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Trib.logically induced nanostructural evolution of carb.n materials: A new perspective

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Friction 2024年第1期12卷 144-163页

作者： Guilherme Oliveira NEVES Nicolás ARAYA Diego b.rti SALVARO Thiago de souza LAMIM Renan Oss GIACOMELLI Cristiano b.NdeR Aloisio Nelmo KLEIN JoséDaniel b.asoli de MELLO Lab.ratório de Materiais Universidade Federal de Santa CatarinaSanta Catarina 88040-900Brazil departamento de Ingeniería Mecánica Facultad de IngenieríaUniversidad del Bío-BíoConcepcion 4070-386Chile Universidad de Concepción Concepcion 4070-386Chile SENAI Innovation Institute for Laser Processing Santa Catarina 89218-153Brazil Universidade Federal de Ub.rlândia Minas Gerais 38408-100Brazil

Carb.n-b.sed solid lub.icants are excellent options to reduce friction and wear,especially with the carb.n capab.lity to adopt different allotropes *** the macroscale,these materials are sheared on the contact along with deb.is and contaminants to form trib.layers that govern the trib.system *** a recently developed advanced Raman analysis on the trib.layers,it was possib.e to quantify the contactinduced defects in the crystalline structure of a wide range of allotropes of carb.n-b.sed solid lub.icants,from graphite and carb.de-derived carb.n particles to multi-layer graphene and carb.n *** addition,these materials were tested under various dry sliding conditions,with different geometries,topographies,and solid-lub.icant application *** of the initial trib.system conditions and allotrope level of atomic ordering,there is a remarkab.e trend of increasing the point and line defects density until a specific saturation limit in the same order of magnitude for all the materials tested.

关键词： carb.n nanostructures trib.logy Raman spectroscopy defects quantification trib.layer solid lub.ication

New therapeutic strategy with extracorporeal memb.ane oxygenation for refractory hepatopulmonary syndrome after liver transplant: A case report

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World Journal of Transplantation 2024年第1期14卷 210-214页

作者： b.linda Sánchez Pérez María Pérez Reyes Jose Aranda Narvaez julio Santoyo Villalb. Jose Antonio Perez Daga Claudia Sanchez-Gonzalez julio Santoyo-Santoyo Hepatob.liary and Trasplantation Unit General and Digestive Surgery DepartmentUniversity Regional HospitalMalaga 29010Spain department of General and Digestive Surgery Regional University Hospital of MalagaMalaga 29010Spain

b.CKGROUND Due to the lack of pub.ished literature ab.ut treatment of refractory hepatopulmonary syndrome(HPS)after liver transplant(LT),this case adds information and experience on this issue along with a treatment with positive *** is a complication of end-stage liver disease,with a 10%-30%incidence in cirrhotic *** can reverse the physiopathology of this process and restore normal ***,in some cases,refractory hypoxemia persists,and extracorporeal memb.ane oxygenation(ECMO)can b. used as a rescue therapy with good *** SUMMARY A 59-year-old patient with alcohol-related liver cirrhosis and portal hypertension was included in the LT waiting list for *** had good liver function(Model for End-Stage Liver Disease score 12,Child-Pugh class b.).He had pulmonary fib.osis and a mild restrictive respiratory pattern with a b.sal oxygen saturation of 82%.The macroaggregated alb.min test result was>*** demonstrated a forced expiratory volume in one second(FEV1)of 78%,forced vital capacity(FVC)of 74%,FEV1/FVC ratio of 81%,diffusion capacity for carb.n monoxide of 42%,and carb.n monoxide transfer coefficient of 57%.He required domiciliary oxygen at 2 L/min(16 h/d).The patient was admitted to the intensive care unit(ICU)and extub.ted in the first 24 h,needing high-flow therapy and non-invasive ventilation and inhaled nitric oxide *** was needed after 72 *** to the non-response to supportive therapies,installation of ECMO was decided with progressive recovery after 9 *** was possib.e on the tenth day,maintaining a high-flow nasal cannula and de-escalating to conventional oxygen therapy after 48 *** was discharged from ICU on postoperative day(POD)20 with a 90%-92%oxygen *** recycling was needed twice for acute *** patient was discharged from hospital on POD 27 with no symptoms,with an 89%-90%oxygen *** Due to the favorab.e results ob.erved,ECMO could b.c

关键词： Liver transplantation Hepatopulmonary syndrome Refractory hypoxemia Treatment Extracorporeal memb.ane oxygenation Case report

Synthesis and applications of lanthanoid complexes of pentadentate and hexadentate N_(5) and N_(6) macrocycles:A review

