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Chinese Journal of Structural Chemistry 2009年第4期28卷 419-426页

作者： Wajid Rehman amin badshah Salimullah Khan Iftikhar Ahmad Department of Chemistry Hazara University Department of Chemistry Quaid-e-Azam University Department of Pharmacy Hazara University Department of Physics Louisiana State University

Some biologically important tin（Ⅳ） complexes derived from 5,5-diethyl sodium barbital have been synthesized and characterized through various analytical and spectroscopic techniques such as IR, ^1H-, ^13C-NMR and ^119mSn mossbauer. On the basis of these spectroscopic techniques, octahedral geometry has been assigned to all the novel compounds. These complexes, soluble in DMSO and DMF, were screened against a wide range of microorganisms. The results proved that the diphenyltin（Ⅳ） and dibutyltin（Ⅳ） complexes exhibit excellent activity against all types of microorganisms, while the rest of the compounds show significant activity that can be used during the biological study.

关键词： 5,5-diethyl sodium barbital spectra antibacterial anti-inflammatory organotin

Structural and Spectral Studies of Some Geometric Isomers of N-Pivaloyl-Nˊ-dichlorophenyl Thiourea

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Chinese Journal of Structural Chemistry 2013年第3期32卷 349-356页

作者： Muhammad Khawar Rauf Masahiro Ebihara Sarwat Sultana amin badshah Department of Chemistry Quaid-I-Azam University Department of Chemistry Faculty of EngineeringGifu University Yanagido

N-pivaloyl-Nˊ-（3,4-dichlorophenyl）thiourea （1）： monoclinic, P21/a, a=11.57（1）, b=9.278（8）, c=13.51（1）, β=103.85（1）°, V=1408（2）3 , Z=4, μ=0.598 mm-1 ; N-pivaloyl-N＇-（3,5- dichlorophenyl）thiourea （2）： monoclinic, P21/a, a=7.176（2）, b=16.441（4）, c=11.923（2）, β=92.48（1）°, V=1405.3（6）3 , Z=4, μ=0.600 mm-1 ; N-pivaloyl-Nˊ-（2,6-dichlorophenyl）thiourea （3）： orthorhombic, Pnma, a=26.79（1）, b=8.780（4）, c=5.955（3）, V=1400.7（11）3 , Z=4, μ=0.601 mm-1 . All three complexes have an intramolecular hydrogen bond between NˊH and the carbonyl oxygen. Solution 1H NMR studies （CDCl3） show the NH resonance considerable downfield for each thiourea and their positions, as well as that of NH, is affected by substituents on the phenyl ring.

关键词： pivaloyl thioureas single-crystal XRD-studies hydrogen bonds spectral studies mirror plane

Characteristic spectral studies and in vitro antifungal activity of some Schiff bases and their organotin (Ⅳ) complexes

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Chinese Science Bulletin 2004年第2期49卷 119-122页

作者： Wajid Rehman Musa Kaleem Baloch Bakhtiar Muhammad amin badshah Khalid M.Khan Department of Chemistry Gomal University Dera Ismail KhanPaki-stanDepartment of Chemistry Gomal UniversityDera Ismail KhanPaki-stanDepartment of Chemistry Gomal UniversityDera Ismail KhanPaki-stanDepartment of ChemistryQuaid-e-Azam UniversityIslamabadPaki-stanHEJ Research Institute University of KarachiPakistan

The synthesis and in vitro antifungal activity of some Schiff bases and their Sn (Ⅳ) complexes has been tested against plant pathogenic fungi and it is found that they possess excellent fungicidal activity. On the basis of ^1H-, ^13C-,^119Sn NMR-, ^119Sn Mǒssbauer, IR and Elemental analysis the tetrahedral geometry is proposed for the synthesized compounds.

