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CRYSTAL STRUCTURE OF DI - NITRATOBIS(ETHYLCAPROLACTAM)URANYL(Ⅱ) UO_2[CH_2(CH_2)_4CONC_2H_5]_2(NO_3)_2

CRYSTAL STRUCTURE OF DI - NITRATOBIS(ETHYLCAPROLACTAM)URANYL(Ⅱ) UO_2[CH_2(CH_2)_4CONC_2H_5]_2(NO_3)_2

作     者:Zheng Bai CAO Han Zhang WANG Zhen Rong LU Li Min ZHU Jian Sheng GU Song Shan GUO Kai Bei YU 

作者机构:Dept.of Chem.Suzhou UniversitySuzhou215006 The Central LaboratorySuzhou UniversitySuzhou215006 Chengdu Center of Analand Determ.Academic SinicaChengdu610051 

出 版 物:《Chinese Chemical Letters》 (中国化学快报(英文版))

年 卷 期:1992年第3卷第3期

页      面:211-212页

核心收录:

学科分类:07[理学] 0703[理学-化学] 

主  题:CRYSTAL STRUCTURE OF DI CH2 ETHYLCAPROLACTAM)URANYL NITRATOBIS UO2[CH2 

摘      要:The crystal structure of Di-nitratobis(ethylcaprolactam)uranyl(Ⅱ) UO_2[CH_2(CH_2)_4CONC_2H_5]_2(NO_3)_2 was established by a single-crystal X-ray diffraction *** is triclinie, space group P1, with a=7.171(2), b=8.655(3), c=10.182(5)A, α=78.27(3), β=70.63(3), γ=81.76(3)°, V=581.7(4)A^3, Z=l, Dc=1.94 ***^(-3).Final R value is *** result reveals that uranyl ion is coordinated to six oxygen atoms, two of them are from two carbonyl groups of ethylcaprolactam and the other four are from two nitrate groups.

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