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Controllable incorporation of CdS nanoparticles into TiO_2 nanotubes for highly enhancing the photocatalytic response to visible light

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Science china chemistry 2009年第12期52卷 2148-2155页

作者： WANG ChengLin1,SUN Lan1,XIE KunPeng1 & LIN ChangJian1,2 1 Department of chemistry,college of chemistry and chemical engineering,xiamen university,xiamen 361005,china 2 State Key Laboratory of Physical chemistry of Solid Surfaces,xiamen university,xiamen 361005,china 1. Department of chemistry College of Chemistry and Chemical Engineering Xiamen University Xiamen 361005 China 2. State Key Laboratory of Physical chemistry of Solid Surfaces Xiamen University Xiamen 361005 China

A constant current electrochemical deposition was employed to incorporate CdS nanoparticles into the TiO2 nanotube arrays (TiO2NTs). The size and amount of CdS nanoparticles in TiO2NTs (CdS@TiO2NTs) were controllable via modulating current,deposition time and electrolyte concentration. It was revealed,from the scanning electron microscopy (SEM) images and X-ray photoelectron spectroscopy (XPS) in depth profile,that CdS nanoparticles were filled into TiO2 nanotubes. A shift of the absorption edge toward the visible region under the optimal electrodeposition condition was observed with the diffuse reflectance spectroscopy (DRS). A 5-fold enhancement in the photocurrent spectrum for TiO2NTs was observed and the photocurrent response range was significantly extended into the visible region because of the CdS incorporation. Compared with pure TiO2NTs,under a visible light irradiation,CdS@TiO2NTs exhibited a 3.5-fold improvement of photocatalytic activity,which was demonstrated by the photocatalytic decomposition of Rhodamine B (RhB).

关键词： TiO2 nanotube CdS photocatalysis RhB

A simple solvothermal route towards the morphological control of ZnO and tuning of its optical and photocatalytic properties

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Science china chemistry 2010年第8期53卷 1711-1717页

作者： JIANG YaQi,LI FangFang,SUN Ran,XIE ZhaoXiong & ZHENG LanSun State Key Laboratory for Physical chemistry of Solid Surfaces Department of chemistry,college of chemistry and chemical engineering,xiamen university,xiamen 361005,china 1. State Key Laboratory for Physical chemistry of Solid Surfaces Department of chemistry College of Chemistry and Chemical Engineering Xiamen University Xiamen 361005 China

ZnO nanoparticles with different morphologies were solvothermally synthesized by controlling the alkali (sodium hydroxide) concentration in an isopropanol *** products were characterized by means of powder X-ray diffraction,UV-visible absorption spectra,scanning electron microscopy,transmission electron microscopy,and selected area electron *** morphologies of the formed ZnO nanocrystals were dependent on the concentration of the alkali,and with increases of sodium hydroxide concentration,the ZnO nanocrystals evolved from rod to hexagonal bipyramid,and then to a flower-like *** flower-like nanostructure resulted from the etching of the hexagonal bipyramid by the excess *** photoluminescence and photocatalytic properties of the prepared ZnO were *** difference of green emission among the ZnO nanocrystals indicated that a higher sodium hydroxide concentration led to a higher level of *** size,the surface structure and defects in the ZnO nanocrystals affected its photo-degradation characteristics.

关键词： zinc oxide solvothermal method nanocrystal photoluminescence photocatalysis

Extended detection range for an optical enzymatic glucose sensor coupling with a novel data-processing method

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Science china chemistry 2010年第6期53卷 1385-1390页

作者： GUO GuangMei1,WANG XuDong2,ZHOU TingYao2 & CHEN Xi2 1college of Sciences,Hebei university of Science and Technology,Shijiazhuang 050018,china 2Department of chemistry,college of chemistry and chemical engineering,xiamen university Key Laboratory of Analytical Sciences of xiamen university,xiamen 361005,china 1. college of Sciences Hebei University of Science and Technology Shijiazhuang 050018 China2. Department of Chemistry College of Chemistry and Chemical Engineering Xiamen University Key Laboratory of Analytical Sciences of xiamen university Xiamen 361005 China

A new data-processing method was established and applied for optical enzymatic glucose sensing,in which oxygen and glucose were simultaneously *** oxygen level remaining in the detection system,which was equal to the difference between the initial and consumed oxygen concentrations,could be measured using fluorescent oxygen indicators immobilized in the sensing *** was deduced that the ratio of I0 and I was inversely proportional to glucose concentration,where I0 is the maximum fluorescence intensity in various glucose solutions,and I is the fluorescence intensity at various concentrations of *** the new data-processing method,the detection range of the calibration curve method was extended from 0 to 1.2 mmol L-1,which was enlarged about 2–3 folds over that in ordinary *** prepared glucose sensor could be directly applied to detect high concentrations of glucose.

