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Beneficial use of mussel shell as a bioadditive for TPU green composites by the valorization of an aqueous waste

Waste Disposal and Sustainable Energy 2024年第1期6卷 123-137页

作者： SedefŞişmanoğlu Yasin Kanbur carmen-Mihaela popescu Diana Kindzera Ümit Tayfun Department of Chemistry Karabuk University78050KarabukTurkey Petru Poni Institute of Macromolecular Chemistry of the Romanian Academy 700487IasiRomania Department of Chemical Engineering Lviv Polytechnic National UniversityLviv79013Ukraine Department of Basic Sciences Bartin University74110BartinTurkey

Scientific studies have focused on environmentally friendly solutions as effective as the reuse of crop products owing to plastic-waste problems in recent *** issue is the main driving force for upcoming academic research attempts in waste valorization-related ***,we integrated an aqua-waste,mussel shell(MS),as a bioadditive form into green thermoplastic polyurethane(TPU)green *** of the MS surface was performed to achieve strong adhesion between composite *** surface functionalities of MS powders were evaluated via infrared spectroscopy and scanning electron microscopy(SEM)*** samples were prepared by melt-compounding followed by injection molding *** was confirmed by morphological analysis that relatively better adhesion between the phases was achieved for composites involving surface-modified MS compared to unmodified *** strength and Young’s modulus of surface-modified MS-filled composites were found to be higher than those of unmodified MS,whereas the elongation at break shifted to lower values with MS *** shore hardness of TPU was remarkably improved after being incorporated with silane-treated MS(AS-MS).Stearic acid-treated MS(ST-MS)additions resulted in an enhancement in the thermal stability of the ***-mechanical analysis showed that the storage moduli of composites were higher than those of unfilled ***-MS additions led to an increase in the characteristic glass transition temperature of *** flow index(MFI)of neat TPU was highly improved after MS loading regardless of modification *** to the wear test,surface modification of MS displayed a positive effect on the wear resistance of *** the water absorption data of the composites were evaluated,the TPU/AS-MS composite yielded the lowest water *** silane layer on MS inclusion promoted water repellency of composites due to the hydrophobicity of *** results of the biodegradation

关键词： Aqua-waste Polyurethane Mussel shell Green composites Sustainability Waste valorization

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Confocal laser endomicroscopy and immunoendoscopy for real-time assessment of vascularization in gastrointestinal malignancies

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World Journal of Gastroenterology 2011年第1期17卷 21-27页

作者： Dan Ionut Gheonea Tatiana Crtnǎ Tudorel Ciurea carmen popescu Anca Bǎdǎrǎu Adrian Sǎftoiu Research Center of Gastroenterology and Hepatology University of Medicine and Pharmacy CraiovaCraiova 200349Romania Physiology Department University of Medicine and Pharmacy Carol Davila BucharestBucharest 050474Romania Cytology Laboratory Emergency Hospital CraiovaCraiova 200642Romania

Gastrointestinal cancers represent a major cause of morbidity and mortality,with incomplete response to chemotherapy in the advanced stages and poor *** plays a crucial part in tumor growth and metastasis,with most gastrointestinal cancers depending strictly on the development of a new and devoted capillary *** laser endomicroscopy is a new technology which allows in vivo microscopic analysis of the gastrointestinal mucosa and its microvascularization during ongoing endoscopy by using topically or systemically administered contrast *** markers of angiogenesis in association with confocal laser endomicroscopic examination(immunoendoscopy),as a future challenge,will add functional analysis to the morphological aspect of the neoplastic *** review describes previous experience in endomicroscopic examination of the upper and lower digestive tract with emphasis on vascularization,resulting in a broad spectrum of potential clinical applications,and also preclinical research that could be translated to human studies.

关键词： Confocal laser endomicroscopy Immunoendoscopy Fluoresceine Acriflavine Cancer

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Preparation of elastomeric nanocomposites using nanocellulose and recycled alum sludge for flexible dielectric materials

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Journal of Advanced Dielectrics 2023年第1期13卷 57-65页

作者： Dongyang Sun Bernard L.H.Saw Amaka J.Onyianta Bowen Wang Callum Wilson Dominic O’Rourke Chan H.See carmen-Mihaela popescu Mark Dorris Islam Shyha Zhilun Lu School of Engineering and Built Environment Edinburgh Napier UniversityEdinburghUK Lee Kong Chian Faculty of Engineering and Science Universiti Tunku Abdul Rahman KajangMalaysia Bristol Composites Institute School of CivilAerospace and Mechanical Engineering University of BristolUniversity WalkBristolBS81TRUK School of Engineering and Materials Science Queen Mary University of LondonLondonUK Petru Poni Institute of Macromolecular Chemistry of the Romanian Academy IasiRomania

