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Multidimensional Hybrid Architecture Encapsulating Cobalt Oxide Nanoparticles into Carbon Nanotube Branched Nitrogen-Doped Reduced Graphene Oxide Networks for Lithium–Sulfur Batteries

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Energy & Environmental Materials 2022年第2期5卷 555-564页

作者： Jeong Seok Yeon Young hun Ko Tae Ho park Hyunyoung park Jongsoon Kim Ho Seok park School of Chemical Engineering College of EngineeringSungkyunkwan University2066Seobu-roJangan-guSuwon-si Gyeonggi-do 440-746Korea Advanced Batteries Research Center Korea Electronics Technology Institute25Saenari-roBundang-guSeongnam-si Gyeonggi-do 13509Korea Department of Energy Science Sungkyunkwan University2066Seobu-roJangan-guSuwon-si Gyeonggi-do 440-746Korea Department of Health Sciences and Technology Samsung Advanced Institute for Health Sciences and Technology(SAIHST)Sungkyunkwan University2066SeoburoJangan-guSuwon 440-746South Korea

Lithium–sulfur batteries(LSBs)are regarded as promising candidates for the next-generation energy storage devices owing to their high-theoretical capacity(1675 mAh g^(−1))and affordable ***,several limitations of LSBs such as the lithium polysulfide shuttle,large volume expansion,and low electrical conductivity of sulfur need to be resolved for practical *** address these limitations,herein,a multidimensional architectured hybrid(Co@CNT/nG),where Co_(3)O_(4) nanoparticles are encapsulated into threedimensional(3D)porous N-doped reduced graphene oxide interconnected with carbon nanotube(CNT)branches,is synthesized through a simple pyrolysis *** synergistic effect achieved through the homogeneously distributed and encapsulated Co_(3)O_(4) nanoparticles,the interconnected CNT branches,and the 3D hierarchical porous structure and N-doping of Co@CNT/nG significantly suppresses the shuttle effect of lithium polysulfides and enhances the conversion redox kinetics for the improved sulfur *** validate this effect through various measurements including symmetric cells,Li_(2)S nucleation,shuttle currents,Tafel slopes,diffusion coefficients,and post-mortem ***,Co@CNT/nG-70S-based LSB cells achieve a high-specific capacity of 1193.1 mAh g^(−1) at 0.1 C and a low capacity decay rate of 0.030%per cycle for 700 cycles at 5 C,delivering a high areal capacity of 5.62 mAh cm^(−2) even with a loading of 6.5 mg cm^(−2).

关键词： graphene/CNT hybrid lithium-sulfur batteries multidimensional architecture nanoparticle encapsulation redox promoter

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Enhanced third-harmonic generation by manipulating the twist angle of bilayer graphene

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Light(Science & Applications) 2021年第2期10卷 176-185页

作者： Seongju Ha Nam hun park Hyeonkyeong Kim Jiseon Shin Jungseok Choi Sungmin park Ji-Yun Moon Kwanbyung Chae Jeil Jung jae-Hyun Lee Youngdong Yoo Ji-Yong park Kwang Jun Ahn Dong-Il Yeom Department of Energy Systems Research Ajou University206 Worldcup-roYeongtong-guSuwon 16499Republic of Korea Korea Research Institute of Standards and Science Daejeon 34113Republic of Korea Department of Physics University of Seoul163 SiripdaeroDongdaemun-guSeoul 02504Republic of Korea Department of Smart Cities University of Seoul163 SiripdaeroDongdaemun-guSeoul 02504Republic of Korea Department of Materials Science and Engineering Ajou University206 Worldcup-roYeongtong-guSuwon 16499Republic of Korea Department of Chemistry Ajou University206 Worldcup-roYeongtong-guSuwon 16499Republic of Korea Department of Physics Ajou University206 Worldcup-roYeongtong-guSuwon 16499Republic of Korea

Twisted bilayer graphene(tBLG)has received substantial attention in various research fields due to its unconventional physical properties originating from Moire *** electronic band structure in tBLG modified by interlayer interactions enables the emergence of low-energy van Hove singularities in the density of states,allowing the observation of intriguing features such as increased optical conductivity and photocurrent at visible or near-infrared ***,we show that the third-order optical nonlinearity can be considerably modified depending on the stacking angle in *** third-harmonic generation(THG)efficiency is found to significantly increase when the energy gap at the van Hove singularity matches the three-photon resonance of incident *** study on electrically tuneable optical nonlinearity reveals that the gate-controlled THG enhancement varies with the twist angle in tBLG,resulting in a THG enhanced up to 60 times compared to neutral monolayer *** results prove that the twist angle opens up a new way to control and increase the optical *** tBLG,,suggesting rotation-induced tuneable nonlinear optics in stacked two-dimensional material systems.

