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High-temperature thermodynamics of silver:Semi-empirical approach

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Chinese Physics B 2017年第11期26卷 400-407页

作者： R H Joshi B Y Thakore P R Vyas A R Jani n k bhatt Department of Physics Sardar Patel University Department of Physics School of Sciences Gujarat University Sardar Patel Center for Science and Technology Department of Physics M.K.Bhavnagar University

We report high-temperature thermodynamics for fcc silver by combining ab initio phonon dynamics to empirical quadratic temperature-dependent term for anharmonic part of Helmholtz free energy. The electronic free energy is added through an interpolation scheme, which connects ambient condition free electron gas model to Thomas-Fermi *** present study shows good agreement with experimental and reported findings for several thermal properties, and the discrepancy observed in some caloric properties is addressed. The decreases in the product of volume thermal expansion coefficient and isothermal bulk modulus and in the constant volume anharmonic lattice specific heat at high temperature are the clear evidences of proper account of anharmonicity. The present study also reveals that T-2-dependent anharmonic free energy is sufficient for correct evaluation of thermal pressure and conventional Grüneisen parameter. We observe that the intrinsic phonon anharmonicity starts dominating above characteristic temperature, which is attributed to higher order anharmonicity and can be related to higher order potential derivatives. We conclude that the uncorrelated and largeamplitude lattice vibrations at high temperature raise dominating intrinsic thermal stress mechanism, which surpasses the phonon-anharmonism and requires future consideration.

关键词： thermodynamics anharmonicity Grüneisen parameter silver

Thermodynamic properties of 3C-SiC

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Chinese Physics B 2013年第10期22卷 429-435页

作者： B.Y.Thakore S.G.khambholja A.Y.Vahora n.k.bhatt A.R.Jani Department of Physics Sardar Patel UniversityVallabh Vidyanagar388120GujaratIndia Indus University Ahmedabad 380001GujaratIndia

In the present paper, we report on the results of various thermodynamic properties of 3C-SiC at high pressure and temperature using first principles calculations. We use the plane-wave pseudopotential density functional theory as im- plemented in Quantum ESPRESSO code for calculating various cohesive properties in ambient condition. Further, ionic motion at a finite temperature is taken into account using the quasiharmonic Debye model. The calculated thermody- namic properties, phonon dispersion curves, and phonon densities of states at different temperatures and structural phase transitions at high pressures are found to be in good agreement with experimental and other theoretical results.

关键词： phase transition phonon dispersion curve Debye model thermodynamic property

Structural and mass transport properties of liquid ytterbium in the temperature range 1123 k–1473 k

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Chinese Physics B 2023年第6期32卷 481-488页

作者： D D Satikunvar n k bhatt B Y Thakore Department of Physics Sardar Patel UniversityVallabh VidyanagarGujarat 388120India Department of Physics Maharaja Krishnakumarsinhji Bhavnagar UniversityBhavnagarGujarat 364001India

We have studied the structural and atomic transport properties of liquid f-shell Yb in the temperature range 1123 k–1473 k. Pair interactions between atoms are derived using a local pseudopotential. The potential parameters are fitted to the phonon dispersion curve at room temperature. The local pseudopotential used in the present study is computationally more efficient with only three parameters, and it is found to be transferable to the liquid phase without changing the *** the various computed properties agree with reported theoretical and experimental findings, the adopted fitting scheme is justified. As a significant outcome of the study, we find that(i) the melting in Yb is governed by the Lindemann's law,(ii)the mass transport mechanism obeys the Arrhenius law,(iii) the role of the three-particle correlation function in deriving the velocity autocorrelation function is small,(iv) the mean-square atomic displacement is more sensitive to the choice of interaction potential than the other bulk properties, and(v) liquid Yb does not show liquid–liquid phase transition within the studied temperature range. Further, due to the good description of the structural and mass transport properties, we propose that Yb remains divalent at reduced density.

