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Charge carrier dynamics in different crystal phases of CH_(3)NH_(3)PbI_(3)perovskite

Opto-Electronic Science 2022年第4期1卷 1-10,22-27页

作者： Efthymis Serpetzoglou Ioannis Konidakis George Kourmoulakis Ioanna Demeridou Konstantinos Chatzimanolis Christos Zervos George Kioseoglou emmanuel kymakis emmanuel Stratakis Institute of Electronic Structure and Laser(IESL) Foundation for Research and Technology-Hellas(FORTH)Herakleio 70013Greece Electrical and Computer Engineering Department Hellenic Mediterranean UniversityHerakleio 71004Greece Department of Materials Science and Technology University of CreteHerakleio 70013Greece Department of Physics University of CreteHerakleio 70013Greece.

Despite that organic-inorganic lead halide perovskites have attracted enormous scientific attention for energy conversion applications over the recent years,the influence of temperature and the type of the employed hole transport layer(HTL)on the charge carrier dynamics and recombination processes in perovskite photovoltaic devices is still largely *** particular,significant knowledge is missing on how these crucial parameters for radiative and non-radiative recombinations,as well as for efficient charge extraction vary among different perovskite crystalline phases that are induced by temperature ***,we perform micro photoluminescence(pPL)and ultrafast time resolved transient absorption spectroscopy(TAS)in Glass/Perovskite and two dierent Glass/ITO/HTL/Perovskite configurations at temperatures below room temperature,in order to probe the charge carrier dynamics of different perovskite crystalline phases,while considering also the effect of the employed HTL ***,CH_(3)NH_(3)Pbb films were deposited on Glass,PEDOT:PSS and PTAA polymers,and the developed Glass/CH_(3)NH_(3)PbI_(3)and Glass/ITO/HTL/CH_(3)NH_(3)PbI_(3)architectures were studied from 85 K up to 215 K in order to explore the charge extraction dynamics of the CH_(3)NH_(3)PbI_(3)orthorhombic and tetragonal crystalline *** is observed an unusual blueshift of the bandgap with temperature and the dual emission at temperature below of 100 K and also,that the charge carrier dynamics,as expressed by hole injection times and free carrier recombination rates,are strongly depended on the actual pervoskite crystal phase,as well as,from the selected hole transport material.

关键词： transient absorption spectroscopy p-photoluminescence variable temperature perovskite crystalline phases hole transport layer charge carrier dynamics

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Improving the operational stability of perovskite solar cells with cesium-doped graphene oxide interlayer

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Journal of Energy Chemistry 2024年第9期96卷 483-490页

作者： Masaud Almalki Katerina Anagnostou Konstantinos Rogdakis Felix T.Eickemeyer Mostafa Othman Minas M.Stylianakis Dimitris Tsikritzis Anwar Q.Alanazi Nikolaos Tzoganakis Lukas Pfeifer Rita Therisod Xiaoliang Mo Christian M.Wolff Aïcha Hessler-Wyser Shaik M.Zakeeruddin Hong Zhang emmanuel kymakis Michael Grätzel Laboratory of Photonics and Interfaces École Polytechnique Fédérale de Lausanne(EPFL)Lausanne 1015Switzerland Department of Electrical and Computer Engineering Hellenic Mediterranean UniversityHeraklionCrete 71410Greece Institute of Electrical and Microengineering(IEM)Photovoltaics and Thin-Film Electronics Laboratory(PV-Lab) École Polytechnique Fédérale de Lausanne(EPFL)Neuchâtel 2000Switzerland Department of Nursing Faculty of Health SciencesHellenic Mediterranean UniversityCrete 71410Greece Centre Interdisciplinaire de Microscopie Electronique École Polytechnique Fédérale de Lausanne(EPFL)Lausanne 1015Switzerland Future Energy Technology Institute King Abdulaziz City for Science and Technology(KACST)P.O.Box 6086Riyadh 11442Saudi Arabia State Key Laboratory of Photovoltaic Science and Technology Shanghai Frontiers Science Research Base of Intelligent Optoelectronics and PerceptionInstitute of OptoelectronicsDepartment of Materials ScienceFudan UniversityShanghai 200433China

