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Ultrasensitive and selective 4-aminophenol chemical sensor development based on nickel oxide nanoparticles decorated carbon nanotube nanocomposites for green environment

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Journal of Environmental Sciences 2017年第3期29卷 27-38页

作者： mohammad Musarraf hussain Chemistry Department Faculty of ScienceKing Abdulaziz UniversityJeddah 21589P.O.Box 80203Saudi Arabia Center of Excellence for Advanced Material Research(CEAMR) King Abdulaziz UniversityJeddah 21589P.O.Box 80203Saudi Arabia

Nickel oxide nanoparticles decorated carbon nanotube nanocomposites （*** NCs） were prepared in a basic medium by using facile wet-chemical routes. The optical, morphological, and structural properties of *** NCs were characterized using Fourier transformed infra-red （FT-IR）, Ultra-violet visible （UV/Vis） spectroscopy, field-emission scanning electron microscopy （FESEM）, X-ray energy dispersed spectroscopy （XEDS）, X-ray photoelectron spectroscopy （XPS）, and powder X-ray diffraction （XRD） methods. Selective 4-aminophenol （4-AP） chemical sensor was developed by a fiat glassy carbon electrode （GCE, surface area： 0.0316 cm2） fabricated with a thin-layer of NCs. Electrochemical responses including higher sensitivity, large dynamic range （LDR）, limit of detection （LOD）, and long-term stability towards 4-AP were obtained using the fabricated chemical sensors. The calibration curve was found linear （R2 = 0.914） over a wide range of 4-AP concentration （0.1 nmol/L-0.1 tool/L）. In perspective of slope （2 x 10.5 gA/gM）, LOD and sensitivity were calculated as 15.0 ＋ 0.1 pM and -6.33 - 10.4 gA/（***） respectively. The synthesized *** NCs using a wet-chemical method is a significant route for the development of ultrasensitive and selective phenolic sensor based on nano-materials for environmental toxic substances. It is suggested that a pioneer and selective development of 4-AP sensitive sensor using *** NCs by a facile and reliable current us voltage （I-V） method for the major application of toxic agents in biological, green environmental, and health-care fields in near future.

关键词： NiO decorated CNT nanocomposltesOptical evaluationFabricationSensitivity4-AminophenolI-V method

A data-mining approach to biomarker identification from protein profiles using discrete stationary wavelet transform

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Journal of Zhejiang University-Science B(Biomedicine & Biotechnology) 2008年第11期9卷 863-870页

作者： hussain MONTAZERY-KORDY mohammad Hossein MIRAN-BAYGI mohammad Hassan MORADI Department of Electrical and Computer Engineering Tarbiat Modares University Faculty of Biomedical Engineering Amir Kabir University of Technology

Objective: To develop a new bioinformatic tool based on a data-mining approach for extraction of the most infor- mative proteins that could be used to find the potential biomarkers for the detection of cancer. Methods: Two independent datasets from serum samples of 253 ovarian cancer and 167 breast cancer patients were used. The samples were examined by surface- enhanced laser desorption/ionization time-of-flight mass spectrometry (SELDI-TOF MS). The datasets were used to extract the informative proteins using a data-mining method in the discrete stationary wavelet transform domain. As a dimensionality re- duction procedure, the hard thresholding method was applied to reduce the number of wavelet coefficients. Also, a distance measure was used to select the most discriminative coefficients. To find the potential biomarkers using the selected wavelet coefficients, we applied the inverse discrete stationary wavelet transform combined with a two-sided t-test. Results: From the ovarian cancer dataset, a set of five proteins were detected as potential biomarkers that could be used to identify the cancer patients from the healthy cases with accuracy, sensitivity, and specificity of 100%. Also, from the breast cancer dataset, a set of eight proteins were found as the potential biomarkers that could separate the healthy cases from the cancer patients with accuracy of 98.26%, sensitivity of 100%, and specificity of 95.6%. Conclusion: The results have shown that the new bioinformatic tool can be used in combination with the high-throughput proteomic data such as SELDI-TOF MS to find the potential biomarkers with high discriminative power.

