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Kumada chain-growth polycondensation as a universal method for synthesis of well-defined conjugated polymers

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Science china Chemistry 2010年第8期53卷 1620-1633页

作者： GENG YanHou1,HUANG Li1,2,WU ShuPeng1,2 & WANG FoSong1 1State Key Laboratory of Polymer Physics and Chemistry Changchun Institute of Applied Chemistry,chinese academy of sciences,Changchun 130022,china 2graduate University of chinese academy of sciences,Beijing 100049,china 1. State Key Laboratory of Polymer Physics and Chemistry Changchun Institute of Applied Chemistry Chinese Academy of Sciences Changchun 130022 China2. Graduate University of Chinese Academy of Sciences Beijing 100049 China

Kumada chain-growth polycondensation (KCGP) is a novel method for the synthesis of well-defined conjugated *** the Ni-catalyst can transfer in an intramolecular process to the propagating chain end,the polymerization follows chain-growth *** this newly developed method,various conjugated polymers,such as polythiophenes,poly(p-phenylene) (PPP),polypyrrole (PPy),and polyfluorene with controlled molecular weights and relatively narrow polydispersities (PDIs),have been ***,the polymerizations for poly(3-alkylthiophene)s (P3ATs),PPP,and PPy exhibited quasi-living characteristics,which allows preparing polymer brushes,fully-conjugated block copolymers,and macroinitiators and macro-reactants for the synthesis of rod-coil block *** the current review,the progress in this new area is summarized.

关键词： chain growth polycondensation conjugated polymers Kumada reaction block copolymers polymer brush

Contributions of phosphatase and microbial activity to internal phosphorus loading and their relation to lake eutrophication

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Science china Earth sciences 2006年第z1期49卷 102-113页

作者： SONG Chunlei, CAO Xiuyun, LI Jianqiu, LI Qingman, CHEN Guoyuan & ZHOU Yiyong Institute of Hydrobiology, chinese academy of sciences, Wuhan 430072, china graduate school of the chinese academy of sciences, Beijing 100039, china 1. Institute of Hydrobiology Chinese Academy of Sciences Wuhan 430072 China 2. graduate school of the chinese academy of sciences Beijing 100039 China

Phosphatase may accelerate the process of lake eutrophication through improving phosphorus bioavailability. This mechanism was studied in three chinese eutrophic shallow lakes (Lake Taihu, Lake Longyang and Lake Lianhua). Phosphatase activity was related to the concentration of soluble reactive phosphorus (SRP) and chlorophyll a. Stability of dissolved phosphatase in reverse micelles may be attributed to molecular size, conformation and active residues of the *** the site with Microcystis bloomed in Lake Taihu, dissolved phosphatase activity was higher and more stable in micelles, SRP concentrations were lower in interstitial water, the contents of different forms of phosphorus and the amounts of aerobic bacteria were lower while respiration efficiency was higher in sediments. Phosphobacteria, both inorganic and organic and other microorganisms were abundant in surface water but rare in sediments. Therefore, internal phosphorus may substantially flux into water column by enzymatic hydrolysis and anaerobic release, together with mobility of bacteria,thereby initiating the bloom. In short, biological mechanism may act in concert with physical and chemical factors to drive the internal phosphorus release and accelerate lake eutrophication.

关键词： dissolved phosphatase, reverse micelle, internal loading, phosphorus form of sediment, microbiology, eutrophication, Microcystis bloom.

Report of Prionospio complex(Annelida:Polychaeta:Spio-nidae) from china's waters,with description of a new species

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Acta Oceanologica Sinica 2009年第1期28卷 116-127页

作者： ZHOU Jin LI Xinzheng Institute of Oceanology. Chinese Aeademy of Sciences Qingdao 266071 China graduate school Chinese Academy of Sciences Beijing 100039 China

Nine species of Prionospio complex are recorded from china＇s waters,including one new species and six newly recorded ***（Prionospio） pacifica ***.,is characterized by having first and forth pairs of branchiae pinnate,second and third pairs of apinnate,ventral crest on Setiger 9 and dorsal crests on Setigers *** kirrae（Wilson,1990）,Prionospio（Aquilaspio） convexa Imajima,1990,Prionospio（Minuspio） multibranchiata Berkeley,1927,Prionospio（Prionospio） bocki Sderstrm,1920,Prionospio（Prionospio） dubia Maciolek,1985 and Prionospio（Prionospio） paradisea Imajima,1990 are recorded for the first time from china＇s waters.

