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Competitive effects of humic acid and wastewater on adsorption of Methylene Blue dye by activated carbon and non-imprinted polymers

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Journal of Environmental Sciences 2018年第4期30卷 310-317页

作者： Audrey Murray banu ormeci Department of Civil and Environmental Engineering Carleton UniversityOttawa ON K1S 5B6 Canada

Natural organic matter（NOM）, present in natural waters and wastewater, decreases adsorption of micropollutants, increasing treatment costs. This research investigated mechanisms of competition for non-imprinted polymers（NIPs） and activated carbon with humic acid and wastewater. Three different types of activated carbons（Norit PAC 200,Darco KB-M, and Darco S-51） were used for comparison with the NIP. The lower surface area and micropore to mesopore ratio of the NIP led to decreased adsorption capacity in comparison to the activated carbons. In addition, experiments were conducted for single-solute adsorption of Methylene Blue（MB） dye, simultaneous adsorption with humic acid and wastewater, and pre-loading with humic acid and wastewater followed by adsorption of MB dye using NIP and Norit PAC 200. Both the NIP and PAC 200 showed significant decreases of 27% for NIP（p = 0.087） and 29% for PAC 200（p = 0.096） during simultaneous exposure to humic acid and MB dye. There was no corresponding decrease for NIP or PAC 200 pre-loaded with humic acid and then exposed to MB. In fact, for PAC 200, the adsorption capacity of the activated carbon increased when it was pre-loaded with humic acid by 39%（p = 0.0005）. For wastewater, the NIP showed no significant increase or decrease in adsorption capacity during either simultaneous exposure or pre-loading. The adsorption capacity of PAC 200 increased by 40%（p = 0.001） for simultaneous exposure to wastewater and MB. Pre-loading with wastewater had no effect on MB adsorption by PAC 200.

关键词： Molecularly imprinted polymer Non-imprinted polymer Water treatment Wastewater treatment Activated carbon Micropollutants Pore-blocking Adsorption

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Degradation of Diclofenac in Molecularly Imprinted Polymer Submicron Particles by UV Light Irradiation and HCl Acid Treatment

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Journal of Water Resource and Protection 2011年第9期3卷 643-654页

作者： Mohammad Hassanzadeh-Khayyat Edward P. C. Lai Kerim Kollu banu ormeci 不详

A new molecularly imprinted polymer (MIP) was synthesized by precipitation polymerization using diclofenac (DFC) as a template. Binding characteristics of the MIP particles were evaluated by equilibrium binding experiments. DFC-MIP aqueous suspension and non-imprinted polymer (NIP) suspension were exposed to monochromatic UV light (253.7 nm) from low-pressure mercury lamps. UV-visible spectrophotometry (especially absorbance at 276 nm) showed that the DFC inside MIP particles degraded completely. After DFC-MIP suspension exposure to UV light the particles were completely regenerated after washing with water at least six times. The regenerated MIP particles rebounded considerable amount of DFC (approximately 88% removal of 44 ppm DFC). The stability of DFC was examined in the presence of various concentrations of hydrochloric acid (0.025 to 125 mM). Experimental results showed that degradation of DFC was efficient, depending on the acid concentration as well as the treatment time. However, there was no re-binding of DFC by the MIP particles after HCl treatment (and DDW washing) when exposed to DFC for 24 hours.

关键词： Diclofenac Molecularly Imprinted Polymer Submicron Particles UV Irradiation Degradation Acid Treatment

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Wind energy feasibility and wind turbine selection studies for the city Surat,India

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Clean Energy 2024年第3期8卷 166-173页

作者： Arshi banu P S Maanat Bhadani Hindustan Institute of Technology and Science ChennaiIndia The Doon School UttarakhandDehradunIndia

Wind energy represents a clean,abundant and cost-effective power source,fostering job growth and environmental *** wind energy harnesses several gigawatts today,its availability hinges on diverse factors,with geographical location standing *** turbines,with varying capacity ranges,saturate the *** site-specific suitability and matching the appropriate turbine to meet specific requirements are of paramount *** study aims to assess the feasibility of wind energy in Surat,Gujarat,India and select an optimal small commercial turbine for residential *** research involves Rayleigh and Weibull probability distribution functions based on yearlong velocity *** distributions are fitted with actual data,revealing the most probable velocity(v_(mf)=3 m/s)and velocity at maximum power(v_(pmax)=5 m/s).The power availability of the site has been assessed as 42.6 W/m^(2)using both graphical and analytical *** commercial turbines have been shortlisted based on on-site power criteria and their specifications are evaluated against site power availability.A comparative analysis culminates in identifying the most suitable turbine for the *** best suitable turbine for the site with an annual energy yield of 8 MW has been suggested amongst selected turbines for small-scale residential applications.

