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Crystallographic Analysis of Isothermally Transformed Bainite in 0.2C-2.0Mn-1.5Si-0.6Cr Steel Using EBSD

journal of Materials Science & Technology 2013年第4期29卷 359-366页

作者： Pasi P.Suikkanen Cyril Cayron Anthony j.DeArdo L.Pentti Karjalainen Ruukki Metals Oy Rautaruukintie 155P.O.Box 93FI-92101 RaaheFinland Department of Mechanical Engineering University of OuluP.O.Box 420090014 University of OuluFinland Ruukki Metals Oy Rautaruukintie 155P.O.Box 93FI-92101 RaaheFinland. CEA LITEN17 rues des Martys38054 GrenobleFrance Department of Mechanical Engineering and Materials Science University of Pittsburgh848 Benedum HallPittsburghPA 15261-2285USA

The crystallography of bainite, transformed isothermally at 450 ℃ in 0.2C-2.0Mn-1.5Si-0.6Cr steel, was investigated by electron backscatter diffraction （EBSD） analysis. The orientation relationship （OR） was found to be closer to Nishiyama-Wassermann （N-W） than Kurdjumov-Sachs orientation relationship. Bainite microstructure consisted of parallel laths forming a morphological packet structure. Typically, there were three different lath orientations in a morphological packet. These orientations were dictated by a three specific N-W OR variants sharing the same {111} austenite plane. A packet of bainite laths with common {111} austenite plane was termed as crystallographic packet. Generally, the crystallographic packet size corresponded to the morphological packet size. Locally, crystallographic packets with only two dominant orientations were observed. This indicates strong local variant selection during isothermal bainite transformation. The relative orientation between the variants in crystallographic packets was found to be near 60°/〈110〉. This appears to explain the strong peak observed in the grain boundary misorientation distribution near 60°. Bainite also contained pronounced fraction of boundaries with their misorientation in the range of 2.5°-8° with quite widely dispersed rotation angles. Spatially these boundaries were found to locate inside the bainite laths, forming lath-like sub-grains.

关键词： Bainite Austenite Nishiyama-Wassermann orientation relationship Electron backscatter diffraction OEBSD) Crystallography Packet

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The effect of particle size and amount of inoculum on fungal treatment of wheat straw and wood chips

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journal of Animal Science and Biotechnology 2017年第1期8卷 217-225页

作者： Sandra j. A. van Kuijk Anton S. M. Sonnenberg johan j. P. Baars Wouter H. Hendriks john W. Cone Animal Nutrition Group Wageningen University De Elst 1 6708WD Wageningen The Netherlands Plant Breeding Wageningen University Droevendaalsesteeg 1 6708PB Wageningen The Netherlands

Background： The aim of this study was to optimize the fungal treatment of lignocellulosic biomass by stimulating the colonization. Wheat straw and wood chips were treated with Ceriporiopsis subvermispora and Lentinula edodes with various amounts of colonized millet grains（0.5, 1.5 or 3.0 % per g of wet weight of substrate） added to the substrates. Also, wheat straw and wood chips were chopped to either 0.5 or 2 *** of the fungal treatment after 0, 2, 4, 6, or 8 wk of incubation was determined by changes in chemical composition, in vitro gas production（IVGP） as a measure for rumen degradability, and ergosterol content as a measure of fungal ***： Incomplete colonization was observed for C. subvermispora treated wheat straw and L. edodes treated wood chips. The different particle sizes and amounts of inoculum tested, had no significant effects on the chemical composition and the IVGP of C. subvermispora treated wood chips. Particle size did influence *** treatment of wheat straw. The L. edodes treatment of 2 cm wheat straw resulted in a more selective delignification and a higher IVGP than the smaller particles. Addition of 1.5 % or 3 % L. edodes inoculum to wheat straw resulted in more selective delignification and a higher IVGP than addition of 0.5 % ***： Particle size and amount of inoculum did not have an effect on C. subvermispora treatment of wood chips. At least 1.5 % L. edodes colonized millet grains should be added to 2 cm wheat straw to result in an increased IVGP and acid detergent lignin（ADL） degradation.

