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Investigating the Absorption and Desorption Behavior of Methylene Chloride in the Poly(aryl ether ketone) Film with Different Crystallinities

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Chinese Journal of Polymer Science 2024年第2期42卷 239-246,I0009页

作者： Hong-Ru Yang Jin-dong Zhang dong-Ting Gao Gang Liu Chun-Hai Chen Jia-Nan Yao Center for Advanced Low-Dimension Materials State Key Laboratory for Modification of Chemical Fibers and Polymer MaterialsCollege of Materials Science and EngineeringDonghua UniversityShanghai201620China

Poly(aryl ether keton e)(PAEK) films with different crystallinities were obtained by controlling the cooling rate,which were subjected to the absorption and desorption of methylene chloride(CH_(2)Cl_(2)).We employed attenuated total reflection Fourier transform infrared(ATR-FTIR)spectroscopy analyses to investigate the diffusion behavior of CH_(2)Cl_(2) in PAEK films with different *** to the Fickian diffusion model,the calculated diffu sion coefficients of CH_(2)Cl_(2) in PAEK films were observed to decrease with increasing *** effect of CH_(2)Cl_(2)absorption and desorption on the mechanical properties of PAEK films with different crystallinity was further analyzed using tensile *** tensile tests exhibited that CH_(2)Cl_(2) has two concurrent effects:plasticization and solvent-induced *** scanning calorimetry(DSC) and wide-angle X-ray diffraction(WXRD) techniques further confirmed solvent-induced crystallization *** results would be beneficial to understand the solvent resistance of PAEK materials and consequently provide the practical application conditions of PAEK with a theoretical basis.

关键词： Poly(aryl ether ketone) Diffusion behavior Infrared spectra Solvent-induced crystallization Mechanical properties

Three-dimensional finite element simulation and reconstruction of jointed rock models using CT scanning and photogrammetry

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Journal of Rock Mechanics and Geotechnical Engineering 2024年第4期16卷 1348-1361页

作者： Yingxian Lang Zhengzhao Liang Zhuo dong State Key Laboratory of Coastal and Offshore Engineering Dalian University of TechnologyDalian116024China School of Energy Science and Engineering Henan Polytechnic UniversityJiaozuo454003China

The geometry of joints has a significant influence on the mechanical properties of *** simplify the curved joint shapes in rocks,the joint shape is usually treated as straight lines or planes in most laboratory experiments and numerical *** this study,the computerized tomography (CT) scanning and photogrammetry were employed to obtain the internal and surface joint structures of a limestone sample,*** describe the joint geometry,the edge detection algorithms and a three-dimensional (3D) matrix mapping method were applied to reconstruct CT-based and photogrammetry-based jointed rock *** comparison tests,the numerical uniaxial compression tests were conducted on an intact rock sample and a sample with a joint simplified to a plane using the parallel computing *** results indicate that the mechanical characteristics and failure process of jointed rocks are significantly affected by the geometry of *** presence of joints reduces the uniaxial compressive strength (UCS),elastic modulus,and released acoustic emission (AE) energy of rocks by 37%–67%,21%–24%,and 52%–90%,*** to the simplified joint sample,the proposed photogrammetry-based numerical model makes the most of the limited geometry information of *** UCS,accumulative released AE energy,and elastic modulus of the photogrammetry-based sample were found to be very close to those of the CT-based *** UCS value of the simplified joint sample (i.e.38.5 MPa) is much lower than that of the CT-based sample (i.e.72.3 MPa).Additionally,the accumulative released AE energy observed in the simplified joint sample is 3.899 times lower than that observed in the CT-based *** scanning provides a reliable means to visualize the joints in rocks,which can be used to verify the reliability of photogrammetry *** application of the photogrammetry-based sample enables detailed analysis for estimating the mechanical properties of jointed rocks.

