions to exclude air or moisture, and can be easily recycled and reused.

关键词： catalysis biphasic catalysis polymeric ionic liquids nanoparticles aqueous phase catalysis Suzuki reaction

Bacterial diversity and distribution in the southeast edge of the Tengger Desert and their correlation with soil enzyme activities

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journal of Environmental Sciences 2012年第11期24卷 2004-2011页

作者： Wei Zhang Gaosen Zhang Guangxiu Liu Zhibao Dong Tuo Chen Manxiao Zhang paul j.dyson Lizhe An Key Laboratory of Desert and Desertification Cold and Arid Regions Environmental and Engineering Research InstituteChinese Academy of SciencesLanzhou 730000China School of Life Sciences Lanzhou UniversityLanzhou 730000China Institute of Life Science College of MedicineSwansea UniversitySwansea SA28PPUK

The nature of microbial communities and their relation to enzyme activities in desert soils is a neglected area of investigation. To address this, the bacterial diversity and distribution and soil physico-chemical factors were investigated in the soil crust, the soil beneath the crust and rhizosphere soil at the southeast edge of the Tengger Desert, using the denaturing gradient gel electrophoresis of 16S rRNA genes amplified by the polymerase chain reaction. Phylogenedc analysis of the sequenced DGGE bands revealed a great diversity of bacteria. The Proteobacteria, consisting of the α, β, and γsubdivisions, were clearly the dominant group at all depths and in rhizosphere soil. Analysis of the enzyme activities indicated that the rhizosphere soil of Caragana korshinskii exhibited the highest protease and polyphenol oxidase activities, and in the soil crust there were increased activities of catalase, urease, dehydrogenase and sucrase. The bacterial community abundance closely correlated with soil enzyme activities in different soils. The presence of Cyanobacteria correlated with significant increases in protease, catalase and sucrase in the soil crust, and increased urease in the rhizosphere soil of Artemisia ordosica. The occurrence of Acidobacteria was associated with significant increases in urease, dehydrogenase, and sucrase in the rhizosphere soil of C. korshinski. The presence of γ-Proteobacteria correlated with a significant increase in polyphenol oxidase in the rhizosphere soil ofA. ordosica. The study indicated a close relationship between the soil bacterial community and soil enzymes, suggesting the necessity of further investigations into bacterial function in this desert ecosystem.

关键词： Tengger Desert DGGE 16S rRNA bacterial community soil enzyme

Single-step conversion of lignin monomers to phenol: Bridging the gap between lignin and high-value chemicals

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Chinese journal of Catalysis 2018年第9期39卷 1445-1452页

作者： jiaguang Zhang Loris Lombardo Gokalp Gozaydin paul j.dyson Ning Yan Department of Chemical and Biomolecular Engineering National University of Singapore117585 Singapore School of Chemistry University of LincolnJoseph Banks LaboratoriesGreen LaneLincolnLN6 7DLUnited Kingdom Institute of Chemical Sciences and Engineering Ecole Polytechnique Fédérale de Lausanne （EPFL） CH‐1015Switzerland

Transformation of lignin into high-value chemicals is hampered by the complexity of monomers obtained from lignin depolymerization. Here we report a strategy, composed of hy-dro-demethoxylation and de-alkylation reactions, that is able to chemically converge various lig-nin-derived phenolic monomers into phenol in a single-step. Using 2-methoxy-4-propylphenol as a model compound, Pt/C exhibited the best performance in hydro-demethoxylation reaction afford-ing 80% 4-propylphenol from 2-methoxy-4-propylphenol, while H-ZSM-5 was identified as the most suitable catalyst for de-alkylation, achieving 83% yield of phenol from 4-propylphenol. Since the two catalysts operate under compatible conditions, combining the two catalysts to simultane-ously promote both hydro-demethoxylation and de-alkylation reactions was achieved. Configura-tion of how to organize the catalysts is a critical parameter, where the physical mixture of the two was most effective, providing over 60% phenol from 2-methoxy-4-propylphenol in a single-step.