关键词： transport properties pseudopotential single-particle dynamics ytterbium

Efficacy of a Diabetes Specific nutritional Supplement (DSnS) on Glycemic Response in Prediabetic Adults: A Two-Armed, Open-Labelled Randomized Controlled Study

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Food and nutrition Sciences 2024年第7期15卷 612-643页

作者： Deepti khanna kejal Joshi Reddy Hema S. Gopalan Jaladhi bhatt Jayanti Gupta Simran Sethi Parth Joshi Manoj Pareek Department of R&D Hindustan Unilever Limited Gurugram India Mumbai India Cliantha Research Ahmedabad India

It is well known that Diabetes Specific nutritional Supplements (DSnSs) are linked to improved glycemic control in individuals with diabetes. However, data on efficacy of DSnSs in prediabetics is limited. This was a two-armed, open-labelled, randomized controlled six-week study on 199 prediabetics [30 - 65 years;Glycosylated Hemoglobin (HbA1c) 5.7% - 6.4% and/or Fasting Blood Glucose (FBG) 100-125 mg/dl]. Two parallel phases were conducted: Acute Blood Glucose Response (ABGR) and Intervention phase. Prediabetic participants were randomized into test (n = 100) and control (n = 99). The primary objective was to assess the ABGR of DSnS versus an isocaloric snack, measured by incremental Area under the Curve (iAUC). Test and control received 60 g of DSnS and 56 g of isocaloric snack (cornflakes) respectively, both in 250 ml double-toned milk on visit days 1, 15, 29 and 43. Postprandial Blood Glucose (PPG) was estimated at 30, 60, 90, 120, 150 and 180 minutes. During the 4 weeks intervention phase, the test group received DSnS with lifestyle counselling (DSnS + LC) and was compared with the control receiving lifestyle counselling alone (LC alone). Impact was studied on FBG, HbA1C, anthropometry, body composition, blood pressure, nutrient intake, and physical activity. The impact of DSnS was also studied using CGM between two 14-day phases: CGM1 baseline (days 1 - 14) and CGM2 endline (days 28 - 42). DSnS showed significantly lower PPG versus isocaloric snack at 30 (p 12, and chromium were reported by DSnS + LC versus LC alone. no other significant changes were reported between groups. It may be concluded that DSnS may be considered as a snack for prediabetic or hyperglycemic individuals requiring nutritional support for improved glycemic control.

关键词： Diabetes Specific nutritional Supplement Prediabetes Acute Blood Glucose Response Incremental Area under Curve Lifestyle Counselling

Pr(Ⅲ) and nd(Ⅲ) Absorption Spectroscopic Probe to Investigate Interaction with Lysozyme (HEW)

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Journal of Rare Earths 2006年第6期24卷 648-652页

作者： Jignasu P.Mehta Prashant n.bhatt Sudhindra n. Misra Department of Chemistry Bhavnagar UniversityBhavnagar-364002India

Pr（ Ⅲ ） and nd（ Ⅲ ） can be utilized as absorption spectroscopic probes to investigate the interaction of biomolecules like Lysozyme （HEW） with Ca（ Ⅱ ） in-vitro ; the most abundant metal ion in the human body system. The spectroscopic techniques involving comparative absorption, absorption difference, and quantitative intensity analysis using 4f-4f transitions are utilized for changes in the inner sphere coordination pattern of Pr（ Ⅲ ） and nd（Ⅲ ） in solution as well as in solid state. The present study deals with an important biomolecule in human metabolism, that is, Lysozyme （HEW）. The absorption er-Condon the probab spectral parameters such as the oscillator strength （P）, the Judd-Ofelt （Tλ） intensity parameters, and the Slatinter electronic parameters are calculated using chi square methods. The obtained results are used to determine le geometry of the complex in the solution, the nature of the bond between Pr（Ⅲ）/nd（Ⅲ） with lysozyme, and the inner sphere coordination environment of f-f transitions. The results obtained from various experimental conditions are utilized to investigate the coordination changes in the Pr（Ⅲ）/nd（Ⅲ） complexes caused by different coordinating sites of lysozyme, normalized bite, denticity, the solvent nature, the coordination number, the nature of bond and other parameters to mimic the interaction of the Ca（ Ⅱ ） ion with such biomolecule.

