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Recent progress in two-dimensional metallenes and their potential application as electrocatalyst

Journal of Energy Chemistry 2024年第7期94卷 577-598页

作者： Umer Shahzad mohsin Saeed muhammad Fazle Rabbee Hadi m.marwani Jehan Y.Al-Humaidi muhammad Altaf Raed H.Althomali Kwang-Hyun Baek md.Rabiul Awual mohammed m.rahman Department of Chemistry Faculty of ScienceKing Abdulaziz UniversityJeddah 21589Saudi Arabia Department of Biotechnology Yeungnam UniversityGyeongsanSouth Korea Center of Excellence for Advanced materials Research(CEAmR) King Abdulaziz UniversityJeddah 21589Saudi Arabia Department of Chemistry College of SciencePrincess Nourah Bint Abdulrahman UniversityP.O.BOX 84428Riyadh 11671Saudi Arabia Department of Chemistry Center of Excellence for Innovation in Chemistry(PERCH-CIC)Center of Excellence in Materials Science and TechnologyFaculty of ScienceChiang Mai UniversityChiang Mai 50200Thailand Department of Chemistry College of Art and SciencePrince Sattam Bin Abdulaziz UniversityWadi Al-Dawasir 11991Saudi Arabia Western Australian School of mines:minerals Energy and Chemical EngineeringCurtin UniversityGPO Box U 1987PerthWA 6845Australia

In this article,we looked at metallenes,a novel class of two-dimensional(2D)metals that are attracting interest in the energy and catalysis *** is one area where their exceptional physicochemical and electrical characteristics might be *** are unique because they include several metal atoms that are not in a coordinated *** makes them more active and improves their atomic uti-lization,which in turn increases their catalytic *** article delves into the potential of two-dimensional metals as electrocatalysts for carbon dioxide reduction,fuel oxidation,oxygen evolution,and oxygen reduction reactions in the context of sustainable energy *** to the exception-ally high surface-to-volume ratio,large surface area as well as their optimized atomic use efficiency,2D materials defined by atomic layers are crucial for surface-related sustainable energy *** to its exceptional properties,such as high conductivity and the ability to enhance the exposure of active metal sites,2D metallenes have recently attracted a lot of interest for use in catalysis,electronics,and energy-related *** their highly mobility,adjustable surface states,and electrical struc-tures that can be fine-tuned,2D metallenes are promising nanostructure materials for use in energy con-version with the sustainable applications.

关键词： metallenes Electrocatalysts Electrochemical processes Atomically thin structure

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Bilirubin sensor based on CuO-CdO composites deposited in a nafion/glassy carbon electrode matrixes

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Progress in Natural Science:materials International 2017年第5期27卷 566-573页

作者： mohammed m.rahman mohammad musarraf Hussain Abdullah m.Asiri Chemistry Department King Abdulaziz UniversityFaculty of Science Center of Excellence for Advanced material Research (CEAmR) King Abdulaziz University

Copper oxide-cadmium oxide nanocomposites(CuO-CdO NCs) were synthesized by solvothermal technique in a basic medium. CuO-CdO NCs were characterized using conventional techniques, such as Fourier Transform Infrared Spectroscopy(FTIR), UV–Visible Spectroscopy(UV/Vis), Field-Emission Scanning Electron microscopy(FESEm), X-ray electron dispersive spectroscopy(XEDS), X-ray photoelectron spectroscopy(XPS), and powder X-ray diffraction(XRD). A selective and enzyme-less Bilirubin(BLR) sensor was developed with a thin-layer of NCs onto a glassy carbon electrode(GCE, surface area = 0.0316 cm~2) using 5% nafion binders at room conditions. Improved electrochemical performances of higher sensitivity, lower detection limit,linear dynamic range(LDR), and long-term stability of preferred BLR were achieved by a reliable currentvoltage(I-V) approach. The calibration curve was found linear(R~2= 0.9347) in a wide range of BLR concentration(10.0 pm ~ 10.0 mm). Based on the signal to noise ratio value of 3, the sensitivity and limit of detection(LOD) of the sensor were calculated as 95.0 pA μm-1cm-2and 1.0 ± 0.1 pm *** synthesized CuO-CdO NCs/GCE is an excellent advancement of developing a selective and sensitive BLR sensor by electrochemical approach and practically implemented in real sample applications.

