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A fibrous hydroelectric generator derived from eco-friendly sodium alginate for low-grade energy harvesting

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Frontiers in Energy 2024年第4期18卷 474-482页

作者： feng GONG Jiaming SONG Haotian chen Hao li Runnan HUANG Yuhang JING Peng YANG Junjie feng Rui XIAO Key Laboratory of Energy Thermal Conversion and Control of the Ministry of Education School of Energy and EnvironmentSoutheast UniversityNanjing 210096China

With the development of renewable energy technologies,the recovery and utilization of low-grade energy based on hydroelectric effect have drawn much attention owing to its environmental ***,a novel hydroelectric generator utilizing sodium alginategraphene oxide(SA-GO)fibers is proposed,which is ecofriendly and *** fibers with a length of 5 cm and a diameter of 0.15 mm can generate an open circuit voltage(Voc)of approximately 0.25 V and a short circuit current(Isc)of 4µ*** connecting SA-GO fibers in either series or parallel,this combination can power some electronic ***,these fibers enable the recovery of low-grade energy from the atmosphere or around the human *** experimental and theoretical analysis confirm that the directional flow of protons driven by water molecules is the main mechanism for power generation of SA-GO *** study not only presents a simple energy transformation method that is expected to be applied to our daily life,but also provides a novel idea for the design of humidity electricity-generation devices.

关键词： fibrous hydroelectric generator sodium alginate(SA) graphene oxide(GO) power generation

Selective leaching of calcium from mechanically activated mixed rare earth concentrate

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Journal of Rare Earths 2024年第6期42卷 1149-1156,I0006页

作者： Jiang liu Bingxue chen Yuanqi feng Yijun Cao Yukun Huang Yuan Shi Meng li Zhongyuan Critical Metals Laboratory School of Chemical EngineeringZhengzhou UniversityZhengzhou450001China State Key Laboratory of Advanced Processing and Recycling of Nonferrous Metals Lanzhou University of TechnologyLanzhou730050China

The loss of rare earths(REs)takes place during the pre-decalcification process of mixed rare earth *** an effort to reduce such RE loss,a novel idea to improve the leaching selectivity of Ca to REs by applying selective mechanical activation was ***,regarding the key minerals affecting the leaching selectivity of Ca to REs,the differences in the mechanical activation behaviors of CaF_(2) and REFCO_(3) were studied,and we find that the lattice strain of CaF_(2) increases from 0.21%to 0.42%,whereas that of REFCO_(3) increases from 0.31%to 0.40%.Notably,CaF_(2) demonstrates a larger lattice strain than REFCO_(3),indicating greater mechanical activation energy storage and higher leaching ***,the HCl leaching process was studied.A significant leaching selectivity of Ca to REs,from 21.6 to 35.1,is achieved through mechanical *** Ca leaching rate reaches 80.7%when the RE loss is 2.3%in the activated *** study provides an novel approach for achieving selective extraction of specific components via mechanical activation pretreatment.

关键词： Mixed rare earth concentrate Pre-decalcification Selective mechanical activation Selective leaching

Suppressing dendritic metallic li formation on graphite anode under battery fast charging

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Journal of Energy Chemistry 2024年第4期91卷 484-500页

作者： Shiyu liu Baoqi Gu Zihe chen Renming Zhan Xiancheng Wang Ruikang feng Yongming Sun Wuhan National Laboratory for Optoelectronics Huazhong University of Science and TechnologyWuhan 430074HubeiChina

lithium-ion batteries(liBs)with fast-charging capability are essential for enhancing consumer experience and accelerating the global market adoption of electric ***,achieving fast-charging capability without compromising energy density,cycling lifespan,and safety of liBs remains a significant challenge due to the formation of dendritic li metal on graphite anode under fast charging *** view of this,the fundamentals for the dendritic metallic li formation and the strategies for suppressing metallic li plating based on analyzing the entire li^(+)transport pathway at the anode including electrolyte,pore structure of electrode,and surface and bulk of materials are summarized and discussed in this ***,we highlight the importance of designing thick electrodes with fast li^(+)transport kinetics and comprehensively understanding the interaction between solid electrolyte interphase(SEI)and li^(+)migration in order to avoid the formation of dendritic li metal in practical fast-charging ***,the regulation of li metal plating with plane morphology,instead of dendritic structure,on the surface of graphite electrode under fast-charging condition is analyzed as a future direction to achieve higher energy density of batteries without safety concerns.