关键词： twist angle harmonic

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Acheivement of Nano-Scale SiGe Layer with Discrete Ge Mole Fraction Profile Using Batch-Type HVCVD

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Journal of Rare Earths 2004年第z2期22卷 178-182页

作者： Gon-sub Lee Tae-hun Shim Jea-gun park Advanced Semiconductor Material and Device Development Center Hanyang UniversitySeoul 133-791Korea Advanced Semiconductor Material and Device Development CenterHanyang UniversitySeoul 133-791Korea Advanced Semiconductor Material and Device Development CenterHanyang UniversitySeoul 133-791Korea

The strained Si grown on the relaxed SiGe-on-insulator C-MOSFET's is a promising device for the future system LSI devices with the design rule of sub-micron. The achievement of the discrete Ge mole fraction in the SiGe layer is a key engineering in low-temperature SiGe epitaxial growth using HVCVD. The pre-flow of GeH4 gas enhanced the Ge mole fraction and SiGe layer thickness. In addition, the Ge mole fraction and SiGe layer thickness increases with the gas ratio of GeH4/SiH4 + GeH4, process temperature, and gas flow time. However, the haze was produced if the Ge mole fraction is above 22wt%. The discrete-like Ge mole fraction with 22 wt% in 10 nm SiGe layer was obtained by the pre-flow of GeH4 for 10 s, the mixture gas ratio of GeH4/SiH4 + GeH4 of 67%, and the gas flow time for 150 s at the process temperature of 550 C.

关键词： strained Si nano scale SiGe layer Ge mole fraction HVCVD gas flow boat-out time

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Anti-inflammatory and anti-apoptotic effects of N-acetylcysteine in diabetic rat corneal epithelium

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International Journal of Ophthalmology(English edition) 2021年第12期14卷 1805-1812页

作者： Sae-Byeok Hwang Jin Hyoung park Ji-Yun park Soon-Suk Kang Ho Seok Chung hun Lee jae Yong Kim hungwon Tchah Research Institute of Miso Eye Clinic Gyeonggi-do 13640Republic of Korea Biomedical Research Center Asan Institute for Life ScienceAsan Medical CenterSeoul 05505Republic of Korea Miso Eye Clinic Gyeonggi-do 13640Republic of Korea Department of Ophthalmology University of Ulsan College of MedicineSeoul 05505Republic of Korea Research Institute for Biomacromolecules University of Ulsan College of MedicineSeoul 05505Republic of Korea Department of Ophthalmology Dankook University HospitalDankook University College of MedicineCheonan 31116Republic of Korea

AIM:To characterize the anti-inflammatory and antiapoptotic effects of N-acetylcysteine(NAC)in streptozotocin(STZ)-induced diabetic rat corneal epithelium and human corneal epithelial cells(HCECs)exposed to a high-glucose ***:HCECs were incubated in 0,5,50 mmol/L glucose medium,or 50 mmol/L glucose medium with NAC for *** was induced in rats by intraperitoneal injection of 65 mg/kg STZ and some of these rats were topically administered NAC to corneas with 3 mice per *** characterized receptor for advanced glycation end-products(RAGE)expression using immunofluorescence,and interleukin(IL)-1βand cleaved caspase-3(CCAP-3)expression using *** tumor necrosis factor(TNF)-αconcentration was measured by ELISA and cleaved poly-ADP ribose polymerase(PARP)concentration was quantified by Western *** cells were detected using TUNEL assay and annexin V and propidium iodide ***:Diabetic rats had higher expression of RAGE(2.46±0.13 fold),IL-1β,and CCAP-3 in apoptotic cells of their corneas than control *** expression of RAGE(1.83±0.11 fold),IL-1β,and CCAP-3,and the number of apoptotic cells,were reduced by topical NAC *** incubated in 50 mmol/L glucose medium showed high concentrations of TNF-α(310±2.00 pg/mL)and cleaved PARP(7.43±0.56 fold),and more extensive apoptosis than cells in 50 mmol/L glucose ***,the addition of NAC reduced the concentrations of TNF-α(153.67±2.31 pg/mL)and cleaved PARP(5.55±0.31 fold)and the number of apoptotic ***:NAC inhibits inflammation and apoptosis in the corneas of diabetic rats and HCECs maintained in a high-glucose environment.