关键词： absorption spectra Pr(Ⅲ), nd(Ⅲ) Lysozyme (HEW) spectral parameters rare earths

Provenance discrimination and Source-to-Sink studies from a dryland fluvial regime:An example from kachchh,western India

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International Journal of Sediment Research 2014年第1期29卷 99-109页

作者： S.P.PRIZOMWALA nilesh bhatt n.BASAVAIAH Institute of Seismological Research Department of Geology The M.S.University of Baroda Indian Institute of Geomagnetism

Tracing the sediment delivery from its source terrain to its ultimate sink envisage multiple factors that play a vital role in understanding present day erosional *** accomplish this,it is significant to distinguish the variable end-members contributing to the *** findings from the study of dryland coastal fluvial regime in kachchh(Western India),which is one of the end members contributing to the Gulf of kachchh coast(partial sink) and finally to the Arabian Sea(ultimate sink) have been presented ***-proxy sediment provenance proxies such as grain-size,clay minerals,geochemistry and magnetic minerals have been employed to evaluate the provenance discriminating characteristics of the kachchh dryland fluvial system and factors influencing *** results of different proxies indicate that the provenance signatures of uplands are quite characteristic with magnetic susceptibility(χ) values of kg-1and smectite(S)/kaolinite(k) ratio between 0.26 and *** middle reaches show marked increase in magnetic mineral concentration with χ values(140×10-7m3kg-1)and S/k ratio(4.92),while the estuarine tract shows χ values(80×10-7m3kg-1),S/k ratio(1.90) and,characteristic heavy minerals(*** minerals),probably reflect the interplay between land and sea *** sources of sediments within catchment scale were identified,viz.,upland sedimentary rocks(Juran and Bhuj Formation sandstone-shale) and middle reaches volcanic(Deccan Trap Formation basalt) *** present study draw cautions in provenance of sediment discrimination in areas influenced by Deccan basalt that has the overwhelming sediment delivery and a comparatively subdued effects of other provenance *** studied proxies of mineralogy of clays,magnetic minerals and geochemistry of heavy and major elements serve as the potential for fingerprint of sediment source regions and hence behold a strong position in source to sink studies globally.

关键词： Provenance Source-to-sink Heavy minerals Clay minerals kachchh

Eu(Ⅲ) Indirect Probe to Investigate Interaction of DOPA (3,4,Di-Hydroxyphenylalanine) and Dopamine (3,4-Dihydroxy Phenyl Ethyl Amine) Using Electrochemical Methods

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Journal of Rare Earths 2006年第6期24卷 653-658页

作者： Prashant n bhatt Trupti V Pathak Jignasu P Mehta G.Ramchandraiha Department of Chemistry Bhavnagar University Bhavnagar-364002 India Central Salt and Marine Chemical Research Institute Waghavadi RoadBhavnagar-364002India

Eu（ Ⅲ ） can be utilized as an indirect electrochemical probe to investigate the interaction of bio-molecules such as DOPA and Dopamine with Ca（ Ⅱ ） in vitro. The interaction of DOPA and Dopamine with Eu（ Ⅲ ）-Eu（ Ⅱ ） redox pair was investigated by electrochemical techniques. Both the neurotransmitters are structurally related and undergo interaction with Eu （Ⅲ ）. Eu （ Ⅲ ） coordinates with DOPA and Dopamine through five-member chelate tings via carboxylic oxygen and amino nitrogen. The electrode kinetic parameters viz, transfer coefficient （αna）, diffusion coefficient （D）, forward heterogeneous rate constant （ k^0 fh） were evaluated for Eu（ Ⅲ ）-DOPA/Eu（ Ⅲ ）-Dopamine. The results obtained were used to investigate the nature of interaction of Eu （Ⅲ） with muhi-donor biomolecules. The possible mechanism was also proposed.

关键词： electrochemistry of Eu ( Ⅲ ) chrono techniques electrochemistry of Eu ( Ⅲ )-neurotransmitters solutionstudy rare earths

Efficacy of a Diabetes Specific nutrition Supplement on Glycemic, Anthropometric, Dietary and Gut Health Markers in Adults with Type 2 Diabetes: An RCT

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Food and nutrition Sciences 2024年第8期15卷 846-867页

作者： Deepti khanna Hema S. Gopalan kuzhandaivelu Abirami Vasudevan Sudha Rajagopal Gayatri kejal Joshi-Reddy Jaladhi bhatt Raman Ganesh Jeevan karthikeyan Parkavi Vadivel Deepika Manoj Pareek Ranjit Mohan Anjana Viswanathan Mohan R&D Department Hindustan Unilever Limited Gurugram India Department of Foods Nutrition & Dietetics Research Madras Diabetes Research Foundation Chennai India Department of Diabetology Dr. Mohans Diabetes Specialities Centre Chennai India