关键词： LigninPhenol ZeoliteDe‐alkylation Hydro‐demethoxylation

Highly Efficient and Stable FAPbI_(3) Perovskite Solar Cells and Modules Based on Exposure of the(011)Facet

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Nano-Micro Letters 2023年第9期15卷 164-174页

作者： Kai Zhang Bin Ding Chenyue Wang Pengju Shi Xianfu Zhang Cheng Liu Yi Yang Xingyu Gao Rui Wang Li Tao Keith G.Brooks Songyuan Dai paul j.dyson Mohammad Khaja Nazeeruddin Yong Ding Beijing Key Laboratory of Novel Thin-Film Solar Cells North China Electric Power UniversityBeijing 102206People’s Republic of China Institut des Sciences et Ingénierie Chimiques Ecole Polytechnique Fédérale de Lausanne(EPFL)Lausanne 1015Switzerland Shanghai Synchrotron Radiation Facility(SSRF) Shanghai Advanced Research InstituteChinese Academy of SciencesShanghai 201204People’s Republic of China School of Engineering Westlake University and Institute of Advanced TechnologyWestlake Institute for Advanced StudyHangzhou 310024People’s Republic of China Hubei Yangtze Memory Laboratories Wuhan 430205People’s Republic of China School of Microelectronics Hubei UniversityWuhan 430062People’s Republic of China

Perovskite crystal facets greatly impact the performance and stability of their corresponding photovoltaic *** to the(001)facet,the(011)facet yields better photoelectric properties,including higher conductivity and enhanced charge carrier ***,achieving(011)facet-exposed films is a promising way to improve device ***,the growth of(011)facets is energetically unfavorable in FAPbI_(3) perovskites due to the influence of methylammonium chloride ***,1-butyl-4-methylpyridinium chloride([4MBP]Cl)was used to expose(011)***[4MBP]^(+)cation selectively decreases the surface energy of the(011)facet enabling the growth of the(011)***[4MBP]^(+)cation causes the perovskite nuclei to rotate by 45°such that(011)crystal facets stack along the out-of-plane ***(011)facet has excellent charge transport properties and can achieve better-matched energy level *** addition,[4MBP]Cl increases the activation energy barrier for ion migration,suppressing decomposition of the *** a result,a small-size device(0.06 cm2)and a module(29.0 cm2)based on exposure of the(011)facet achieved power conversion efficiencies of 25.24%and 21.12%,respectively.

关键词： Renewable energy Perovskite solar cell Perovskite solar module Facet engineering

经由木材中的木质素组分制备“汽油”,“柴油”和甲醇

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经由木材中的木质素组分制备“汽油”,“柴油”和甲醇

中国化学会第26届学术年会绿色化学分会场

作者：颜宁赵晨 paul j.dyson 王晨刘凌涛寇元北京大学绿色化学研究中心北京分子科学国家实验室北京大学化学与分子工程学院北京大学绿色化学研究中心北京分子科学国家实验室北京大学化学与分子工程学院北京大学绿色化学研究中心北京分子科学国家实验室北京大学化学与分子工程学院北京大学绿色化学研究中心北京分子科学国家实验室北京大学化学与分子工程学院北京大学绿色化学研究中心北京分子科学国家实验室北京大学化学与分子工程学院北京大学绿色化学研究中心北京分子科学国家实验室北京大学化学与分子工程学院

＜正＞木质素与纤维素、半纤维素并称为植物体的三大组成部分。木质素是一种芳环聚合物,由单体通过C-O键或者C-C连接起来。通过使用贵金属催化剂,在一定的条件下,木质素可通过C-O键断

关键词：木质素贵金属催化解聚

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方形Rh纳米粒子生长机理解析

方形Rh纳米粒子生长机理解析

A functional tacrolimus-releasing nerve wrap for enhancing nerve regeneration following surgical nerve repair

中国化学会第28届学术年会

作者：姚思宇袁媛肖超贤寇元 paul j.dyson 颜宁 Tsunehiro Tanaka 北京大学理论与计算中心北京大学绿色化学中心北京大学化学与分子工程学院 Institut des Sciences et Ingenierie Chimiques Ecole Polytechnique Federale de Lausanne(EPFL)Lausanne

＜正＞本文采用原位XAFS及MALDI-TOFMS,TEM,XRD,UV-Vis Spectroscopy等非原位表征手段深入研究了乙二醇还原法制备的方形Rh纳米粒子的生长机理。对原位XAFS的数据分析发现方形Rh纳米粒子的生长过程分为配体取代、缓慢成核、

关键词： Rh纳米粒子成核生长机理原位XAFS 极限成核物种

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Neural Regeneration Research 2025年第1期20卷 291-304页