关键词： N-acetylcysteine apoptosis inflammation diabetes corneal epithelium rat

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Multiplexed electrospraying of water in cone-jet mode using a UV-embossed pyramidal micronozzle film

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Microsystems & Nanoengineering 2022年第5期8卷 247-256页

作者： Ji-hun Jeong Kwangseok park Hyoungsoo Kim Inyong park Jinyoung Choi Seung S.Lee Department of Mechanical Engineering Korea Advanced Institute of Science and TechnologyDaejeon 34141Republic of Korea Department of Environmental Machinery Korea Institute of Machinery and MaterialsDaejeon 34103Republic of Korea Department of Mechanical Engineering Dongshin UniversityNaju 58245Republic of Korea

The electrospraying of water in the cone-jet mode is difficult in practical applications owing to its low throughput and the electrical discharge caused by the high surface tension of water.A film with multiple dielectric micronozzles is essential for multiplexed electrospraying of water in cone-jet mode without electrical ***,a pyramidal micronozzle film with five nozzles was fabricated using the UV-embossing *** pyramidal micronozzle film consisted of pyramidal micronozzles,a micropillar array,and an in-plane extractor,which were proposed to minimize wetting and concentrate the electric field to the water meniscus at the tip of the pyramidal *** electrospraying of water using a single pyramidal micronozzle was visualized by a high-speed camera at a flow rate of 0.15–0.50ml/h with voltages of 0.0–2.3 kV,−1.6 kV,and−4.0 kV at the water,guide ring,and collector,*** distinct modes,the dripping,spindle,and cone-jet modes,were observed and distinguished according to the motion of the water meniscus at the nozzle *** steady Taylor cone and jet were observed in a voltage range of 1.3–2.0 kV in water,particularly in cone-jet *** electrospraying of water in cone-jet mode at a flow rate of 1.5ml/h was performed using a pyramidal micronozzle film,demonstrating the potential for a high-throughput electrospraying system.

关键词： process. film pyramidal

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Spontaneous rupture of hepatic metastasis from a thymoma: A case report

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World Journal of Gastroenterology 2016年第44期22卷 9860-9864页

作者： Ho jae Kim Yong Eun park Min Seo Ki Se Ju Lee Seung hun Beom Dai Hoon Han Young Nyun park Jun Yong park Department of Internal Medicine Yonsei University College of Medicine Department of Surgery Yonsei University College of Medicine Department of Pathology Yonsei University College of Medicine

Bleeding resulting from spontaneous rupture of the liver is an infrequent but potentially life threatening complication that may be associated with an underlying liver disease. A hepatocellular carcinoma or hepatic adenoma is frequently reported is such cases. However, hemoperitoneum resulting from a hepatic metastatic thymoma is extremely rare. Here, we present a case of a 62-year-old man with hypovolemic shock induced by ruptured hepatic metastasis from a thymoma. At the first hospital admission, the patient had a 45-mm anterior mediastinal mass that was eventually diagnosed as a type A thymoma. The mass was excised, and the patient was disease-free for 6 years. He experienced sudden-onset right upper quadrant pain and was again admitted to our hospital. We noted large hemoperitoneum with a 10-cm encapsulated mass in S5/8 and a 2.3-cm nodular lesion in the right upper quadrant of the abdomen. He was diagnosed with hepatic metastasis from the thymoma, and he underwent chemotherapy and surgical excision.

关键词： Spontaneous rupture Hemoperitoneum Transarterial chemoembolization Hepatic metastasis Thymoma

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Primordial germ cell-mediated transgenesis and genome editing in birds

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Journal of Animal Science and Biotechnology 2018年第2期9卷 257-267页

作者： jae Yong Han Young Hyun park Department of Agricultural Biotechnology and Research Institute of Agriculture and Life Sciences College of Agriculture and Life Sciences Seoul National University Institute for Biomedical Sciences Shinshu University

Transgenesis and genome editing in birds are based on a unique germline transmission system using primordial germ cells(PGCs), which is quite different from the mammalian transgenic and genome editing system. PGCs are progenitor cells of gametes that can deliver genetic information to the next generation. Since avian PGCs were first discovered in nineteenth century, there have been numerous efforts to reveal their origin, specification, and unique migration pattern, and to improve germline transmission efficiency. Recent advances in the isolation and in vitro culture of avian PGCs with genetic manipulation and genome editing tools enable the development of valuable avian models that were unavailable before. However, many challenges remain in the production of transgenic and genome-edited birds,including the precise control of germline transmission, introduction of exogenous genes, and genome editing in ***, establishing reliable germline-competent PGCs and applying precise genome editing systems are critical current issues in the production of avian models. Here, we introduce a historical overview of avian PGCs and their application, including improved techniques and methodologies in the production of transgenic and genome-edited birds, and we discuss the future potential applications of transgenic and genome-edited birds to provide opportunities and benefits for humans.

