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Rare Metals 2024年第6期43卷 2536-2545页

作者： Lin-Tao dou Bei Li Hao-Long Nie Dong-Dong Xiao Chao-Qun Shang Xiao-Min Wang Zhan-Hui Zhang Katerina E.Aifantis Pu Hu School of Materials Science and Engineering Wuhan Institute of TechnologyWuhan 430205China Huairou Division Institute of PhysicsChinese Academy of SciencesBeijing 101400China Department of Mechanical and Aerospace Engineering University of FloridaGainesvilleFL 32603USA

LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2)(NCM811)is the most promising cathode for high-energy Li-ion batteries,despite its poor cycling stability that originates from the reactions that occur with the ***,to solve this interfacial issue,a facile electrolytic electrochemical polymerization process was introduced in this paper,and a uniform conductive electrolyte interface(polyaniline)was successfully constructed on the surface of the NCM811 porous electrode(PANI-NCM),which facilitated the charge transfer during charge/*** side reactions at the interface between the cathode and the electrolyte are suppressed,and thereby,the cycling performance and rate capability are considerably ***-NCM delivers an initial capacity of 157.2 mAh·g^(-1)as well as excellent cyclability(capacity retention of 88%after 500 cycles at 2C),whereas the capacity of the bare NCM811 has dropped to 31.3 mAh·g^(-1).In addition,polypyrrole and polythiophene also can be formed through electrolytic electrochemical polymerization process,which provides a practicable tactic to modify the interfacial stability of cathodes for high-energy Li-ion batteries.

关键词： Lithium-ion battery Ni-rich cathode In-situ polymerization Conductive polymer Electrochemical performance

Building stabilized Cu_(0.17)Mn_(0.03)V_(2)O_(5−□)·2.16H_(2)O cathode enables an outstanding room‐/low‐temperature aqueous Zn‐ion batteries

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Carbon Energy 2024年第8期6卷 25-35页

作者： Ao Wang Dai‐Huo Liu Lin Yang Fang Xu Dan Luo Haozhen dou Mengqin Song Chunyan Xu Beinuo Zhang Jialin Zheng Zhongwei Chen Zhengyu Bai Key Laboratory of Green Chemical Media and Reactions Ministry of EducationCollaborative Innovation Center of Henan Province for Green Manufacturing of Fine ChemicalsSchool of Chemistry and Chemical EngineeringHenan Normal UniversityXinxiangHenanChina The State Key Laboratory of Catalysis(SKLC) Power Battery and System Research CenterDalian Institute of Chemical PhysicsChinese Academy of SciencesDalianChina

Vanadium oxide cathode materials with stable crystal structure and fast Zn^(2+)storage capabilities are extremely important to achieving outstanding electrochemical performance in aqueous zinc‐ion *** this work,a one‐step hydrothermal method was used to manipulate the bimetallic ion intercalation into the interlayer of vanadium *** pre‐intercalated Cu ions act as pillars to pin the vanadium oxide(V‐O)layers,establishing stabilized two‐dimensional channels for fast Zn^(2+)*** occupation of Mn ions between V‐O interlayer further expands the layer spacing and increases the concentration of oxygen defects(Od),which boosts the Zn^(2+)diffusion *** a result,as‐prepared Cu_(0.17)Mn_(0.03)V_(2)O_(5−□)·2.16H_(2)O cathode shows outstanding Zn‐storage capabilities under room‐and lowtemperature environments(e.g.,440.3 mAh g^(−1)at room temperature and 294.3 mAh g^(−1)at−60°C).Importantly,it shows a long cycling life and high capacity retention of 93.4%over 2500 cycles at 2 A g^(−1)at−60°***,the reversible intercalation chemistry mechanisms during discharging/charging processes were revealed via operando X‐ray powder diffraction and ex situ Raman *** strategy of a couple of 3d transition metal doping provides a solution for the development of superior room‐/lowtemperature vanadium‐based cathode materials.

