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CRYSTAL STRUCTURE OF DI - NITRATOBIS(ETHYLCAPROLACTAM)URANYL(Ⅱ) UO_2[CH_2(CH_2)_4CONC_2H_5]_2(NO_3)_2

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Chinese Chemical Letters 1992年第3期3卷 211-212页

作者： Zheng Bai CAO Han Zhang WANG Zhen Rong LU Li Min ZHU jian sheng gu Song Shan guO Kai Bei YU Dept.of Chem.Suzhou University Suzhou215006 The Central Laboratory Suzhou UniversitySuzhou215006 Chengdu Center of Anal and Determ.Academic SinicaChengdu610051

The crystal structure of Di-nitratobis(ethylcaprolactam)uranyl(Ⅱ) UO_2[CH_2(CH_2)_4CONC_2H_5]_2(NO_3)_2 was established by a single-crystal X-ray diffraction *** is triclinie, space group P1, with a=7.171(2), b=8.655(3), c=10.182(5)A, α=78.27(3), β=70.63(3), γ=81.76(3)°, V=581.7(4)A^3, Z=l, Dc=1.94 ***^(-3).Final R value is *** result reveals that uranyl ion is coordinated to six oxygen atoms, two of them are from two carbonyl groups of ethylcaprolactam and the other four are from two nitrate groups.

关键词： CRYSTAL STRUCTURE OF DI CH2 ETHYLCAPROLACTAM)URANYL NITRATOBIS UO2[CH2

DIRECT　ELECTROCHEMICAL　SYNTHESIS　AND　CHARACTERIZATION　OF　SAMARIUM　（Ⅲ）　COMPLEX　WITH　2－HYDROXY－2，　4，　6－CYCLOHEPTATRIENONE　（TROPOLONE）

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Chinese Chemical Letters 1995年第3期6卷 259-260页

作者： jian sheng gu jian Ying TONG and Mei Hua MA(Department of Chemistry,Suzhou University,Suzhou,215006Dennis G.TUCK)(Dept.of Chem.and Biochem,Univ.of Windsor,Windsor,Ont.,Canada N9B 3P4)

Tris(tropolonato) samarium (Ⅲ) has been prepared in high yield, by the electrochemical oxidation of samarium metal anode in acetonitrile solution of 2-hydroxy-2, 4, 6-cycloheptatrienone (trogolone, HL). The unusual divalent samarium (Ⅱ) complex was formed at the first step of electrosynthesis. The final product, Sm(C7H8O2)3, has been characterized by microanalysis and the studies of IR and 1H1 13C NMR spectra.

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Exploration of Gas‑Dependent Self‑Adaptive Reconstruction Behavior of Cu_(2)O for Electrochemical CO_(2)Conversion to Multi‑Carbon Products

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Nano-Micro Letters 2025年第3期17卷 280-296页

作者： Chaoran Zhang Yichuan gu Qu jiang Ziyang sheng Ruohan Feng Sihong Wang Haoyue Zhang Qianqing Xu Zijian Yuan Fang Song State Key Laboratory of Metal Matrix Composites School of Materials Science and EngineeringShanghai Jiao Tong UniversityShanghai 200240People’s Republic of China

Structural reconstruction of electrocatalysts plays a pivotal role in catalytic performances for CO_(2)reduction reaction(CO_(2)RR),whereas the behavior is by far superficially ***,we report that CO_(2)accessibility results in a universal self-adaptive structural reconstruction from Cu_(2)O to Cu@CuxO composites,ending with feeding gas-dependent microstructures and catalytic *** CO_(2)-rich atmosphere favors reconstruction for CO_(2)RR,whereas the CO_(2)-deficient one prefers that for hydrogen evolution *** the assistance of spectroscopic analysis and theoretical calculations,we uncover a CO_(2)-induced passivation behavior by identifying a reductionresistant but catalytic active Cu(I)-rich amorphous layer stabilized by*CO ***,we find extra CO production is indispensable for the robust production of *** inverse correlation between durability and FECO/FEC2H4 is disclosed,suggesting that the selfstabilization process involving the absorption of*CO intermediates on Cu(I)sites is essential for durable *** by this insight,we design hollow Cu_(2)O nanospheres for durable and selective CO_(2)RR electrolysis in producing *** work recognizes the previously overlooked passivation reconstruction and self-stabilizing behavior and highlights the critical role of the local atmosphere in modulating reconstruction and catalytic processes.