关键词： optical glucose sensor glucose oxidase extended detection range

Progress in the development of techniques based on light scattering for single nanoparticle detection

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Science china chemistry 2011年第8期54卷 1244-1253页

作者： ZHU ShaoBin, WANG Shuo, YANG LingLing, HUANG TianXun & YAN XiaoMei Department of chemical Biology, college of chemistry and chemical engineering Key Laboratory for chemical Biology of Fujian Province Key Laboratory of Analytical Science, xiamen university, xiamen 361005, china 1. Department of chemical Biology College of Chemistry and Chemical Engineering Key Laboratory for chemical Biology of Fujian Province Key Laboratory of Analytical Science Xiamen University Xiamen 361005 China

Nanoparticles have recendy attracted extensive attention in view of their great potential in biomedicine and bioanalytical applications. Single particle detection via light scattering offers a simple and efficient approach for the size, size distribution, and concentration analysis of nanoparticles. In particular, intrinsic heterogeneity or rare events masked by ensemble averaging can be revealed. However, the sixth power dependence of Rayleigh scattering on particle size makes it very challenging to detect individual nanoparficles of small sizes. This article is intended to provide an overview of recent progress in the development of techniques based on light scattering for the detection of single nanoparticles.

关键词： light scattering single particle detection nanoparticles confocal correlation spectroscopy flow cytometry

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Foreword

电化学 2012年第5期18卷 385-386页

作者： Dr.Bin Ren Professor of chemistry State Key Laboratory of Physical chemistry of Solid Surfaces,college of chemistry and chemical engineering,xiamen university,xiamen 361005,china

On the request of ***-Gang Sun,Editor-in-Chief of Journal of Electrochemistry,I served asthe guest editor for this International Special Issueon Current *** Journal of Electrochemistry was founded in1995 associated

关键词：电化学电化学平衡电解质电解

Adsorption and corrosion inhibition behavior of imidazole on cobalt electrodes studied by SERS and electrochemical methods

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Science china chemistry 2005年第6期48卷 497-503页

作者： GU Wei1, LIU Guokun2, REN Bin2, WU Deyin2, GU Renao1 & TIAN Zhongqun2 1. Department of chemistry, college of chemistry and chemical engineering, Suzhou university, Suzhou 215006, china 2. State Key Laboratory for Physical chemistry of Solid Surfaces and Department of chemistry, college of chemistry and chemical engineering, xiamen university, xiamen 361005, china 1. Department of chemistry College of Chemistry and Chemical Engineering Suzhou University 215006 Suzhou China 2. State Key Laboratory for Physical chemistry of Solid Surfaces and Department of chemistry College of Chemistry and Chemical Engineering Xiamen University 361005 Xiamen China

The interaction of imidazole with Co electrodes in an electrochemical system was studied by surface-enhanced Raman scattering (SERS) and electrochemical methods. The SER spectra of Co in an imidazole solution as a function of the applied potential were analyzed and the assignment of the Raman bands was made. It was found that there were three kinds of sur-face species on the Co surface in different potential regions and they were interchangeable de-pending on the potential. In a relatively negative potential region (?1.2 to ?0.9 V), imidazole was adsorbed on the surface and its orientation might change from a vertical configuration via the N-end of the pyridine ring to a tilted configuration via the C2=N3 double bond. In a more positive potential region (?0.8 to ?0.7 V), the SERS signal from the adsorbed imidazole weakened and finally disappeared, meanwhile the signal from the Co and imidazole complex strengthened gradually. At the open circuit potential (?0.6 V), we detected very strong bands from the Co ox-ides. By comparing the Tafel curves of the Co electrode in the solution without and with imidazole, we found that imidazole has a marked effect on the corrosion inhibition of the Co electrode. This result demonstrates that we may be able to reveal the complicated interaction of surface species with metal surface at the molecular level by combining the SERS and electrochemical methods.

关键词： cobalt, imidazole, inhibition, surface-enhanced Raman spectroscopy, Tafel plot.

