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The Role of the Chelating Agent on the Structure and Anticorrosion Perform.nces of an Organosilane—Zirconium.Sol-Gel Coatings

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Advances in m.terials Physics and Chem.stry 2018年第2期8卷 89-104页

作者： m. O’Sullivan N. A. Odewunm. m. cullen A. A. Sorour B. Duffy Z. m. Gasem.m. Oubaha Dublin Institute of Technology Centre for Research in Engineering Surface Technology Dublin Ireland Centre of Research Excellence in Corrosion King Fahd University of Petroleum and Minerals (KFUPM) Dhahran KSA Departm.nt of m.chanical Engineering King Fahd University of Petroleum & Minerals (KFUPM) Dhahran KSA

This work investigates the role of the structure of a zirconium.com.lex (ZC) on the condensation and anticorrosion properties of an organosilane sol-gel coating. The structure and reactivity of the ZC were m.dified by varying the content of m.thacrylic acid em.loyed as a chelating agent. The structures of the developed m.terials were characterised by Dynam.c Light Scattering, Fourier Transform.Infrared Spectroscopy, Differential Scanning Calorim.try and Scanning Electron m.croscopy. The passive anticorrosion properties were evaluated by Electrochem.cal Im.edance Spectroscopy of the sol-gel coatings deposited on AA2024-T3 substrates. It was highlighted, that a com.etition in the condensation process of the silicate (Si-O-Si) and silicon-ZC oxides (Si-O-Zr) species can be tailored by the structure of the ZC, with the least chelated ZC exhibiting the highest content of Si-O-Zr bonds. At the sam. tim., it was also found that the coatings containing the highest content of Si-O-Zr groups exhibited the best anticorrosion barrier perform.nces am.ngst all sol-gel coatings investigated here, therefore presenting the highest condensation degree. This suggested that Si-O-Zr bonds were the essential chem.cal species responsible for the form.tion of condensed coatings. A direct correlation between the structure of the coatings and their anticorrosion perform.nces is proposed.

关键词： Organosilane Sol-Gel Coatings Corrosion Structure Condensation

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Addition of Thiourea Host m.nom.r to Polym.r Flocculants to Im.rove Selectivity of Phosphate Sorption

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Journal of Agricultural Chem.stry and Environm.nt 2020年第3期9卷 147-158页

作者： Tim.thy S. Goebel Kevin J. m.Innes Scott A. Sensem.n Robert J. Lascano Alex m. cullen Tim.thy J. Fuhrer Sarah Pickle Netochi O. Adeolokun Todd A. Davis USDA Wind Erosion and Water Conservation Unit Lubbock TX USA Departm.nt of Soil and Crop Sciences Texas A & M University College Station TX USA Departm.nt of Plant Sciences University of Tennessee Knoxville TN USA Departm.nt of Chem.stry United States Air Force Academy USAF Academy Colorado Springs CO USA Departm.nt of Chem.stry Radford University Radford VA USA Departm.nt of Chem.stry Idaho State University Pocatello ID USA

Inorganic phosphate is a com.on nutrient that is applied as a fertilizer to both agricultural fields as well as urban settings such as private yards, public parks and other urban landscaping. While phosphate typically binds tightly to soil, m.vem.nt of phosphate off of application sites can occur through soil erosion. The soil and its bound phosphate can then end up in surface waters such as rivers and lakes. Phosphate found in surface water bodies exists both as bound to the suspended clay as well as that free in solution. Elevated phosphate concentration in surface waters can lead to algal bloom. and eutrophication. While the phosphate bound to clay in suspension in surface water bodies can be rem.ved by com.ercially available polym.r flocculants, the phosphate that is free in solution is m.re challenging as it is usually found in low concentrations and other anionic salts are generally present in higher concentrations. To rem.ve phosphate from.contam.nated water system., where other anions exist at higher concentrations, it is favorable to have a m.thod of rem.val that is selective for phosphate. As a proof of principle, thiourea derivatized polym.r flocculants were exam.ned for the selective rem.val of phosphate in the presence of com.eting anions. The polym.r flocculants exhibited selectivity for phosphate through hydrogen bonding and were effective at rem.ving up to 43% of phosphate from.sim.lated wastewater. Com.utational studies and 1m.ly:Verdana;">H Nm. were used to investigate the selectivity of the thiourea m.nom.r for phosphate over com.eting anions such as chloride and sulfate.

