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Urethane Modified Hydrophobic Compact Wood Pulp Paper for Oil Spill Cleanup: A Preliminary Study

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journal of Renewable Materials 2020年第10期8卷 1257-1268页

作者： Gustavo de Souza Ricardo K.Kramer antonio j.F.Carvalho Department of Materials Engineering Sao Carlos School of Engineering(EESC)University of São Paulo(USP)São PauloBrazil

Oil spills and oil/water wastewater are among the great concerns regarding oil *** technologies face many limitations and in some cases are responsible for causing secondary pollution,therefore there is as seek for environmental friendly ***,from which celluloses are highlighted,are being employed for oil/water separation or oil absorbents ***,these membranes are obtained by freeze drying of CNF(cellulose nano-fibrils)suspensions followed by chemical modification for hydrophobization,which involves expensive process as chemical vapor deposition and expensive reactants as sylanes,turning these processes hardly ***,we produced a natural porous structure paper from eucalyptus pulp fibers modified by a dipping and heating process in a blocked diisocyanate *** the surface treatment,contact angle with water reached 144°and water absorption reduced seven times,keeping the good oil *** chemical modification process is simple to be performed and use a very low quantity of reactant estimated to be less than 0.1 wt%based on *** good mechanical properties of the material allows its use in non usual conditions which can be of great importance depending on the environmental conditions.

关键词： Cellulose oil removal hydrophobization water repellency blocked isocyanates

Mesenchymal stem cells secretome:current trends and future challenges

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Neural Regeneration Research 2020年第1期15卷 75-77页

作者： Fabio G.Teixeira antonio j.Salgado Life and Health Sciences Research Institute(ICVS) School of MedicineUniversity of MinhoBragaPortugalICVS/3B’s Associate LabPT Government Associated LabBraga/GuimaraesPortugal

Mesenchymal stem cells(MSCs)secretome:a good candidate for medical biotechnology?Medical biotechnology is currently defined as the application of biotechnological tools for producing multiple technologies and products to health care,becoming an important bridge between different fields,namely neuroscience,regenerative medicine,pharmacology and bio-engineering(Pham,2018).The use and manipulation of stem cells can potentially represent a medical biotechnology breakthrough that brings regenerative medicine to a new ***,over the last decade,the use of stem cells has remarkably been proposed as a regenerative tool,and within it,MSCs have emerged as a promising therapeutic option.

关键词： manipulation breakthrough becoming

Erratum to:Influence of metal support in-plane symmetry on the corrugation of hexagonal boron nitride and graphene monolayers

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Nano Research 2019年第5期12卷 1217-1218页

作者： antonio j.Martinez-Galera jose M.Gomez-Rodriguez Departamento de Fisica de la Materia Condensada Universidad Autonoma de MadridMadrid E-28049Spain Condensed Matter Physics Center(IFIMAC) Universidad Autonoma de MadridMadrid E-28049Spain Instituto Nicolas Cabrera Universidad Autonoma de MadridMadrid E-28049Spain

The writings of the text on the last line,left column on the 4^th page and the text on lines 8^th,10^th,11^th and 16^th in the 4^th paragraph,left column and on lines from 1st to 8^th in the 1st paragraph,right column on the 5^th page,and the text on line 4^th in the 1^st paragraph,left column on the 9^th page,and Fig.3 and its caption on the 5^th page in the original version of this article were unfortunately incorrect.

