检索结果-南通市图书馆

Multivariate chemical analysis:From sensors to sensor arrays

在线全文

学校读者我要写书评

暂无评论

Chinese Chemical Letters 2024年第7期35卷 14-24页

作者： Xueling Yu Lixing Fu Tong Wang Zhixin liu Na Niu Ligang Chen College of Chemistry Chemical Engineering and Resource UtilizationKey Laboratory of Forest Plant EcologyNortheast Forestry UniversityHarbin 150040China

Chemical sensor arrays can obtain more comprehensive analyte information through high-dimensional *** is of great significance in the analysis of multi-component complex *** review summarizes the development and status of chemical sensor *** focused on the design of chemical sensor arrays based on various sensing *** addition,several pattern recognition methods in chemometrics are *** applications of chemical sensor arrays in food monitoring,medical diagnosis,and environmental monitoring are *** on the analysis of the limitations of current sensor array technology,the direction of the array is also *** review aims to help the broad readership understand the research state of chemical sensor arrays and their development prospects.

关键词： Chemical sensor arrays Sensing materials Pattern recognition methods Analytical application

Intelligent Dynamic Heterogeneous Redundancy Architecture for IoT Systems

在线全文

学校读者我要写书评

暂无评论

China Communications 2024年第7期21卷 291-306页

作者： Zhang Han Wang Yu liu Hao Lin Hongyu Chen Liquan School of Cyber Science and Engineering Southeast UniversityNanjing 211102China Purple Mountain Laboratories Nanjing 211111China ZTE Corporation Nanjing 210012China Carbon Peaking&Carbon Neutrality Application Technology R&D Institute Nanjing University of Posts and TelecommunicationsNanjing 210002China

The conventional dynamic heterogeneous redundancy(DHR)architecture suffers from the security threats caused by the stability differences and similar vulnerabilities among the *** overcome these challenges,we propose an intelligent DHR architecture,which is more feasible by intelligently combining the random distribution based dynamic scheduling algorithm(RD-DS)and information weight and heterogeneity based arbitrament(IWHA)*** the proposed architecture,the random distribution function and information weight are employed to achieve the optimal selection of executors in the process of RD-DS,which avoids the case that some executors fail to be selected due to their stability difference in the conventional DHR ***,through introducing the heterogeneity to restrict the information weights in the procedure of the IWHA,the proposed architecture solves the common mode escape issue caused by the existence of multiple identical error output results of similar *** experimental results characterize that the proposed architecture outperforms in heterogeneity,scheduling times,security,and stability over the conventional DHR architecture under the same conditions.

关键词： dynamic heterogeneous redundancy heterogeneity IoT security security defense

Modeling displacement flow inside a full-length casing string for well cementing

在线全文

学校读者我要写书评

暂无评论

Petroleum Research 2024年第1期9卷 1-16页

作者： Hu Dai Ali Eslami Jason Schneider Gefei liu Fred Schwering Pegasus Vertex Inc.USA Laval University Canada Sanjel Energy Services Canada Athabasca Oil Corporation Canada

While computer modeling of annular displacement efficiency is widely applied in cementing engineering,modeling the displacement flow inside a casing or drill string for cementing operations has received less *** predicting displacement efficiency inside a full-length pipe is desired by cementing engineers,the attempt of developing a model with both efficiency and accuracy faces *** to computer simulators for this purpose is *** with annular flow,the displacement flow inside pipe,although within a simpler geometry and without eccentricity effect,is not simpler in physics,modelling strategy and predictability,because a variety of flow patterns and flow instabilities can develop to create complicated fluid *** this paper,we present an integrated numerical model developed to simulate displacement flows inside a full-length pipe,which connects an existing annulus model to enable complete displacement simulations of cementing *** model uses three-dimensional grid to solve fluid concentrations with degrees of mixing,and incorporates flow instability detection and flow regime *** in cementing,the model accounts for effects of pumping rate,well inclination,pipe rotation,fluid densities,rheological parameters and *** computationally efficient model does not rely on high-resolution mesh as often required by conventional Computational Fluid Dynamics models,thus it is suitable to be implemented in a cementing software for daily use by well cementing *** methodology of the model is discussed in detail in this *** validate the model,we examine simulation results against experimental results obtained in our laboratory tests and CFD simulations;acceptable agreement is found under different testing *** also presented two case studies of real cementing jobs with cement evaluation logs compared to simulation results,showing that the model can predict consistent displacement efficie

关键词： Inside pipe displacement Displacement efficiency Numerical model Primary cementing Displacement flow

Designing unimolecular photoinitiator by installing NHPI esters along the TX backbone for acrylate photopolymerization and their applications in coatings and 3D printing

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Chinese Chemical Letters 2024年第7期35卷 417-421页

