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Reversibly sensitizing-storing-releasing ^(1)O_(2) within a single platinum(Ⅱ)-acetylide-based metallacycle molecule via laser power modulation

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Science China Chemistry 2024年第2期67卷 604-611页

作者： Ruyi Zhou Wen Lv bo li bo Yu Sudi Zhang Yucheng Zhou Shujuan liu Qiang Zhao State Key Laboratory of Organic Electronics and Information Displays&Jiangsu Key Laboratory for Biosensors Institute of Advanced Materials(IAM)&Institute of Flexible Electronics(Future Technology)Nanjing University of Posts and Telecommunications(NUPT)Nanjing210023China College of Electronic and Optical Engineering&College of Flexible Electronics(Future Technology) Jiangsu Province Engineering Research Center for Fabrication and Application of Special Optical Fiber Materials and DevicesNanjing University of Posts and Telecommunications(NUPT)Nanjing210023China

Tumor hypoxia severely limits the therapeutic efficacy of photodynamic therapy(PDT) for solid tumors,which is highly dependent on tissue oxygen *** this study,we developed a platinum(Ⅱ)-acetylide-based metallacycle compound bearing six 1,4-dimethylnaphthalenes(DMN) groups,and controlled the photodynamic and photothermal effects of the compound by adjusting the power of 730 nm laser to achieve reversible sensitization,storage and release of 1~O_(2) within a single *** compound formed nanoparticles by self-assembly and exhibited good water solubility and *** laser irradiation,the strong spin-orbit coupling of platinum atoms in the metallacycle facilitated 1~O_(2) *** produced 1~O_(2) was captured by the DMN carriers and transported into the hypoxic tumor,where 1~O_(2) release was triggered owing to the good photothermal effect of the extended conjugation of the *** therapy,the metallacycle serving as a photosensitizer,1~O_(2) carrier,and photothermal reagent,achieved the synergistic therapy of PDT/PTT,demonstrating the versatility of the *** study proposes a new strategy to develop phototherapy agents that are suitable for hypoxic tumors.

关键词： metallacycles singlet oxygen endoperoxides near-infrared absorption synergistic treatment

Low-temperature replacement construction of three-dimensional corrosion-resistant interface for deeply rechargeable Zn metal batteries

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Nano Materials Science 2024年第3期6卷 329-336页

作者： Jinze li Daniel Rohrens Gianluca Dalfollo Xiaochao Wu Ziheng Lu Qiang Gao bo Han Ruimin sun Chenggang Zhou Jindi Wang Zhao Cai Faculty of Materials Science and Chemistry China University of GeosciencesWuhan430074China Institute of Inorganic Chemistry RWTH Aachen UniversityAachen52074Germany Microsoft Research AI4Science Beijing10080China Institute of New Energy on Chemical Storage and Power Sources College of Applied Chemistry and Environmental EngineeringYancheng Teachers UniversityYancheng224000China

Aqueous Zn batteries are promising candidates for grid-scale renewable energy *** electrodes have been widely investigated and applied as anode materials for aqueous Zn batteries,however,they suffer from limited surface area and severe interfacial issues including metallic dendrites and corrosion side reactions,limiting the depth of discharge(DOD)of the foil electrode ***,a low-temperature replacement reaction is utilized to in-situ construct a three-dimensional(3D)corrosion-resistant interface for deeply rechargeable Zn foil ***,the deliberate low-temperature environment controlled the replacement rate between polycrystalline Zn metal and oxalic acid,producing a Zn foil electrode with distinct 3D corrosion-resistant interface(3DCI-Zn),which differed from conventional two-dimensional(2D)protective structure and showed an order of magnitude higher surface ***,the 3DCI-Zn electrode exhibited dendrite-free and anticorrosion properties,and achieved stable plating/stripping performance for 1000 h at 10 mA cm^(-2)and 10 mAh cm^(-2)with a remarkable DOD of 79%.After pairing with a MnO2cathode with a high areal capacity of 4.2 mAh cm^(-2),the pouch cells delivered 168 Wh L^(-1)and a capacity retention of 89.7%after 100 cycles with a low negative/positive(N/P)ratio of 3:1.