With increasing incidence of diabetes, use of diabetes specific nutrition supplements (DSnS) is common for better management of the disease. To study effect of 12-week DSnS supplementation on glycemic markers, anthropometry, lipid profile, SCFAs, and gut microbiome in individuals with diabetes. Markers studied were glycemic [Fasting Blood Glucose (FBG), Post Prandial Glucose (PPG), HbA1c, Incremental Area under curve (iAUC), Mean Amplitude of Glycemic Excursions (MAGE), Time in/above Range (TIR/TAR)], anthropometry [weight, Body Mass Index (BMI), waist circumference (WC)], lipid profile, diet and gut health [plasma short chain fatty acids (SCFAs)]. n = 210 adults were randomized to receive either DSnS with standard care (DSnS + SC;n = 105) or standard care alone (SC alone;n = 105). After 12 weeks, significant differences between DSnS + SC versus SC alone was observed in FBG [−3 ± 6 vs 14 ± 6 mg/dl;p = 0.03], PPG [−35 ± 9 vs −3 ± 9 mg/dl;p = 0.01], weight [−0.6 ± 0.1 vs 0.2 ± 0.1 kg;p = 0.0001], BMI [−0.3 ± 0.1 vs 0.1 ± 0.1 kg/m2;p = 0.0001] and WC [−0.3 ± 0.2 vs 0.2 ± 0.2 cm;p = 0.01]. HbA1C and low-density lipoprotein (LDL) were significantly reduced in DSnS + SC [−0.2 ± 0.9;p = 0.04 and −5 mg/dl;p = 0.03] respectively with no change in control. Continuous Glucose Monitoring (CGM) reported significant differences between DSnS + SC versus SC alone for mean glucose [−12 ± 65 vs 28 ± 93 mg/dl;p nificantly reduced for both DSnS + SC (−19 ± 67;p nd SC alone (−8 ± 70;p = 0.04), with reduction being more pronounced for DSnS + SC. DSnS + SC reported a decrease in carbohydrate energy % [−9.4 (−11.3, −7.6) %;p nd amount [−47.4 (−67.1, −27.7) g;p ncreased dietary fiber [9.5 (7.2, 11.8) g;p nd protein energy % [0.9 (0.5, 1.3) %;p ne. DSnS + SC reported signi

关键词： Diabetes Specific nutrition Supplement Standard of Care Diabetes Glycemic Markers HbA1C

Carbon Disulphide Induced Sensitivity Changes of Rat Anococcygeus Muscle to noradrenaline(nA)

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Biomedical and Environmental Sciences 1993年第3期6卷 223-230页

作者： D.n.GAnDHI H.VEnkATAkRISHnA-bhatt Department Department of Neurobehavioural Toxicology National Institute of Occupational Health(ICMRMeghani NagarAhmedabad 380016Indiaof Neurobehavioural Toxicology National Institute of Occupational Health(ICMRMeghani NagarAhmedabad 380016India

The sensitivity of rat anococcygeus muscle to noradrenaline (nA) was reduced following carbon disulphide (CS2) pretreatment. Preparations incubated in excess Ca++ (4.2 mrnol-L-1) or Zero Ca++ (***-L-1) media showed decrease in sensitivity to nA. Reserpinization failed to induce supersensitivity to nA in any Mg+ + concentration in the media. Reserpinized tissue in Mg++ free media with EDTA showed increased sensitivity while decreased sensitivity and maximum response to nA in Mg+ + (1.2 mmol-L-1) and excess Mg+ + (3.6mmol-1 ') concentration of the medium. In the presence of EDTA, the inhibition observed with CS2 in excess Mg+ + (3.6m mol-L-1') medium was comparatively much less in both non-reserpinized and reserpinized preparations. In normal Ca++ and its deficient medium decrease in sensitivity to CS2 and the relevant maximum response to nA were observed. In excess Ca + +, the CS2 effect depressed corresponding to its maximal response to nA. Thus CS2 may be inhibiting responses to nA by interfering with Ca+ + utilization.

关键词： nA