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Three new sesquiterpenes from Euonymus schensianus Maxim

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Chinese Chemical Letters 2009年第8期20卷 952-954页

作者： Xiao Ke Zheng Jin hui Guo wei Sheng feng Hong wei Li Henan University of Traditional Chinese Medicine Zhengzhou 450008 China

Three new sesquiterpenes, namely schensianol A （1）, schensianolside A （2） and schensianolside B （3） were isolated from the stems and leaves of Euonymus schensianus Maxim. Their structures were established by chemical methods and spectroscopic techniques including 2D NMR. ？ 2009 wei Sheng feng. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.

关键词： Euonymus schensianus Maxim Sesquiterpenes Schensianol A Schensianolside A Schensianolside B

Adenotonsillectomy outcomes regarding bone age and osteocalcin in treatment of obstructive sleep apnea syndrome in children

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World Journal of Pediatrics 2017年第2期13卷 158-164页

作者： Qing-Biao Zhang Yin-feng Li Ming-Xiu Li Ling-Yu Kong Liang-Fu Jiang hui-wei feng Xian-Liang Fan Department of Pediatric Internal Medicine Linyi People's HospitalLinyiChina Department of Pediatric Surgery Linyi People's HospitalLinyiChina Department of Breast Surgery Linyi Cancer HospitalLinyiChina

Background:To investigate the effect of adenotonsillec tomy (AT) on bone development,quality of life and polysomnography evaluation in children with obstructive sleep apnea syndrome (OSA).Methods:Preoperative and postoperative (6 months) physical examination,PSG,bone age (BA) and osteocalcin (OC) evaluation were performed on the selected OSA children (n=92) and the healthy children (n=87).The OSA children were also scored based on the OSA 18-item questionnaire.A two-year follow-up was conducted to evaluate BA and OC ***:After AT,81 (88.04%) OSA children recovered completely,eight (8.70%) achieved remarkable improvements,and three (3.26%) achieved moderate *** the OSA children,postoperative OSA 18-item score and the scores of the five domains were significantly higher than preoperative *** with the preoperative,body mass index (BMI),weight for age Z-sores,height for age Z-sores,weight for height Z-sores and BMI Z-score in the OSA group 6 months after the operation were significantly increased,but no significant difference was detected between the OSA and the control *** changes of BA and chronological age in the OSA group were significantly different from those in the control *** years after AT,BA between the two groups was no longer significantly *** serum OC in the OSA group was lower than that in the control group,but increased to normal levels 6 months after *** analysis showed serum OC levels were negatively correlated with apnea hyponea index,obstructive apnea index,arousal index,and lowest oxygen ***:After AT,bone growth and development in children with OSA recovered gradually,and the serum OC levels decreased to the normal ***,preventive measures and positive treatments should be applied to minimize the negative effects of OSA in children.

关键词： obstructive sleep apnea syndrome OSA-18 score osteocalcin polysomnography

Graphene-Oxide-Based Q-Switched Fiber Laser with Stable Five-Wavelength Operation

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Chinese Physics Letters 2012年第11期29卷 81-84页

作者： ZHAO Jun-Qing WANG Yong-Gang YAN Pei-Guang RUAN Shuang-Chen CHENG Jian-Qun DU Ge-Guo YU Yong-Qin ZHANG Ge-Lin wei hui-feng LUO Jie Yuen H.Tsang Shenzhen Key Laboratory of Laser Engineering College of Electronic Science and TechnologyShenzhen UniversityShenzhen 518060 Department of Applied Physics Hong Kong Polytechnic UniversityHong KongChina State Key Laboratory of Optical Fiber and Cable Manufacture Technology Yangtze Optical Fiber and Cable Company Ltd.R&D CenterWuhan 430073

We demonstrate an erbium-doped ring-cavity fiber laser Q-switched by a graphene oxide-based saturable absorber(GOSA).The GOSA was fabricated by vertically evaporating GO-polyvinylalcohol(GO/PVA)composite dispersion,and has a good performance under room *** a specially fabricated fiber Bragg grating(FBG),stable five-wavelength lasing is realized and stabilized at different pump powers under any *** the pump power increases from 78.4 mW to 379.3 mW,the output power ranging from 1.9 mW to 16.6 mW could be obtained,with pulse duration from 6.8μs to 2.72μs,single pulse energy from 123.73 nJ to 229.74 nJ,and pulse repetition rate from 15.36 kHz to 72.25 *** the best of our knowledge,it is the first simultaneous realization of five-wavelength operation and pulse output in a GO Q-switched all fiber laser system.