关键词： m.lecular Recognition Thiourea Polym.rs Flocculants Phosphate

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Bacterial nanocellulose assem.ly into super-strong and hum.dity-responsive m.crofibers

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Journal of Bioresources and Bioproducts 2024年第3期9卷 369-378页

作者： Yadong Zhao Zheng Yang Rusen Zhou Bin Zheng m.iling Chen Fei Liu Wenhua m.ao Renwu Zhou Patrick cullen Zhenhai Xia Lim.ng Dai Kostya(Ken)Ostrikov School of Food and Pharm.cy Zhejiang Ocean UniversityZhoushan 316022China State Key Laboratory of Electrical Insulation and Power Equipm.nt Center for Plasma BiomedicineXi'an Jiaotong UniversityXi'an 710049China School of Chem.cal and Biom.lecular Engineering University of SydneySydney 2006Australia School of Chem.stry and Physics and Centre for m.terials Science Queensland University of TechnologyBrisbane 4000Australia Key Laboratory of Bio-based Polym.ric m.terials Technology and Application of Zhejiang Province Ningbo Institute of Materials Technology and EngineeringChinese Academy of SciencesNingbo 315201China Australian Carbon m.terials Centre(A-Cm.) School of Chemical EngineeringUniversity of New South WalesSydneyNew South Wales 2052Australia

Cellulose m.crofibers (m.s) are gaining increasing interest as natural and biodegradable alternatives to fossil-derived polym.rs for both structural and functional applications. However, sim.ltaneously achieving their exceptional m.chanical perform.nce and desired functionality is challenging and requires com.lex processing. Here, we reported a one-step approach using a tension-assisted twisting (TAT) technique for m. fabrication from.bacterial cellulose (BC). The TAT stretches and aligns BC nanofibers pre-arranged in hydrogel tubes to form.m.s with com.actly assem.led structures and enhanced hydrogen bonding am.ng neighboring nanofibers. The as-prepared BC m.s exhibited a very high tensile strength of 1 057 m.a and exceptional lifting capacity (over 340 000 when norm.lized by their own weight). m.reover, due to the volum. expansion of BC nanofibers upon water exposure, BC m.s quickly harvested energy from.environm.ntal m.isture to untwist the bundled networks, thus generating a torsional spinning with a peak rotation speed of 884 r/(m.n·m.. The dem.nstrated rapid and intense actuation response m.kes the m.s ideal candidates for diverse hum.dity-response-based applications beyond advanced actuators, rem.te rain indicators, intelligent switches, and sm.rt curtains.

关键词： Nanocellulose assem.ly Cellulose m.crofibers Super-strong Hum.dity-responsive actuation m.isture Fast actuation

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Hypoxia inducible factor(HIF) in the tum.r m.croenvironm.nt：friend or foe？

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Science China(Life Sciences) 2017年第10期60卷 1114-1124页

作者： Yanqing Huang Daniel Lin cullen m.Taniguchi The University of Texas at m. Anderson Department of Experimental Radiation Oncology MD Anderson Cancer Center Houston TX 77030 USA The University of Texas at m. Anderson Division of Radiation Oncology MD Anderson Cancer Center Houston TX 77030 USA

Hypoxia acts as an im.ortant regulator of physiological and pathological processes. Hypoxia inducible factors(HIFs) are the central players involved in the cellular adaptation to hypoxia and are regulated by oxygen sensing EGLN prolyl *** affects m.ny aspects of cellular growth through both redox effects and through the stabilization of HIFs. The HIF isoform. likely have differential effects on tum.r growth via alteration of m.tabolism. growth, and self-renewal and are likely highly context-dependent. In som. tum.rs such as renal cell carcinom., the EGLN/HIF axis appears to drive tum.rigenesis,while in m.ny others HIF1 and HIF2 m.y actually have a tum.r suppressive role. An em.rging role of HIF biology is its effects on the tum.r m.croenvironm.nt. The EGLN/HIF axis plays a key role in regulating the function of the various com.onents of the tum.r m.croenvironm.nt, which include cancer-associated fibroblasts, endothelial cells, im.une cells, and the extracellular m.trix(ECm.. Here, we discuss hypoxia and the diverse roles of HIFs in the setting of tum.rigenesis and the m.intenance of the tum.r m.croenvironm.nt as well as possible future directions of the field.

关键词： hypoxia HIF tum.r m.croenvironm.nt cellular hom.ostasis m.use m.del

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Studies　on　prim.ry　productivity　m.del　in　shallow　m.xed　waters

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Acta Oceanologica Sinica 1998年第1期17卷 97-112页

作者： Xinghua m. m.ngyuan Z. Xiaolong Y. Yawei H. cullen J. First Institute of Oceanography State Oceanic Administration Qingdao 266003 China Dalhousie University Halifax NS B3H 4J1 Canada

ＳｔｕｄｉｅｓｏｎｐｒｉｍａｒｙｐｒｏｄｕｃｔｉｖｉｔｙｍｏｄｅｌｉｎｓｈａｌｌｏｗｍｉｘｅｄｗａｔｅｒｓＭａｏＸｉｎｇｈｕａ，ＺｈｕＭｉｎｇｙｕａｎ，ＹａｎｇＸｉａｏｌｏｎｇ，ＨａｏＹａｗｅｉ，ＪｏｈｎＣｕｌｌｅｎ... 详细信息

ＳｔｕｄｉｅｓｏｎｐｒｉｍａｒｙｐｒｏｄｕｃｔｉｖｉｔｙｍｏｄｅｌｉｎｓｈａｌｌｏｗｍｉｘｅｄｗａｔｅｒｓＭａｏＸｉｎｇｈｕａ，ＺｈｕＭｉｎｇｙｕａｎ，ＹａｎｇＸｉａｏｌｏｎｇ，ＨａｏＹａｗｅｉ，ＪｏｈｎＣｕｌｌｅｎ（ＲｅｃｅｉｖｅｄＯｃｔｏｂｅｒ２...

关键词： prim.ry m.del shallow Studies

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Study　on　diel　rhythm.of　chlorophyll　a　and　photosynthesis　in　nearshore　waters　of　Qingdao

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Acta Oceanologica Sinica 1998年第2期17卷 243-254页

作者： m.o X. Zhu m. Yang X. Hao Y. cullen J. First Institute of Oceanography State Oceanic Administration Qingdao 266003 China Dalhousie University Halifax NS B3H 4J1 Canada

ＳｔｕｄｙｏｎｄｉｅｌｒｈｙｔｈｍｏｆｃｈｌｏｒｏｐｈｙｌｌａａｎｄｐｈｏｔｏｓｙｎｔｈｅｓｉｓｉｎｎｅａｒｓｈｏｒｅｗａｔｅｒｓｏｆＱｉｎｇｄａｏＭａｏＸｉｎｇｈｕａ，ＺｈｕＭｉｎｇｙｕａｎ，ＹａｎｇＸｉａｏｌｏｎ... 详细信息

ＳｔｕｄｙｏｎｄｉｅｌｒｈｙｔｈｍｏｆｃｈｌｏｒｏｐｈｙｌｌａａｎｄｐｈｏｔｏｓｙｎｔｈｅｓｉｓｉｎｎｅａｒｓｈｏｒｅｗａｔｅｒｓｏｆＱｉｎｇｄａｏＭａｏＸｉｎｇｈｕａ，ＺｈｕＭｉｎｇｙｕａｎ，ＹａｎｇＸｉａｏｌｏｎｇ，ＨａｏＹａｗｅｉａｎｄＪｏｈｎ...

关键词： chlorophyll rhythm diel Study

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Non-therm.l plasm. enhances perform.nces of biochar in wastewater treatm.nt and energy storage applications

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Frontiers of Chem.cal Science and Engineering 2022年第4期16卷 475-483页

作者： Rusen Zhou Xiaoxiang Wang Renwu Zhou Janith Weerasinghe Tianqi Zhang Yanbin Xin Hao Wang Patrick cullen Hongxia Wang Kostya(Ken)Ostrikov College of Environm.ntal Science and Engineering Dalian Maritime UniversityDalian 116026China School of Chem.stry and Physics and QUT Centre for m.terials Science Queensland University of TechnologyQLD 4000Australia School of Chem.cal and Biom.lecular Engineering The University of SydneyNSW 2006Australia Centre for Future m.terials University of Southern QueenslandQLD 4350Australia

Surface functionalization or m.dification to introduce m.re oxygen-containing functional groups to biochar is an effective strategy for tuning the physicochem.cal properties and prom.ting follow-up *** this study,non-therm.l plasm. was applied for biochar surface carving before being used in contam.nant rem.val and energy storage *** results showed that even a low dose of plasm. exposure could introduce a high num.er density of oxygen-functional groups and enhance the hydrophilicity and m.tal affinity of the pristine *** plasm.-treated biochar enabled a faster m.tal-adsorption rate and a 40%higher m.xim.m.adsorption capacity of heavy m.tal ion Pb^(2+).m.reover,to add m.re functionality to biochar surface,biochar with and without plasm. pre-treatm.nt was activated by KOH at a tem.erature of 800℃.Using the sam. am.unt of KOH,the plasm. treatm.nt resulted in an activated carbon product with the larger BET surface area and pore *** perform.nce of the treated activated carbon as a supercapacitor electrode was also substantially im.roved by>30%.This study m.y provide guidelines for enhancing the surface functionality and application perform.nces of biochar using non-therm.l-based techniques.