关键词： X-ray computerized tomography(CT)scanning Photogrammetry Parallel computing Numerical simulation Uniaxial compression test Digital image processing

Bioleaching of vanadium from stone coal vanadium ore by Bacillus mucilaginosus:Influencing factors and mechanism

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International Journal of Minerals,Metallurgy and Materials 2024年第8期31卷 1828-1838页

作者： Yingbo dong Jinyu Zan Hai Lin School of Energy and Environmental Engineering University of Science and Technology BeijingBeijing 100083China Beijing Key Laboratory on Resource-oriented Treatment of Industrial Pollutants Beijing 100083China

Vanadium and its derivatives are used in various industries,including steel,metallurgy,pharmaceuticals,and aerospace *** China has massive reserves of stone coal resources,these resources have low ***,the effective extraction and recovery of metallic vanadium from stone coal is an important way to realize the efficient resource utilization of stone coal vanadium ***,Bacillus mucilaginosus was selected as the leaching *** vanadium leaching rate reached 35.5%after 20 d of bioleaching under optimal operating *** cumulative vanadium leaching rate in the contact group reached 35.5%,which was higher than that in the noncontact group(9.3%).The metabolites of ***,such as oxalic,tartaric,citric,and malic acids,dominated in bioleaching,accounting for 73.8%of the vanadium leaching ***,during leaching,the presence of stone coal stimulated the expression of carbonic anhydrase in bacterial cells,and enzyme activity increased by 1.335-1.905 *** activity positively promoted the production of metabolite organic acids,and total organic acid content increased by 39.31 mg·L^(-1),resulting in a reduction of 2.51 in the pH of the leaching system with stone *** effect favored the leaching of vanadium from stone *** force microscopy illustrated that bacterial leaching exacerbated corrosion on the surface of stone coal beyond 10 *** study provides a clear and promising strategy for exploring the bioleaching mechanism from the perspective of microbial enzyme activity and metabolites.

关键词： Bacillus mucilaginosus stone coal vanadium ore bioleaching carbonic anhydrase organic acids

Is the spatial impact of digital financial inclusion on CO_(2) emissions real?A spatial fluctuation spillover perspective

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Geoscience Frontiers 2024年第4期15卷 494-504页

作者： Jianda Wang Kangyin dong Xiaohang Ren School of International Trade and Economics University of International Business and EconomicsBeijing 100029China School of Business Central South UniversityChangsha 410083China

Digital financial inclusion(DFI)has the advantage of promoting information sharing,reducing transaction costs,and providing microloan platforms for small and medium-sized *** has also made outstanding contributions to decreasing CO_(2) ***,the volatility correlation between DFI and CO_(2) emissions is still relatively *** research uses the spatial autoregressive process with conditional heteroscedastic errors(SARspARCH)model to evaluate the spatial fluctuation spillover impacts of DFI on CO_(2) emissions in 284 Chinese cities covering the period 2011-2016 following the IPAT *** results indicate that CO_(2) emissions have significant spatial spillover and volatility *** fitted value of SARspARCH estimation results is more realistic than the SAR and spARCH *** alleviates average CO_(2) emissions in Chinese ***,spatial volatility weakens the negative influence of DFI on average carbon *** study provides insights from which governments can strengthen inter-regional communication and synergistic emission-reduction capabilities,and promote the digitization of the financial sector to achieve carbon neutrality goals.

关键词： SARspARCH model Spatial fluctuation spillover effect CO_(2)emissions Digital financial inclusion(DFI) China

Density functional theory study of B- and Si-doped carbons and their adsorption interactions with sulfur compounds

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Carbon Energy 2024年第2期6卷 195-208页

作者： Peng Guo Hong Zhang Shuliang dong Libao An College of Mechanical Engineering North China University of Science and TechnologyTangshanHebeiChina College of Life Sciences North China University of Science and TechnologyTangshanHebeiChina

Understanding the adsorption interactions between carbon materials and sulfur compounds has far-reaching impacts,in addition to their well-known important role in energy storage and conversion,such as lithium-ion *** this paper,properties of intrinsic B or Si single-atom doped,and B-Si codoped graphene(GR)and graphdiyne(GDY)were investigated by using density functional theory-based calculations,in which the optimal doping configurations were explored for potential applications in adsorbing sulfur *** showed that both B or Si single-atom doping and B-Si codoping could substantially enhance the electron transport properties of GR and GDY,improving their surface ***,B and Si atoms displayed synergistic effects for the codoped configurations,where B-Si codoped GR/GDY exhibited much better performance in the adsorption of sulfurcontaining chemicals than single-atom doped *** addition,results demonstrated that,after B-Si codoping,the adsorption energy and charge transfer amounts of GDY with sulfur compounds were much larger than those of GR,indicating that B-Si codoped GDY might be a favorable material for more effectively interacting with sulfur reagents.