关键词： Proteomics Discrete stationary wavelet transform Data mining Feature selection Biomarker Cancer classification

Spatial modeling of solar photovoltaic power plant in Kabul,Afghanistan

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Journal of Mountain Science 2021年第12期18卷 3291-3305页

作者： NASERI mohammad hussainI mohammad Salem IQBAL mohammad Wasim JAWADI hussain Ali PUYA Marzia Afghanistan National Water and Environmental Research Center(ANWERC) Kabul 1006Afghanistan Department of Geology Faculty of GeosciencesBamyan UniversityBamyan 1601Afghanistan School of Sustainable Engineering and the Built Environment Arizona State UniversityTempe AZ 85287-3005USA Department of Engineering Geology and Hydrogeology Kabul Polytechnic UniversityKabul 1006Afghanistan

Energy planning and solar plant site selections are vital strategic decisions and one of the most complex executive challenges in the interconnected *** is essential to study the potential renewable energy sources in Afghanistan to select the most sustainable sites for solar power production in populated *** study is based on the combination of a Geographic Information System,Remote sensing,and multi-criteria decision-making technique to evaluate the optimal placement of photovoltaic solar power plants in the Kabul province,capital of *** models,Analytical Hierarchy Process(AHP)and Analytical Network Process(ANP),were used to select suitable areas for establishing a solar power *** application of the proposed model has been made possible by integrating four constraints such as climate,environmental,topography,and economical which comprised twelve criteria:solar radiation,yearly average rainfall,land slope,aspect,land use,dust,geology and proximity to faults,main roads,Normalized difference vegetation index,urban areas river and water *** findings indicate that there is no considerable difference between the results of both models since both models identified more than 20%of the total area of Kabul province in suitable *** maps conclude that northern and southern parts of Kabul city and the eastern part of Kabul province came to the range of suitable *** can be concluded that Kabul province is a source of sufficient potential for producing solar *** results of this study can support the plans of the Afghanistan government in solar energy production and the implementation of photovoltaic power plants.

关键词： Photovoltaic Spatial modeling AHP ANP Kabul GIS

Nitrate contamination in groundwater of Kabul Province,Afghanistan:Reasons behind and conceptual management framework discourse

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Journal of Mountain Science 2022年第5期19卷 1274-1291页

作者： JAWADI hussain Ali IQBAL mohammad Wasim NASERI mohammad FARAHMAND Asadullah AZIZI Abdul Haseeb EQRAR mohammad Naiem Afghanistan National Water and Environmental Research Center(ANWERC) Kabul 1006Afghanistan Department of Geology Faculty of GeosciencesBamyan UniversityBamyan CityBamyan 1601Afghanistan School of Sustainable Engineering and the Built Environment Arizona State UniversityTempe AZ 85287-8704USA Department of Hydrogeology Ministry of Energy and WaterKabul 1006Afghanistan CITEngineering International Co. LtdTokyoJapan Department of Geology Faculty of GeosciencesKabul UniversityKabul 1006Afghanistan

Groundwater contamination has been on the rise in *** has become a major concern among the policy *** paper aims to propose practical options for the management of nitrate contamination in one of Afghanistan’s groundwater polluted provinces,*** management framework utilized Mann-Kendall and Sen Slope tests to detect nitrate trend and geostatistical analysis option in Arc GIS 10.5 to assess the nitrate *** explore the impact of various management options,a number of legislative documents were *** results indicate a decline in the nitrate storage of Kabul aquifers from 108 mg/L in 2005 to 0.044 mg/L in *** the whole period of the study,the results show that the nitrate volumes remain lower than the nitrate concentration range proposed by World Health Organization(50 mg/L).Groundwater dynamics in Kabul aquifers were influenced by nitrate derived from precipitation and nitrate input from root zones in agricultural ***,different management options for groundwater pollution from nitrate and corresponding authorities,incorporated urban,rural and agriculture,were *** is expected that this study will help policy makers to better manage the nitrate storage of Kabul aquifers by implementing the proposed management options.