关键词： site feasibility wind energy commercial wind turbine probability distribution function rated power

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Computational study of flow separation in truncated ideal contour nozzles under high-altitude conditions

International Journal of Fluid Engineering

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International Journal of Fluid Engineering 2024年第1期 21-30页

作者： Ijas Muhammed V V Shamsia banu N Abhilash Suryan Vincent Lijo David Simurda Heuy Dong Kim College of Engineering Trivandrum Government Engineering College Thrissur Faculty of Mechanical Engineering Technical University of Liberec Andong National University

Flow separation in rocket nozzles has been studied mostly under sea-level conditions, which fail to take into account changes in ambient density and ambient pressure during the flight of a rocket. In the present study, numerical analysis is conducted of flow characteristics within a truncated ideal contour(TIC) nozzle to investigate the influence of ambient density and pressure on flow separation. Six different altitudes from a typical flight are considered, from a very low altitude to a high altitude. The flow is analyzed by varying the nozzle pressure ratios corresponding to these altitudes. Both cold flow and hot flow simulations are conducted. The locations of separation positions at various altitude conditions are accurately captured and are found to be in good agreement with experimental results. The results of the study establish that for a given nozzle pressure ratio, the flow separation point is shifted upstream with increasing altitude. This clearly points to a dependence of separation position on the altitude of operation for TIC rocket nozzles.

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均相和非均相催化微藻脂质提取和酯交换制备生物燃料的研究进展

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Chinese Journal of Catalysis 2024年第4期59卷 97-117页

作者： Vinoth Kumar Ponnumsamy Hussein E.Al-Hazmi Sutha Shobana Jeyaprakash Dharmaraja Dipak Ashok Jadhav Rajesh banu J Grzegorz Piechota Bartłomiej Igliński Vinod Kumar Amit Bhatnagar Kyu-Jung Chae Gopalakrishnan Kumar 高雄医科大学药物与应用化学系环境医学研究中心中国台湾高雄高雄医科大学医学研究部中国台湾高雄格但斯克理工大学土木与环境工程学院波兰纳鲁特维察格但斯克范朗大学工程与技术学院建筑绿色技术与可持续发展研究组越南胡志明市工程技术学院科学与人文系化学部印度泰米尔纳德邦韩国海洋大学海洋科学与工程学院环境工程系韩国釜山泰米尔纳德邦中央大学生命科学系印度泰米尔纳德邦 GPCHEM沼气研究与分析实验室波兰尼古拉斯哥白尼大学化学系波兰克兰菲尔德大学水与能源学院英国拉彭兰塔工业大学工程科学学院分离科学系芬兰韩国海洋大学海洋可再生能源工程专业韩国釜山延世大学土木与环境工程学院韩国首尔斯塔万格大学科学技术学院化学、生物科学与环境工程研究所挪威斯塔万格

随着化石燃料燃烧导致的二氧化碳排放不断加剧气候变化,且化石燃料储量日益减少,寻求可再生能源已成为一项紧迫的任务.其中,藻类衍生可持续燃料因具有成本优势和可运输性,在解决全球能源危机方面展现出广阔前景,备受关注.利用化学转化... 详细信息