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Journal of Rare Earths 2024年第1期42卷 1-15,I0001页

作者： julio Corredoira-Vázquez Cristina González-b.rreira Paula Oreiro-Martínez Ana M.García-deib. Jesús Sanmartín-Matalob.s Matilde Fondo departamento de Química Inorganica Facultade de QuímicaUniversidade de Santiago de CompostelaCampus Vida15782Santiago de CompostelaSpain Phantom-g CICECO-Aveiro Institute of MaterialsDepartment of PhysicsUniversity of Aveiro3810-193AveiroPortugal Institute of Materials(iMATUS) Universidade de Santiago de Compostela15782Santiago de CompostelaSpain

In this paper,the lanthanoid complexes of N_(5) and N_(6) macrocycle ligands,without pendant arms or additional heteroatoms,are *** review covers the period from 2015 to the current date,since in 2014 Schiff b.se macrocyclic ligands incorporating the pyridine moiety,and their complexes,were revised,and in 2015 the chemistry of pentaaza macrocycle ligands with rare earth metals was also *** and phthalocyanine ligands are not included in this review,which primarily focuses on complexes with Schiff b.ses and amines without pendant arms or any additional donor other than *** synthetic methods,structural characterization,b.sed on single X-ray crystal data,and properties of the lanthanoid complexes,with special attention to magneto-structural correlations,are presented herein.

关键词： Lanthanoid N_(5),N_(6)macrocycle Coordination chemistry Chirality b.ological activity Molecule magnet

Effect of Silicon Amendment on Growth and Nitrogen Status of Common Landscaping Plants

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American Journal of Plant Sciences 2024年第8期15卷 603-616页

作者： b.rb.ra Nogueira souza Costa Milagros Ninoska Munoz Salas Kylie Gil Amir Ali Khoddamzadeh department of Earth and Environment Institute of Environment Florida International University Miami FL USA

Agriculture and natural vegetations in South Florida face with significant environmental threats such as heat and saltwater intrusion. This study aimed to investigate how silicon application could improve growth parameters and plant health of landscaping plants under extreme temperatures, influenced b. glob.l climate changes. Cocoplum (Chrysob.lanus icaco), cab.age palm (Sab.l palmetto), satinleaf (Chrysophyllum oliviforme), and wild coffee (Psychotria nervosa) plants received an initial slow-release fertilizer of 15 g/pot with an 8N-3P-9K composition. Silicon was applied as a 1% silicic acid solution, with concentrations ranging from 0 g/pot to 6 g/pot of 7.5 L. Evaluations were carried out every 30 days, continuing until 180 days after the treatment was completed. Phenotypic traits, including leaf count and plant height, were assessed alongside measurements from handheld optical non-destructive sensors. These measurements included the normalized difference vegetation index (NDVI), SPAD-502, and atLEAF chlorophyll meters. Application of 4 g/pot and 6 g/pot of silicon significantly improved NDVI values (0.78). Conversely, cocoplum plants exhib.ted greater plant height (79.6) at 0 g/pot silicon compared to other treatments. In wild coffee samplings, the control group showed the highest plant height and SPAD readings (93.49) compared to other treatments. Interestingly, the control treatment also demonstrated a superior atLEAF value as compared to other treatments, while the tallest samplings were ob.erved with 6 g/pot of silicon (62.82) in cab.age palm plants. The findings indicate that silicon application positively influenced plant growth, particularly evident in cab.age palms. However, cocoplum and wild coffee exhib.ted a negative correlation b.tween plant height and silicon concentrations.

关键词： Silicon Application Chlorophyll Content Cocoplum Cab.age Palm Satinleaf Wild Coffee

Linking leaf elemental traits to b.omass across forest b.omes in the Himalayas

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Science China Earth Sciences 2024年第5期67卷 1518-1528页

作者： Nita DYOLA Eryuan LIANG Josep PEÑUELAS J.julio CAMARERO Shalik Ram SIGdeL Sugam ARYAL Wentao LIN Xiang LIU Yongwen LIU Xingliang XU Sergio ROSSI State Key Lab.ratory of Tib.tan Plateau Earth System Environment and Resources(TPESER)Institute of Tibetan Plateau ResearchChinese Academy of SciencesBeijing 100101China University of Chinese Academy of Sciences Beijing 100049China Lab.ratoire sur lesécosystèmes terrestres b.réaux Département des Sciences FondamentalesUniversitédu QuébecàChicoutimi555Boulevard de l′UniversitéChicoutimi(QC)G7H2B1Canada CSIC Global Ecology Unit CREAF-CSIC-UABBellaterraE-08193 CataloniaSpain CREAF Cerdanyola del VallèsE-08193 CataloniaSpain Instituto Pirenaico de Ecología(IPE-CSIC) Avenida Montañana 1005Zaragoza 50059Spain Friedrich-Alexander-Universität Erlangen-Nürnb.rg Institut für GeographieErlangen 91058Germany State Key Lab.ratory of Grassland Agro-Ecosystems College of EcologyLanzhou UniversityLanzhou 730000China Key Lab.ratory of Ecosystem Network Ob.ervation and Modeling Institute of Geographic Sciences and Natural Resources ResearchChinese Academy of SciencesBeijing 100101China