Perovskite solar cells(PSCs)have made great advances in terms of power conversion efficiency(PCE),yet their subpar stability continues to hinder their *** interface between the perovskite layer and the charge-carrier transporting layers plays a crucial role in undermining the stability of *** this work,we propose a strategy to stabilize high-performance PSCs with PCE over 23%by introducing a cesium-doped graphene oxide(GO-Cs)as an interlayer between the perovskite and hole-transporting *** GO-Cs treated PSCs exhibit excellent operational stability with a projected T80(the time where the device PCE reduces to 80%of its initial value)of 2143 h of operation at the maximum powering point under one sun illumination.

关键词： Perovskite solar cells Doped graphene oxide Graphene related material Long-term operational stability

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A Triethyleneglycol C60 Mono-adduct Derivative for Efficient Electron Transport in Inverted Perovskite Solar Cells

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Chinese Journal of Chemistry 2023年第4期41卷 431-442页

作者： Azhar Fakharuddin Konstantina-Kalliopi Armadorou Leandros P.Zorba Marinos Tountas Tobias Seewald Anastasia Soultati Polychronis Tsipas Emilia R.Schütz Nikolaos Tzoganakis Stylianos Panagiotakis Konstantina Yannakopoulou Athanasios Dimoulas Vassilis Psycharis emmanuel kymakis Abd Rashid bin Mohd Yusoff Konstantinos Aidinis Lukas Schmidt-Mende Georgios C.Vougioukalakis Mohammad Khaja Nazeeruddin Maria Vasilopoulou Department of Physics University of Konstanz78457 KonstanzGermany Institute of Nanoscience and Nanotechnology National Center for Scientific Research DemokritosAgia Paraskevi15341 AthensGreece Department of Chemistry National and Kapodistrian University of Athens15771 AthensGreece Department of Electrical&Computer Engineering Hellenic Mediterranean UniversityEstavromenosHeraklionGR-71410 CreteGreece Department of Chemical Engineering Pohang University of Science and Technology(POSTECH)PohangGyeongbuk37673 Republic of Korea Department of Electrical and Computer Engineering Ajman UniversityP.O.Box 346AjmanUnited Arab Emirates Center of Medical and Bio-allied Health Sciences Research AjmanUnited Arab Emirates Institute of Chemical Sciences and Engineering École Polytechnique Fédérale de Lausanne(EPFL)Rue de l'Industrie 17CH-1951 SionSwitzerland

Inverted perovskite solar cells(PSCs)have attracted increasing attention in recent years owing to their low-temperature fabrication proces ***,they suffer from a limited number of electron transport materials available with[6,6]-phenyl C61 butyric acid methyl ester(PCBM)to be the most widely studied based on its appropriate energy levels and high electron *** low relative permittivity and aggregation tendency upon illumination of PCBM,however,compromises the solar cell efficiency whereas its modest hydrophobicity negatively impacts on the device *** electron transport materials with desired properties and appropriate degree of hydrophobicity are thus desirable for further developments in inverted ***,we synthesize a triethyleneglycol C60 mono-adduct derivative(termed as EPF03)and test it as a novel electron transport material to replace PCBM in inverted PSCs based on a quadruple cation(RbCsMAFA)*** also compare this derivative with two novel fullerenes decorated with two(EPF01)or one dodecyl(EPF02)long side *** latter two fail to perform efficiently in inverted PSCs whereas the former enabled a power conversion efficiency of 18.43%,which represents a 9%improvement compared to the reference device using PCBM(17.21%).The enhanced performance mainly stems from improved electron extraction and reduced recombination enabled by the insertion of the large relative permittivity amongst other properties of ***,our results indicate that triethylene glycol side chains can also passivate perovskite trap states,suppress ion migration and enhance photostability and long-term stability of EPF03 based perovskite solar cells.