随着化石燃料燃烧导致的二氧化碳排放不断加剧气候变化,且化石燃料储量日益减少,寻求可再生能源已成为一项紧迫的任务.其中,藻类衍生可持续燃料因具有成本优势和可运输性,在解决全球能源危机方面展现出广阔前景,备受关注.利用化学转化技术从微藻中提取脂质,并通过酯交换反应可以将其转化为脂肪酸甲酯,是生产绿色生物燃料的有效途径.这一过程涉及游离脂肪酸、磷脂和甘油三酯的提取,并且生产过程能耗低,成为满足日益增长的能源需求的一种理想解决方案.本文综述了微藻脂质提取和酯交换制备生物燃料的相关研究进展.首先,介绍了微藻脂质的提取方法,包括溶剂提取法、索氏提取法、布利格和戴耶法、超临界二氧化碳提取以及离子液体溶剂法等,并分析了各方法的优缺点.随后,重点阐述了酯交换技术在微藻脂质转化中的应用,包括酸碱催化、酶催化以及原位酯交换反应等,并探讨了这些技术的反应机理、催化剂选择、反应器设计以及生物油生产工艺等方面的研究进展.通过综述上述研究进展,为微藻脂质的生产和应用提供了理论指导.研究表明,通过优化催化剂种类、反应条件以及提取方法,可以有效提高微藻脂质的转化效率和生物油品质.同时,本文也指出了当前微藻脂质生产中面临的挑战,如微藻栽培和生长条件优化、高效转化技术的开发等.随着可持续能源日益受到重视,微藻脂质作为一种可再生能源具有巨大的发展潜力.未来研究应进一步关注微藻的规模化栽培、生长条件优化以及高效转化技术的研发,以提高微藻脂质的产量和品质.同时,应进一步推动和实现微藻生物燃料的实际应用,从而为应对气候变化和能源危机提供有效的解决方案.

关键词：微藻脂质提取酯交换催化酶催化原位技术

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An incidental case of triple gallbladder

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World Journal of Gastroenterology 2007年第13期13卷 2004-2006页

作者： banu Alicioglu Department of Radiology Trakya University School of Medicine Edirne 22030 Turkey

Triplication of the gallbladder is a very rare congenital anomaly of the biliary tract; there are only eleven reported cases to date. Gallbladder multiplications are not likely to be discovered unless associated with cholelithiasis, sludge, cholecystitis and carcinoma. Here we report an incidentally diagnosed triplicate gallbladder in a patient with sigmoid diverticulitis; two of the triplicate gallbladder were demonstrated with ultrasound and computed tomography, and an additional galballder was found at surgery.

关键词： Biliary system Biliary tract imaging Multiplegallbladders Triple gallbladder

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Use of polymeric sub-micron ion-exchange resins for removal of lead,copper,zinc,and nickel from natural waters

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Journal of Environmental Sciences 2019年第1期31卷 247-254页

作者： Audrey Murray banu ?rmeci Department of Civil and Environmental Engineering Carleton University

This research investigated the removal capacity of polymeric sub-micron ion-exchange resins(SMR) for removal of lead, copper, zinc, and nickel from natural waters in competition with natural organic matter(NOM). Polymeric SMR particles were created and tested to ensure that they were adequately dispersed in the solution. They removed little NOM(10%or less) from river water and wastewater, indicating that competition from NOM was not a major concern. SMR were able to remove 82% ± 0.2% of lead, 46% ± 0.6% of copper, 55% ±20% of zinc, and 17% ± 2% of nickel from river water spiked with 500 μg/L of each. Similarly,in wastewater, they were able to remove 86% ± 0.1% of lead, 38% ± 0.8% of copper, 28% ± 1%of zinc, and 11% ± 1% of nickel.

关键词： Water Wastewater Heavy metals Ion exchange Polymeric submicron resin Natural organic matter (NOM)

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An Effective Discrete Artificial Bee Colony Based SPARQL Query Path Optimization by Reordering Triples

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Journal of Computer Science & Technology 2021年第2期36卷 445-462页

作者： Zeynep banu Ozger Nurgul Yuzbasioglu Uslu Department of Computer Engineering Sutcu Imam UniversityKahramanmaras 46040Turkey Department of Computer Engineering Yildiz Technical UniversityIstanbul 34220Turkey

Semantic Web has emerged to make web content machine-readable,and with the rapid increase in the number of web pages,its importance has *** description framework(RDF)is a special data graph format where Semantic Web data are stored and it can be queried by SPARQL query *** challenge is to find the optimal query order that results in the shortest period of *** this paper,the discrete Artificial Bee Colony(dABCSPARQL)algorithm is proposed,based on a novel heuristic approach,namely reordering SPARQL *** processing time of queries with different shapes and sizes is minimized using the dABCSPARQL *** performance of the proposed method is evaluated on chain,star,cyclic,and chain-star queries of different sizes from the Lehigh University Benchmark(LUBM)*** results obtained by the proposed method are compared with those of ARQ(a SPARQL processor for Jena)query engine,the Ant System,the Elitist Ant System,and MAX-MIN Ant System *** experiments demonstrate that the proposed method significantly reduces the processing time,and in most queries,the reduction rate is higher compared with other optimization methods.