关键词： CO_(2)reduction reaction Electrocatalysts Cu_(2)O Reconstruction Self-adaptive electrocatalysis

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文明叙事:习近平文化思想的方法论审视

新疆师范大学学报（哲学社会科学版） 2025年第1期46卷 34-42页

作者：张明谷生秀南京大学马克思主义学院江苏南京210023

文明是中国共产党百余年推进马克思主义中国化时代化的核心线索,文明叙事是中国共产党历史叙事的重要维度,也是习近平文化思想的重要方法论。习近平文化思想的深厚文明意蕴体现在四个方面:一是从历史纵深出发把握“走自己的路”的文明基... 详细信息

文明是中国共产党百余年推进马克思主义中国化时代化的核心线索,文明叙事是中国共产党历史叙事的重要维度,也是习近平文化思想的重要方法论。习近平文化思想的深厚文明意蕴体现在四个方面:一是从历史纵深出发把握“走自己的路”的文明基因,即从中华5000多年文明的历史传承中把握中国道路的来龙去脉及其内在逻辑必然;二是以“第二个结合”为根本方法,重塑发展中华文明的使命担当,不断推动建设中华民族现代文明实现传统文明的现代新生;三是坚守文明超越理念,将新文明的建构与中国式现代化的现实实践相互关联,以中国式现代化创造人类文明新形态,打破西方以资本逻辑为核心的形而上学抽象文明观的历史困境;四是坚持文明交流互鉴,推动落实全球文明倡议,构建人类文明交往新范式。

关键词：习近平文化思想文明叙事 “走自己的路” “第二个结合” 文明交流互鉴

大直径水下盾构隧道水下不分散砂浆应用与效果分析

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山西建筑 2025年第2期51卷 169-174页

作者：盛健中铁十四局集团大盾构工程有限公司江苏南京210000

随着现代工程建设技术的发展,特殊砂浆作为一种性能优越的建筑材料,在工程中的应用越来越广泛。其中水下不分散砂浆在基岩裂隙水发育丰富、地下动水丰沛且受潮汐影响流动性强的地下工程建设中取得了较好的效果。依托广州海珠湾隧道工程... 详细信息

随着现代工程建设技术的发展,特殊砂浆作为一种性能优越的建筑材料,在工程中的应用越来越广泛。其中水下不分散砂浆在基岩裂隙水发育丰富、地下动水丰沛且受潮汐影响流动性强的地下工程建设中取得了较好的效果。依托广州海珠湾隧道工程大直径水下盾构隧道试验段,结合普通砂浆与水下不分散砂浆在相同环境使用下的情况,从室内试验、地质雷达扫描、地表沉降监测、管片错台、渗漏水、上浮等方面进行对比分析跟踪验证,来对水下不分散砂浆的可行性开展分析。

关键词：大直径水下盾构隧道水下不分散砂浆基岩裂隙水发育地下动水丰沛

A new radar stealth design excited by ^(210)Po and ^(242)Cm

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Nuclear Science and Techniques 2022年第6期33卷 45-53页

作者： Jin-jian Yuan gui-Ping Meng Min gu Run-sheng Huang School of Physics Nanjing UniversityNanjing 210093China

Open plasma stealth technology excited by radionuclides is known to have several problems:(1)owing to disturbance from airflow,the plasma distribution is unstable.(2)The plasma is highly dependent on the atmosphere;therefore,it is difficult to modulate in target stealth.(3)Concerns regarding radiation harassment prevent the application of this *** avoid these problems,an enclosed plasma stealth method is *** simulation on an infinite conducting plate,this method was found to effectively solve the above concerns,which may offer a new approach for the practical application of plasma stealth technology excited by radionuclides,especially for small-satellite stealth because of its lightweight and selfprovided plasma.