关键词： adsorption density functional theory doping graphdiyne graphene sulfur compounds

Current understanding of ELF4 deficiency:a novel inborn error of immunity

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World Journal of Pediatrics 2024年第5期20卷 444-450页

作者： Hong-Qiang Du Xiao-dong Zhao Department of Rheumatology&Immunology National Clinical Research Center for Child Health and DisordersMinistry of Education Key Laboratory of Child Development and DisordersChongqing Key Laboratory of Child Rare Diseases in Infection and ImmunityChildren’s Hospital of Chongqing Medical UniversityZhongshan Er Road 136Yuzhong DistrictChongqingChina

Background ELF4 deficiency has been recently recognized as a novel disorder within the spectrum of inborn errors of immunity(IEIs),specifically categorized as a“disease of immune dysregulation.”Cases of this condition,reported by our team and others,are very limited *** such,our current knowledge of this new disease remains *** review aims to provide a brief overview of the clinical manifestations,pathogenesis,and treatment strategies for this novel *** sources A comprehensive review was conducted after an extensive literature search in the PubMed/Medline database and websites concerning transcriptional factor ELF4 and reports concerning patients with ELF4 *** search strategy was“ELF4 OR ETS-related transcription factor Elf-4 OR EL4-like factor 4 OR myeloid Elf-1-like factor”as of the time of manuscript *** The current signature manifestations of ELF4 deficiency disorder are recurrent and prolonged oral ulcer,abdominal pain,and diarrhea in pediatric *** some cases,immunodeficiency and autoimmunity can also be *** Sanger sequencing or whole exome sequencing can be used to detect variation in ELF4 *** blotting for ELF4 expression of the patient’s cells can confirm the pathogenic effect of the *** fully confirm the pathogenicity of the variant,further functional test is strongly *** and biologics are the mainstream management of ELF4 deficiency *** Pediatric males presenting with recurring ulcerations in digestive tract epithelium with or without recurrent fever should be suspected of *** atypical presentations are prominent,variations in ELF4 gene should be carefully evaluated functionally due to the complex nature of ELF4 *** of treating DEX includes use of glucocorticoid and biologics and more precise treatment needs more patients to identify and further mechanistic study.

关键词： ELF4 transcription factor Immune dysregulation Inborn errors of immunity Mechanism Recurrent infections

Towards net zero carbon buildings:Accounting the building embodied carbon and life cycle-based policy design for Greater Bay Area,China

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Geoscience Frontiers 2024年第3期15卷 284-297页

作者： Hanwei Liang Xin Bian Liang dong Collaborative Innovation Center on Forecast and Evaluation of Meteorological Disasters/Research Center of Urban Sustainable Development/School of Geographical Sciences Nanjing University of Information Science&Technology(NUIST)Nanjing 210044China Department of Architecture and Civil Engineering Chalmers University of TechnologySE-41296 GothenburgSweden Shenzhen Research Institute(SRI) City University of Hong KongShenzhenChina Department of Public and International Affairs(PIA) City University of Hong Kong999077Hong Kong Special Administrative Region School of Energy and Environment(SEE) City University of Hong Kong999077Hong Kong Special Administrative RegionChina Centre for Public Affairs and Law City University of Hong Kong999077Hong Kong Special Administrative RegionChina

