检索结果-南通市图书馆

Chinese Journal of Polymer Science 2024年第9期42卷 1270-1277,I0005页

作者： Yue Huang guang-tao mei Zan Hua guang-Ming Liu Hefei National Research Center for Physical Sciences at the Microscale Department of Chemical PhysicsKey Laboratory of Surface and Interface Chemistry and Energy Catalysis of Anhui Higher Education InstitutesUniversity of Science and Technology of ChinaHefei230026China The Key Laboratory of Functional Molecular Solids Ministry of Educationand Department of Materials ChemistrySchool of Chemistry and Materials ScienceAnhui Normal UniversityWuhu214002China

The counterion-mediated hydrogen bonding(CMHB)is related to the hydrogen bonding between bound counterions and polyelectrolyte chains in polyelectrolyte systems,where the counterions can both electrostatically bind to the charged groups of polyelectrolyte chains and act as hydrogen bond donors or acceptors to form hydrogen bonds with the hydrogen bond sites associated with polyelectrolyte chains simultaneously.A large number of literatures illustrate that strong polyelectrolytes(SPs)are insensitive to pH,which severely limmits the applications of SPs as smart ***,our studies have demonstrated that the CMHB makes SPs *** perspective discusses the mechanism of pH responsiveness of SPs and the pH-tunable properties of SPs,based on the pH-controlled CMHB *** future research directions on the pH responsiveness of SPs are also discussed *** is anticipated that the study of the pH responsiveness of SPs not only will provide a new understanding of the fundamental properties of SPs,but also will greatly expand the applications of SPs in the field of smart materials.

关键词： Counterion binding Hydrogen bond Polyelectrolyte brush Polyelectrolyte complexation

在线全文

学校读者我要写书评

暂无评论

大采高工作面末采阶段联合注浆加固技术

煤炭工程 2019年第4期51卷 49-53页

作者：马赛陶广美史中刚山西晋煤集团技术研究院有限责任公司山西晋城048006 山西晋城煤业集团寺河煤矿山西晋城048200

针对寺河矿大采高工作面末采阶段矿压显现剧烈,易出现片帮、冒顶,进而影响液压支架顺利撤出的问题,采用新型无机注浆材料对距主撤架通道后40m范围煤体进行超前预加固,并在撤架通道开采侧煤体局部地区补注少量有机注浆材料的联合注浆加... 详细信息

针对寺河矿大采高工作面末采阶段矿压显现剧烈,易出现片帮、冒顶,进而影响液压支架顺利撤出的问题,采用新型无机注浆材料对距主撤架通道后40m范围煤体进行超前预加固,并在撤架通道开采侧煤体局部地区补注少量有机注浆材料的联合注浆加固技术,有效解决了大采高工作面末采阶段片帮、漏顶等难题,实现了工作面与主撤架通道的安全快速贯通。通过对末采时间和末采注浆成本的对比分析,联合注浆加固较单纯使用有机材料注浆加固获得了更好的经济效益。

关键词：大采高末采联合注浆加固效率效益

Palladium installed copper-organic framework for C–C coupling reactions

在线全文

学校读者我要写书评

暂无评论

Science China Chemistry 2025年

作者： Yu-mei Wang mei-Xia tao Kai-Ming Mo Xu Chen Shu-Hua Zhong Elena S Shubina Guo-Hong Ning Dan Li College of Chemistry and Materials Science Guangdong Provincial Key Laboratory of Supramolecular Coordination ChemistryJinan University A.N.Nesmeyanov Institute of Organoelement Compounds Russian Academy of Sciences

The formation of C–C bonds is a crucial aspect of organic synthesis. Synthesists' long-term objective is to identify novel catalysts to optimize reaction systems based on traditional transition metal catalysis. This study explores the synthesis and catalytic potential of palladium-installed covalent metal-organic frameworks(CMOFs) based on copper cyclic trinuclear units(Cu-CTUs). By incorporating palladium ions into the imine-based framework JNM-7 through a straightforward immersion method, we achieved a notable enhancement in catalytic activity for critical C–C coupling reactions, including C–H arylation and Sonogashira cross-coupling. The resulting JNM-7-Pd demonstrated remarkable stability and recyclability, maintaining its efficiency over at least three cycles without any decline in efficiency.