关键词： Amount of inoculum Fungal treatment In vitro rumen degradability Lignin degradation Lignocellulosic biomass Particle size

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Semi-solid processing of hypereutectic A390 alloys using novel rheoforming process

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Transactions of Nonferrous Metals Society of China 2010年第9期20卷 1743-1748页

作者： M.TEBIB j.B.MORIN F.A jERSCH X.GRANT CHEN Université du Québec à Chicoutimi cole polytechnique de Montréal

The feasibility of semi solid processing of hypereutectic A390 alloys using a novel rheoforming process was investigated. A combination of the swirl enthalpy equilibration device （SEED） process, isothermal holding using insulation and addition of solid alloy during swirling was introduced as a novel method to improve the processability of semi solid slurry. The effects of isothermal holding and the addition of solid alloy on the temperature gradient between the centre and the wall and on the formation of a（Al） particles were examined. In additional tests, phosphorus and strontium were added to the molten metal to refine the primary and eutectic silicon structure to facilitate semi solid processing. The results show that the combination of the SEED process with two additional processing steps can produce semi-solid A390 alloys that can be rheoprocessed. The microstructure reveals an adequate amount of non-dendritic a（Al） globules surrounded by liquid, which greatly improves the processability of semi-solid slurry.

关键词： semi-solid forming rheoforming process hypereutectic A390 alloys microstructure

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Spectroscopic investigations of Gd_3Sc_2Ga_3O_(12) garnet doped with Cr^(3+) and Nd^(3+) ions

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journal of Rare Earths 2009年第4期27卷 560-563页

作者： K.Lemański P.j.Dereń A.Gagor W.Strek Institute of Low Temperatures and Structure Research Polish Academy of Sciences

Absorption, excitation and emission spectra as well as decay time measurements at 10, 77, and 300 K were perfumed for Gd3Sc2Ga3O12 garnet single-crystal doped with Cr^3＋ and Nd^3＋ ions. Strong reabsorption of Cr3＋ emission by Nd3＋ absorption lines was ob- served. The assignments of f-f and d-d transitions were proposed. The broad emission band of chromium ions is an indication that weak/intermediate crystal field strength is present at the Cr3＋ site.

关键词： Gd3Sc2Ga3O12 crystal reabsorption Cr Nd rare earths

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Degradation of indomethacin in river water under stress and non-stress laboratory conditions:degradation products,long-term evolution and adsorption to sediment

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journal of Environmental Sciences 2017年第1期29卷 13-20页

作者： juan j.jimenez Maria I.Sanchez Rafael Pardo Beatriz E.Munoz Department of Analytical Chemistry Faculty of SciencesCampus Miguel DelibesUniversity of ValladolidPaseo de Belen 747012 ValladolidSpain I.U.CINQUIMA Campus Miguel DelibesUniversity of ValladolidPaseo de Belen 547011 ValladolidSpain Department of Analytical Chemistry School of Industrial EngineersUniversity of ValladoliclFrancisco Mendizdbal 147014 ValladolidSpain

The pharmaceutical compound indomethacin is not totally removed in wastewater treatment plants,whose effluents flow into aquatic environments;concentrations in the 0.1-100 ng/L range are commonly found in surface waters,and its fate is ***,biological,photochemical and thermal degradation assays were conducted under stress and non-stress conditions to estimate its degradation rate in river water and establish its degradation products over *** results revealed that direct sunlight irradiation promoted the complete degradation of indomethacin（2 μg/L） in less than 6 hr,but indomethacin was detected over a period of 4 months when water was kept under the natural day-night cycle and the exposure to sunlight was partially limited,as occurs inside a body of *** biological degradation in water was negligible,while the hydrolysis at pH 7.8 was *** were monitored by ultra-pressure liquid chromatography/quadrupole time-of-flight/mass spectrometry after solid-phase extraction,and six degradation products were found;their structures were proposed based on the molecular formulae and fragmentation observed in high-resolution tandem mass spectra.4-Chlorobenzoic and 2-acetamido-5-methoxybenzoic acids were the long-term transformation products,persisting for at least 30 weeks in water kept under non-stress ***,the degradation in the presence of sediment was also monitored over time,with some differences being *** adsorption coefficients of indomethacin and degradation products on river sediment were calculated;long-term degradation products did not have significant adsorption to sediment.