Carbon mitigation of buildings is critical to promote a net-zero *** international society has vigorously promoted‘‘Net Zero Carbon Buildings”across the globe,and accounting for building carbon emissions is critical to support this *** carbon,which represents carbon emissions from the entire lifecycle of the buildings,is fundamental for realizing the idea of zero ***,only limited studies have been conducted so far that take into account the city *** paper aimed to act as a first try to account for the embodied carbon emissions in buildings in 2020 for the Guangdong-Hong Kong Macao Greater Bay Area in China(GBA).We integrated remote sensing techniques such as night-time light data(NLT)and building material flows analysis to calculate and spatialize the newly generated building material stocks(MS).Based on the MS data,we further applied life cycle assessment(LCA)to assess the embodied carbon in the *** results highlighted that over 163 million tons of embodied carbon in buildings of GBA are expected to be generated,from 497 million tons of newly generated building MS in *** embodied carbon in each life cycle stage is valuable for further lifecyclebased policy designs for:(i)supporting the updating of the green building certification system with consideration of the embodied carbon;(ii)promoting the green building material application and certification;and(iii)reducing the embodied carbon intensity from compact urban planning policy,such as the urban agglomeration policies in *** goal of this paper was to shed a light on reducing carbon emissions from the perspective of the entire lifecycle and promote the development of net zero carbon buildings in China and Asia-Pacific.

关键词： Net zero carbon building Embodied carbon Life cycle assessment Life cycle-based policies Greater Bay area

Hydrothermal liquefaction of biomass for jet fuel precursors:A review

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Chinese Chemical Letters 2024年第8期35卷 36-49页

作者： Shengfei dong Ziyu Liu Xiaoyi Yang School of Energy and Power Engineering Energy and Environment International CentreBeihang UniversityBeijing 100191China School of Aeronautic Science and Engineering Beihang UniversityBeijing 100191China

Climate change is an important issue facing the world today and carbon reduction has become the fo-cus of attention for all *** bio-fuels are an important means to achieve carbon emis-sion *** production of jet fuel precursors from biomass by hydrothermal liquefaction(HTL)has received a lot of attention due to its mild conditions and environmental *** biomass and algal biomass are considered as the second and the third generation biomasses as promising raw materials for alternative fuel *** them,lignocellulosic biomass has been extensively studied due to its wide range of sources and can be divided into one-step HTL and stepwise HTL accord-ing to the process *** biomass has been extensively studied experimentally due to its short growth cycle and the fact that it can sequester large amounts of carbon without taking up arable *** this paper,the feedstock composition of different biomasses is reviewed for the HTL of biomass.A detailed review of the process characteristics,reaction pathways and influencing factors for the HTL pro-duction of jet fuel precursors from lignocellulosic biomass and algal biomass is also *** references are provided for further process optimization and bio-crude quality upgrading.

关键词： Hydrothermal liquefaction(HTL) Lignocellulosic biomass Microalgae Bio-crude Jet fuel precursors

Design strategies for rechargeable aqueous metal-ion batteries

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Science China Chemistry 2024年第1期67卷 165-190页

作者： Yang Li Xin Zhao Yifu Gao Yichen Ding Zhichun Si Liubing dong dong Zhou Feiyu Kang Tsinghua Shenzhen International Graduate School Tsinghua UniversityShenzhen 518055China College of Chemistry and Materials Science Jinan UniversityGuangzhou 511443China

Rechargeable aqueous metal-ion batteries(AMBs)have attracted extensive scientific and commercial interest due to their potential for cost-effective,highly safe,and scalable stationary energy ***,their limited output voltage,inadequate energy density,and poor reversibility of ambiguous electrode reactions in aqueous electrolytes strongly limit their practical *** review aims to elucidate the challenges of existing AMBs from the material design to whole device *** summarize the emerging electrochemistry,fundamental properties,and key issues in interfacial behaviors of various classes of prevailing AMBs,including aqueous alkali metal-ion batteries and multivalent-ion batteries,and present an appraisal of recent advances for addressing the performance ***,the progress of zinc-ion batteries is highlighted to provide a ubiquitous guideline for their commercialization in the grid-scale energy ***,we figure out the dominating general challenges for achieving high-performance AMBs,laying out a perspective for future breakthroughs.

关键词： aqueous metal-ion batteries aqueous alkali metal-ion batteries zinc-ion batteries interfacial behavior stationary energy storage