关键词： Electron transport layer Defect passivation Biexponential trap flling Charge transfer Fullerenes

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Modelling die filling with charged particles using DEM/CFD

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Particuology 2012年第2期10卷 229-235页

作者： emmanuel Nkem Nwose School of Chemical Engineering University of Birmingham Birmingham B15 2TT UK

The effects of electrostatic charge on powder flow behaviour during die filling in a vacuum and in air were analysed using a coupled discrete element method and computational fluid dynamics （DEM]CFD） code, in which long range electrostatic interactions were implemented. The present 2D simulations revealed that both electrostatic charge and the presence of air can affect the powder flow hehaviour during die filling. It was found that the electrostatic charge inhibited the flow of powders into the die and induced a loose packing structure. At the same filling speed, increasing the electrostatic charge led to a decrease in the fill ratio which quantifies the volumetric occupancy of powder in the die. In addition, increasing the shoe speed caused a further decrease in the fill ratio, which was characterised using the concept of critical filling speed, When the electrostatic charge was low, the air/particle interaction was strong so that a lower critical filling speed was obtained for die filling in air than in a vacuum. With high electrostatic charge, the electrostatic interactions became dominant. Consequently, similar fill ratio and critical filling speed were obtained for die filling in air and in a vacuum.

关键词： DEMCFDElectrostaticsDie fillingPowder flowCohesionCharged particles

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Systems Analysis of Vulnerability to Hydrometeorological Threats: An Exploratory Study of Vulnerability Drivers in Northern Zimbabwe

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International Journal of Disaster Risk Science 2019年第2期10卷 204-219页

作者： emmanuel Mavhura Department of Geography Bindura University of Science Education

Disasters result from complex interactions of hazards and vulnerability conditions. Reducing human exposure and sensitivity to threats can reduce disaster impact. Prior knowledge about community vulnerability levels is crucial to minimizing potential losses from future threats. Most vulnerability studies focus on high-impact disasters and their temporal and spatial analyses. Yet highfrequency, low-impact disasters have a cumulative potential to severely disrupt or damage socioeconomic *** is limited knowledge especially in the global south about the creation of vulnerability to hydrometeorological threats. Using a systems approach, this study explores ways in which communities in the northern semiarid tropics of Zimbabwe are vulnerable to hydrometeorological *** predominantly qualitative study used literature review, interviews, transect walks, and focus groups to gather data from selected samples involving smallholder farmers with in-depth knowledge about community vulnerability. The results show that the communities are vulnerable to multiple hydrometeorological threats due to multiple interacting factors including rainfed and floodbased farming, land tenure, topography, climate, and other socioeconomic conditions such as inadequate income sources and high poverty. In order to reduce vulnerability,this study provides five policy options for government and nongovernmental organization interventions, including the need to transform rural economies beyond the traditional rainfed and flood-based farming systems.

关键词： Community vulnerability Flood-based farming Hydrometeorological threats Rainfed agriculture Zimbabwe

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Physico-chemical characterization of a farmland affected by wastewater in relation to heavy metals

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Journal of Zhejiang University-Science A(Applied Physics & Engineering) 2008年第3期9卷 366-372页

作者： emmanuel U. ONWEREMADU Department of Soil Science and Technology Federal University of Technology PMB 1526 Owerri Nigeria

This study investigated selected properties of soils affected by wastewater and its relationship with some heavy metals. A free survey technique involving target sampling was used in siting soil profile pits. Soil samples were collected based on horizon differentiation and analyzed using routine and special analytical techniques. Soil data were subjected to correlation analysis using SAS program. Results show that all heavy metals studied had values above critical limits in the polluted soils using known standards and that these biotoxic metals decreased with soil depths. Highly significant (P=0.01 and 0.05) relationships were established between investigated heavy metals and some soil properties, especially soil pH and organic matter. Further studies involving more edaphic properties, biotoxic metals and their bioaccessibility in crops growing on wastewater soils will surely enhance knowledge and management of these highly anthropogenically influenced soils of the study site.