关键词： CuO-CdO nanocomposites Bilirubin biosensor Glassy carbon electrode Sensitivity Real sample analysis Health care field

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Sensitive and fast response ethanol chemical sensor based on as-grown Gd_2O_3 nanostructures

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Journal of Rare Earths 2015年第2期33卷 214-220页

作者： m.m.Abdullah mohammed m.rahman Houcine Bouzid m.Faisal Sher Bahadar Khan S.A.Al-Sayari Adel A.Ismail Promising Centre for Sensors and Electronic Devices (PCSED) College of Science and Arts Najran University P.O. Box-1988Najran 11001 Saudi Arabia Center of Excellence for Advanced materials Research (CEAmR) & Chemistry Department King Abdulaziz University P.O. Box 80203Jeddah 21589 Saudi Arabia Laboratory of Ferroelectric materials Faculty of Sciences of Sfax Route Soukra Km 35B.P. 802 F-3018 Sfax Tunisia College of Science and Arts-Sharoura Najran University P.O. Box-1988Najran 11001 Saudi Arabia Central metallurgical Research and Development Institute (CmRDI) P.O.Box: 87 Helwan 11421 Cairo Egypt

Well crystalline gadolinium oxide（Gd2O3） nanostructures were grown by annealing the hydrothermally as-prepared nanostructures without using any template. microscopic studies of Gd2O3 nanostructures were recorded along the [111] direction due to the clearly resolved interplanar distance d（222）-0.31 nm of the cubic crystal structure Gd2O3. Sensing mechanism of Gd2O3 as efficient electron mediator for the detection of ethanol was explored. As-fabricated sensor demonstrated the high-sensitivity of -0.266 μAm/m/cm2 with low detection limit（-52.2 μmol/L） and correlation coefficient（r^2, 0.618）. To the best of our knowledge, this was the first report for the detection of ethanol using as-grown（at 1000 oC） Gd2O3 nanostructures by simple and reliable Ⅰ-Ⅴ technique and rapid assessment of the reaction kinetics（in the order of seconds）. The low cost of the starting reagents and the simplicity of the synthetic route made it a promising chemical sensor for the detection of various toxic analytes, which are not environmentally safe.

关键词： growth Gd2O3 nanostructures ethanol Ⅰ-Ⅴ technique chemical sensing rare earths

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A Review and Bibliometric Analysis of the Current Studies for the 6G Networks

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Computer modeling in Engineering & Sciences 2024年第9期140卷 2165-2206页

作者： Qusay m.Salih md.Arafatur rahman Ahmad Firdaus mohammed Rajih Jassim Hasan Kahtan Jasni mohamad Zain Ahmed Hussein Ali Faculty of Computing Universiti Malaysia Pahang Al-Sultan Abdullah(UMPSA)PekanPahang26600Malaysia Department of medical Equipment Technology Engineering Al Salam University CollegeBaghdadIraq School of mathematics and Computer Science University of WolverhamptonWolverhampton01902UK Department of Production Engineering and metallurgy University of TechnologyBaghdadIraq Cardiff School of Technologies Cardiff Metropolitan UniversityCardiffCF52YBUK Institute for Big Data Analytics and Artificial Intelligence(IBDAAI) Kompleks Al-KhawarizmiUniversiti Teknologi MARAShah AlamSelangor40450Malaysia Department Computer Science Al-Salam University CollegeBaghdadIraq

The race to develop the next generation of wireless networks,known as Sixth Generation(6G)wireless,which will be operational in 2030,has already *** realize its full potential over the next decade,6G will undoubtedly necessitate additional improvements that integrate existing solutions with cutting-edge ***,the studies about 6G are mainly limited and scattered,whereas no bibliometric study covers the 6G ***,this study aims to review,examine,and summarize existing studies and research activities in *** study has examined the Scopus database through a bibliometric analysis of more than 1,000 papers published between 2017 and ***,we applied the bibliometric analysis methods by including(1)document type,(2)subject area,(3)author,and(4)country of *** study’s results reflect the research 6G community’s trends,highlight important research challenges,and elucidate potential directions for future research in this interesting area.