关键词： Safety Fast-charging lithium-ion batteries Dendritic metallic lithium li^(+) transport

Regioselective and asymmetric allylic alkylation of vinyl epoxides for the construction of allylic alcohols via synergistic catalysis

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Science China Chemistry 2024年第2期67卷 542-550页

作者： Min chen Longqing Yang Yuzhen li Yinhe Qu Guihua Pan Xiaoming feng Xiaohua liu Key Laboratory of Green Chemistry&Technology Ministry of EducationCollege of ChemistrySichuan UniversityChengdu610064China

A highly efficient asymmetric allylic alkylation of cyclic and acyclic carbon nucleophiles with vinyl epoxides has been developed,which exhibits good functional group compatibility,high atomic and step *** protocol utilizes a strategy of synergistic catalysis with a chiral N,N'-dioxide/Ni~Ⅱ complex and an achiral Pd~0 catalyst,generating a series of multisubstituted allylic alcohols with a quaternary carbon stereocenter in high yield and excellent regio-,Z/E-and enantioselectivity under mild *** transformations of the product demonstrate the potential utility of this protocol in the synthesis of allyl alcohol derivatives and natural product *** studies revealed that the N,N′-dioxide/metal complexes play an important role in controlling the Z/E-and *** density functional theory(DFT) calculations further demonstrated that multiple C–H···π interactions between the aromatic rings of the two substrates and the amide moiety in the ligand stabilized the dominant transition state.

关键词： asymmetric allylic alkylation synergistic catalysis vinyl epoxides allyl alcohol multiple weak interactions

BET inhibitors enhance the anti-cancer effect of etoposide by suppressing the MRN-ATM axis in the DNA damage response

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Genes & Diseases 2024年第1期11卷 19-22页

作者： Zhenhai li Wenchao Xu feng chen Jun Zhang Wei-Guo Zhu Guangdong Key Laboratory of Genome Instability and Human Disease Prevention Department of Biochemistry and Molecular BiologyShenzhen University School of MedicineShenzhenGuangdong 518055China School of Pharmaceutical Sciences Shenzhen University Health Science CenterShenzhenGuangdong 518055China Base for International Science and Technology Cooperation:Carson Cancer Stem Cell Vaccines R&D Center International Cancer CenterShenzhen University Health Science CenterShenzhenGuangdong 518055China Shenzhen Bay Laboratory Shenzhen University School of MedicineShenzhenGuangdong 518055China Marshall Laboratory of Biomedical Engineering Shenzhen University School of MedicineShenzhenGuangdong 518055China

Etoposide is widely used for cancer chemotherapy in the ***,long-term etoposide treatment can lead to adverse effects or drug *** improve the situation,we evaluated the therapeutic efficiency of etoposide combined with inhibitors of bromodomain and extraterminal(BET)family proteins,which have recently emerged as novel anti-cancer targets due to their critical roles in cancer ***,we showed BRD4,one of the main targets of BET inhibitors,was involved in DNA damage response(DDR)via the homologous recombination(HR)repair pathway.

关键词： etoposide damage cancer

Intelligent gold nanocluster for effective treatment of malignant tumor via tumor-specific photothermal–chemodynamic therapy with AIE guidance

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National Science Review 2024年第5期11卷 326-342页

作者： feng liu Tianfeng Yang Xiaowei Chang li chen cheng cheng Xiuhong Peng Haihu liu Yanmin Zhang Xin chen School of Energy and Power Engineering Xi'an Jiaotong University Department of Chemical Engineering Shaanxi Key Laboratory of Energy Chemical Process IntensificationInstitute of Polymer Science in Chemical Engineering School of Chemical Engineering and Technology Xi'an Jiaotong University School of Pharmacy Health Science Center Xi'an Jiaotong University

Precise and efficient therapy of malignant tumors is always a challenge. Herein, gold nanoclusters co-modified by aggregation-induced-emission（AIE） molecules, copper ion chelator（acylthiourea） and tumor-targeting agent（folic acid） were fabricated to perform AIE-guided and tumor-specific synergistic therapy with great spatio-temporal controllability for the targeted elimination and metastasis inhibition of malignant tumors. During therapy, the functional gold nanoclusters（Au NTF） would rapidly accumulate in the tumor tissue due to the enhanced permeability and retention effect as well as folic acid-mediated tumor targeting, which was followed by endocytosis by tumor cells. After that, the overexpressed copper ions in the tumor cells would trigger the aggregation of these intracellular Au NTF via a chelation process that not only generated the photothermal agent in situ to perform the tumor-specific photothermal therapy damaging the primary tumor, but also led to the copper deficiency of tumor cells to inhibit its ***, the copper ions were reduced to cuprous ions along with the chelation, which further catalysed the excess H2O2in the tumor cells to produce cytotoxic reactive oxygen species, resulting in additional chemodynamic therapy for enhanced antitumor efficiency. The aggregation of Au NTF also activated the AIE molecules to present fluorescence, which not only imaged the therapeutic area for real-time monitoring of this tumor-specific synergistic therapy, but also allowed us to perform near-infrared radiation at the correct time point and location to achieve optimal photothermal therapy. Both in vitro and in vivo results revealed the strong tumor elimination, effective metastasis inhibition and high survival rate of tumor-bearing mice after treatment using the Au NTF nanoclusters, indicating that this AIE-guided and tumor-specific synergistic strategy could offer a promising approach for tumor therapy.