作者： Yi Zhu Jingyan Zhang Yuchao Zhang Ying Chen Guanghui An Ren liu Key Laboratory of Synthetic and Biological Colloids Ministry of EducationSchool of Chemical and Material EngineeringJiangnan UniversityWuxi 214122China International Research Center for Photoresponsive Molecules and Materials Jiangnan UniversityWuxi 214122China School of Chemistry and Materials Science Heilongjiang UniversityHarbin 150080China Scientific Experiment Center Hangzhou Institute of Medicine(HIM)Chinese Academy of SciencesHangzhou 310022China

Developing efficient and long wavelength sensitive unimolecular photoinitiators(PIs)is still facing a great *** this work,a series of thioxanthone-based N-hydroxyphthalimide esters(TX-NHPIEs)were synthesized by installing NHPIEs along the TX backbone and *** investigated TX-NHPIEs have a 60 nm redshift and demonstrate sterling initiating efficiency for free radical photopolymerization(FRP)under LED@450 nm light irradiation compared with the commercialized isopropylthioxanthone(ITX).Real-time1Hnuclear magnetic resonance(1H NMR),electron spin resonance(ESR),decarboxylation and gas chromatograph-mass spectrometer(GC–MS)experiments and density functional theory(DFT)reveal that TX-NHPIEs can generate one alkyl radical and one N-centered iminyl radical,which can initiate FRP directly and indirectly,*** other words,TX-NHPIEs absorb one photon and can generate two active radicals,which break through the limitations of common ***-NHPIE-Cpe demonstrates the highest initiating efficiency,and its application in coatings and 3D printing was also studied,indicating TX-NHPIEs have broad potential applications in photopolymerization processes.

关键词： Photopolymerization Photoinitiator Energy transfer Thioxanthone N-Hydroxyphthalimide ester

Interferon-induced MXB protein restricts vimentin-dependent viral infection

在线全文

学校读者我要写书评

暂无评论

Acta Pharmaceutica Sinica B 2024年第6期14卷 2520-2536页

作者： dongrong Yi Ni An Quanjie Li Qian liu Huihan Shao Rui Zhou Jing Wang Yongxin Zhang Ling Ma Fei Guo Xiaoyu Li zhenlong liu Shan Cen Institute of Medicinal Biotechnology Chinese Academy of Medical ScienceBeijing 100050China Institute of Pathogen Biology Chinese Academy of Medical ScienceBeijing 100730China Lady Davis Institute for Medical Research Jewish General HospitalMontrealQuebec H3T 1E2Canada

Type I interferon(IFN)inhibits a wide spectrum of viruses through stimulating the expression of antiviral *** an IFN-induced protein,myxovirus resistance B(MXB)protein was reported to inhibit multiple highly pathogenic human *** remains to be determined whether MXB employs a common mechanism to restrict different ***,we find that IFN alters the subcellular localization of hundreds of host proteins,and this IFN effect is partially lost upon MXB *** results of our mechanistic study reveal that MXB recognizes vimentin(VIM)and recruits protein kinase B(AKT)to phosphorylate VIM at amino acid S38,which leads to reorganization of the VIM network and impairment of intracellular trafficking of virus protein complexes,hence causing a restriction of virus *** results highlight a new function of MXB in modulating VIM-mediated trafficking,which may lead towards a novel broad-spectrum antiviral strategy to control a large group of viruses that depend on VIM for successful replication.

关键词： MXB Vimentin Broad antiviral strategy Cytoskeleton network AKT

Uncertainty quantification of inverse analysis for geomaterials using probabilistic programming

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Journal of Rock Mechanics and Geotechnical Engineering 2024年第3期16卷 895-908页

作者： Hongbo Zhao Shaojun Li Xiaoyu Zang Xinyi liu Lin Zhang Jiaolong Ren School of Civil Engineering and Geomatics Shandong University of TechnologyZibo255000China State Key Laboratory of Geomechanics and Geotechnical Engineering Institute of Rock and Soil MechanicsChinese Academy of SciencesWuhan430071China

Uncertainty is an essentially challenging for safe construction and long-term stability of geotechnical *** inverse analysis is commonly utilized to determine the physico-mechanical ***,conventional inverse analysis cannot deal with uncertainty in geotechnical and geological *** this study,a framework was developed to evaluate and quantify uncertainty in inverse analysis based on the reduced-order model(ROM)and probabilistic *** ROM was utilized to capture the mechanical and deformation properties of surrounding rock mass in geomechanical *** programming was employed to evaluate uncertainty during construction in geotechnical engineering.A circular tunnel was then used to illustrate the proposed framework using analytical and numerical *** results show that the geomechanical parameters and associated uncertainty can be properly obtained and the proposed framework can capture the mechanical behaviors under ***,a slope case was employed to demonstrate the performance of the developed *** results prove that the proposed framework provides a scientific,feasible,and effective tool to characterize the properties and physical mechanism of geomaterials under uncertainty in geotechnical engineering problems.