关键词： Bioavailability Characterization Heavy metals Soil pollution Wastewater

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A Unified Spatio-Temporal Framework of the Cuerno-Barabasi Stochastic Continuum Model of Surface Sputtering

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Communications in Theoretical Physics 2012年第7期58卷 165-170页

作者： Oluwole emmanuel Oyewande Department of Physics University of Ibadan

The nonlinear continuum model proposed by Cuerno and Barabasi is the most successful and widely acceptable theoretical description of oblique incidence ion sputtered surfaces to date and is quite robust in its predictions of the time evolution and scaling of interfaces driven by ion bombardment. However, this theory has thus far predicted only ripple topographies and rough surfaces for short and large scales, respectively. As a result, its application to the interpretation and study of nanodots, predicted by Monte Carlo simulations for, and observed in experiments of, oblique incidence sputtering is still unclear and, hence, an open problem. In this paper, we provide a new insight to the theory, within the same length scale, that explains nanodot formation on off-normal incidence sputtered surfaces, among others, and propose ways of observing the predicted topographies of the MC simulations, as well as possible control of the size of the nanodots, in the framework of the Cuerno-Barabasi continuum theory.

关键词： topographic phase diagrams surface nanostructures surface nanodots Cuerno-Barabasi model

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Abiraterone acetate for prostate cancer： a new era ot hormonal therapies

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Asian Journal of Andrology 2011年第5期13卷 663-664页

作者： emmanuel S Antonarakis Johns Hopkins Sidney Kimmel Comprehensive CancerCenter Baltimore MD 21231 USA

Therapies targeting the androgen receptor （AR） axis have constituted the HolyGraft in the management of advanced prostate cancer for seven decades） These hormonal therapies have traditionally taken two main forms： those that suppress gonadal androgen synthesis （e.g., the gonadotropin releasing hormone agonists/antagonists, such as leuprolide）, and those that inhibit the AR directly （e.g., the anti-androgens, such as bicalutamide）. However, although the vast majority of patients with prostate cancer initiaUy respond favorably to androgen-ablative therapies （manifested by tumor regressions and symptomatic improvements）, all patients will eventually develop further disease progression after a median of 18-24 months. This transformed disease state, known as castration-resistant prostate cancer （CRPC）, is invariably fatal.

关键词： Enzyme mechanisms

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Recent developments in the application of oil palm fibers in cement composites

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Frontiers of Structural and Civil Engineering 2020年第1期14卷 94-108页

作者： emmanuel Owoichoechi MOMOH Adelaja Israel OSOFERO School of Engineering University of AberdeenAberdeenAB243UEUK

Fibers obtained from different parts of the oil palm tree(Elaeis guineensis)have been under investigation for possible use in *** have been carried out investigating the engineering properties and possible applications of these ***,the experimental methods employed and the values of mechanical and physical properties recorded by various authors are *** has therefore become necessary to organize information which would be useful in the design of oil palm fiber cement composites and help researchers and engineers make informed decisions in further research and *** review provides information about fibers from different parts of the oil palm,their properties,enhancement techniques,current and potential application in cement composites.

关键词： broom cement composite concrete oil palm fiber Natural fiber-concrete sustainability

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Combining active immunotherapy with immune checkpoint blockade for the treatment of advanced prostate cancer

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Asian Journal of Andrology 2012年第4期14卷 520-521页

作者： emmanuel S Antonarakis Johns Hopkins Sidney Kimmel Comprehensive Cancer Center Baltimore MD 21231 USA

Combination immunotherapy is emerging as a promising approach for the treatment of advanced prostate cancer. This research highlight discusses the combination of a PSA-directed pox-viral vaccine and a monoclonal antibody blocking an important immune checkpoint molecule to treat men with metastatic castration- resistant prostate cancer. The results demonstrate feasibility and safety, as well as intriguing clinical responses to this combination therapy.

关键词： Dementia Nutrition Obesity Weight management

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