关键词： Radiation ionization αDecay particles Plasma film Radar stealth technology

Effect of Mn Modification on the Corrosion Susceptibility of Mg–Mn Alloys by Magnesium Scrap

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Acta Metallurgica Sinica(English Letters) 2021年第1期34卷 1-11页

作者： Dong-Dong gu jian Peng Jia-Wen Wang Zheng-Tao Liu Fu-sheng Pan State Key Laboratory of Mechanical Transmission College of Materials Science and EngineeringChongqing UniversityChongqing 400044China Chongqing Research Center for Advanced Materials Chongqing Academy of Science and TechnologyChongqing 401123China

The microstructure and anti-corrosion behavior of Mg–Mn alloys by magnesium scrap have been investigated in this *** results show that the size of the Fe-rich particles in magnesium scrap decreases but the quantity increases with the Mn *** the presence of Mn-containing Fe-rich particles with unique symbiotic structure can eff ectively weaken the micro-galvanic corrosion,the presence of more free Fe(Fe-rich particles)does not necessarily lead to severe corrosion of the *** corrosion susceptibility of Mg–Mn–Fe alloy primarily depends on the solubility of iron in the Mg matrix,while it can be significantly reduced by suitable Mn ***,the tolerance limit of the Fe impurity can be expressed as Femax=0.0083 Mn(relative to the iron solubility).Only when the Fe/Mn ratio is below 0.0083 can the alloy have excellent corrosion resistance,with the corrosion rate changing in the scope of 0.38±0.09 to 0.54±0.15 mg/cm^(2) day and icorr from 3 to 9×10^(–4) A/cm^(2).

关键词： Magnesium scrap Mn modification Fe impurity Corrosion susceptibility Corrosion resistance

Volume of fluid simulation of single argon bubble dynamics in liquid steel under RH vacuum conditions

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Journal of Iron and Steel Research International 2024年第4期31卷 828-837页

作者： gu-jun Chen sheng-ping He College of Materials Science and Engineering Yangtze Normal UniversityChongqing 400044China College of Materials Science and Engineering Chongqing UniversityChongqing 400044China

Single argon bubble dynamics in liquid steel under Ruhrstahl-Heraeus(RH)vacuum conditions were simulated using the volume of fluid method,and the ideal gas law was used to consider bubble growth due to heat transfer and pressure *** simulation with a constant bubble density was also performed to validate the numerical method,and the predicted terminal bubble shape and velocity were found to agree with those presented in the Grace diagram and calculated by drag correlation,*** simulation results under RH conditions indicate that the terminal bubble shape and velocity cannot be *** primary bubble growth occurs within a rising distance of 0.3 m owing to heating by the high-temperature liquid steel;subsequently,the bubble continues to grow under equilibrium with the hydrostatic *** the initial diameter is 8-32 mm,the bubble diameter and rising velocity near the liquid surface are 80-200 mm and 0.5-0.8 m/s,*** bubble rises rectilinearly with an axisymmetric shape,and the shape evolution history includes an initial sphere,(dimpled)ellipsoid,and spherical cap with satellite bubbles.

关键词： Bubble dynamics Liquid steel Volume of fluid Bubble growth Bubble shape Rising velocity

Prediction of liquid circulation flow rate in RH degasser:improvement of decarburization at low atmospheric pressure

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Journal of Iron and Steel Research International 2024年第7期31卷 1661-1667页

The two-fluid model coupled with population balance model was used for simulating the gas-liquid flow in the Ruhrstahl-Heraeus(RH)*** predicted circulation flow rate was compared with that measured from a water model experiment to validate the mathematical ***,influence of snorkel immersion depth on liquid circulation flow rate was numerically investigated under an atmospheric pressure of 101 and 84 kPa,*** result indicates that the circulation flow rate of the RH degasser in the high-altitude area was severely reduced because of the decrease in atmospheric ***,increasing the snorkel immersion depth from 0.5 to 0.7 m can compensate for the decrease in atmospheric *** test result indicates that decarburization rate is significantly enhanced by increasing the snorkel immersion *** optimization,the percentage of heats with a final carbon content less than 0.002 wt.%is significantly increased from 22.0%to 96.4%.

关键词： RH degasser Two-fluid model Population balance model-Circulation flow rate Decarburization Snorkel immersion depth