关键词：特征光谱抗真菌活性有机锡有机金属化合物

Antituberculosis and cytotoxic activities of triorganotin(Ⅳ) complexes

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Chinese Chemical Letters 2012年第6期23卷 731-735页

作者： Hidayat Hussain NaziaBibi Ahmed Al-Harrasi Salman Siddiqi Shahana U. Kazmi Ying Zhang amin badshah Department of Chemisty University of Paderborn 33098 Paderborn Germany Department of Biological Siences and Chemistry College of Arts and Sciences University of Nizwa Oman Immnology and Infectious Disease Research Laboratory Department of Microbiology University of＂ Karachi Pakistan Department of Molecular Muclvbiology and Immunology Bloomberg School of Public Health Johns Hopkins University Baltimore MD 21205 USA Becton Dickinson Diagnostic Systems Sparks MD 21152 USA Department of Chemistry Quaid-e-Azam University lslamabad 45320 Pakistan

Five triorganotin（IV）（1-5） complexes of cinnamic acid, （Z）-2-acetamido-3-phenylacrylic acid, 3-methylbut-2-enoic acid, and 2,2-diphenylacetic acid have been synthesized and characterized by IH-13C-119Sn NMR, UV, and IR. The spectroscopic investigation demonstrated that the carboxylate group acts as a monodentate ligand in triorganotin（IV） compounds. Five triorganotin（IV） complexes were screened against the log phase culture of Mycobacterium tuberculosis H37Rv by colorimetric method using XTT dye as growth indicator. The MICs were found to he 0.08 and 1.25μg/mL.

关键词： Triorganotin(IV) complexes Antituberculosis activity MICs Cytotoxicity

Numerical study of flow and thermal characteristics of pulsed impinging jet on a dimpled surface

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Theoretical & Applied Mechanics Letters 2024年第2期14卷 106-117页

作者： amin Bagheri Kazem Esmailpour Morteza Heydari Renewable Energy Research Center Damavand BranchIslamic Azad UniversityDamavandIran

This research comprehensively investigates the flow and thermal characteristics of a pulsating impinging jet over a dimpled *** analyzes the impact of key parameters(e.g.,inlet velocity pulsation functions,pulsation frequency,amplitude,dimple pitch,dimple depth,Reynolds number)on flow patterns and heat *** computational fluid dynamics and the Re-normalization group turbulence model are employed to accurately simulate complex turbulent flow *** and average heat transfer coefficients are calculated and compared to steady impingement cases,revealing the potential benefits of pulsation for heat transfer *** study also examines how pulsation-induced flow modulation and thermal mixing affect heat transfer *** indicate that combining fluctuating flow with a dimpled surface can improve heat transfer *** summary,increasing pulsation amplitude consistently enhances heat transfer,while the effect of frequency varies between impinging and wall jet zones.

关键词： Pulsating impinging jet Dimpled surface Heat transfer enhancement Pulsation frequency and amplitude Coherent structures

Dual PPAR delta/gamma agonist offer therapeutic potential for Alzheimer's disease

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Neural Regeneration Research 2024年第6期19卷 1175-1176页

作者： Ian Steinke Meenakshi Singh Rajesh amin Department of Drug Discovery and Development Auburn University

The increasing incidence of Alzheimer’s disease(AD) in the aging population, indicates the critical need for the development of novel targeted molecular therapies for ameliorating AD pathology. Moreover, clinical and preclinical evidence demonstrates that peroxisomal proliferator activating receptors(PPAR) agonists regulate energy and lipid homeostasis in models of diabetes, as well as improve spatial memory in animal models of AD(Khan et al., 2019).

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Antimicrobial chemical constituents from endophytic fungus Phoma sp.

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Asian Pacific Journal of Tropical Medicine 2014年第9期7卷 699-702页

作者： Hidayat Hussain Ines Kock Ahmed Al-Harrasi Ahmed Al-Rawahi Ghulam Abbas Ivan R.Green Afzal Shah amin badshah Muhammad Saleem Siegfried Draeger Barbara Schulz Karsten Krohn Department of Chemistry University of PaderbornWarburger Strasse 10033098 PaderbornGermany UoN Chair of Oman's Medicinal Plants and Marine Natural Products University of NizwaP.O Box 33Postal Code 616Birkat Al MauzNizwaSultanate of Oman Department of Chemistry CUTAbbottabad CampusAbbottabad-22060Pakistan Department of Chemistry and Polymer Science University of StellenboschP/Bag X1 Matieland 7602South Africa Department of Chemistry Quaid-i-Azam University45320 IslamabadPakistan Department of Chemistry The Islamia University of BahawalpurBaghdad Campus-ul-JadidBahawalpurPakistan Institute of Microbiology University of BraunschweigSpielmannstraβe 738106 BraunschweigGermany