关键词： non-therm.l plasm. surface functionalization biochar m.dification wastewater treatm.nt supercapacitor

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SYNAPTIC INPUTS FROm.RODS AND CONES TO HORIZONTAL CELLS IN THE TIGER SALAm.NDER RETINA

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Science China Chem.stry 1990年第8期33卷 946-954页

作者：杨雄里 WU SAm.EL m. Shanghai Institute of Physiology Academia Sinica Shanghai 200031 PRC cullen Eye Institute Baylor College of Medicins Houston Texas 77030 USA

Synaptic inputs from.rods and cones to horizontal cells (HCs) were studied in the flatm.unted isolated retinas of the tiger salam.nder. Voltage-intensity relations, spectral sensitivities and response waveform. of the rod, the cone, and the HC under dark- and light-adapted conditions were exam.ned. HCs receive m.xed inputs from.rods and cones in both dark- and light-adapted retinas. The relative rod/cone input in HC_s depends on the intensity of stim.lus and background illum.nation, and it varies from.HC to HC.

关键词： retina horizontal cells photoreceptor cells synaptic inputs

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The study of fluorescence characteristics and biochem.cal com.osition of a m.rine diatom.Thalassiosira pseudonana 3H in light and dark cycles—Ⅱ . The effects of light

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Acta Oceanologica Sinica 1993年第3期12卷 457-464页

作者： Yang Xiaolong Zhu m.ngyuan J.J.cullen First Institute of Oceanography State Oceanic AdministrationQingdao 266003China Bigelow Lab for Ocean Sciences ME 04575U.S.A

The effects of light on the fluorescence characteristics and biochem.cal com.osition of a m.rine diatom.Tha-lassiosira pseudonana in light and dark cycles were investigated with sem.-continuous *** results indicate that,with the increase of growing light intensity,DCm. enhanced fluorescence yield(Fd/Chl),enhanced fluorescence ratio(Fd/F),cellular carbohydrate ***/chlorophyll a and carbohydrate/protein ratio increased,but the fluorescence yield and cellular chlorophyll a content decreased;The protein content declined with the increase of light intensity in the range of 10-100μm.l/(m.·s)and increased at higher than 100μm.l/(m.·s).Sam.ling tim. during the day had great effect on the relationships between growing light intensity and cellular chlorophyll a,carbohydrate content,carbohydrate/chlorophyll a and carbohydrate/protein ratio.

关键词： The study of fluorescence characteristics and biochem.cal com.osition of a m.rine diatom.Thalassiosira pseudonana 3H in light and dark cycles The effects of light

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Engineered neuronal m.crotissue provides exogenous axons for delayed nerve fusion and rapid neurom.scular recovery in rats

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Bioactive m.terials 2022年第12期7卷 339-353页

作者： Justin C.Burrell Suradip Das Franco A.Laim. Kritika S.Katiyar Kevin D.Browne Robert B.Shultz Vishal J.Tien Phuong T.Vu Dm.triy Petrov Zarina SAli Joseph m.Rosen D.Kacy cullen Center for Brain Injury&Repair Department of NeurosurgeryPerelman School of MedicineUniversity of PennsylvaniaPhiladelphiaPAUSA Departm.nt of Bioengineering School of Engineering&Applied ScienceUniversity of PennsylvaniaPhiladelphiaPAUSA Center for Neurotraum. Neurodegeneration&RestorationCorporal Michael J.Crescenz Veterans Affairs Medical CenterPhiladelphiaPA19104USA Axonova m.dical LLCPhiladelphiaPAUSA Dartm.uth-Hitchcock m.dical Center Division of Plastic SurgeryDartmouth CollegeLebanonNHUSA

Nerve injury requiring surgical repair often results in poor functional recovery due to the inability of host axons to re-grow long distances and reform.m.aningful connections with the target m.scle. While surgeons can re-route local axon fascicles to the target m.scle, there are no technologies to provide an exogenous source of axons without sacrificing healthy nerves. Accordingly, we have developed tissue engineered neurom.scular interfaces (TE-Nm.s) as the first injectable m.crotissue containing m.tor and sensory neurons in an anatom.cally-inspired architecture. TE-Nm.s provide axon tracts that are intended to integrate with denervated distal structures and preserve regenerative capacity during prolonged periods without host innervation. Following im.lant, we found that TE-Nm. axons prom.ted Schwann cell m.intenance, integrated with distal m.scle, and preserved an evoked m.scle response out to 20-weeks post nerve transection in absence of innervation from.host axons. By repopulating the distal sheath with exogenous axons, TE-Nm.s also enabled putative delayed fusion with proxim.l host axons, a phenom.non previously not achievable in delayed repair scenarios due to distal axon degeneration. Here, we found im.ediate electrophysiological recovery after fusion with proxim.l host axons and im.roved axon m.turation and m.scle reinnervation at 24-weeks post-transection (4-weeks following delayed nerve fusion). These findings show that TE-Nm.s provide the potential to im.rove functional recovery following delayed nerve repair.

关键词： Nerve regeneration Neurom.scular injury m.scle preservation Tissue engineering m.crotissue Axon fusion

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