Plants require a numb.r of essential elements in different proportions for ensuring their growth and *** elemental concentrations in leaves reflect the functions and adaptations of plants under specific environmental ***,less is known ab.ut how the spectrum of leaf elements associated with resource acquisition,photosynthesis and growth regulates forest b.omass along b.oad elevational *** examined the influence of leaf element distrib.tion and diversity on forest b.omass b. analyzing ten elements(C,N,P,K,Ca,Mg,Zn,Fe,Cu,and Mn)in tree communities situated every 100 meters along an extensive elevation gradient,ranging from the tropical forest(80 meters ab.ve sea level)to the alpine treeline(4200 meters ab.ve sea level)in the Kangchenjunga Landscape in eastern Nepal *** calculated communityweighted averages(reflecting dominant traits governing b.omass,i.e.,mass-ratio effect)and functional divergence(reflecting increased trait variety,i.e.,complementarity effect)for leaf elements in a total of 1,859 trees representing 116 *** increasing mass-ratio effect and decreasing complementarity in leaf elements enhance forest b.omass accumulation.A comb.nation of elements together with elevation explains b.omass(52.2%of the variance)b.tter than individual elemental trait diversity(0.05%to 21%of the variance).Elevation modulates trait diversity among plant species in b.omass *** promotes b.omass at lower elevations,b.t reduces b.omass at higher elevations,demonstrating an interaction b.tween elevation and *** interaction b.tween elevation and mass-ratio effect produces heterogeneous effects on b.omass along the elevation *** research indicates that b.omass accumulation can b. disproportionately affected b. elevation due to interactions among trait diversities across vegetation *** higher trait variation enhances the adaptation of species to environmental changes,it reduces

关键词： Ecosystem function Elevational gradient Functional diversity Functional traits Leaf elements Niche complementarity

Driving factors b.hind multiple populations

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Science China(Physics,Mechanics & Astronomy) 2024年第5期67卷 172-181页

作者： Ruoyun Huang b.itian Tang Chengyuan Li Doug Geisler Mario Mateo Ying-Yi Song Holger b.umgardt julio A.Carb.llo-b.llo Yue Wang Jundan Nie b.uno Dias JoséG.Fernández-Trincado School of Physics and Astronomy Sun Yat-sen UniversityZhuhai 519082China CSST Science Center for the Guangdong-Hong Kong-Macao Greater b.y Area Zhuhai 519082China departamento de Astronomía Universidad de ConcepcionConcepcionChile Instituto de Investigación Multidisciplinario en Ciencia y Tecnología Universidad de La SerenaLa SerenaChile departamento de Astronomía Facultad de CienciasUniversidad de La SerenaChile department of Astronomy University of MichiganAnn Arbor 48109USA David A.Dunlap department of Astronomy&Astrophysics University of TorontoToronto ON M5S 3H4Canada Dunlap Institute for Astronomy&Astrophysics University of TorontoToronto ON M5S 3H4Canada School of Mathematics and Physics The University of QueenslandSt.Lucia QLD 4072Australia Instituto de Alta Investigación Universidad de TarapacáAricaChile CAS Key Lab.ratory of Optical Astronomy National Astronomical ObservatoriesChinese Academy of SciencesBeijing 100101China Instituto de Astrofísica Departamento de Ciencias FísicasFacultad de Ciencias ExactasUniversidad Andres BelloSantiagoChile Instituto de Astronomía Universidad Católica del NorteAntofagastaChile

Star clusters were historically considered simple stellar populations,with all stars sharing the same age and initial chemical ***,the presence of chemical anomalies in glob.lar clusters(GCs),called multiple stellar populations(MPs),has challenged star formation theories in dense *** studies show that mass,metallicity,and age are likely controlling parameters for the manifestation of *** the limit b.tween clusters with/without MPs in physical parameter space is crucial to reveal the driving mechanism b.hind their *** this study,we look for MP signals in Whiting 1,which is traditionally considered a young *** the Magellan telescope,we ob.ained low-resolution spectra withinλλ=3850-5500?for eight giants of Whiting *** measured the C and N ab.ndances from the CN and CH spectral indices.C and N ab.ndances have variations comparab.e with their measurement errors(~0.1 dex),suggesting that MPs are ab.ent from Whiting *** these findings with literature studies,we propose a limit in the metallicity *** compactness index parameter space,which relatively clearly separates star clusters with/without MPs(GCs/open clusters).This limit is physically *** a larger scale,the galactic environment determines cluster compactness and metallicity,leading to metal-rich,diffuse,old clusters formed ex *** proposed limit also impacts our understanding of the formation of the Sagittarius dwarf galaxy:star clusters formed after the first starb.rst(age≤8-10 Gyr).These clusters are simple stellar populations b.cause the enriched galactic environment is no longer suitab.e for MP formation.

关键词： stellar galactic galaxy

b.ndamustine and rituximab.as frontline therapy in extranodal marginal zone lymphoma:a single-institution experience

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Oncology Research 2024年第6期32卷 1031-1036页

作者： CONSTANTINE N.LOGOTHETIS NATHAN P.HORVAT TONY KURIAN CELESTE b.LLO julio CHAVEZ LEIDY ISENALUMHE b.JAL SHAH LUb.MIR SOKOL HAYdeR SAEED JAVIER PINILLA SAMEH GAb.LLA department of Internal Medicine University of South FloridaTampaFL33602USA College of Medicine University of South Florida MorsaniTampaFL33602USA H.Lee Moffitt Cancer Center and Research Institute TampaFL33612USA

Extranodal marginal zone lymphoma(EMZL)encompasses 70%of cases of marginal zone *** b.ndamustine and rituximab.b.)were derived from trials involving other indolent non-Hodgkin’s *** one trial has evaluated frontline b. prospectively in *** retrospective study reports outcomes among EMZL patients receiving frontline ***-five patients were included with a median age of 69 years(40–81).Five(20.0%)patients had stage Ⅰ/Ⅱ disease,and 20(80.0%)had stage Ⅲ/Ⅳ *** median numb.r of cycles was 6.0(3.0–6.0).Maintenance rituximab.was administered to 10(41.7%)*** response rate(ORR)was 100.0%(60.0%complete response,40.0%partial response).Medians of overall survival and progression-free survival were not *** estimated 2-year progression-free survival was 85.2%and overall survival was 100.0%.Four(16.6%)patients had infections related to treatment;3(12.0%)transformed to diffuse large b.cell lymphoma;5(20.8%)had a relapse or progression of EMZL;and 3(12.0%)died unrelated to *** is an efficacious and well-tolerated front-line regimen for EMZL with response data consistent with existing literature.

关键词： Extranodal marginal zone lymphoma b.ndamustine Rituximab Front-line therapy

Rifaximin on epigenetics and autophagy in animal model of hepatocellular carcinoma secondary to metab.lic-dysfunction associated steatotic liver disease

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World Journal of Hepatology 2024年第1期16卷 75-90页

作者： Matheus Truccolo Michalczuk Larisse Longo Melina b.lén Keingeski b.uno de souza b.sso Gab.iel Tayguara Silveira Guerreiro Jessica T Ferrari JoséEduardo Vargas Cláudia P Oliveira Carolina Urib.-Cruz Carlos Thadeu Schmidt Cerski Eduardo Filippi-Chiela Mário ReisÁlvares-da-Silva Division of Gastroenterology Hospital de Clínicas de Porto AlegrePorto Alegre 90035-903Rio Grande do SulBrazil Graduate Program in Gastroenterology and Hepatology Universidade Federal do Rio Grande do SulPorto Alegre 90035-003Rio Grande do SulBrazil Experimental Lab.ratory of Hepatology and Gastroenterology Hospital de Clínicas de Porto AlegrePorto Alegre 90035-903Rio Grande do SulBrazil Lab.ratory of Inflammatory and Neoplastic Cells Universidade Federal do ParanáParaná81530900Brazil department of Gastroenterology(LIM07) Faculdade de Medicina da Universidade de São PauloSão Paulo 01246903Brazil Facultad de Ciencias de la Salud Universidad Católica de las MisionesPosadasMisiones 3300Argentina Unit of Surgical Pathology Hospital de Clinicas de Porto AlegrePorto Alegre 90035-903Rio Grande do SulBrazil Center of b.otechnology Universidade Federal do Rio Grande do SulPorto Alegre 90035-003Rio Grande do SulBrazil department of Morphological Sciences Universidade Federal do Rio Grande do SulPorto Alegre 90.050-170Rio Grande do SulBrazil Conselho Nacional de desenvolvimento Científico e Tecnológico(CNPq) Conselho Nacional de Desenvolvimento Científico e Tecnológico(CNPq)ResearcherBrasília 71.605-001Brazil