关键词： Indomethacin Degradation products River water Adsorption coefficients High-resolution mass spectrometry

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Biomarkers of Aging: Changes in Circadian Rhythms Related to the Modulation of Metabolic Output

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Biomedical and Environmental Sciences 1991年第1期4卷 182-191页

作者： PETER H.DUFFY RITCHIE j.FEUERS Food and Drug Administration Natiomd Center Jbr Toxicological Research JeffersonFood and Drug Administration Natiomd Center Jbr Toxicological Research Jefferson Arkansas 72079 To whom correspondence should be addressedArkansas 72079

Twenty-four hour (circadian) rhythmicity is an important component of biological variability associated with studies relating to biomarkers of aging. Chronobiological testing techniques must be utilized because (1) many variables that are related to the modulation of metabolic output vary dramatically at different times of the day; (2) various experimental variable and treatment groups must be synchronized with environmental cues that control circadian rhythms; and (3) multiple circadian variables may interact together to modulate the rate of aging. The rhythm for physiological factors such as whole animal metabolic output, body temperature, heart rate, urine flow, potassium, etc. were found to be dissociated or altered by the senescence process; behavioral variables such as spontaneous activity, wheel running, feeding and drinking, verbal performance, as well as sleep-wakefulness rhythms, seem to be accurate predictors of biological age. Circadian rhythms for a variety of enzymes of intermediary metabolism which are directly associated with energy metabolism have been well documented. These well-defined rhythms of enzyme activity have also been shown to degenerate with aging. Rhythms tend to lose amplitude as activity falls with age and as a general loss of regulation (especially time of day where maximal activity might be found) of activity across the 24-h span occurs. As with behavioral variables, changes in enzyme rhythms appear to accurately predict aging. Generally speaking, the loss of temporal organization with age, characterized by decreased circadian amplitude, loose internal synchronization, and poor response to external environmental time queues, is associated with poor health states and decreased longevity. Temporal rhythms for whole animal parameters are highly correlated with molecular events, such as regulation of cellular metabolism. DNA repair, and gene expression. Automated data acquisition and process control systems will be required for future C

关键词： Biomarkers of Aging Changes in Circadian Rhythms Related to the Modulation of Metabolic Output

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Harnessing memory adaptive regulatory T cells to control autoimmunity in type 1 diabetes

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分子细胞生物学报:英文版 2012年第1期4卷 38-47页

作者： Cheng-Rui Li Bas j.G.Baaten Linda M.Bradley Infectious and Inflammatory Disease Center Sanford-Burnham Medical Research Institute10901 North Torrey Pines RoadLa JollaCA 92037USA

Type 1 diabetes(T1D)results from autoimmune destruction of insulin-producing b-cells in the pancreatic *** is an immediate need to restore both b-cell function and immune tolerance to control disease progression and ultimately cure ***,there is no effective treatment strategy to restore glucose regulation in patients with ***3-expressing CD4^(+) regulatory T cells(Tregs)are potential candidates to control autoimmunity because they play a central role in maintaining ***,deficiencies in either naturally occurring Tregs(nTregs)themselves and/or their ability to control pathogenic effector T cells have been associated with ***,we hypothesize that nTregs can be replaced by FoxP3^(+) adaptive Tregs(aTregs),which are uniquely equipped to combat autoreactivity in *** nTregs,aTregs are stable and provide long-lived *** this review,we summarize the current understanding of aTregs and their potential for use as an immunological intervention to treat T1D.