关键词： Aqueous batteries Foil electrodes Depth of discharge Dendrites Corrosion side reactions

A novel method for AFRPs burrs removal:Principle of mechanochemo-induced fiber fracture

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Chinese Journal of Aeronautics 2024年第7期37卷 522-538页

作者： Jie XU bo li Pingfa FENG Qiang WANG Feng FENG Division of Advanced Manufacturing Tsinghua Shenzhen International Graduate SchoolTsinghua UniversityShenzhen 518055China Department of Mechanical Engineering Tsinghua UniversityBeijing 100084China Changhe Aircraft Industry(Group)Co.Ltd Jingdezhen 333000China

Burrs generated during the machining of Aramid-Fiber-Reinforced Composites(AFRPs)pose a challenge for the production efficiency of aircraft and helicopter housing *** studies have generally attempted to suppress burrs by referring to delamination suppression *** contrast to stratification,burrs are remediable machining *** such,a mechanochemical method with burrs trimming technological strategy are implemented to effectively combat ***,we clarify the mechanism by which aramid fibers cannot be cut off using analytical and numerical *** addition,the mechanism of fiber fracture with Modified Polyurethane Reactive Polymer(M-PUR),and development of anti-burr devices(thermostatic adhesive sealed generator)are ***,the experimental results show that the reduction rate in burr length is 87%-91%through the mechanochemical *** method not only opens a new avenue to solve the burr problem of aramid fibers but also builds an interdisciplinary bridge between polymer science and composite machining.

关键词： Mechanochemical method Burrs Orthogonal cutting Aramid fiber-reinforced composites Milling

Prediction of undeformed chip thickness distribution and surface roughness in ultrasonic vibration grinding of inner hole of bearings

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Journal of Zhejiang University-Science A(Applied Physics & Engineering) 2024年第4期25卷 311-323页

作者： Yanqin li Daohui XIANG Guofu GAO Feng JIAO bo ZHAO School of Mechanical and Power Engineering Henan Polytechnic UniversityJiaozuo 454000China

Ultrasonic vibration grinding differs from traditional grinding in terms of its material removal *** randomness of grain-workpiece interaction in ultrasonic vibration grinding can produce variable chips and impact the surface roughness of ***,previous studies used iterative method to calculate the unformed chip thickness(UCT),which has low computational *** this study,a symbolic difference method is proposed to calculate the *** UCT distributions are obtained to describe the stochastic interaction characteristics of ultrasonic grinding ***,the UCT distribution characteristics under different machining parameters are ***,a surface roughness prediction model is established based on the UCT ***,the correctness of the model is verified by *** study provides a quick and accurate method for predicting surface roughness in longitudinal ultrasonic vibration grinding.

关键词： Ultrasonic vibration grinding Undeformed chip thickness(UCT) Distribution characteristics Surface roughness

Optimal Planning of Hybrid AC/DC Low-voltage Distribution Networks Considering DC Conversion of Three-phase Four-wire Low-voltage AC Systems

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Journal of Modern Power Systems and Clean Energy 2024年第1期12卷 141-153页

作者： bo Zhang Lu Zhang Wei Tang Gen li Chen Wang the College of Information and Electrical Engineering China Agricultural UniversityBeijing 100083China the Electric Energy Group Department of Engineering TechnologyTechnical University of Denmark(DTU)2750 BallerupDenmark the Power Distribution Technology Center State Grid Beijing Electric Power Research InstituteBeijing 100075China