关键词： artificial bee colony resource description framework(RDF) query optimization reordering triple pattern SPARQL

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Synthesis and characterization of monosize magnetic poly(glycidyl methacrylate) beads

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China Particuology 2007年第1期5卷 174-179页

作者： Evrim banu Alt■ntas■ Lokman Uzun Adil Denizli Department of Chemistry Biochemistry Division Hacettepe University Ankara Turkey

Monosize, 1.6 μm, magnetic beads of poly（glycidyl methacrylate） [M-poly（GMA）], were prepared by dispersion polymerization in the presence of Fe3O4 nano-powder. Monosize M-poly（GMA） beads were characterized by swelling tests, density measurements, electron spin resonance （ESR）, vibrating sample magnetometer （VSM） and scanning electron microscopy （SEM）. The characteristic functional groups of M-poly（GMA） beads were analyzed by Fourier transform infrared spectrometer （FTIR）. The M-poly（GMA） beads are highly uniform in size and have a spherical shape and non-porous structure. Polydispersity index （PDI） of M-poly（GMA） beads was calculated to be around 1.008. The hydrated density of the M-poly（GMA） beads measured at 25 ℃ was 1.14 g/cm^3. The content of oxirane groups on the surface of the M-poly（GMA） sample was found to be 3.46 mmol/g by using perchloric acid titration. The specific surface area of the M-poly（GMA） beads was determined to be 3.2 m^2/g. The equilibrium swelling ratio was 52%. The volume fraction of magnetite nanopowder in the M-poly（GMA） beads was found to be 4.5%. The g factor, that can be considered as a quantity characteristic of the molecules in which the unpaired electrons are located, was found to be 2.28 for M-poly（GMA）. The external magnetic field at resonance was calculated to be 2055 Gs which was found sufficient to excite all of the dipole moments present in 1.0 g of M-poly（GMA） sample.

关键词： Polyglycidyl methacrylate Monosize beads Magnetic materials

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元话语标记在不同英语媒介教学(EMI)学科口语表达中的运用

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Chinese Journal of Applied Linguistics 2024年第2期47卷 281-308,365页

作者：坎苏·艾库特-科莱巴努·伊南-卡拉古尔哈杰泰佩大学土耳其

经过多年的研究,元话语(MD)已成为教育领域的重要概念,尤其在书面语境中得到了广泛关注。元话语允许教师在授课过程中有效地组织课堂话语,并展示个人的教学风格。尽管近年来对口语语境下元话语的研究有所增加,但在不同教育环境下仍需进... 详细信息

经过多年的研究,元话语(MD)已成为教育领域的重要概念,尤其在书面语境中得到了广泛关注。元话语允许教师在授课过程中有效地组织课堂话语,并展示个人的教学风格。尽管近年来对口语语境下元话语的研究有所增加,但在不同教育环境下仍需进一步探索其在实践中的应用。鉴于英语为媒介的教学(EMI)在全球范围内日益普及,MD在EMI课堂话语中所扮演的角色已然成为一个具有研究价值的领域。在土耳其的语境下,MD近期已成为一个备受瞩目的研究领域。然而,关于土耳其语境中口语互动中的MD的研究却相对较少。本研究旨在深入探究教师在不同EMI课程的口语教学中,对于元话语标记的分布情况以及词法实现的具体表现。研究以?del(2010)提出的元话语框架为参照,运用语料库方法进行了话语分析。通过对36小时课堂观察所收集的语料进行严谨的定性与定量分析,我们发现,在不同的EMI课程中,元话语范畴的分布与实现均呈现出一定的差异性。

关键词：元话语课堂话语英语语言教学口语话语

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