Synthesis and characterization of stable osmafuran starting from HC≡CCH(OH)C≡CH and OsHCl(CO)(PPh_3)_3

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Science china chemistry 2010年第9期53卷 1978-1981页

作者： ZHANG Hong,LIN Ran,LUO Ming & XIA HaiPing State Key Laboratory for Physical chemistry of Solid Surfaces college of chemistry and chemical engineering,xiamen university,xiamen 361005,china 1. State Key Laboratory for Physical chemistry of Solid Surfaces college of chemistry and chemical engineering Xiamen University Xiamen 361005 China

This paper presents a new convenient route to prepare osmafuran starting from readily accessible HC≡C CH(OH)C≡CH and OsHCl(CO)(PPh3)*** of a solution of OsHCl(CO)(PPh3)3 in dichloromethane with HC≡C CH(OH)C≡CH,followed by the addition of acetic acid,produced osmafuran [Os(CHC(PPh3)CO(CH2CH3))Cl(CO)(PPh3)2]Cl(2).2 has been isolated in good yield and fully characterized.1H and 13C NMR spectra show the characteristic downfield chemical shifts of the ring hydrogen and carbon *** and X-ray diffraction data provide strong evidence for the aromatic nature of *** due to the effect of the phosphonium substituent,2 exhibits remarkable thermal stability,air stability and lower reactivity.

关键词： osmafuran metallaaromatics phosphonium salt synthesis stability

Study on interaction between macrocell and microcell in the early corrosion process of reinforcing steel in concrete

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Science china(Technological Sciences) 2010年第5期53卷 1285-1289页

作者： LI LanQiang1,DONG ShiGang1,WANG Wei2,HU RongGang1,DU RongGui1,LIN ChangJian1,ZHUO XiangDong1 & WANG Jia2 1 State Key Laboratory of Physical chemistry of Solid Surfaces,Department of chemistry,college of chemistry and chemical engineering,xiamen university,xiamen 361005,china 2 college of chemistry and chemical engineering,Ocean university of china,Qingdao 266100,china 1. State Key Laboratory of Physical chemistry of Solid Surfaces Department of Chemistry College of Chemistry and Chemical Engineering Xiamen University Xiamen 361005 China2. College of Chemistry and Chemical Engineering Ocean University of China Qingdao 266100 China

An array electrode technique was developed as a novel electrochemical method for studying the interaction between macrocell and microcell in the early corrosion process of reinforcing steel in cement *** corrosion potential and galvanic current of macrocell corrosion of the reinforcing steel in cement mortar were imaged by the array electrode technique during the corrosion initiation and *** was certified that the corrosion macrocell current is closely related with the difference of corrosion potential between the anodic and cathodic *** corrosion macrocell and microcell always exist during the corrosion *** interaction of corrosion macrocell and corrosion microcell of steel in concrete was directly sensed by the array electrode for the first time,and was discussed in terms of corrosion electrochemistry.

关键词： reinforcing steel in concrete array electrode macrocell microcell

Size and support effects for CO oxidation on supported Pd catalysts

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Science china chemistry 2010年第9期53卷 2047-2056页

作者： WANG ZhaoWen,LI Bin,CHEN MingShu,WENG WeiZheng & WAN HuiLin State Key Laboratory of Physical chemistry of Solid Surfaces National engineering Laboratory for Green chemical Productions of Alcohols-Ethers-Esters Department of chemistry,college of chemistry and chemical engineering,xiamen university,xiamen 361005,china 1. State Key Laboratory of Physical chemistry of Solid Surfaces Xiamen University Xiamen 361005 China2. National Engineering Laboratory for Green Chemical Productions of Alcohols-Ethers-Esters Xiamen University Xiamen 361005 China3. Department of Chemistry College of Chemistry and Chemical Engineering Xiamen University Xiamen 361005 China

Supporting Pd catalysts characterized significant different size distribution were obtained using PdCl2,[Pd(NH3)4](NO3)2 and Pd(acac)2 as ***-resolution transmission electron microscopy(TEM),X-ray diffraction(XRD),in-situ Fourier transform infrared spectroscopy(FTIR) and Raman spectroscopy were used to examine the dispersion of *** performance measurements show that the activities for CO oxidation increase as the Pd particle size decreases and the O2/CO ratio *** activities under oxygen rich conditions are significantly higher than those at near the stoichiometric *** on TiO2 prepared by the Pd(acac)2 precursor is highly dispersed,leading to a considerable activity for CO oxidation at near room *** oxidation on the 1 wt% Pd/TiO2 and under an O2/CO ratio of 1 characterized an apparent activation energy of 36.7 kJ/mol,which is closed to those reported for CO oxidation on the supported Au *** present work demonstrates a high catalytic activity of highly dispersed noble metals,and suggests a promising approach of using noble metals as catalysts with exceeding high efficiency.

关键词： noble metals supported palladium CO oxidation size effect support effect