关键词： aqueous zinc‐ion batteries Cu_(0.17)Mn_(0.03)V_(2)O_(5−□)·2.16H_(2)O oxygen defects room‐/lowtemperature performance stabilized nanostructure

Establishing a new testing protocol of the electrochemical stability window for electric double-layer capacitors

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Science China Chemistry 2024年

作者： Ruilin Hou Xiaoxi Zhao Tingting Liang Qingyun dou Shan Xu Xingbin Yan School of Materials Science and Engineering Sun Yat-sen University Laboratory of Clean Energy Chemistry and Materials Lanzhou Institute of Chemical PhysicsChinese Academy of Sciences College of Engineering and Applied Sciences Nanjing University Center of Industrial Analysis and Testing Guangdong Academy of Science

The electrochemical stability window (ESW) is crucial for determining the energy density of electric double-layer capacitors(EDLCs).However,current ESW testing protocols of EDLCs are strongly affected by artificial factors,thereby leading to unreliable *** solve this problem,we first identify the key shortcomings of the traditional protocols by analyzing their test ***,taking an aqueous carbon-based EDLC as an example,we design a side reaction descriptor to represent the response difference in the charging capacitance to side reactions between the cyclic voltammetry and galvanostatic chargedischarge *** the aid of this descriptor,we propose a new ESW testing protocol,which is not only able to completely avoid the adverse influence of subjective factors but also fully consider the operating condition *** protocol can be extended from the single electrode to the full *** work proposes a more rigorous definition of ESW and provides a reliable protocol for evaluating the ESW of EDLCs.

关键词：

受限回程链路下无人机辅助MEC的空地能耗折中

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华中科技大学学报（自然科学版） 2024年第3期52卷 142-148页

作者：李安窦邵婷南昌大学信息工程学院江西南昌330031

针对无人机(UAV)辅助的移动边缘计算(MEC)网络中无人机的能耗和地面用户的能耗的矛盾关系,研究了受限回程链路下的UAV辅助的MEC网络的空地能耗折中问题,同时考虑到无人机的能耗与地面用户的能耗通常相差几个数量级,引入放大因子兼顾地... 详细信息

针对无人机(UAV)辅助的移动边缘计算(MEC)网络中无人机的能耗和地面用户的能耗的矛盾关系,研究了受限回程链路下的UAV辅助的MEC网络的空地能耗折中问题,同时考虑到无人机的能耗与地面用户的能耗通常相差几个数量级,引入放大因子兼顾地面用户能耗.通过联合优化计算任务分配、GUs发射功率、GUs卸载时间和无人机轨迹,以最小化加权总能耗,可以表示空地能耗之间的权衡关系.由于所提出问题的非凸性使其难以优化,提出了一种基于块坐标下降法和连续凸近似技术的两阶段交替迭代优化算法得到该问题的次优解.仿真实验结果验证了所提出的方案在兼顾公平性条件下刻画了无人机能耗和用户能耗之间的折中关系,并在降低总能耗方面优于其他基准方案.

关键词：无人机辅助的移动边缘计算受限回程链路空地能耗折中计算资源分配轨迹优化

Nanocarbon catalysts with co-active S−P−C sites enhance metal-free direct oxidation of alcohols

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SusMat 2024年第5期4卷 202-215页

作者： Juan Meng Huidong Liu Jianing Xu Yuhan Lou Haixin Sun Bo Jiang Yongzhuang Liu Hengfei Qin Shuo dou Haipeng Yu Key Laboratory of Bio-Based Material Science and Technology of Ministry of Education Northeast Forestry UniversityHarbinChina School of Resources and Environmental Engineering Jiangsu University of TechnologyChangzhouChina School of Urban Construction Changzhou UniversityChangzhouChina College of Chemistry Chemical Engineering and Resource UtilizationNortheast Forestry UniversityHarbinChina

In this study,a sulfur–phosphorus co-doped nanocarbon(SPC)catalyst was syn-thesized using a straightforward one-step colloidal carbonization method and demonstrated high performance in the metal-free direct oxidation of alcohols to *** metal-free SPC catalyst showed exceptional efficiency,achiev-ing a conversion rate of 90%for benzyl alcohol and a selectivity of 94%toward benzaldehyde within only 1 h at 130◦***,it displays exceptional cycle stability and a high turnover frequency(17.1×10-3 mol g-1 h-1).Theoretical analysis suggested that the catalyst’s superior performance is attributed to the presence of unsaturated edge defects and S-P-moieties,which increase the density of states at the Fermi level,lower the band gap energy,and promote electron ***,the doping introduces cooperative co-active S-P-C sites,facilitating a synergistic multisite catalytic effect that lowers the energy *** findings represent a significant advancement in the field of metal-free direct alcohol oxidation.