关键词： taxonomy Prionospio complex new species newly recorded species china's waters.

Estimation on dynamic release of phosphorus from wind-induced suspended particulate matter in Lake Taihu

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Science china Earth sciences 2004年第8期47卷 710-719页

作者： FAN Chengxin1, ZHANG Lu1,2, QIN Boqiang1, WANG Sumin1, HU Weiping1 & ZHANG Chen1 1. Taihu Lake Laboratory for Ecosystem Research, Nanjing Institute of Geography & Limnology, chinese academy of sciences, Nanjing 210008, china 2. graduate school of chinese academy of sciences, Beijing 100039, china 1. Taihu Lake Laboratory for Ecosystem Research Nanjing Institute of Geography & Limnology Chinese Academy of Sciences 210008 Nanjing China 2. graduate school of chinese academy of sciences 100039 Beijing China

Through man-made disturbance experiments, the corresponding relationships be-tween suspended particulate matter (SPM) and wind speed in different lake areas were simu-lated, the physicochemical formal transformation and biological mineralizing and decaying processes of phosphorus in SPM were studied, the contribution of phosphorus transformation to phosphorus loading of the water of Lake Taihu was quantitatively estimated. The results show that about 0.44 t·a-1 loading in Lake Taihu mainly comes from phosphorus-releasing action of SPM in physicochemical transformed to soluble reactive phosphorus (SRP), and the contribution mainly from biological mineralizing and decaying was about 425.8 t·a-1, which is equal to 15.0% of the total external loading of Lake Taihu, namely 4.7—7.5 times as much as SRP loading en-tering the lake by the rivers; thus it is the important source in dynamical internal loading of the lake. The determining factors for dynamical internal loading in lakes are organic phosphorus content in suspended solid and its biological transition availability.

关键词： phosphorus release,wind wave disturbance,particulate decaying,dynamical loading,Lake Taihu.

Synthesis and characterization of a pH-sensitive shielding system for polycation gene carriers

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Science china Chemistry 2010年第3期53卷 502-507页

作者： XIA JiaLiang1,2,CHEN Jie1,TIAN HuaYu1 & CHEN XueSi1 1Key Laboratory of Polymer Ecomaterials Changchun Institute of Applied Chemistry,chinese academy of sciences,Changchun 130022,china 2graduate University of chinese academy of sciences,Beijing 100049,china 1. Key Laboratory of Polymer Ecomaterials Changchun Institute of Applied Chemistry Chinese Academy of Sciences Changchun 130022 China2. Graduate University of Chinese Academy of Sciences Beijing 100049 China

To increase the in vivo stability of polycation gene carriers,a pH-sensitive shielding system,γ-benzyl L-glutamate-co-glutamate acid polymer(PGA(60)(60 refers to the molar ratio of glutamate acid in the polymer)),was synthesized and ***(60) showed pH sensitivity at about pH ***(60) shielded the positive charge of DNA/PEI(1:1) *** retardation assay showed that no DNA-strand exchange with PGA(60) occurred after PGA(60) was added to DNA/PEI complexes at different *** cytotoxicity tests demonstrated that neither PGA(60) nor DNA/PEI/PGA(60) ternary complexes had cytotoxicity at the test *** transfection efficiency was improved when the positive charge was partly shielded by PGA(60).Because of the charge repulsion between the surface of cells and ternary complex particles,there was almost no transfection efficiency when the zeta potential of ternary complexes turned to *** of the suitable pH sensitive range,PGA(60) may be a potential shielding system for polycation gene carriers to be used in vivo.

关键词： gene delivery shielding system pH-sensitive polyglutamate

The solid lubricating material experiment device for Shenzhou-7 Spaceship

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Science china(Technological sciences) 2010年第9期53卷 2521-2527页

作者： WANG Ke1,2,REN WeiJia1,WANG ShiDa1 & WENG LiJun3 1 academy of Opto-Electronics,chinese academy of sciences,Beijing 100190,china 2 graduate University of chinese academy of sciences,Beijing 100049,china 3 Lanzhou Institute of Chemical Physics,chinese academy of sciences,Lanzhou 730000,china 1. academy of Opto-Electronics Chinese Academy of Sciences Beijing 100190 China2. Graduate University of Chinese Academy of Sciences Beijing 100049 China3. Lanzhou Institute of Chemical Physics Chinese Academy of Sciences Lanzhou 730000 China