关键词： 6G bibliometric wireless networks review

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Kaoline-based catalyst for a high stability desulfurization of sour heavy naphtha in a three-phase oscillatory baffled reactor

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Particuology 2024年第1期84卷 249-260页

作者： Hassan m.Hmood Saba A.Gheni Safaa m.R.Ahmed mudheher m.Ali Hamid Yonis Saleh mohammed H.mohammed Awad E.mohammed marwan A.mahomood Hiba R.mohammed Ahmed A.Hassan Adam Harvey North Refineries Company Ministry of OilIraq Chemical Engineering Department Tikrit UniversityIraq ministry of Oil Iraq AL-Hawija Technical Institute Northern Technical UniversityMoselIraq School of Engineering Newcastle UniversityUK

To meet the rapidly increasing demand for energy and the dramatic depletion of conventional crude oil,it is imperative to utilize sour *** no coke being produced,oxidative desulfurization(ODS)of naphtha lowers its sulfur content and average molecular *** this article,we outline a method for heavy naphtha non-extractive ODS using a very stable *** technique involves the use of a solid catalyst with oxygen gas as the *** necessitated relatively high mixing intensities;hence a three-phase Oscillatory Baffled Reactor(OBR)was *** catalyst was based on the zeolite ZSm-5,prepared from natural kaolin by a series of delamination and activation steps and impregnated with Fe.A TiO2 nanolayer was applied,using the sol-gel method,to prevent rapid *** reactor performance was evaluated to minimize the sulfur content in the naphtha *** to the protective coating,the sulfur conversion stabilized at 90%.The results of this work establish the use of natural clay-based catalysts in a continuous,three-phase ODS,particularly with regard to proving long-term *** also showed that modest ODS can be achieved using an environmentally friendly oxidant,at mild operating conditions,whilst maintaining stability.

关键词： Natural kaoline Desulfurization Three-phase Oscillatory baffled reactor

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Smartphone-Based Wi-Fi Analysis for Bus Passenger Counting

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Computers, materials & Continua 2024年第4期79卷 875-907页

作者： mohammed Alatiyyah Department of Computer Science College of Computer Engineering and SciencesPrince Sattam Bin Abdulaziz UniversityAl-Kharj16278Saudi Arabia

In the contemporary era of technological advancement,smartphones have become an indispensable part of individuals’daily lives,exerting a pervasive *** paper presents an innovative approach to passenger countingonbuses throughthe analysis ofWi-Fi signals emanating frompassengers’mobile *** study seeks to scrutinize the reliability of digital Wi-Fi environments in predicting bus occupancy levels,thereby addressing a crucial aspect of public *** proposed system comprises three crucial elements:Signal capture,data filtration,and the calculation and estimation of passenger *** pivotal findings reveal that the system demonstrates commendable accuracy in estimating passenger counts undermoderate-crowding conditions,with an average deviation of 20%from the ground truth and an accuracy rate ranging from 90%to 100%.This underscores its efficacy in scenarios characterized by moderate levels of ***,in densely crowded conditions,the system exhibits a tendency to overestimate passenger numbers,occasionally doubling the actual *** acknowledging the need for further research to enhance accuracy in crowded conditions,this study presents a pioneering avenue to address a significant concern in public *** implications of the findings are poised to contribute substantially to the enhancement of bus operations and service quality.

关键词： Public transportation digital environment passenger estimation signal capturing Wi-Fi

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Complex Decision modeling Framework with Fairly Operators and Quaternion Numbers under Intuitionistic Fuzzy Rough Context

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Computer modeling in Engineering & Sciences 2024年第5期139卷 1893-1932页

作者： Nadeem Salamat muhammad Kamran Shahzaib Ashraf manal Elzain mohammed Abdulla Rashad Ismail mohammed m.Al-Shamiri Institute of mathematics Khwaja Fareed University of Engineering&Information TechnologyRahim Yar Khan64200Pakistan Department of mathematics Thal University BhakkarPunjab30000Pakistan Department of mathematics Faculty of Science and ArtsKing Khalid UniversityMuhayl Assir61913Saudi Arabia