关键词： Geological engineering Geotechnical engineering Inverse analysis Uncertainty quantification Probabilistic programming

Quantitative characterization of the brittleness of deep shales by integrating mineral content,elastic parameters,in situ stress conditions and logging analysis

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

International Journal of Coal Science & Technology 2024年第1期11卷 167-179页

作者： Tongtong Luo Jianguo Wang Li Chen Chaoya Sun Qian liu Fenggang Wang CCDC Geological Exploration&Development Research Institute Chengdu610056SichuanChina China University of Petroleum(Beijing) ChangpingBeijing102249China Exploration and Development Department of Chongqing Shale Gas Exploration and Development Co. Ltd.Chongqing834000China

Deep shale reservoirs(3500–4500 m)exhibit significantly different stress states than moderately deep shale reservoirs(2000–3500 m).As a result,the brittleness response mechanisms of deep shales are also *** is urgent to investigate methods to evaluate the brittleness of deep shales to meet the increasingly urgent needs of deep shale gas *** this paper,the quotient of Young’s modulus divided by Poisson’s ratio based on triaxial compression tests under in situ stress conditions is taken as SSBV(Static Standard Brittleness Value).A new and pragmatic technique is developed to determine the static brittleness index that considers elastic parameters,the mineral content,and the in situ stress conditions(BIEMS).The coefficient of determination between BIEMS and SSBV reaches 0.555 for experimental data and 0.805 for field *** coefficient is higher than that of other brittleness indices when compared to *** can offer detailed insights into shale brittleness under various conditions,including different mineral compositions,depths,and stress *** technique can provide a solid data-based foundation for the selection of‘sweet spots’for single-well engineering and the comparison of the brittleness of shale gas production layers in different areas.

关键词： Deep shale reservoirs Brittleness Pressure effect Evaluation method Longmaxi formation Sichuan Basin

Chatter suppression techniques in milling processes:A state of the art review

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Chinese Journal of Aeronautics 2024年第7期37卷 1-23页

作者： zhenmin LI Qinghua SONG Peijian JIN Zhanqiang liu Bing WANG Haifeng MA Key Laboratory of High Efficiency and Clean Mechanical Manufacture Ministry of EducationSchool of Mechanical EngineeringShandong UniversityJinan 250061China National Demonstration Center for Experimental Mechanical Engineering Education Shandong UniversityJinan 250061China

Chatter in the machining system can result in a decrease in tool life,poor surface finish,conservative cutting parameters,*** many review papers promoting the understanding and research of this area,chatter suppression techniques are generally discussed within limited pages in the framework of comprehensive chatter-related *** recent years,the developments of smart materials,advanced sensing techniques,and more effective control strategies have led to some new progress in chatter ***,the widely used thin-walled parts present more and more severe machining challenges in their milling *** the above deficiencies,this paper summarizes the current state of the art in milling chatter *** classifications of chatter suppression techniques are proposed according to the working principle and control *** on the new classified framework,the mechanism and comparisons of different chatter suppression strategies are ***,the current challenges and potential tendencies of milling chatter suppression techniques are ***,integration,compactness,adaptability to workpiece geometry,and the collaboration of multiple control methods are predicted to be important trends in the future.

关键词： Active control Chatter suppression Damping Milling Regenerative effect

Ni-Catalyzed Enantioselective Difunctionalization of Alkynes to Azepine Derivatives Bearing a Quaternary Center and an Unprotected Imine

在线全文

学校读者我要写书评

暂无评论

Chinese Journal of Chemistry 2024年第8期42卷 873-878页

作者： Jian Long Zhiwu Lu Xiao-Lin Li Peng Xue Wen-Bo liu Engineering Research Center of Organosilicon Compounds&Materials(Ministry of Education)and College of Chemistry and Molecular Sciences Wuhan UniversityWuhanHubei430072 China

Comprehensive Summary,The azepine ring is a prominent structural scaffold in biologically significant molecules. In this study, we present a Ni(II)-catalyzed asymmetric difunctionalization of alkynes, involving intermolecular regioselective arylation and intramolecular nitrile addition, enabling the synthesis of enantioenriched azepine derivatives. This reaction simultaneously installs an all-carbon quaternary stereocenter and introduces an unprotected imine functionality, showing great promise for subsequent transformations. The reaction exhibits good tolerance toward various functional groups, resulting in high yields and enantioselectivities. The synthetic utility of this methodology is further demonstrated through gram-scale synthesis and product derivatization. This research offers an efficient approach to the synthesis of seven-membered nitrogen heterocycles.

关键词： Nickel Asymmetric catalysis N-Heterocycles Alkyne functionalization Quaternary centers