关键词： pump fiber switched

Metal-organic frameworks with dinuclear metal centers for synergistically boosting CO2 photoreduction

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Science China Chemistry 2025年第1期68卷 201-208页

作者： hui-feng Wang Wen-Jie Shi Yu-Xin Yang Bao-Xia Dong Tong-Bu Lu Di-Chang Zhong School of Chemistry and Chemical Engineering Yangzhou University Institute for New Energy Materials and Low Carbon Technologies School of Materials Science and Engineering Tianjin University of Technology

Dinuclear metal synergistic catalysis （DMSC） has been proved powerful in boosting CO2reduction,while this has not been achieved in heterogeneous catalysts with long-range order *** this study,we,by introduction of metal catalytic centers into an indium-based metal-organic framework （MOF）,obtained a series of isostructural In-MOFs,including three MOFs with mononuclear metal catalytic center （M-In）,three MOFs with dinuclear homometallic catalytic centers （MM-In）,and three MOFs with dinuclear heterometallic catalytic centers (MM’-In,M/M’=Co（II）,Ni（II）,Zn（II）).It was found that all these MOFs can serve as catalysts for photochemical CO2reduction to *** with M-In,the catalytic activities of MM-In were obviously enhanced,and that of MM’-In was further significantly *** example,the CO yield of Co Zn-In reaches a record value of 12,700μmol g-1h-1,which is 4.0,8.1,9.4,and 18.6-fold higher than that of Co Co-In,Zn Zn-In,Co-In,and Zn-In,***,the catalytic activities of Co Ni-In and Ni Zn-In also show different fold increase than those of corresponding dinuclear homometallic and mononuclear metallic *** results of control experiments and theoretical calculation reveal that the higher catalytic activities of MM-In over M-In can be ascribed to the DMSC effect,and the higher catalytic activity of MM’-In over MM-In can be ascribed to the strengthened DMSC *** work reveals the relationship between DMSC effect and bimetal centers in CO2reduction,which provides new insights into the DMSC and paves a new way to design highly active catalysts for photochemical CO2reduction.

关键词： metal-organic frameworks dinuclear metal centers synergistic catalysis CO2 reduction photocatalysis

Interaction of major facilitator superfamily domain containing 2A with the blood-brain barrier

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Neural Regeneration Research 2025年第8期20卷 2133-2152页

作者： Yilun Ma Taiwei Dong Fei Luan Juanjuan Yang feng Miao Peifeng wei College of Pharmacy and First Clinical Medical College Shaanxi University of Chinese MedicineXianyangShaanxi ProvinceChina National Drug Clinical Trial Agency The Second Affiliated Hospital of Shaanxi University of Chinese Medicine/Xixian New District Central HospitalXi′anShaanxi ProvinceChina