Objective:To evaluate the antiniicrobial polenlial of different extracts of the endophytic fungus Phoma *** the tentative identification of their active ***:The extract and compounds were screened for antimicrobial activity using the Agar Well Diffusion *** compounds were purified using column chromatography and tlieir structures were assigned using～1H and～(13)C NMR spectra,DEPT,2D COSY,HMQC and HMBC ***:The ethyl acetate fraction of Phoma *** good antifungal,antibacterial,and algicidal *** new dihydrofuran derivative,named phomafuranol(1),together with tliree known compounds,phomalacton(2),(3R)-5-hydroxymellein(3)and emodin(4)were isolated from the ethyl acetate fraction of Phoma *** studies indicated that phomalacton(2)displayed strong antibacterial,good antifungal and antialgal ***(3R)-5-hydroxymellein(3)and emodin(4)showed good antifungal,antibacterial and algicidal ***:Antimicrobial activities of the ethyl acetate fraction of the endophytic fungus Phoma *** isolated compounds clearly demonstrate that Phoma *** its active compounds represent a great potential for the food,cosmetic and pharmaceutical industries.

关键词： Natural product Endrophytic fungi Phoma sp

Geyser Inspired Algorithm:A New Geological-inspired Meta-heuristic for Real-parameter and Constrained Engineering Optimization

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Journal of Bionic Engineering 2024年第1期21卷 374-408页

作者： Mojtaba Ghasemi Mohsen Zare Amir Zahedi Mohammad-amin Akbari Seyedali Mirjalili Laith Abualigah Department of Electronics and Electrical Engineering Shiraz University of TechnologyShirazIran Department of Electrical Engineering Faculty of EngineeringJahrom UniversityJahromFrasIran Department of Electrical and Computer Engineering Tarbiat Modares UniversityTehranIran Department of Electrical and Computer Engineering University ofCyprusNicosiaCyprus Centre for Artificial Intelligence Research and Optimisation Torrens University AustraliaBrisbaneQLD 4006Australia University Research and Innovation Center Obuda University1034 BudapestHungary Department of Electrical and Computer Engineering Lebanese American UniversityByblos 13-5053Lebanon Hourani Center for Applied Scientific Research Al-Ahliyya Amman UniversityAmman 19328Jordan MEU Research Unit Middle East UniversityAmman 11831Jordan Applied Science Research Center Applied Science Private UniversityAmman 11931Jordan

Over the past years,many efforts have been accomplished to achieve fast and accurate meta-heuristic algorithms to optimize a variety of real-world *** study presents a new optimization method based on an unusual geological phenomenon in nature,named Geyser inspired Algorithm(GEA).The mathematical modeling of this geological phenomenon is carried out to have a better understanding of the optimization *** efficiency and accuracy of GEA are verified using statistical examination and convergence rate comparison on numerous CEC 2005,CEC 2014,CEC 2017,and real-parameter benchmark ***,GEA has been applied to several real-parameter engineering optimization problems to evaluate its *** addition,to demonstrate the applicability and robustness of GEA,a comprehensive investigation is performed for a fair comparison with other standard optimization *** results demonstrate that GEA is noticeably prosperous in reaching the optimal solutions with a high convergence rate in comparison with other well-known nature-inspired algorithms,including ABC,BBO,PSO,and *** that the source code of the GEA is publicly available at https://***/projects/gea.