关键词： alcohol oxidation reaction carbon catalysts electronic structures

Preparation of water-soluble fluorescent probe based on copper nanoparticles and its detection of tetracycline in meat

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Optoelectronics Letters 2024年

作者： ZULPIYE Hasanjan dou Xiaozong ZHANG hongyan Xinjiang Key Laboratory of Solid State Physics and Devices， Xinjiang University School of Physics Science and Technology， Xinjiang University

In this study， a water-soluble fluorescent probe based on copper nanoparticles (CuNPs) was synthesized using a hydrothermal method with BSA (BSA@CuNPs) as a protectant， and it was utilized to efficiently detect the concentration of tetracycline (TC). Upon the addition of TC to the BSA@CuNPs probe， its fluorescence intensity is obviously diminished due to the keto-enol functions C=O group in TC connects with the hydroxyl group on the BSA@CuNPs probe to form a non-fluorescent complex， which can be successfully utilized for detecting TC concentration. Linear range and detection limit for TC detection are 0.1-130 μmol/L and 90 nmol/L. Furthermore， the BSA@CuNPs probe was applied to detect TC concentrations in real meat samples， with recoveries ranging from 95.40% to 102.13%， and the relative standard deviation was below 2.73%. Therefore， BSA@CuNPs probe exhibits high sensitivity and selectivity for TC， which will be used for the study of TC analysis in meat.

关键词：

Nonlinear Multimodal Interference as Ultrafast Photonic Device for Dual-Wavelength Domain-Wall Dark Pulse Generation

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Chinese Physics Letters 2024年第7期41卷 47-52页

作者：王珊宋博乐窦鑫河乔飞鸿李响王锦波吕志国 School of Physical Science and Technology Key Laboratory of Semiconductor Photovoltaic Technology of Inner Mongolia Autonomous RegionInner Mongolia UniversityHohhot 010021China

In comparison to bright pulses, better stability that is not susceptible to loss makes dark pulses accessible for applications in such fields as signal processing, optics sensing, and quantum communication. Here we investigate the dual-wavelength domain-wall dark pulse generation in a graded-index multimode fiber(GIMF) based anomalous dispersion single-mode fiber(SMF) laser. By optimizing intra-cavity nonlinearity and pulse polarization, the mode-locked states can evolve each other between bright pulses, dark pulses, and bright-dark pulse pairs. The evolution mechanism among them may be relevant to the coherent mode superposition, spectral filtering, and mode selection in SMF-GIMF-SMF hybrid-fiber modulation devices that affect the pulse formation and evolution in temporal, frequency, and space domains. These results provide a valuable reference for promoting further development of nonlinear optics and ultrafast optics, in which ultrafast photonic devices, with low cost, simple manufacture as well as wide adaptability, as novel pulsed generation technique, play a vital role.

关键词： fiber polarization optics

HPLC combined with chemometrics for quality control of Huamoyan Granules or Capsules

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Chinese Herbal Medicines 2024年第3期16卷 449-456页

作者： Minhang dou Jiayi Huang Mimi Yu Huahua Li Yang Song Ziwei Peng Shouying Du Jie Bai School of Chinese Materia Medica Beijing University of Chinese MedicineBeijing 100029China Beijing Institute for Drug Control NMPA Key Laboratory for Quality Evaluation of Traditional Chinese Medicine(Traditional Chinese Patent Medicine)Beijing Key Laboratory of Analysis and Evaluation on Chinese MedicineBeijing 102206China

Objective:Huamaoyan Granules(HMYG)and Huamaoyan Capsules(HMYC)are Chinese patent medicines with different dosage forms of the same *** to the different preparation process,the chemical composition of these Chinese patent medicines varies greatly among different forms,but there were few studies on the difference comparison and quality control of *** order to improve the effectiveness and safety in its clinical application,an idea combining high performance liquid chromatography(HPLC)and chemometrics was put forward to study the quality control of Chinese patent medicines in different dosage forms of the same ***:The differential markers of HMYG and HMYC were explored based on HPLC fingerprint and chemometrics including orthogonal projections to latent structures-discriminant analysis(OPLS-DA),principal component analysis(PCA),and hierarchical cluster analysis(HCA).Finally,the quantitative analysis method of related components was established by ***:A quality control method for HMYG and HMYC was ***,the chemical components of HMYG and HMYC were systematically analyzed by HPLC *** exploration showed that there were 20 characteristic peaks and 57 common ***,the potential differential markers between HMYG and HMYC were explored by chemometrics,and the differential markers were screened after intersection with the 20 characteristic ***,HPLC quantitative analysis methods for nine components were established,including seven differential markers(neochlorogenic acid,protocatechualdehyde,chlorogenic acid,cryptochlorogenic acid,caffeic acid,rosmarinic acid and salvianolic acid A).The results of HPLC quantitative analysis showed that the contents of eight components in HMYG and HMYC samples were significantly *** to the above results,the differential markers between HMYG and HMYC screened based on HPLC fingerprint and chemometrics can effectively characterize the differ