关键词： corrugation hexagonal boron nitride graphene monolayers

Nanostructured biohybrid material with wide-ranging antiviral action

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Nano Research 2023年第8期16卷 11455-11463页

作者： Noelia Losada-Garcia Angela Vazquez-Calvo David Ortega-Alarcon Olga Abian Adrian Velazquez-Campoy Pilar Domingo-Calap antonio Alcami jose M.Palomo Instituto de Catálisis y Petroleoquímica(ICP) CSICC/Marie Curie 2.Madrid 28049Spain Centro de Biología Molecular Severo Ochoa Consejo Superior de Investigaciones Científicas(CSIC)-Universidad Autónoma de Madrid(UAM)Madrid 28049Spain Institute of Biocomputation and Physics of Complex Systems(BIFI) Joint Unit GBsC-CSIC-BIFIUniversity of ZaragozaZaragoza 50018Spain Fundación Instituto de Investigación Sanitaria de Aragón(IIS Aragón) Zaragoza 50009Spain CIBERehd Madrid 28029Spain Instituto de Biología Integrativa de Sistemas I2SyBioUniversitat de València-CSICValència E-46071Spain

Respiratory pathogens kill more people than any other infectious agent each year *** of novel,economically friendly,sustainable,and highly efficient materials against viruses is a major ***,we describe a nanostructured material composed of very small crystalline phosphate copper nanoparticles synthesized using a new biohybrid technology that employs a biological agent for its formation at room temperature in aqueous *** evaluation of different enzymes in the final preparation of the nanomaterial or even in synthetic methods was *** characterization revealed the formation of Cu species in the protein *** best biomaterial synthesized using a lipase called BioCuNPs showed excellent inhibition capacity against functional proteins of severe acute respiratory syndrome coronavirus 2(SARS-CoV-2);for example,assent 3-chymotrypsin like protease(3CLpro)complete inhibition was achieved by using 5µg/mL,or acetone(ACE)–spike protein interaction was inhibited by more than 80%in the presence of 400µg/mL of *** these in vitro results into account,an efficacy analysis against human coronavirus 229E(HCoV-E229)coronavirus was performed.A virus reduction of 99%was obtained in 5 ***,SARS-CoV-2 virus was tested to demonstrate high efficiency,with>99%inhibition in 15 min using 500 microgram of *** determine the wide applicability of this nanohybrid against viruses,an evaluation was carried out against a non-enveloped virus such as Human Rhinovirus(HRV-14),obtaining a virus reduction of 99.9%in 5 ***,the virucidal capacity against different bacteriophages was also evaluated,obtaining an excellent inhibition effect against PhageΦX174(99.999%reduction in 5 min).

关键词： antiviral compound coronaviruses copper nanoparticles nanobiotechnology viruses

Protective effect of resveratrol against cadmium-induced toxicity on ovine oocyte in vitro maturation and fertilization

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journal of Animal Science and Biotechnology 2023年第1期14卷 152-165页

作者： Anna Rita Piras Federica Ariu Alessio Maltana Giovanni Giuseppe Leoni Nicola antonio Martino Antonella Mastrorocco Maria Elena Dell’Aquila Luisa Bogliolo Department of Veterinary Medicine University of Sassari07100 SassariSardiniaItaly. Department of Biosciences Biotechnologies&BiopharmaceuticsUniversity of Bari Aldo Moro70125 BariItaly.

Background:Heavy metal cadmium(Cd)is a widespread environmental contaminant with a potential toxicity that might negatively affect female reproduction and *** has been reported that Cd exposure impaired the quality of oocytes and led to a defective maturation and fertilization,through oxidative stress ***(Res)is a natural polyphenol with strong antioxidant properties that exhibited protective role in preventing oocyte redox homeostasis disruption and quality ***,we explored whether the addition of Res to in vitro maturation(IVM)medium might act as a protection against Cd-induced toxicity on ovine oocyte maturation and ***,we evaluated the effect of supplementing IVM medium with two different Res concentrations(1and 2μmol/L)on nuclear maturation and fertilization of oocytes matured under CdCl2(2μmol/L)***,the concentration of 1μmol/L Res was selected to analyse the effects of this compound on intracellular ROS levels,mitochondrial(mt)distribution and activity,chromatin configuration,cytoskeleton morphology,cortical granules(CGs)distribution and mRNA expression of genes associated with cellular response to oxidative stress(***1,SOD 1,GPX1,GSR,CAT)in Cd-exposed in vitro matured ***:We found that 1μmol/L Res restored the reduced oocyte meiotic competence induced by Cd exposure as well as,Res sustained oocyte ability to be normally fertilized and decreased polyspermic fertilization at both tested ***,we demonstrated that 1μmol/L Res mitigated Cd-induced alterations of oocyte cytoplasmic maturation by reducing reactive oxygen species(ROS)accumulation,preventing mt dysfunction,maintaining the correct meiotic spindle and cortical F-actin assembly and the normal cortical granule distribution as well as up-regulating SIRT1,SOD1 and GPX1 ***:Taken together,our findings highlighted the beneficial influence exerted by Res in preventing Cdinduced disturbance of