关键词： Nitrate concentration Groundwater Afghanistan Effective parameter Management option

Global sensitivity analysis of certain and uncertain factors for a circular tunnel under seismic action

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Frontiers of Structural and Civil Engineering 2019年第6期13卷 1289-1300页

作者： Nazim Abdul NARIMAN Raja Rizwan hussain Ilham Ibrahim mohammad Peyman KARAMPOUR Department of Civil Engineering Tishk International University SulaimaniSulaimaniya 46001Iraq Civil Engineering Department College of EngineeringKing Saud UniversityRiyadh 11421Saudi Arabia Department of Mechanical Engineering Faculty of EngineeringArak UniversityArak 38156-875Iran

There are many certain and uncertain design factors which have unrevealed rational effects on the generation of tensile damage and the stability of the circular tunnels during seismic *** this research paper,we have dedicated three certain and four uncertain design factors to quantify their rational effects using numerical simulations and the Sobol's sensitivity *** effects and interaction effects between the design factors have been determined supporting on variance-based global sensitivity *** results detected that the concrete modulus of elasticity for the tunnel lining has the greatest effect on the tensile damage generation in the tunnel lining during the seismic *** the other direction,the interactions between the concrete density and both of concrete modulus of elasticity and tunnel diameter have appreciable effects on the tensile ***,the tunnel diameter has the deciding effect on the stability of the tunnel *** the interaction between the tunnel diameter and concrete density has appreciable effect on the stability *** is worthy to mention that SoboFs sensitivity indices manifested strong efficiency in detecting the roles of each design factor in cooperation with the numerical simulations explaining the responses of the circular tunnel during seismic actions.

关键词： shear waves SoboFs sensitivity indices maximum principal stress maximum overall displacement tensile damage

Correction‐enabled reversible data hiding with pixel repetition for high embedding rate and quality preservation

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IET Cyber-Systems and Robotics 2024年第3期6卷 49-61页

作者： mohammad Ali Kawser hussain Nyeem Md Abdul Wahed School of Transportation Science and Engineering Beihang UniversityBeijingChina Department of Electrical Electronic and Communication Engineering(EECE)Military Institute of Science and Technology(MIST)DhakaBangladesh

A novel correction‐enabled Pixel Repetition(PR)‐based Reversible Data Hiding(RDH)framework,featuring a new embedding scheme is *** proposed RDH scheme uses contextually redundant block pixels,generated via PR,in a two‐phase adaptive embedding process,enhancing both image quality and data embedding ***,each 2×2 block encodes 4 bits of data using new mapping conditions that facilitate seed pixel reconstruction from remaining block pixels and provide additional embedding ***,an innovative post‐embedding error correction technique,based on 2^(k)‐bit error‐correction,minimises post‐embedding distortion,further improving image *** error correction approach augments data embedding robustness,vital for applications like medical imaging,telemedicine,and digital watermarking that requires high embedding capacity with minimum possible *** proposed scheme surpasses existing state‐of‐the‐art methods in embedding ratedistortion performance,validated through subjective and objective ***,statistical analysis,including histogram and fragility testing,confirms the scheme's potential for image authentication across diverse multimedia *** correctionenabled RDH with PR offers enhanced embedding capacity and image quality preservation,making it particularly advantageous for applications requiring robust data hiding while maintaining visual fidelity.

关键词： data assimilation vision

Analysis of Eigenvalues for Molecular Structures

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Computers, Materials & Continua 2022年第10期73卷 1225-1236页

作者： Muhammad Haroon Aftab Kamel Jebreen mohammad Issa Sowaity Muhammad hussain Department of Mathematics and Statistics The University of LahoreLahore54000Pakistan Department of Mathematics An-Najah National UniversityNablusP400Palestine Department of Mathematics Palestince Polytechnic UniversityHebronP766Palestine Department of Mathematics Comsats University IslamabadLahore CampusLahore54000Pakistan