关键词： type 1 diabetes adaptive regulatory T cells autoimmunity immunotherapy

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Transforming bilayer MoS2 into single-layer with strong photoluminescence using UV-ozone oxidation

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Nano Research 2015年第12期8卷 3878-3886页

作者： Weitao Su Naresh Komar Steve j. Spencer Ning Dai Debdulal Roy Institute of Materials Physics Hangzhou Dianzi University Hangzhou 310018 China Ningbo Institute of Materials Technology & Engineering Chinese Academy of Sciences Ningbo 315201 China National Physical Laboratory Hampton Road Teddington Middlesex TWI 10LW UK

The use of single-layer MoS2 in light emitting devices requires innovative methods to enhance its low photoluminescence （PL） quantum yield. In this work, we report that single-layer MoS2 with a strong PL can be prepared by oxidizing bilayer MoS2 using W-ozone oxidation. We show that as compared to mechanically-exfoliated single-layer MoS2, the PL intensity of the single-layer MoS2 prepared by W-ozone oxidation is enhanced by 20-30 times. We demonstrate that the PL intensity of both neutral excitons and trions （charged excitons） can be greatly enhanced in the oxidized MoS2 samples. These results provide novel insights into the PL enhancement of single-layer MoS2.

关键词： single-layer MoS2 W-ozone oxidation photoluminescence enhancement tip-enhanced Raman spectroscopy

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Control of synthetic gene networks and its applications

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Frontiers of Electrical and Electronic Engineering in China 2017年第2期5卷 124-135页

作者： David j Menn Ri-Qi Su Xiao Wang School of Biological and Health Systems Engineering Arizona State University Tempe AZ 85287 USA

Background： One of the underlying assumptions of synthetic biology is that biological processes can be engineered in a controllable way. Results： Here we discuss this assumption as it relates to synthetic gene regulatory networks （GRNs）. We first cover the theoretical basis of GRN control, then address three major areas in which control has been leveraged： engineering and analysis of network stability, temporal dynamics, and spatial aspects. Conclusion： These areas lay a strong foundation for further expansion of control in synthetic GRNs and pave the way for future work synthesizing these disparate concepts.

关键词： synthetic biology gene regulatory networks modeling GRN control stochasticity

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Effects of glycaemic management on diabetic kidney disease

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World journal of Diabetes 2017年第5期8卷 172-186页

作者： Richard j MacIsaac George jerums Elif I Ekinci Department of Endocrinology and Diabetes St Vincent’s Hospital Department of Medicine University of Melbourne Endocrine Centre Austin Health

Hyperglycaemia contributes to the onset and progression of diabetic kidney disease(DKD). Observational studies have not consistently demonstrated a glucose threshold, in terms of HbA1c levels, for the onset of DKD. Tight glucose control has clearly been shown to reduce the incidence of micro-or macroalbuminuria. However, evidence is now also emerging to suggest that intensive glucose control can slow glomerular filtration rate loss and possibly progression to end stage kidney disease. Achieving tight glucose control needs to be balanced against the increasing appreciation that glucose targets for the prevention of diabetes related complications need be individualised for each patient. Recently, empagliflozin which is an oral glucose lowering agent of the sodium glucose cotransporter-2 inhibitor class has been shown to have renal protective effects. However, the magnitude of empagliflozin's reno-protective properties are over and above that expected from its glucose lowering effects and most likely largely result from mechanisms involving alterations in intra-renal haemodynamics. Liraglutide and semaglutide, both injectable glucose lowering agents which are analogues of human glucagon like peptide-1 have also been shown to reduce progression to macroalbuminuria through mechanisms that remain to be fully elucidated. Here we review the evidence from observational and interventional studies that link good glucose control with improved renal outcomes. We also briefly review the potential reno-protective effects ofnewer glucose lowering agents.

关键词： Diabetic nephropathy Albuminuria Glucose control Glomerular filtration rate Diabetes Chronic kidney disease Empagliflozin Liraglutide Semaglutide

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