关键词：

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

综放工作面注水降尘技术

西安科技大学学报 2013年第4期33卷 394-399页

作者：熊祖强袁广玉陶广美河南理工大学能源科学与工程学院河南焦作454000

赵庄二号井开采的3#煤层为厚煤层,选用的是综采放顶煤采煤方法,生产过程中粉尘浓度较大,传统的喷雾降尘方法不能够满足现场降尘的需要。为了进一步降低工作面粉尘浓度,改善工作面劳动环境,为创建安全、高效型矿井提供良好的生产条件,文... 详细信息

赵庄二号井开采的3#煤层为厚煤层,选用的是综采放顶煤采煤方法,生产过程中粉尘浓度较大,传统的喷雾降尘方法不能够满足现场降尘的需要。为了进一步降低工作面粉尘浓度,改善工作面劳动环境,为创建安全、高效型矿井提供良好的生产条件,文中针对3#煤层孔隙率小、渗透性低、润湿性差等特征,采用混合注水方式进行煤层注水降尘技术分析研究及现场试验。分别从钻孔布置方式、注水封孔工艺、注水工艺及参数和降尘效果等方面进行了阐述,分析了煤层注水对工作面超前支承压力的影响变化,并提出了添加烷基酚聚氧乙烯醚TX-10表面活性剂改善煤体润湿性,增强了煤层注水润湿效果。结果表明,实施注水工艺技术后,煤层水分平均增量为1.61%,全尘平均降尘率达58.71%,呼尘平均降尘率为57.34%,大幅度降低了工作面粉尘浓度;添加润湿剂后,增加了钻孔注水量,缩短了注水时间,扩大了润湿范围,改善了注水效果。实践证明,该套注水降尘工艺用于综放工作面降尘是切实可行的。

关键词：综放工作面煤层注水润湿剂混合注水方式降尘技术

叠加应力影响巷道围岩变形规律及控制技术研究

在线全文

学校读者我要写书评

暂无评论

煤炭工程 2020年第11期52卷 47-51页

作者：陶广美周晋碧马赛张江利山西晋煤集团技术研究院有限责任公司山西晋城048000 山西晋城无烟煤矿业集团有限责任公司山西晋城048000

为了解决上覆煤柱应力叠加影响下巷道变形严重的问题,通过现场实测对巷道变形规律进行研究,采用钻孔窥视及静压注水试验对围岩破碎特征进行分析,制定了先注浆、再对锚杆二次预紧、最后预应力锚索补强的综合围岩控制方案,并进行工业性试... 详细信息

为了解决上覆煤柱应力叠加影响下巷道变形严重的问题,通过现场实测对巷道变形规律进行研究,采用钻孔窥视及静压注水试验对围岩破碎特征进行分析,制定了先注浆、再对锚杆二次预紧、最后预应力锚索补强的综合围岩控制方案,并进行工业性试验,结果表明:巷道修复后0~18d为初始变形阶段,是巷道治理的关键阶段;巷道浅层煤体裂隙发育数量较多且连通性较好,深层裂隙发育较少且连通性差,需要采用预应力锚索进行全长锚固补强;采用综合围岩控制方案后,巷道变形量得到有效控制,底鼓量最大为51mm,两帮最大移近量为42mm,顶板沉降量为4mm,巷道变形得到有效控制。

关键词：叠加应力持续变形注浆加固巷道治理全长预应力锚固

在线全文

学校读者我要写书评

暂无评论

近水平远距离下保护层开采卸压范围

西安科技大学学报 2014年第2期34卷 147-151页

作者：熊祖强陶广美袁广玉河南理工大学能源科学与工程学院河南焦作454000

为了确定晋城矿区保护层开采的卸压保护范围,采用相似模拟、现场实测的方法,研究了保护层开采过程中被保护层的竖向变形规律,得出了保护层开采的有效卸压范围,为相似条件下保护层开采及被保护层巷道布置提供依据。研究表明:保护层开采后... 详细信息