关键词： Nature-inspired algorithms Real-world and engineering optimization Mathematical modeling Geyser algorithm(GEA)

Tuning structural,electrical,dielectric and magnetic properties of Mg-Cu-Co ferrites via dysprosium(Dy^(3+))doping

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Journal of Rare Earths 2024年第1期42卷 137-146,I0005页

作者： Maria Akhtar M.S.Hasan Nasir amin N.A.Morley Muhammad Imran Arshad Department of Physics Government College UniversityFaisalabad38000Pakistan Department of Physics The University of Lahore53700Pakistan Department of Materials Science and Engineering The University of SheffieldS13JDUK Department of Physics&Astronomy University College LondonUK

In current research work,Dy3+substituted Mg0.5Cu0.25Co0.25Fe2-xDyxO4(0.0≤x≤0.04 with the step interval of 0.01)soft ferrites were synthesized by the sol-gel auto combustion *** prepared samples were characterized by the techniques using X-ray diffraction(XRD),scanning electron microscopy(SEM),energy dispersive X-ray spectroscopy(EDS),Fourier transform infrared(FTIR)spectroscopy,curre nt-voltage(Ⅰ-Ⅴ)measurement,LCR meter,vibrating sample magnetometer(VSM)and *** data reveal that the average crystallite size is 49.71 nm and the lattice constant is 0.83703 nm for sample x=*** non-uniform grain growth was demonstrated by micrographs and impurity-free elemental composition was observed from EDX *** DC resistivity has an increasing and decreasing trend in ferromagnetic and paramagnetic regions with an increase in ***,the high resistivity is observed with the order of 1010Ω·cm,and the activation energy is 0.944 eV for samples x=*** dielectric parameters including dielectric constant,dielectric losses,and impedance gradually decrease with the increase in frequency from 8 Hz to 8 *** minimum dielectric loss at high frequency is found for sample x=*** coercivity(Hc)and saturation magnetization(Ms)are found in the ranges of 520.82-544.02 Oe and 20.5841-21.1473 emu/g,*** observations confirm that dysprosium(x=0.03)doped MCC-soft ferrites may be applicable in transformer cores,microwave absorbance,and telecommunication devices.

关键词： Soft ferrites DC resistivity Dielectric loss Impedance Coercivity Rare earths

Modeling the dynamical behavior of the interaction of T-cells and human immunodeficiency virus with saturated incidence

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Communications in Theoretical Physics 2024年第3期76卷 1-14页

作者： Salah Boulaaras Rashid Jan amin Khan Ali Allahem Imtiaz Ahmad Salma Bahramand Department of Mathematics College of ScienceQassim UniversityBuraydah51452Saudi Arabia Institute of Energy Infrastructure(IEI) Department of Civil EngineeringCollege of EngineeringUniversiti Tenaga Nasional(UNITEN)Putrajaya CampusJalan IKRAM-UNITEN43000 KajangSelangorMalaysia Department of Mathematics University of SwabiSwabi 23561Pakistan Department of Mathematics College of SciencesQassim UniversitySaudi Arabia Institute of Informatics and Computing in Energy(IICE) Universiti Tenaga NasionalKajangSelangorMalaysia Department of Political Science Bacha Khan University CharsaddaCharsadda 24420KPK Pakistan

In the last forty years,the rise of HIV has undoubtedly become a major concern in the field of public health,imposing significant economic burdens on affected ***,it becomes imperative to undertake comprehensive investigations into the mechanisms governing the dissemination of HIV within the human *** this work,we have devised a mathematical model that elucidates the intricate interplay between CD4^(+)T-cells and viruses of HIV,employing the principles of fractional *** production rate of CD4^(+)T-cells,like other immune cells depends on certain factors such as age,health status,and the presence of infections or ***,we incorporate a variable source term in the dynamics of HIV infection with a saturated incidence rate to enhance the precision of our *** introduce the fundamental concepts of fractional operators as a means of scrutinizing the proposed HIV *** facilitate a deeper understanding of our system,we present an iterative scheme that elucidates the trajectories of the solution pathways of the *** show the time series analysis of our model through numerical findings to conceptualize and understand the key factors of the *** addition to this,we present the phase portrait and the oscillatory behavior of the system with the variation of different input *** information can be utilized to predict the long-term behavior of the system,including whether it will converge to a steady state or exhibit periodic or chaotic oscillations.

关键词： HIV infection fractional-calculus dynamics of HIV iterative scheme dynamical behaviour mathematical model fractional derivatives