关键词： Cadmium In vitro maturation Oocyte Ovine Resveratrol

ScY@C_(3v)(8)-C_(82):Metal-Metalσ^(2)Bond in Mixed Rare-Earth Di-metallofullerenes

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Chinese journal of Chemistry 2023年第15期41卷 1809-1814页

作者： Lihao Zheng Yannick Roselló Yingjing Yan Yang-Rong Yao Xiaolin Fan josep M.Poblet antonio Rodríguez-Fortea Ning Chen College of Chemistry Chemical Engineering and Materials Scienceand State Key Laboratory of Radiation Medicine and ProtectionSoochow UniversitySuzhouJiangsu 215123China Departament de Quimica Fisica i Inorganica Universitat Rovira i VirgiliMarcelli Domingo 143007 TarragonaSpain Department of Materials Science and Engineering CAS Key Laboratory of Materials for Energy ConversionAnhui Laboratory of Advanced Photon Science and TechnologyUniversity of Science and Technology of ChinaHefeiAnhui 230026China

Comprehensive Summary The experimental investigation of rare-earth metal-metal bonds remains a challenge in the study of chemical ***,we report the synthesis and characterization of a novel heteronuclear di-metallofullerene,ScY@C_(3v)(8)-C_(82),which contains a mixed rare-earth metal-metal ***@C_(3v)(8)-C_(82)was successfully synthesized by arc-discharging method and characterized by mass spectrometry,UV-vis-NIR spectroscopy and single-crystal X-ray diffraction crystallography,which unambiguously determined its molecular *** calculations were also performed to study the optimized positions of Sc-Y metallic dimer and the electronic *** combined experimental and theoretical results confirmed that both Sc and Y atoms transfer two electrons to the C_(3v)(8)-C_(82)cage,i.e.,(ScY)4+@(C_(3v)(8)-C_(82))4-.In particular,a covalent Sc-Yσ2 bond,which has never been reported before,is proven to be formed inside C_(3v)(8)-C_(82)fullerene *** work presents a novel di-metallofullerene containing mixed rare-earth metal-metal bond and expands the understanding of metal-metal bonding of rare earth elements.

关键词： Fullerenes Endohedral fullerenes Rare earths Densityfunctional calculations Metal-metal bond

Linking the Gawler Craton and Mount Isa Province through hydrothermal systems in the Peake and Denison Domain,northeastern Gawler Craton

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Geoscience Frontiers 2023年第5期14卷 108-125页

作者： Mitchell j.Bockmann justin L.Payne Martin Hand Laura j.Morrissey antonio P.Belperio Department of Earth Sciences University of AdelaideAdelaideSAAustralia Mineral Exploration Cooperative Research Centre University of AdelaideAdelaideSAAustralia UniSA STEM University of South AustraliaAdelaideSAAustralia Mineral Exploration Cooperative Research Centre Future Industries InstituteUniversity of South AustraliaAdelaideSAAustralia Demetallica Ltd NorwoodSAAustralia