A solid lubricating material exposure experiment in space is one of the missions during the seventh manned spaceflight of china,and the key is to develop a device which can be fixed reliably outside of the orbital module and can be fetched conveniently by an astronaut during space *** solid lubricating material experiment device needs to be locked reliably in a vibrating and impacting environment during the launch phase,and should meet the requirement that it can be unlocked and fetched reliably by the astronaut wearing an extravehicular spacesuit via simple operations in orbit in an environment of high and low *** for the device we developed,the environmental characteristic of the mission was analyzed,the mechanical analysis and thermal analysis were carried out,and then a mechanism with functions of mechanical locking,structural self-locking and manual unlocking was *** device was verified by a sequence of experiments and was fetched by the astronaut during the flight of the Shenzhou-7 Spaceship.

关键词： manned spaceflight exposure experiment mechanism unlock

Exploration of combined adjustment laws about IGV,stator and rotational speed in off-design conditions in an axial compressor

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中国科学：技术科学英文版 2010年第4期53卷 969-975页

作者： HU YanMing1,2 & NIE ChaoQun1 1 Key Laboratory of Advanced Energy and Power Technology,Institute of Engineeting Thermophysics,chinese academy of Science,Beijing 100190,china 2 graduate school of chinese academy of sciences,Beijing 100190,china 1. Key Laboratory of Advanced Energy and Power Technology Institute of Engineeting Thermophysics Chinese Academy of Science Beijing 100190 China2. Graduate School of Chinese Academy of Sciences Beijing 100190 China

Experimental investigations are performed in a three-stage low-speed axial compressor with variable inlet guide vanes(IGV) and adjustable *** characteristics of the compressor,especially the efficiency and stall margin,are analyzed in design and off-design operation conditions by adjusting stagger angles of IGV and stators as well as changing the rotational *** experimental results show that the off-design performance of the multistage axial compressor is improved by restaggering of IGV and stators related to rotational *** the background of engineering applications,digital signal processing(DSP) technique is used to realize online adjustment of stagger angles according to the corresponding relations between incidence angles of rotor and rotational speed.

关键词： axial compressor IGV surge DSP techniques off-design

Applications of URANS on predicting unsteady turbulent separated flows

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Acta Mechanica Sinica 2009年第3期25卷 319-324页

作者： Jinglei Xu Huiyang Ma Department of Physics, graduate University of the chinese academy of sciences, 100049 Beijing, china Department of Physics Graduate University of the Chinese Academy of Sciences 100049 Beijing China

Accurate prediction of unsteady separated turbulent flows remains one of the toughest tasks and a practi cal challenge for turbulence modeling. In this paper, a 2D flow past a circular cylinder at Reynolds number 3,900 is numerically investigated by using the technique of unsteady RANS （URANS）. Some typical linear and nonlinear eddy viscosity turbulence models （LEVM and NLEVM） and a quadratic explicit algebraic stress model （EASM） are evaluated. Numerical results have shown that a high-performance cubic NLEVM, such as CLS, are superior to the others in simulating turbulent separated flows with unsteady vortex shedding.

关键词： URANS Nonlinear eddy viscosity turbulencemodel ,Separated flows Circular cylinder

Twistor bundle theory and its application

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Science china Mathematics 2004年第4期47卷 605-616页

作者： PENG Chia-Kuei & TANG ZizhouDepartment of Mathematics, graduate school of chinese academy of sciences, Beijing 100039, china Department of Mathematical sciences, Tsinghua University, Beijing 100084, china 1. Department of Mathematics Graduate School of Chinese Academy of Sciences 100039 Beijing China 2. Department of Mathematical sciences Tsinghua University 100084 Beijing China

Over an oriented even dimensional Riemannian manifold(M 2m ,ds2 ), in terms of the Levi-Civita connection form Ω and the canonical form Θ on the bundle of positive orthonormal frames, we give a detailed description of the twistor bundle Гm = SO(2m)/U(m)? J +(@#@ M,ds2 ) →M. The integrability on an almost complex structureJ compatible with the metric and the orientation, is shown to be equivalent to the fact that the corresponding cross section of the twistor bundle is holomorphic with respect toJ and the canonical almost complex structureJ 1 onJ +(M,ds2 ), by using moving frame theory. Moreover, for various metrics and a fixed orientation onM, a canonical bundle isomorphism is established. As a consequence, we generalize a celebrated theorem of LeBrun.

关键词： almost complex structure, integrability, twistor bundle.