Flexible dielectric materials with environmental-friendly,low-cost and high-energy density characteristics are in increasing demand as the world steps into the new Industrial 4.0 *** this work,an elastomeric nanocomposite was developed by incorporating two components:cellulose nanofibrils(CNFs)and recycled alum sludge,as the reinforcement phase and to improve the dielectric properties,in a bio-elastomer *** and alum sludge were produced by processing waste materials that would otherwise be disposed to landfills.A biodegradable elastomer polydimethylsiloxane was used as the matrix and the nanocomposites were processed by casting the materials in Petri *** extraction and heat treatment of alum sludge were conducted and characterized using various techniques including scanning electron microscopy(SEM),thermogravimetric analysis/derivative thermogravimetric(TGA/DTG)and X-ray diffraction(XRD)*** preparing the nanocomposite samples,various amount of alum sludge was added to examine their impact on the mechanical,thermal and electrical *** have shown that it could be a sustainable practice of reusing such wastes in preparing flexible,lightweight and miniature dielectric materials that can be used for energy storage applications.

关键词： Nanocellulose biodegradable sustainable alum sludge nanocomposite flexible dielectric

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Molecular diagnosis in cat allergy

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World Journal of Methodology 2021年第3期11卷 46-60页

作者： Florin-Dan popescu carmen Saviana Ganea carmen Panaitescu Mariana Vieru Department of Allergology and Clinical Immunology “Nicolae Malaxa”Clinical HospitalBucharest 022441Romania Department of Allergology “Carol Davila”University of Medicine and PharmacyBucharest 022441Romania Department III Functional Sciences Physiology Discipline“Victor Babes”University of Medicine and PharmacyTimișoara 300041Romania Center for Gene and Cell Therapies in Cancer Treatment OncoGen-SCJUPB Timisoara Timișoara 300041Romania

Domestic cats represent one of the most common sources of indoor *** over the world,many households own cats,whose allergens are persistent and *** allergy itself is frequent,and its symptoms vary from rhinoconjunctivitis to life-threatening *** vitro diagnosis using precision medicine allergy immunoassays is important because natural cat dander extracts may differ in quality and quantity of some of the individual allergen components and other *** the component-resolved diagnosis of cat allergy,singleplex and multiplex specific immunoglobulin(Ig)E assays include use of the cat-specific major allergen,secretoglobin Fel d 1(as a species-specific molecule),other allergen components(such as lipocalins Fel d 4,cross-reacting with other animal similar molecules,and Fel d 7,present in small quantities in natural extracts),and serum albumin Fel d 2(related to the cat-pork syndrome).IgA Fel d 5 and IgM Fel d 6 are not available as allergen components in the current commercial IgE immunoassays,but they may impair the in vitro diagnostic evaluation of cat allergy because galactose-α1,3-galactose is an IgE-binding epitope of these native feline *** benefits of molecular-based cat allergy diagnosis are continually evaluated,as the role of recombinant allergen components already known is detailed and new other molecules of interest may be discovered in the future.

关键词： Feline Allergens Component-resolved diagnosis Immunoglobulin E Immunoassays

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High plasma levels of COL10A1 are associated with advanced tumor stage in gastric cancer patients

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World Journal of Gastroenterology 2020年第22期26卷 3024-3033页

作者： Laura Necula Lilia Matei Denisa Dragu Ioana Pitica Ana Iulia Neagu Coralia Bleotu Simona Dima Irinel popescu carmen C Diaconu Mihaela Chivu-Economescu Department of Cellular and Molecular Pathology Stefan S.Nicolau Institute of VirologyBucharest 030304Romania Titu Maiorescu University Faculty of MedicineBucharest 040441Romania Fundeni Clinical Institute Bucharest 022328Romania

BACKGROUND Gastric cancer(GC)remains an aggressive malignancy with a high rate of mortality,being the third leading cause of cancer-related *** than one million newly diagnosed cases and 782685 deaths due to GC were reported in *** is characterized by limited effective treatment options and the lack of consistent biomarkers for the diagnosis and prognosis of these *** discovery of new biomarkers useful in the early diagnosis of GC is *** To evaluate the potential of COL10A1 as a circulating biomarker for the diagnosis and prognosis of gastric adenocarcinoma *** Plasma and tissue obtained from 49 patients with gastric adenocarcinoma have been used in exploring the expression of ***-time PCR and western blot techniques were used to evaluate COL10A1 level in gastric tumor tissue compared to normal adjacent *** circulating level of COL10A1 was also evaluated by ELISA in plasma of gastric adenocarcinoma *** analysis was made in order to evaluate the potential of COL10A1 as a biomarker for the diagnosis and prognosis of gastric adenocarcinoma *** Our results showed a significant increase in COL10A1 gene expression and protein levels in gastric tumor tissue compared to adjacent normal tissue(P<0.05).COL10A1 seems to show an elevated expression from the beginning of carcinogenesis,in the early stages,and its increased level remains elevated during cancer progression.A significant increase of COL10A1 plasma level in gastric adenocarcinoma patients was also ***,increased COL10A1 plasma level was associated with poor survival of the *** COL10A1 performed a diagnostic value in GC with area under the receiver operating characteristic curve(AUC)of 0.9171(P=0.0002),sensitivity of 87.76%,and specificity of 100.0%.Furthermore,this study demonstrated the potential role of plasma COL10A1 in the early detection of GC,as in the early stage,we obtained an AUC of 0.8789(P=0.00