The main goal of informal computing is to overcome the limitations of hypersensitivity to defects and uncertainty while maintaining a balance between high accuracy,accessibility,and *** paper investigates the potential applications of intuitionistic fuzzy sets(IFS)with rough sets in the context of sparse *** it comes to capture uncertain information emanating fromboth upper and lower approximations,these intuitionistic fuzzy rough numbers(IFRNs)are superior to intuitionistic fuzzy sets and pythagorean fuzzy sets,*** use rough sets in conjunction with IFSs to develop several fairly aggregation operators and analyze their underlying *** present numerous impartial laws that incorporate the idea of proportionate dispersion in order to ensure that the membership and non-membership activities of IFRNs are treated equally within these *** operations lead to the development of the intuitionistic fuzzy rough weighted fairly aggregation operator(IFRWFA)and intuitionistic fuzzy rough ordered weighted fairly aggregation operator(IFRFOWA).These operators successfully adjust to membership and non-membership categories with fairness and *** highlight the unique qualities of these suggested aggregation operators and investigate their use in the multiattribute decision-making *** use the intuitionistic fuzzy rough environment’s architecture to create a novel strategy in situation involving several decision-makers and non-weighted ***,we developed a novel technique by combining the IFSs with quaternion *** establish a unique connection between alternatives and qualities by using intuitionistic fuzzy quaternion numbers(IFQNs).With the help of this framework,we can simulate uncertainty in real-world situations and address a number of decision-making *** the examples we have released,we offer a sophisticated and systematically constructed illustrative scenario that is intricately wo

关键词： Intuitionistic fuzzy set quaternion numbers fuzzy logic decision-making rough set

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Amachine Learning Approach to Cyberbullying Detection in Arabic Tweets

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Computers, materials & Continua 2024年第7期80卷 1033-1054页

作者： Dhiaa musleh Atta rahman mohammed Abbas Alkherallah menhal Kamel Al-Bohassan mustafa mohammed Alawami Hayder Ali Alsebaa Jawad Ali Alnemer Ghazi Fayez Al-mutairi may Issa Aldossary Dalal A.Aldowaihi Fahd Alhaidari Department of Computer Science College of Computer Science and Information TechnologyImam Abdulrahman Bin Faisal UniversityP.O.Box 1982Dammam31441Saudi Arabia Department of Computer Information Systems College of Computer Science and Information TechnologyImam Abdulrahman Bin Faisal UniversityP.O.Box 1982Dammam31441Saudi Arabia Department of Networks and Communications College of Computer Science and Information TechnologyImam Abdulrahman Bin Faisal UniversityP.O.Box 1982Dammam31441Saudi Arabia

With the rapid growth of internet usage,a new situation has been created that enables practicing *** has increased over the past decade,and it has the same adverse effects as face-to-face bullying,like anger,sadness,anxiety,and *** the anonymity people get on the internet,they tend to bemore aggressive and express their emotions freely without considering the effects,which can be a reason for the increase in cyberbullying and it is the main motive behind the current *** study presents a thorough background of cyberbullying and the techniques used to collect,preprocess,and analyze the ***,a comprehensive review of the literature has been conducted to figure out research gaps and effective techniques and practices in cyberbullying detection in various languages,and it was deduced that there is significant room for improvement in the Arabic *** a result,the current study focuses on the investigation of shortlisted machine learning algorithms in natural language processing(NLP)for the classification of Arabic datasets duly collected from Twitter(also known as X).In this regard,support vector machine(SVm),Na飗e Bayes(NB),Random Forest(RF),Logistic regression(LR),Bootstrap aggregating(Bagging),Gradient Boosting(GBoost),Light Gradient Boosting machine(LightGBm),Adaptive Boosting(AdaBoost),and eXtreme Gradient Boosting(XGBoost)were shortlisted and investigated due to their effectiveness in the similar ***,the scheme was evaluated by well-known performance measures like accuracy,precision,Recall,and ***,XGBoost exhibited the best performance with 89.95%accuracy,which is promising compared to the state-of-the-art.