The increasing integration of distributed household photovoltaics(PVs)and electric vehicles(EVs)may further ag gravate voltage violations and unbalance of low-voltage distribu tion networks(LVDNs).DC distribution networks can increase the accommodation of PVs and EVs and mitigate mutilple pow er quality problems by the flexible power regulation capability of voltage source *** paper proposes schemes to es tablish hybrid AC/DC LVDNs considering the conversion of the existing three-phase four-wire low-voltage AC systems to DC op *** characteristics and DC conversion constraints of typical LVDNs are *** addition,converter configura tions for typical LVDNs are proposed based on the three-phase four-wire characteristics and quantitative analysis of various DC ***,an optimal planning method of hybrid AC/DC LVDNs is proposed,which is modeled as a bi-level programming model considering the annual investments and three-phase *** are conducted to verify the effectiveness of the proposed optimal planning *** ulation results show that the proposed optimal planning method can increase the integration of PVs while simultaneously reduc ing issues related to voltage violation and unbalance.

关键词： Optimal planning low-voltage distribution net work three-phase unbalance DC conversion

Transferable adversarial slow feature extraction network for few-shot quality prediction in coal-to-ethylene glycol process

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Chinese Journal of Chemical Engineering 2024年第7期71卷 258-271页

作者： Cheng Yang Chao Jiang Guo Yu Jun li Cuimei bo School of Electrical Engineering and Control Science Nanjing Tech UniversityNanjing 211816China Department of Intelligent Manufacturing Nanjing Tech UniversityNanjing 210009China

In the coal-to-ethylene glycol(CTEG)process,precisely estimating quality variables is crucial for process monitoring,optimization,and control.A significant challenge in this regard is relying on offline laboratory analysis to obtain these variables,which often incurs substantial monetary costs and significant time *** resulting few-shot learning scenarios present a hurdle to the efficient development of predictive *** address this issue,our study introduces the transferable adversarial slow feature extraction network(TASF-Net),an innovative approach designed specifically for few-shot quality prediction in the CTEG ***-Net uniquely integrates the slowness principle with a deep Bayesian framework,effectively capturing the nonlinear and inertial characteristics of the CTEG ***,the model employs a variable attention mechanism to identify quality-related input variables adaptively at each time step.A key strength of TASF-Net lies in its ability to navigate the complex measurement noise,outliers,and system interference typical in CTEG *** learning strategy using a min-max game is adopted to improve its robustness and ability to model irregular industrial data accurately and ***,an incremental refining transfer learning framework is designed to further improve few-shot prediction performance achieved by transferring knowledge from the pretrained model on the source domain to the target *** effectiveness and superiority of TASF-Net have been empirically validated using a real-world CTEG *** with some state-of-the-art methods,TASF-Net demonstrates exceptional capability in addressing the intricate challenges for few-shot quality prediction in the CTEG process.

关键词： Chemical process Neural networks Slowness principle Transfer learning Prediction

Probabilistic seismic inversion based on physics-guided deep mixture density network

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Petroleum Science 2024年第3期21卷 1611-1631页

作者： Qian-Hao sun Zhao-Yun Zong Xin li National Key Laboratory of Deep Oil and Gas China University of Petroleum(East China)Qingdao266580ShandongChina Laoshan Laboratory Qingdao266580ShandongChina CNOOC Research Institute Ltd. Beijing100028China

Deterministic inversion based on deep learning has been widely utilized in model parameters *** by logging data,seismic data,wavelet and modeling operator,deterministic inversion based on deep learning can establish nonlinear relationships between seismic data and model ***,seismic data lacks low-frequency and contains noise,which increases the non-uniqueness of the *** conventional inversion method based on deep learning can only establish the deterministic relationship between seismic data and parameters,and cannot quantify the uncertainty of *** order to quickly quantify the uncertainty,a physics-guided deep mixture density network(PG-DMDN)is established by combining the mixture density network(MDN)with the deep neural network(DNN).Compared with Bayesian neural network(BNN)and network dropout,PG-DMDN has lower computing cost and shorter training time.A low-frequency model is introduced in the training process of the network to help the network learn the nonlinear relationship between narrowband seismic data and low-frequency *** addition,the block constraints are added to the PG-DMDN framework to improve the horizontal continuity of the inversion *** illustrate the benefits of proposed method,the PG-DMDN is compared with existing semi-supervised inversion *** synthetic data examples of Marmousi II model are utilized to quantify the influence of forward modeling part,low-frequency model,noise and the pseudo-wells number on inversion results,and prove the feasibility and stability of the proposed *** addition,the robustness and generality of the proposed method are verified by the field seismic data.