关键词： Gastric cancer COL10A1 Circulating biomarkers Early diagnosis Poor prognosis Tumor stage

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Severe liver trauma with complex portal and common bile duct avulsion:A case report and review of the literature

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World Journal of Clinical Cases 2023年第16期11卷 3837-3846页

作者： Bianca Mitricof Alin Kraft Florentina Anton Alexandru Barcu Darina Barzan carmen Haiducu Vladislav Brasoveanu Irinel popescu Cosmin Alec Moldovan Florin Botea Medicine Doctoral School Titu Maiorescu University of BucharestBucharest 040441Romania Department of General Surgery Regina Maria Military Emergency HospitalBrasov 500007Romania Faculty of Medicine Carol Davila University of Medicine and PharmacyBucharest 050474Romania Dan Setlacec Center for General Surgery and Liver Transplant Fundeni Clinical InstituteBucharest 022328Romania Department of Medical-Surgical and Prophylactic Disciplines Faculty of MedicineTitu Maiorescu University of BucharestBucharest 031593Romania Department of General Surgery Witting Clinical HospitalBucharest 010243Romania

BACKGROUND Given its size and location,the liver is the third most injured organ by abdominal *** to recent advances,it is unanimously accepted that the nonoperative management is the current mainstay of treatment for hemodynamically stable ***,those patients with hemodynamic instability that generally present with severe liver trauma associated with major vascular lesions will require surgical ***,an associated injury of the main bile ducts makes surgery compulsory even in the case of hemodynamic stability,thereby imposing therapeutic challenges in the tertiary referral hepato-biliopancreatic centers’*** SUMMARY We present the case of a 38-year-old male patient with The American Association for the Surgery of Trauma grade V liver injury and an associated right branch of portal vein and common bile duct avulsion,due to a crush *** patient was referred to the nearest emergency hospital and because of the hemorrhagic shock,damage control surgery was performed by means of ligation of the right portal vein branch and right hepatic artery,and hemostatic ***,the patient was referred immediately to our tertiary hepato-bilio-pancreatic *** performed depacking,a right hepatectomy and Roux-en-Y *** the 9th postoperative day,the patient developed a high output anastomotic bile leak that required a redo of the *** postoperative period was marked by a surgical incision site of incomplete evisceration that was managed non-operatively by negative wound *** follow-up was optimal,with no complications at 55 *** In conclusion,the current case clearly supports that a favorable outcome in severe liver trauma with associated vascular and biliary injuries is achieved thru proper therapeutic management,conducted in a tertiary referral hepato-bilio-pancreatic center,where a stepwise and complex surgical approach is mandatory.

关键词： Severe Liver Trauma Avulsion Right portal vein Common bile duct Case report

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Is ARFI elastography reliable for predicting fibrosis severity in chronic HCV hepatitis?

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World Journal of Radiology 2011年第7期3卷 188-193页

作者： Ioan Sporea Roxana Sirli Simona Bota carmen Fierbinteanu-Braticevici Alina popescu Radu Badea Monica Lupsor Ana Petrisor Mirela Dnil Department of Gastroenterology and Hepatology University of Medicine and Pharmacy Timi oara10 Iosif Bulbuca Bv.300736 TimisoaraRomania IInd Medical Clinic and Gastroenterology University Hospital169 Independen ei AvenueSector 5050098 BucharestRomania Department of Medical Imaging 3rd Medical ClinicUniversity of Medicine and PharmacyClujNapoca21-23 Croitorilor Str.400162Cluj-NapocaRomania

AIM:To determine whether acoustic radiation force impulse(ARFI) elastography is a reliable method for predicting fibrosis severity in patients with chronic hepatitis C virus(HCV) ***:We performed a multicenter study including 274 subjects with HCV chronic hepatitis in which we compared ARFI with liver biopsy(LB).In each patient we performed LB(evaluated according to the Metavir score) and ARFI measurements(using a Siemens Acuson S2000TM ultrasound system:10 valid measurements were performed and median values were calculated and expressed in meters/second(m/s).RESULTS:A direct,strong,correlation(Spearman r = 0.707) was found between ARFI measurements and fibrosis(P < 0.0001).For predicting the presence of fibrosis(F ≥ 1 Metavir),significant fibrosis(F ≥ 2),severe fibrosis(F ≥ 3) and cirrhosis(F = 4),the cutoff values of 1.19,1.21,1.58 and 1.82 m/s were determined,respectively,liver stiffness measurements had 73%,84%,84% and 91% Se respectively;93%,91%,94%,90% Sp,respectively;with AUROCs of 0.880,0.893,0.908 and 0.937,***:ARFI measurement is a reliable method for predicting the severity of fibrosis in HCV

关键词： Acoustic radiation force impulse elastography Chronic HCV hepatitis Cirrhosis Liver fibrosis Liver stiffness

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