关键词： chemometrics Chinese patent medicine high performance liquid chromatography fingerprint Huamoyan Granules/Capsules quality control synovitis

端羟基叠氮呋咱醚氧杂丁烷-HTPE嵌段共聚物合成及内增塑性能

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含能材料 2024年第6期32卷 651-659,I0003页

作者：温昱佳张婧窦金康谭博军刘宁西安近代化学研究所陕西西安710065 氟氮化工资源高效开发与利用国家重点实验室陕西西安710065

针对增塑剂易迁移、渗出进而严重影响聚合物基复合材料物化性能和机械性能的问题,研究通过3-硝基-4-羟基呋咱与3,3-二溴甲基氧杂丁环(BBMO)偶联合成2种新单体3-(4-硝基呋咱-3-氧甲基)-3-溴甲基氧杂环丁烷(BrNFMO)、3,3-二(4-硝基呋咱-3... 详细信息

针对增塑剂易迁移、渗出进而严重影响聚合物基复合材料物化性能和机械性能的问题,研究通过3-硝基-4-羟基呋咱与3,3-二溴甲基氧杂丁环(BBMO)偶联合成2种新单体3-(4-硝基呋咱-3-氧甲基)-3-溴甲基氧杂环丁烷(BrNFMO)、3,3-二(4-硝基呋咱-3-氧甲基)氧杂环丁烷(BNFMO),以端羟基聚醚(HTPE)为大分子引发剂,在三氟化硼乙醚催化下分别与BrNFMO、BNFMO以及对照组BBMO共聚后叠氮化,制备得到三种内增塑嵌段共聚物,对其进行结构、热分解行为、内增塑性能测试,并对所设计目标共聚单元进行量化计算以评估其爆轰性能。最后对共聚工艺进行了优化,通过“假活性”聚合策略对引入嵌段的程度进行控制。结果表明,该系列新型含能共聚单元具有优于现有叠氮基氧杂环丁烷单体的能量水平。与直接将叠氮基团引入聚合物相比,通过呋咱醚桥联结构将叠氮基团进行引入能够通过内增塑策略获得具有更低玻璃化转变温度T_(g)与黏度的含能共聚物(T_(g)可降低5.27℃,黏度可降低4.90 Pa·s),其热稳定性也得到了提高(T_(d)可提高7.3℃)。

关键词：呋咱含能聚合物阳离子开环聚合含能粘合剂热稳定性内增塑

Oxygenated carbon nitride-based high-energy-density lithium-metal batteries

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Interdisciplinary Materials 2024年第5期3卷 791-800页

作者： Mengnan Shen Ying Wei Man Ge Shengdong Yu Ronghui dou Liuhua Chen Feng Wang Yunhui Huang Henghui Xu School of Materials Science and Engineering Huazhong University of Science and TechnologyWuhanChina School of Chemistry and Material Science Hubei Engineering UniversityXiaoganChina

Lithium(Li)-metal batteries with polymer electrolytes are promising for high-energy-density and safe energy storage ***,current polymer electrolytes suffer either low ionic conductivity or inadequate ability to suppress Li dendrite growth at high current *** study addresses both issues by incorporating two-dimensional oxygenated carbon nitride(2D OCN)into a polyvinylidene fluoride(PVDF)-based composite polymer electrolyte and modifying the Li anode with *** OCN nanosheets incorporated PVDF electrolyte exhibits a high ionic conductivity(1.6×10^(-4)S cm^(-1)at 25℃)and Li+transference number(0.62),wide electrochemical window(5.3),and excellent fire ***,the OCN-modified Li anode in situ generates a protective layer of Li_(3)N during cycling,preventing undesirable reactions with PVDF electrolyte and effectively suppressing Li dendrite *** cells using the upgraded PVDF polymer electrolyte and modified Li anode demonstrate long cycling stability over 2500 h at 0.1 mA cm^(-2).Full cells with a high-voltage LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2)cathode exhibit high energy density and long-term cycling stability,even at a high loading of 8.2 mg cm^(-2).Incorporating 2D OCN nanosheets into the PVDF-based electrolyte and Li-metal anode provides an effective strategy for achieving safe and high-energy-density Li-metal batteries.

关键词： additive lithium protection oxygenated carbon nitride polymer electrolytes