关键词： Deep learning Probabilistic inversion Physics-guided Deep mixture density network

A review on the chemical speciation and influencing factors of heavy metals in Municipal Solid Waste landfill humus

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Waste Disposal and Sustainable Energy 2024年第2期6卷 209-218页

作者： Qiongyu sun bo sun Defeng Wang Yuyuan Pu Mingxiu Zhan Xu Xu Jinqing Wang Wentao Jiao College of Metrology and Measurement Engineering China Jiliang UniversityHangzhou 310018Zhejiang ProvinceChina Zhongke Hualu Soil Remediation Engineering Co. LtdDezhou 253011Shandong ProvinceChina Zhejiang Environmental Protection Group Co. LtdHangzhou 310020Zhejiang ProvinceChina Institute for Thermal Power Engineering Zhejiang UniversityHangzhou 310027Zhejiang ProvinceChina Research Center for Eco-Environmental Sciences Chinese Academy of SciencesHaidian District18 Shuangqing RoadBeijing 100085China

Heavy metal pollution in landfill humus can cause serious environmental problems and may endanger soil ecosystems and human *** biological toxicity of heavy metals is not only related to their total amount but also influenced to a greater extent by the distribution of their chemical *** the different chemical speciation and proportions of heavy metals can provide a more comprehensive and accurate understanding of the pollution characteristics and biological toxic-ity of heavy metals in landfill *** on a review of the relevant literature,this paper systematically summarizes the recent research status of typical heavy metal chemical speciation in landfill *** chemical speciation is diverse and *** instance,heavy metals in residual states and organically bound states have little impact on organisms,while heavy metals in exchangeable states and Fe-Mn oxide states can easily migrate and *** chemical speciation of heavy metals is affected by many factors,among which the soil pH and organic matter content are some of the most important ***,the existing gaps in the current research on the chemical speciation of heavy metals in landfills are described and future research directions are *** work provides a theoretical reference for researching the restoration of heavy metal-contaminated humus soil and the resource utilization of humus soil.

关键词： Landflls Humus soil containing heavy metal-Chemical speciation Distribution characteristics Influencing factors

Compositionally graded high-voltage P2-type cathode with superior structural stability and redox kinetics for advanced Na-ion batteries

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Nano Research 2024年第4期17卷 2755-2762页

作者： Peiyu Hou Mohan Dong Zhenbo sun Feng li School of Physics and Technology University of JinanJinan 250022China

Layered P2-type cathodes with high voltage,large capacity,and easy synthesis show great potential for developing sodium(Na)-ion batteries(NIBs).However,the P2–O2 phase transition makes their structural degradation and the Na^(+)/vacancy ordering lowers their redox ***,we rationally propose a compositionally graded P2-type cathode,where nickel(Ni)and manganese(Mn)fractions decrease gradually,and cobalt(Co)content increases contiguously from the inside to the outside of a secondary *** these particles,the Ni/Mn-based compound delivers high capacity and high *** the surface of particles,the Co/Mn-based solid solution offers a stable buffer *** from these synergistic effects,this graded P2-type cathode shows the elimination of P2–O2 transformation even when charged to 4.4 V,which enables good structural stability,maintaining capacity retention reaching~80%within 300 ***,the Na^(+)/vacancy ordering superstructure is further suppressed,and the Na^(+)diffusion kinetics is significantly *** proposed graded structure with optimized chemical composition offers a new perspective for eliminating the unwanted phase transition and thus enhancing the electrochemistry of high-voltage layered cathodes for advanced NIBs.

关键词： Na-ion battery P2-type cathode composition regulation phase transition redox stability