关键词： Supervised machine learning ensemble learning cyberbullying Arabic tweets NLP

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EECLP: AWireless Sensor Networks Energy Efficient Cross-Layer Protocol

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Computers, materials & Continua 2024年第8期80卷 2611-2631页

作者： mohammed Kaddi mohammed Omari moamen Alnatoor LDDI Laboratory University of AdrarAdrar01000Algeria Computer Science and Engineering Department School of EngineeringAmerican University of Ras Al KhaimahRas Al Khaimah72603United Arab Emirates

Recent advancements in wireless communications have allowed the birth of novel wireless sensor networks(WSN).A sensor network comprises several micro-sensors deployed randomly in an area of interest.A micro-sensor is provided with an energy resource to supply electricity to all of its ***,the disposed energy resource is limited and battery replacement is generally *** this restriction,the sensors must conserve energy to prolong their *** energy conservation strategies for WSNs have been presented in the literature,from the application to the physical *** of these solutions focus only on optimizing a single layer in terms of energy *** this research,a novel cross-layer technique for WSNs’effective energy usage is *** most energy consumption factors exist in the medium Access Control(mAC)layer and network layer,our EECLP protocol(Energy Efficient Cross-Layer Protocol for Wireless Sensor Networks)integrates these two layers to satisfy energy efficiency *** gain access to the transmission channel,we implement a communication regime at the mAC layer based on CSmA/CA(Carrier Sense multiple Access/Collision Avoidance)***,depending on the activity and a standby period,we employ the RTS/CTS(Request to Send/Clear to Send)method to prevent collisions and resolve hidden node concerns by utilizing the network allocation vector(NAV)to calculate the transmission *** a greedy strategy,we establish chains amongst cluster members to mitigate the issue of high energy consumption in routing *** objective function was utilized to determine the optimal cross-chain path based on the distances to the base station(BS)and residual energy(RE).The simulation,testing,and comparison of the proposed protocol to peer protocols have shown superior outcomes and a prolonged network *** the suggested protocol,the network lifetime increases by 10%compared to FAmACO(Fuzzy and Ant Col

关键词： WSN energy consumption mAC layer network layer EECLP energy-efficient lifespan

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Synthetic polymers:A review of applications in drilling fluids

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Petroleum Science 2024年第1期21卷 475-518页

作者： Shadfar Davoodi mohammed Al-Shargabi David A.Wood Valeriy S.Rukavishnikov Konstantin m.minaev School of Earth Sciences&Engineering Tomsk Polytechnic UniversityLenin AvenueTomskRussia DWA Energy Limited LincolnUnited Kingdom

With the growth of deep drilling and the complexity of the well profile,the requirements for a more complete and efficient exploitation of productive formations increase,which increases the risk of various ***,reagents based on modified natural polymers(which are naturally occurring compounds)and synthetic polymers(SPs)which are polymeric compounds created industrially,are widely used to prevent emerging complications in the drilling ***,compared to modified natural polymers,SPs form a family of high-molecular-weight compounds that are fully synthesized by undergoing chemical polymerization *** provide substantial flexibility in their ***,their size and chemical composition can be adjusted to provide properties for nearly all the functional objectives of drilling *** can be classified based on chemical ingredients,type of reaction,and their responses to ***,some of SPs,due to their structural characteristics,have a high cost,a poor temperature and salt resistance in drilling fluids,and degradation begins when the temperature reaches 130℃.These drawbacks prevent SP use in some medium and deep ***,this review addresses the historical development,the characteristics,manufacturing methods,classification,and the applications of SPs in drilling *** contributions of SPs as additives to drilling fluids to enhance rheology,filtrate generation,carrying of cuttings,fluid lubricity,and clay/shale stability are explained in *** mechanisms,impacts,and advances achieved when SPs are added to drilling fluids are also *** typical challenges encountered by SPs when deployed in drilling fluids and their advantages and drawbacks are also *** issues also impact the applications of SPs in drilling ***,the cost of the most relevant SPs,and the monomers used in their synthesis,are *** impacts of SPs when deployed in drilling fluids,and t

关键词： Synthetic versus natural polymers Nanopolymers Drilling fluid additives Lubricity Clay swelling Hole cleaning

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