关键词： AIE-guided precise tumor treatment copper-dependent photothermal therapy copper-triggered chemodynamic therapy primary tumor elimination copper-plunder-induced metastasis inhibition

Enhanced cyclic stability of partially disordered spinel cathodes through direct fluorination with gaseous fluorine

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Rare Metals 2024年第4期43卷 1635-1646页

作者： Yong-Nian Ma ling-chen Kong Shao-Shan chen Yong Wang li-Dong Sun Cong Peng Meng-Meng Qin Yu li Wei feng Tianjin Key Laboratory of Composite and Functional Materials School of Materials Science and EngineeringTianjin UniversityTianjin300072China Institute of Advanced Technology and Equipment Beijing University of Chemical TechnologyBeijing100029China

Spinel-type cathodes are considered an optimal substitute for conventional layered oxide cathodes owing to their use of inexpensive and earth-abundant manganese as the redox-active ***,the introduction of cation disorder can effectively suppress the detrimental two-phase reaction to realize high capacities in a wide voltage ***,the continuous capacity decay during cycles has hindered the widespread application of these cathode *** fluorides exhibit excellent electrochemical stability at high voltage;therefore,in this study,the direct F2 gas reaction with a partially disordered spinel cathode(li_(1.6)Mn_(1.6)O_(3.7)F_(0.3,)LMOF1.6)was initially applied to investigate the impacts of fluorination on the surface structure and electrochemical *** inorganic fluorinated layer,mainly containing liF,was distributed uniformly on the surface of LMOF1.6nanoparticles after fluorination for an appropriate time without the turbulence caused by the valency of manganese cation,which improved the capacity retention and rate capability by the suppression of structural damage,parasitic reaction,and cation *** LMOF1.6cathode fluorinated for 0.5 h exhibited a capacity of283.6 mAh·g^(-1)at 50 mA·g^(-1)and an enhanced capacity retention of 29.6%after 50 cycles in the voltage range of1.5-4.8 V,as compared to the pristine LMOF1.6 with only27.9%capacity retention.

关键词： Spinel-type cathodes Direct fluorination Capacity retention ability High rate capability

Mechanoluminescent Materials Enable Mechanochemically Controlled Atom Transfer Radical Polymerization and Polymer Mechanotransduction

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Research 2024年第3期2023卷 97-104页

作者： Zexuan li Zhenhua Wang chen Wang Wenxi li Wenru Fan Ruoqing Zhao Haoyang feng Dengfeng Peng Wei Huang Frontiers Science Center for Flexible Electronics Institute of Flexible ElectronicsNorthwestern Polytechnical UniversityXi’an 710072China. School of Materials Science and Engineering Northwestern Polytechnical UniversityXi’an 710072China Key Laboratory of Optoelectronic Devices and Systems of Ministry of Education and Guangdong Province College of Physics and Optoelectronic EngineeringShenzhen UniversityShenzhen 518060China.

Organic mechanophores have been widely adopted for polymer ***,most examples of polymer mechanotransduction inevitably experience macromolecular chain rupture,and few of them mimic mussel’s mechanochemical regeneration,a mechanically mediated process from functional units to functional materials in a controlled *** this paper,inorganic mechanoluminescent(ML)materials composed of CaZnOS-ZnS-SrZnOS:Mn2+were used as a mechanotransducer since it features both piezoelectricity and *** utilization of ML materials in polymerization enables both mechanochemically controlled radical polymerization and the synthesis of ML polymer *** procedure features a mechanochemically controlled manner for the design and synthesis of diverse mechanoresponsive polymer composites.

关键词： chemically polymerization luminescent

3D laparoscopic anatomical hepatectomy guided by 2D real-time indocyanine green fluorescence imaging for hepatocellular carcinoma

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Hepatobiliary Surgery and Nutrition 2024年第3期13卷 494-499,I0015页

作者： feng Tian li Cao Jian chen Shuguo Zheng Jianwei li Department of Hepatobiliary Surgery Southwest HospitalArmy Medical University(Third Military Medical University)ChongqingChina

Laparoscopic anatomical hepatectomy(LAH)for patients with hepatocellular carcinoma(HCC)has been advocated by many surgeons in the hope of producing better oncological *** recent techniques,3D laparoscopic system and 2D real-time indocyanine green fluorescence imaging(r-ICG)guidance,are benefit for improving the operative precision of LAH in different ***,these two techniques cannot be applied concomitantly because of the technical *** a new modern laparoscopic system with both 3D and indocyanine green(ICG)imaging mode has been designed,it has not been listed in many countries including ***,we design a new procedure to perform the 3D LAH with 2D r-ICG guidance for HCCs with conventional laparoscopic *** this procedure,both 3D and 2D laparoscopic systems were used.A total of 11 patients with HCC received 3D laparoscopic right posterior sectionectomy(LRPS)with 2D r-ICG *** right posterior Glissonian pedicle was clamped under the 3D *** ICG solution was then intravenously *** liver parenchyma was transected under the 3D vision and guided by 2D ICG vision *** was no severe complications(Clavien-Dindo≥III)and operation related *** 90-day mortality was also *** using this procedure,the advantages of two techniques,3D laparoscopic system and 2D r-ICG guidance,were combined so that LAH could be performed with more ***,it should be validated in more studies.

关键词： Laparoscopic anatomical hepatectomy(LAH) indocyanine green fluorescence imaging(ICG fluorescence imaging) 3D laparoscopy 2D laparoscopic ICG fluorescence imaging