The functional and structural integrity of the blood-brain barrier is crucial in maintaining homeostasis in the brain microenvironment;however,the molecular mechanisms underlying the formation and function of the blood-brain barrier remain poorly *** major facilitator superfamily domain containing 2A has been identified as a key regulator of blood-brain barrier *** plays a critical role in promoting and maintaining the formation and functional stability of the blood-brain barrier,in addition to the transport of lipids,such as docosahexaenoic acid,across the blood-brain ***,an increasing number of studies have suggested that major facilitator superfamily domain containing 2A is involved in the molecular mechanisms of blood-brain barrier dysfunction in a variety of neurological diseases;however,little is known regarding the mechanisms by which major facilitator superfamily domain containing 2A affects the blood-brain *** paper provides a comprehensive and systematic review of the close relationship between major facilitator superfamily domain containing 2A proteins and the blood-brain barrier,including their basic structures and functions,cross-linking between major facilitator superfamily domain containing 2A and the blood-brain barrier,and the in-depth studies on lipid transport and the regulation of blood-brain barrier *** comprehensive systematic review contributes to an in-depth understanding of the important role of major facilitator superfamily domain containing 2A proteins in maintaining the structure and function of the blood-brain barrier and the research progress to *** will not only help to elucidate the pathogenesis of neurological diseases,improve the accuracy of laboratory diagnosis,and optimize clinical treatment strategies,but it may also play an important role in prognostic *** addition,the effects of major facilitator superfamily domain containing 2A on blood-brain barrier lea

关键词： blood-brain barrier(BBB) caveolin-1 central nervous system docosahexaenoic acid endothelial cells lysophosphatidylcholine major facilitator superfamily domain containing 2A(MFSD2A) transcytosis

Modular assembly of Co4-thiacalix[4]arene units and Keggin-type SiW12O40 for visible-light photothermal conversion

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Tungsten 2025年第1期7卷 112-119页

作者： Jia-hui Li Qing Zhao Dong-Ao Mao Kun Zhou Bao-Kuan Chen Yan-feng Bi School of Petrochemical Engineering Liaoning Petrochemical University

The construction of metal-organic coordination clusters（MCCs） using modular secondary building units is an important method for preparing functional *** this study,two new MCCs modularly assembled from Keggin-type {SiW12O40}H4TC4A=p-tert-Butylthiacalix[4]arene(SiW12) units and thiacalixarene-supported Co4-thiacalix[4]arene(Co4-TC4A polynuclear second-building units（PSBUs,H4TC4A=p-tert-Butylthiacalix[4]arene） are *** two MCCs,abbreviated as Co4-SiW12and Co8-SiW12,were structurally characterized by single-crystal X-ray *** Co4-SiW12is a supramolecular structure involving cation-anion interactions between Co4-TC4A PSBUs and ***8-SiW12features "barbell-like" shapes with two Co4-TC4A coordinatively linked to a Keggin-type SiW12unit on opposite via W-O_t-Co *** coordination of Co4-TC4A to SiW12in Co8-SiW12resulted in significantly improved photothermal conversion performances compared with Co4-SiW12and pure SiW12or ***-gap determination and photophysical analysis combined with density functional theory calculations indicated the binding mode between Co4-TC4A PSBUs and SiW12,which considerably influences the way of electron transport and the conversion ability of visible light to heat.

关键词： Modular construction Photothermal conversion Polyoxometalate Thiacalixarene

Depression mechanism of sulfite ions on sphalerite and Pb^(2+)activated sphalerite in the flotation separation of galena from sphalerite

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International Journal of Minerals,Metallurgy and Materials 2025年第2期32卷 335-345页

作者： feng Zhang Chenyang Zhang Linlin Wu wei Sun Hongliang Zhang Jianhua Chen Yong Pei Songjiang Li Engineering Research Center of Ministry of Education for Carbon Emission Reduction in Metal Resource Exploitation and Utilization Hunan International Joint Research Center for Efficient and Clean Utilization of Critical Metal Mineral ResourcesSchool of Minerals Processing and BioengineeringCentral South UniversityChangsha 410083China State Key Laboratory of Mineral Processing Beijing General Research Institute of Mining&MetallurgyBeijing 100160China Hunan Provincial Key Laboratory of Micro&Nano Materials Interfaces Science College of Chemistry and Chemical EngineeringCentral South UniversityChangsha 410083China School of Resources Environment and MaterialsGuangxi UniversityNanning 530004China Department of Chemistry Xiangtan UniversityXiangtan 411105China China Railway Resource Group Co.Ltd Beijing 102300China