b.CKGROUND Prevalence of hepatocellular carcinoma(HCC)is increasing,especially in patients with metab.lic dysfunctionassociated steatotic liver disease(MASLD).AIM To investigate rifaximin(RIF)effects on epigenetic/autophagy markers in *** Adult Sprague-Dawley rats were randomly assigned(n=8,each)and treated from 5-16 wk:Control[standard diet,water plus gavage with vehicle(Veh)],HCC[high-fat choline deficient diet(HFCD),diethylnitrosamine(deN)in drinking water and Veh gavage],and RIF[HFCD,deN and RIF(50 mg/kg/d)gavage].Gene expression of epigenetic/autophagy markers and circulating miRNAs were *** All HCC and RIF animals developed metab.lic-dysfunction associated steatohepatitis fib.osis,and cirrhosis,b.t three RIF-group did not develop *** animals who developed HCC with those who did not,miR-122,miR-34a,tub.lin alpha-1c(Tub.-1c),metalloproteinases-2(Mmp2),and metalloproteinases-9(Mmp9)were significantly higher in the *** opposite occurred with b.cn1,coactivator associated arginine methyltransferase-1(Carm1),enhancer of zeste homolog-2(Ezh2),autophagy-related factor LC3A/b.Map1 Lc3b.,and p62/sequestosome-1(p62/SQSTM1)-*** with controls,Map1 Lc3b.b.cn1 and Ezh2 were lower in HCC and RIF-groups(Pb.erved for p62/Sqstm1(Pb.-1c,Aldolase-b.alpha-fetoprotein,and Mmp2(P>0.05).miR-122 was higher in HCC,and miR-34a in RIF compared to controls(Pb.was lower in HCC compared to RIF,and the inverse was ob.erved for miR-224(P0.05).CONCLUSION RIF might have a possib.e b.neficial effect on preventing/delaying liver carcinogenesis throu

关键词： Animal model Autophagy Epigenetic Hepatocellular carcinoma Metab.lic dysfunction-associated steatotic liver disease Rifaximin

Storylines of family medicine Ⅸ:people and places—diverse populations and locations of care

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Family Medicine and Community Health 2024年第S3期12卷 79-88页

作者： William b.Ventres Leslie A Stone Emad R Ab.u-Arab.julio Meza David S b.ck Jerome W Crowder Jennifer Y C Edgoose Alexander b.own Ellen J Plumb.Amb.r K Norris Jay J Allen Lauren E Giammar John E Wood Scott M Dickson G Austin b.own Family and Preventive Medicine University of Arkansas for Medical Sciences College of MedicineLittle RockArkansasUSA Family Medicine University of Michigan Medical SchoolAnn ArborMichiganUSA Family Medicine University of California Los AngelesDavid Geffen School of MedicineLos AngelesCaliforniaUSA Community Medicine University of HoustonTilman J Fertitta Family College of MedicineHoustonTexasUSA Social and b.havioral Sciences University of HoustonTilman J Fertitta Family College of MedicineHoustonTexasUSA Family Medicine and Community Health University of Wisconsin-Madison School of Medicine and Public HealthMadisonWisconsinUSA NH Dartmouth Family Medicine Residency ConcordNew HampshireUSA San Francisco VA Medical Center San FranciscoCaliforniaUSA Duluth Family Medicine Residency Program University of Minnesota Medical School Duluth CampusDuluthMinnesotaUSA UAMS Northeast Regional Campus Family Medicine Residency Program JonesboroArkansasUSA Cascades East Family Medicine Residency Program Oregon Health&Science University School of MedicineKlamath FallsOregonUSA

Storylines of Family Medicine is a 12-part series of thematically linked mini-essays with accompanying illustrations that explore the many dimensions of family medicine as interpreted b. individual family physicians and medical educators in the USA and elsewhere around the ***‘Ⅸ:people and places—diverse populations and locations of care’,authors address the following themes:‘LGb.QIA+health in family medicine’,‘A family medicine approach to sub.tance use disorders’,‘Shameless medicine for people experiencing homelessness’,“Difficult”encounters—finding the person b.hind the patient’,‘Attending to patients with medically unexplained symptoms’,‘Making house calls and home visits’,‘Family physicians in the procedure room’,‘Rob.st rural family medicine’and‘Full-spectrum family medicine’.May readers appreciate the b.eadth of family medicine in these essays.

关键词： illustration family dimensions