关键词： Avian Genome editing Primordial germ cell Transgenesis

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Effects of homogenization temperature on microstructure and mechanical properties of high-speed-extruded Mg–5Bi–3Al alloy

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Journal of Magnesium and Alloys 2022年第10期10卷 2833-2846页

作者： jae Won Cha Sang-Cheol Jin jae-Gil Jung Sung Hyuk park School of Materials Science and Engineering Kyungpook National University80 DaehakroDaegu 41566Republic of Korea Advanced Metals Division Korea Institute of Materials ScienceChangwon 51508Republic of Korea

This study investigates the effects of billet homogenization temperature on the dynamic recrystallization behavior during high-speed extrusion and resultant microstructure and tensile properties of the Mg–5Bi–3Al(BA53,wt%)*** billets homogenized at 350 and450℃(350H and 450H billets)are extruded at a high speed of 69 m/*** 350H billet has a relatively smaller grain size and a higher abundance of fine Mg3Bi2particles compared to the 450H *** extrusion of the 350H billet,enhanced dynamic recrystallization occurs as a result of its finer grains and abundance of particles,while the growth of recrystallized grains is suppressed by the grain-boundary pinning effect of ***,the extruded 350H material is characterized by smaller grains,relatively greater number of Mg3Bi2particles,and a higher internal strain energy than the extruded 450H *** tensile strength of the extruded 350H material is higher than that of the extruded 450H material owing to stronger grain-boundary hardening,particle hardening,and strain hardening *** extruded 350H material also exhibits a higher tensile elongation as its smaller grains inhibit the formation of crack-inducing undesirable twins during *** results from this study demonstrate that a decrease in the homogenization temperature from 450 to 350℃leads to improved strength and ductility in the high-speed-extruded BA53 material.

关键词： Mg–Bi–Al alloy High-speed extrusion Homogenization Dynamic recrystallization Tensile properties

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Silver nanoislands on cellulose fibers for chromatographic separation and ultrasensitive detection of small molecules

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Light(Science & Applications) 2016年第1期5卷 796-802页

作者： Hyukjin Jung Moonseong park Minhee Kang Ki-hun Jeong Department of Bio and Brain Engineering KAIST Institute for Optical Science and TechnologyKorea Advanced Institute of Science and Technology291 Daehak-roYuseong-guDaejeon 305-701Korea

High-throughput small-molecule assays play essential roles in biomedical diagnosis,drug discovery,environmental analysis,and physiological function *** holds a great potential for the label-free detection of small molecules at extremely low ***,we report the development of nanoplasmonic paper(NP-paper)for the rapid separation and ultrasensitive detection of mixed small ***-paper employs nanogap-rich silver nanoislands on cellulose fibers,which were simply fabricated at the wafer level by using low-temperature solid-state dewetting of a thin silver *** nanoplasmonic detection allows for the scalable quantification and identification of small molecules over broad concentration ***,the combination of chromatographic separation and nanoplasmonic detection allows both the highly sensitive fluorescence detection of mixed small molecules at the attogram level and the label-free detection at the sub-nanogram level based on surface-enhanced Raman *** novel material provides a new diagnostic platform for the high-throughput,low-cost,and label-free screening of mixed small molecules as an alternative to conventional paper chromatography.

关键词： nanoplasmonics paper chromatography plasmon-enhanced spectroscopy silver nanoislands small-molecule assay

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First Record of the Blue-banded Sea Krait(Laticauda laticaudata,Reptilia:Squamata:Elapidae:Laticaudinae)on Jeju Island,South Korea

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Asian Herpetological Research 2017年第2期18卷 131-136页

作者： jaejin park Kyo-Soung KOO Il-hun KIM Woo-Jin CHOI Daesik park Department of Biology Kangwon National UniversityChuncheonKangwon 24341South Korea National Marine Biodiversity Institute of Korea SeocheonChungnam 33662South Korea Division of Science Education Kangwon National UniversityChuncheonKangwon 24341South Korea

We report the first recorded capture of a blue-banded sea snake（Laticauda laticaudata Linnaeus, 1758, Jobeuntti Kun Badabam in Korean） in South Korea based on one male specimen collected from Marado-ri, Seogwiposi, Jeju-do on 20 October 2016. The morphological features of the lateral nostrils, the much wider ventrals than adjacent dorsals, the horizontally undivided rostral, the two prefrontals, and the uniform black bands on the body indicate that the specimen is L. laticaudata. An analysis of the partial mitochondrial cytochrome b gene sequence indicated that the specimen fits well into the known L. laticaudata phylogenetic group, which confirms that the sea krait is L. laticaudata. Including this report, five species of sea snakes（L. laticaudata, L. semifasciata, Hydrophis platurus, H. cyanocinctus, and H. melanocephalus） have now been reported in Korean waters.

关键词： sea snake Hydrophiinae Laticaudinae blue-banded sea snake Laticauda laticaudata

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