The depression mechanism of sulfite ions on sphalerite and Pb^(2+)activated sphalerite in the flotation separation of galena from sphalerite still lacked in-depth ***,the depression mechanism of sulfite ions on sphalerite and Pb^(2+)activated sphalerite in the flotation separation of galena from sphalerite was further systematically investigated with experiments and density functional theory(DFT)*** X-ray photoelectric spectroscopy(XPS)results,DFT calculation results,and frontier molecular orbital analysis indicated that sulfite ions were difficult to be adsorbed on sphalerite surface,suggesting that sulfite ions achieved depression effects on sphalerite through other non-adsorption ***,the oxygen content in the surface of sphalerite treated with sulfite ions in creased,which enhanced the hydrophilicity of the sphalerite and further increased the difference in hydrophilicity between sphalerite and ***,sulfite ions were chelated with lead ions to form PbSO_(3)in *** hydrophilic PbSO_(3)was more easily adsorbed on sphalerite than *** interaction between sulfite ions and lead ions could effectively inhibit the activation of *** addition the UV spectrum showed that after adding sulfite ions,the peak of perxanthate in the sphalerite treated xanthate solution was significantly stronger than that in the galena with xanthate solution,indicating that xanthate interacted more readily with sulfite ions and oxygen mo lecules within the sphalerite system,leading to the formation of ***,sulfite ions hardly depressed the flotation of ga lena and could promote the flotation of galena to some *** study deepened the understanding of the depression mechanism o sulfite ions on sphalerite and Pb^(2+)activated sphalerite.

关键词： sphalerite galena sulfite ion density functional theory depression mechanism

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光子晶体光纤超连续谱光源

深圳大学学报（理工版） 2011年第4期28卷 295-301页

作者：阮双琛闫培光郭春雨韦会峰深圳大学电子科学与技术学院深圳市激光工程重点实验室深圳518060 长飞光纤光缆有限公司研发中心武汉430073

介绍该课题组近两年在光子晶体光纤超连续谱方面的主要研究成果,包括基于连续波泵浦研制全光纤化超连续谱源,利用级联一段高非线性正常色散光纤,通过光纤的受激拉曼散射效应实现超连续谱的平坦化;基于皮秒锁模光纤激光器实现全光纤化5 ... 详细信息

介绍该课题组近两年在光子晶体光纤超连续谱方面的主要研究成果,包括基于连续波泵浦研制全光纤化超连续谱源,利用级联一段高非线性正常色散光纤,通过光纤的受激拉曼散射效应实现超连续谱的平坦化;基于皮秒锁模光纤激光器实现全光纤化5 W输出超连续谱源;拉制一段145 m的锥形光子晶体光纤,利用自制的纳秒光纤激光器与锥形光子晶体光纤熔接,制备输出功率2.2 W的宽带超连续谱源;利用自制的网状光子晶体光纤和全固态光子带隙光纤,分别研究亚微米薄壁上偏振相关的超连续谱产生,以及基于四波混频效应产生的超连续谱.

关键词：光电子与激光技术光纤激光器光子晶体光纤超连续谱锥形光纤色散

Properties of PAn/PVA Conducting Composite Film by Electrochemical Polymerization

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Semiconductor Photonics and Technology 1999年第4期5卷 216-220页

作者： ZHENG Jian-bang,WANG hui,feng wei,WU Hong-cai (School of Electron & Information Engineering, Xi’an Jiaotong University, Xi’an 710049,CHN)

The polyaniline (PAn)/poly(vinyl alcohol) (PVA) conductive composite film is synthesized with perchloric acid (HClO 4) as the dopant and oxidant in reaction system by electrochemical polymerization. The result shows that this composite film has very high conductive properties, the maximum value of conductivity reaches 0.173 S/cm at the concentration 0.75 mol. The influences of HClO 4 on the conductivity of the composite film are *** addition,the electrode reaction progress is discussed with the result that obtained from SEM and FTIR analyzing.

关键词： Conducting Composites Film Electrochemical Polymerization Polyaniline Poly(Vinyl Alcohol)