为了确定晋城矿区保护层开采的卸压保护范围,采用相似模拟、现场实测的方法,研究了保护层开采过程中被保护层的竖向变形规律,得出了保护层开采的有效卸压范围,为相似条件下保护层开采及被保护层巷道布置提供依据。研究表明:保护层开采后,被保护层煤体出现明显的竖向变形,沿工作面推进方向上依次分为压缩区、膨胀区、卸压膨胀区、膨胀区、压缩区;沿煤层上山方向的有效卸压保护角为81.6°,下山方向的有效卸压保护角为79°,走向有效卸压保护角为67.7°;在工作面后方37 m以远,3#煤体膨胀逐渐趋于稳定膨胀值为93 mm,膨胀率为1.55%,煤体卸压充分。

关键词：下保护层开采卸压范围相似模拟膨胀变形

Preparation of Low Ratio Magnesium Ccement by Acid Leaching Treatment of Boron Mud

在线全文

学校读者我要写书评

暂无评论

Journal of Wuhan University of Technology(Materials Science) 2025年第1期40卷 120-129页

作者： YANG mei ZHANG Mingzhe CHEN Hao School of Materials Science and Engineering Shenyang Jianzhu UniversityShenyang 110168China School of Physical Science and Technology Shenyang Normal UniversityShenyang 110168China

The effects of liquid-solid ratio and reaction time on the leaching rate of magnesium at room temperature were investigated,as well as the effects of the molar ratio of MgO/MgCl_(2),the amount of water added,and the amount of acid-impregnated slag dosed on the compressive strength and water resistance of *** results showed that the magnesium element in the boron mud could be maximally leached under the conditions of 1:1 concentration of hydrochloric acid at room temperature,liquid-solid ratio of 2.5 mL·g^(-1),and reaction time of 5 h,and the main products were amorphous SiO_(2) as well as a small amount of magnesium olivine which had not been completely *** LR-MOC prepared using the acid-soaked mixture could reach a softening coefficient of 0.85 for 28 d of water immersion when the molar ratio of MgO/MgCl_(2) was 2.2,the amount of water added was 0 g,and the acid-soaked slag dosing was 40 wt%,which also led to an appreciable late-strength,with an increase of 19.4%in compressive strength at 28 d compared to that at 7 *** previous studies,LR-MOC prepared in this way has a final strength phase that is not the more easily hydrolysed 3-phase but the lath-like *** this phenomenon,we analyzed the mechanism and found that,during the acid leaching process,a part of amorphous SiO_(2) dissolved in the acid leaching solution formed a silica sol,in which Mg^(2+)played a bridging role to make the silica sol more *** the addition and hydrolysis of MgO,the silica sol gel coagulation slows down,providing a capping layer to inhibit the hydrolysis of the 5-phase crystals and providing some strength after *** amorphous SiO_(2) in the other part of the acid-impregnated slag generated M-S-H gel with Mg^(2+)and OH-,which synergised with the dense structure composed of interlocking crystals to improve the water resistance of LR-MOC.

关键词： boron mud magnesium chloride-oxygen cement acid immersion water resistance silica sol

在线全文

学校读者我要写书评

暂无评论

Tor被动流量分析综述

软件学报 2025年第1期36卷 253-288页

作者：梅汉涛程光朱怡霖周余阳东南大学网络空间安全学院江苏省泛在网络安全工程研究中心(东南大学) 网络空间国际治理研究基地(东南大学) 紫金山实验室

随着网络的蓬勃发展,用户隐私正面临着前所未有的挑战.人们开发出多种匿名通信系统来保护隐私,第2代洋葱路由Tor (the second-generation onion router)是目前最为广泛使用的匿名通信系统.然而,卓越的匿名性也使之成为不法分子犯罪的温... 详细信息

随着网络的蓬勃发展,用户隐私正面临着前所未有的挑战.人们开发出多种匿名通信系统来保护隐私,第2代洋葱路由Tor (the second-generation onion router)是目前最为广泛使用的匿名通信系统.然而,卓越的匿名性也使之成为不法分子犯罪的温床,如今Tor中充斥着非法交易、网络犯罪等. Tor被动流量分析通过被动观察网络流量对Tor进行去匿名化,已成为最热门的去匿名化技术.从Tor与流量分析基本概念出发,介绍Tor被动流量分析技术的应用场景与威胁模型.按照技术类型将现有工作分为流量分类技术与流关联技术,依据分析流程分别对比其流量采集方法、特征提取方法、使用算法.最后探讨当前研究面临的主要挑战与未来可能的研究趋势.