作者： Simeon C.Daeschler Katelyn j.W.So Konstantin Feinberg Marina Manoraj jenny Cheung jennifer Zhang Kaveh Mirmoeini jpaul Santerre Tessa Gordon Gregory HBorschel SickKids Research Institute Neuroscience and Mental Health ProgramTorontoONCanada Institute of Biomaterials and Biomedical Engineering University of TorontoTorontoONCanada Indiana University School of Medicine IndianapolisINUSA Division of Plastic and Reconstructive Surgery the Hospital for Sick ChildrenTorontoONCanada Translational Biology and Engineering Program Ted Rogers Centre for Heart ResearchInstitute of Biomedical EngineeringFaculty of DentistryUniversity of TorontoTorontoONCanada

Axonal regeneration following surgical nerve repair is slow and often incomplete,resulting in poor functional recovery which sometimes contributes to lifelong ***,there are no FDA-approved therapies available to promote nerve *** accelerates axonal regeneration,but systemic side effects presently outweigh its potential benefits for peripheral nerve *** authors describe herein a biodegradable polyurethane-based drug delivery system for the sustained local release of tacrolimus at the nerve repair site,with suitable properties for scalable production and clinical application,aiming to promote nerve regeneration and functional recovery with minimal systemic drug *** is encapsulated into co-axially electrospun polycarbonate-urethane nanofibers to generate an implantable nerve wrap that releases therapeutic doses of bioactive tacrolimus over 31 *** and drug loading are adjustable for applications in small and large caliber nerves,and the wrap degrades within 120 days into biocompatible *** released from the nerve wrap promotes axon elongation in vitro and accelerates nerve regeneration and functional recovery in preclinical nerve repair models while off-target systemic drug exposure is reduced by 80%compared with systemic *** its surgical suitability and preclinical efficacy and safety,this system may provide a readily translatable approach to support axonal regeneration and recovery in patients undergoing nerve surgery.

关键词： biodegradable local drug delivery nerve injury nerve regeneration nerve wrap tacrolimus

Advances in newly developing therapy for chronic hepatitis C virus infection

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Frontiers of Medicine 2014年第2期8卷 166-174页

作者： paul j. Pockros Division of Gastro/Hepatology Scripps Clinic 10666 N Torrey Pines Road N203 La Jolla CA 92067 USA

Chronic hepatitis C virus （HCV） infection afflicts a reported 170 million people worldwide and is often complicated by cirrhosis and hepatocellular carcinoma. Morbidity and mortality are decreased with the successful treatment of chronic HCV infection. Increased understanding of the HCV has allowed further development of new direct-acting antiviral （DAA） agents against the HCV and has also allowed the development of IFN-free oral treatment regimens. In late 2013 the first nucleotide polymerase inhibitor regimen with RBV alone for genotypes 2/3 and in combination with a 12-week regimen of PEG-IFN ＋ RBV for genotypes 1, 4 was approved for use in the US. A number of promising new DAA regimens which are IFN-free are in phase 3 development and the first will likely be approved for use in the US in 2014. The currently approved regimens are discussed in detail and currently available data on future regimens are reviewed herein.

关键词： direct-acting antiviral (DAA) nucleotide polymerase inhibitors protease inhibitors

The Bemisia tabaci Species Complex:Questions to Guide Future Research

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journal of Integrative Agriculture 2012年第2期11卷 187-196页

作者： paul j De Barro CSIRO Ecosystem Sciences Brisbane QLD 4001Australia

Since 2007 we have began to consider the relationships between the different members of the Bemisia tabaci species complex in a more structured and systematic *** of these relationships has been infered from considerations of a portion of the mitochondrial cytochrome oxidase one（mtCOI）*** this is a quite limited approach which would benefit from the consideration of a much greater diversity of genetic material,it is the only publically available data that spans the diversity of the species *** the limitations,the phylogenetic reconstruction that can be derived from this data is useful and can be used as a basis to frame questions and construct testable hypotheses that will form the basis for future *** study uses the largest available mtCOI dataset,consisting of 383 unique mtCOI haplotypes that spans the full diversity of the *** species complex as we currently know it,to make a range of observations which are then used to develop questions as guide for future research.

关键词： mitochondrial cytochrome oxidase one phylogenetic analysis