In this article,we study different molecular structures such as Polythiophene network,PLY(n)for n=1,2,and 3,Orthosilicate(Nesosilicate)SiO4,Pyrosilicates(Sorosilicates)Si2O7,Chain silicates(Pyroxenes)(SiO3)n,and Cyclic silicates(Ring Silicates)Si3O9 for their cardinalities,chromatic numbers,graph variations,eigenvalues obtained from the adjacency matrices which are square matrices in order and their corresponding characteristics *** convert the general structures of these chemical networks in to mathematical graphical *** transform the molecular structures of these chemical networks which are mentioned above,into a simple and undirected planar graph and sketch them with various techniques of *** matrices obtained from these simple undirected graphs are *** also label the molecular structures by assigning different *** graphs have also been studied for *** a connected graph,the eigenvalue that shows its peak point(largest value)obtained from the adjacency matrix has multiplicity ***,the gap between the largest and its smallest eigenvalues is interlinked with some form of“connectivity measurement of the structural graph”.We also note that the chemical structures,Orthosilicate(Nesosilicate)SiO4,Pyrosilicates(Sorosilicates)Si2O7,Chain silicates(Pyroxenes)(SiO3)n,and Cyclic silicates(Ring Silicates)Si3O9 generally have two same *** matrices have great importance in the field of computer science.

关键词： Vertex degree edges eigenvalues characteristics polynomials adjacency matrices graphical model genetics polythiophene silicates

Development and characterization of SSR markers in Himalayan species Betula utilis

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Journal of Forestry Research 2020年第4期31卷 1453-1460页

作者： mohammad Saleem Wani Vikas Sharma Raghbir Chand Gupta Abid hussain Munshi Department of Botany Punjabi University PatialaPatialaPunjabIndia Department of Botany University of KashmirSrinagarJammu&KashmirIndia Department of Botany Sant Baba Bhag Singh UniversityKhialaJalandharPunjabIndia

Betula utilis *** an important species of alpine Himalaya and forms the major treeline component of western *** different populations of *** are declining and are under high *** the present study,novel expressed sequence tag-simple sequence repeat(EST-SSR)primers were developed from expressed sequence tag(EST)data of different Betula *** the10,796 designed primers,the percentages of di-,tri-,tetra-,penta-,and hexa-repeats were 36%,35%,15%,5.5%and7.7%,*** validation,50 primers were synthesized randomly and were characterized in 20 different *** accessions from north-western *** these,45 primers amplified fragments in a range of *** 24 polymorphic primers produced 111 fragments in aggregate with 4.6 fragments on *** information content(PIC)ranged from 0.288 in marker BUMS-24 to 0.497 in BUMS-3 and BUMS-7,with an average of 0.447 among polymorphic *** based on Jaccard’s similarity coefficient and UPGMA method showed that newly developed SSR markers distinguished twenty accessions of *** into two *** no SSR markers were available in this species,the newly developed markers will foster molecular genetics research and conservation efforts for this species.

关键词： Betula utilis Simple sequence repeat(SSR) Western Himalaya Polymorphism information content(PIC) Genetic diversity

Flow-injection Spectrophotometric Determination of Uric Acid in Urine via Prussian Blue Reaction

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Chemical Research in Chinese Universities 2011年第6期27卷 929-933页

作者： WASEEM Amir YAQOOB mohammad NABI Abdul MURTAZA Ghulam hussain Izhar Department of Chemistry COMSATS Institute of Information Technology Department of Chemistry University of Balochistan Department of Pharmacy COMSATS Institute of Information Technology

A simple and sensitive flow injection（FI） spectrophotometric method was reported for the determination of uric acid based on the reduction of Fe（III）/ferricyanide in the presence of uric acid. The in situ reduced ions reacted with unreduced portion of ferricyanide/Fe（III） to form soluble Prussian blue, which was monitored at an absorption wavelength of 735 nm. The optimized conditions allow a linear calibration graph in a concentration range of 1―100 μmol/L. The relative standard deviation was in a range of 0.5%―2.5%, with a detection limit（3σ blank） of 0.3 μmol/L and a sampling frequency of 60 injection/h was obtained. The effect of common substances present in human physiological fluids on the determination of uric acid was examined. The method was applied to determining uric acid in human urine samples with the recoveries in a range of 96%―105%. The results agree well with those by spectrophotometric reference method at a confidence level of 95%. Spectrophotometric procedures for uric acid determination in clinical samples were reviewed briefly.

关键词： Flow injection analysis Spectrophotometry Uric acid Prussian blue Urine