关键词： Tor 流量分析流量分类网站指纹流关联

Microstructural evolution during the progressive transformation-induced plasticity effect in a Fe-0.1C-5Mnmedium manganese steel

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

International Journal of Minerals,Metallurgy and Materials 2025年第2期32卷 369-379页

作者： mei Zhang Wenhao Li Yangfei Chen Yang Jiang Xiaofei Guo Han Dong School of Materials Science and Engineering Shanghai UniversityShanghai 200444China State Key Laboratory of Advanced Special Steel Shanghai UniversityShanghai 200444China

The microstructural evolution of a cold-rolled and intercritical annealed medium-Mn steel(Fe-0.10C-5Mn)was investigated during uniaxial tensile ***-situ observations under scanning electron microscopy,transmission electron microscopy,and X-ray diffraction analysis were conducted to characterize the progressive transformation-induced plasticity process and associated fracture initiation *** findings were discussed with the local strain measurements via digital image *** results indicated that Lüders band formation in the steel was limited to 1.5%strain,which was mainly due to the early-stage martensitic phase transformation of a very small amount of the less stable large-sized retained austenite(RA),which led to localized stress concentrations and strain hardening and further retardation of *** small-sized RA exhibited high stability and progressively transformed into martensite and contributed to a stably extended Portevin-Le Chatelier *** volume fraction of RA gradually decreased from 26.8%to 8.2%prior to *** the late deformation stage,fracture initiation primarily occurred at the austenite/martensite and ferrite/martensite interfaces and the ferrite phase.

关键词： medium-Mn steel retained austenite progressive transformation-induced plasticity effect local strain fracture initiation

MixerKT:A Knowledge Tracing Model Based on Pure MLP Architecture

在线全文

学校读者我要写书评

暂无评论

Computers, Materials & Continua 2025年第1期82卷 485-498页

作者： Jun Wang Mingjie Wang Zijie Li Ken Chen Jiatian mei Shu Zhang Key Laboratory of Education Informatization for Nationalities Ministry of EducationYunnan Normal UniversityKunming650000China Yunnan Key Laboratory of Smart Education Yunnan Normal UniversityKunming650000China

In the field of intelligent education,the integration of artificial intelligence,especially deep learning technologies,has garnered significant *** tracing(KT)plays a pivotal role in this field by predicting students’future performance through the analysis of historical interaction data,thereby assisting educators in evaluating knowledgemastery and tailoring instructional *** knowledge tracingmethods,largely based on Recurrent Neural Networks(RNNs)and Transformer models,primarily focus on capturing long-term interaction patterns in sequential ***,these models may neglect crucial short-term dynamics and other relevant *** paper introduces a novel approach to knowledge tracing by leveraging a pure Multilayer Perceptron(MLP)*** proposeMixerKT,a knowledge tracing model based on theHyperMixer framework,which uniquely integrates global and localMixer feature *** architecture enables more effective extraction of both long-terminteraction trends and recent learning behaviors,addressing limitations in currentmodels thatmay overlook these key *** evaluations on twowidely-used datasets,ASSIS Tments2009 and Algebra2005,demonstrate that MixerKT consistently outperforms several state-of-the-art models,including DKT,SAKT,and Separated Self-Attentive Neural Knowledge Tracing(SAINT).Specifically,MixerKT achieves higher prediction accuracy,highlighting its effectiveness in capturing the nuances of learners’knowledge *** results indicate that our model provides a more comprehensive representation of student learning patterns,enhancing the ability to predict future performance with greater precision.

关键词： Knowledge tracing multilayer perceptron channel mixer sequence mixer