Tectonic reconstructions of Proterozoic Australia commonly place the Peake and Denison Domain of the northeastern Gawler Craton at the interface between the North and South Australian cratons prior to the reconfiguration of Australia’s main tectonic components in the ***,this reconstruction is largely based on palaeomagnetic data as the geological correlations between these regions are currently limited,particularly during the *** early Mesoproterozoic period is significant as it corresponds to major IOCG mineralization in the eastern Gawler Craton between 1600 Ma and 1575 Ma,and IOCG mineralization in the Mount Isa Province largely between 1550 Ma and 1490 ***,determining the relationship of the Peake and Denison Domain to the Gawler Craton and Mount Isa Province during this period is essential to evaluating mineral prospectivity in the northeastern Gawler *** U–Pb LA-ICP-MS geochronology on zircon and titanite improves our understanding of the tectonothermal and hydrothermal history the Peake and Denison Domain during the latePalaeoproterozoic,early-Mesoproterozoic and the Cambrian–Ordovician *** formed within largely calc-silicate alteration assemblages indicates the Peake and Denison Domain has a protracted history of hydrothermal activity,recording events at c.1565 Ma,1530–1515 Ma,c.1500 Ma,c.1465 Ma and c.490 *** highly calcic nature of the c.1565–1500 Ma alteration in the Peake and Denison Domain shares strong similarities in age and character to the regional calcic-sodic alteration recorded in the Mount Isa *** suggest the two regions were influenced by similar hydrothermal systems during the early Mesoproterozoic,supporting reconstruction models that place the Peake and Denison Domain near the Mount Isa Province during the *** highlights the prospectivity of the Peake and Denison Domain for Isan-style IOCG mineralization,but requires consideration of the post-

关键词： Peake and Denison Gawler Craton Mount Isa IOCG Tectonic reconstruction Titanite

A Comprehensive Survey on Fault Diagnosis and Fault Tolerance of DC-DC Converters

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Chinese journal of Electrical Engineering 2018年第3期4卷 1-12页

作者： Fernando Bento antonio j.Marques Cardoso CISE-Electromechatronic Systems Research Centre Universidade da Beira InteriorCalcada Fonte do LameiroP-6201-001 CovilhaPortugal Department of Electromechanical Engineering Universidade da Beira InteriorCalcada Fonte do LameiroP-6201-001 CovilhaPortugal

DC-DC converters are becoming more commonly used in power conversion solutions for energy management purposes,being employed in an ever-increasing range of DC-based applications,such as LED lighting,electric vehicles,energy storage solutions,and consumer electronics(laptops,smartphones,etc.).In this context,efficiency and reliability are *** research efforts made in improving reliability of DC-DC converters are still quite narrow and ***,DC-DC converters take the shape of an endless number of topologies,with different functionalities and operation principles,thus complicating the task of improving reliability of all forms of DC-DC ***,compiling the information about the main failure modes,corresponding fault diagnostic algorithms and fault tolerance strategies developed so far,in a single document,becomes increasingly ***,this paper presents an up-to-date review of the recent achievements attained regarding the improvement of availability and reliability of DC-DC converters.

关键词： DC-DC converters fault diagnosis fault tolerance reliability

A Boundary Meshless Method for Solving Heat Transfer Problems Using the Fourier Transform

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Advances in Applied Mathematics and Mechanics 2011年第5期3卷 572-585页

作者： A.Tadeu C.S.Chen j.antonio Nuno Simoes Department of Civil Engineering Faculty of Sciences and TechnologyUniversity of CoimbraPolo II-Pinhal de Marrocos3030-290 CoimbraPortugal Department of Mathematics University of Southern MississippiHattiesburgMS 39406USA

Fourier transform is applied to remove the time-dependent variable in the diffusion *** non-harmonic initial conditions this gives rise to a non-homogeneous Helmholtz equation,which is solved by the method of fundamental solutions and the method of particular *** particular solution of Helmholtz equation is available as shown in[4,15].The approximate solution in frequency domain is then inverted numerically using the inverse Fourier transform *** frequencies are used in order to avoid aliasing phenomena and to allow the computation of the static *** numerical examples are given to illustrate the effectiveness of the proposed approach for solving 2-D diffusion equations.

关键词： Transient heat transfer meshless methods method of particular solutions method of fundamental solutions frequency domain Fourier transform