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Chinese Journal of Structural Chemistry 2009年第4期28卷 419-426页

作者： Wajid Rehman amin badshah Salimullah Khan Iftikhar Ahmad Department of Chemistry Hazara University Department of Chemistry Quaid-e-Azam University Department of Pharmacy Hazara University Department of Physics Louisiana State University

Some biologically important tin（Ⅳ） complexes derived from 5,5-diethyl sodium barbital have been synthesized and characterized through various analytical and spectroscopic techniques such as IR, ^1H-, ^13C-NMR and ^119mSn mossbauer. On the basis of these spectroscopic techniques, octahedral geometry has been assigned to all the novel compounds. These complexes, soluble in DMSO and DMF, were screened against a wide range of microorganisms. The results proved that the diphenyltin（Ⅳ） and dibutyltin（Ⅳ） complexes exhibit excellent activity against all types of microorganisms, while the rest of the compounds show significant activity that can be used during the biological study.

关键词： 5,5-diethyl sodium barbital spectra antibacterial anti-inflammatory organotin

Structural and Spectral Studies of Some Geometric Isomers of N-Pivaloyl-Nˊ-dichlorophenyl Thiourea

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Chinese Journal of Structural Chemistry 2013年第3期32卷 349-356页

作者： Muhammad Khawar Rauf Masahiro Ebihara Sarwat Sultana amin badshah Department of Chemistry Quaid-I-Azam University Department of Chemistry Faculty of EngineeringGifu University Yanagido

N-pivaloyl-Nˊ-（3,4-dichlorophenyl）thiourea （1）： monoclinic, P21/a, a=11.57（1）, b=9.278（8）, c=13.51（1）, β=103.85（1）°, V=1408（2）3 , Z=4, μ=0.598 mm-1 ; N-pivaloyl-N＇-（3,5- dichlorophenyl）thiourea （2）： monoclinic, P21/a, a=7.176（2）, b=16.441（4）, c=11.923（2）, β=92.48（1）°, V=1405.3（6）3 , Z=4, μ=0.600 mm-1 ; N-pivaloyl-Nˊ-（2,6-dichlorophenyl）thiourea （3）： orthorhombic, Pnma, a=26.79（1）, b=8.780（4）, c=5.955（3）, V=1400.7（11）3 , Z=4, μ=0.601 mm-1 . All three complexes have an intramolecular hydrogen bond between NˊH and the carbonyl oxygen. Solution 1H NMR studies （CDCl3） show the NH resonance considerable downfield for each thiourea and their positions, as well as that of NH, is affected by substituents on the phenyl ring.

关键词： pivaloyl thioureas single-crystal XRD-studies hydrogen bonds spectral studies mirror plane

Characteristic spectral studies and in vitro antifungal activity of some Schiff bases and their organotin (Ⅳ) complexes

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Chinese Science Bulletin 2004年第2期49卷 119-122页

作者： Wajid Rehman Musa Kaleem Baloch Bakhtiar Muhammad amin badshah Khalid M.Khan Department of Chemistry Gomal University Dera Ismail KhanPaki-stanDepartment of Chemistry Gomal UniversityDera Ismail KhanPaki-stanDepartment of Chemistry Gomal UniversityDera Ismail KhanPaki-stanDepartment of ChemistryQuaid-e-Azam UniversityIslamabadPaki-stanHEJ Research Institute University of KarachiPakistan

The synthesis and in vitro antifungal activity of some Schiff bases and their Sn (Ⅳ) complexes has been tested against plant pathogenic fungi and it is found that they possess excellent fungicidal activity. On the basis of ^1H-, ^13C-,^119Sn NMR-, ^119Sn Mǒssbauer, IR and Elemental analysis the tetrahedral geometry is proposed for the synthesized compounds.

关键词：特征光谱抗真菌活性有机锡有机金属化合物

Antituberculosis and cytotoxic activities of triorganotin(Ⅳ) complexes

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Chinese Chemical Letters 2012年第6期23卷 731-735页

作者： Hidayat Hussain NaziaBibi Ahmed Al-Harrasi Salman Siddiqi Shahana U. Kazmi Ying Zhang amin badshah Department of Chemisty University of Paderborn 33098 Paderborn Germany Department of Biological Siences and Chemistry College of Arts and Sciences University of Nizwa Oman Immnology and Infectious Disease Research Laboratory Department of Microbiology University of＂ Karachi Pakistan Department of Molecular Muclvbiology and Immunology Bloomberg School of Public Health Johns Hopkins University Baltimore MD 21205 USA Becton Dickinson Diagnostic Systems Sparks MD 21152 USA Department of Chemistry Quaid-e-Azam University lslamabad 45320 Pakistan

Five triorganotin（IV）（1-5） complexes of cinnamic acid, （Z）-2-acetamido-3-phenylacrylic acid, 3-methylbut-2-enoic acid, and 2,2-diphenylacetic acid have been synthesized and characterized by IH-13C-119Sn NMR, UV, and IR. The spectroscopic investigation demonstrated that the carboxylate group acts as a monodentate ligand in triorganotin（IV） compounds. Five triorganotin（IV） complexes were screened against the log phase culture of Mycobacterium tuberculosis H37Rv by colorimetric method using XTT dye as growth indicator. The MICs were found to he 0.08 and 1.25μg/mL.

关键词： Triorganotin(IV) complexes Antituberculosis activity MICs Cytotoxicity

Antimicrobial chemical constituents from endophytic fungus Phoma sp.

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Asian Pacific Journal of Tropical Medicine 2014年第9期7卷 699-702页

作者： Hidayat Hussain Ines Kock Ahmed Al-Harrasi Ahmed Al-Rawahi Ghulam Abbas Ivan R.Green Afzal Shah amin badshah Muhammad Saleem Siegfried Draeger Barbara Schulz Karsten Krohn Department of Chemistry University of PaderbornWarburger Strasse 10033098 PaderbornGermany UoN Chair of Oman's Medicinal Plants and Marine Natural Products University of NizwaP.O Box 33Postal Code 616Birkat Al MauzNizwaSultanate of Oman Department of Chemistry CUTAbbottabad CampusAbbottabad-22060Pakistan Department of Chemistry and Polymer Science University of StellenboschP/Bag X1 Matieland 7602South Africa Department of Chemistry Quaid-i-Azam University45320 IslamabadPakistan Department of Chemistry The Islamia University of BahawalpurBaghdad Campus-ul-JadidBahawalpurPakistan Institute of Microbiology University of BraunschweigSpielmannstraβe 738106 BraunschweigGermany

Objective:To evaluate the antiniicrobial polenlial of different extracts of the endophytic fungus Phoma *** the tentative identification of their active ***:The extract and compounds were screened for antimicrobial activity using the Agar Well Diffusion *** compounds were purified using column chromatography and tlieir structures were assigned using～1H and～(13)C NMR spectra,DEPT,2D COSY,HMQC and HMBC ***:The ethyl acetate fraction of Phoma *** good antifungal,antibacterial,and algicidal *** new dihydrofuran derivative,named phomafuranol(1),together with tliree known compounds,phomalacton(2),(3R)-5-hydroxymellein(3)and emodin(4)were isolated from the ethyl acetate fraction of Phoma *** studies indicated that phomalacton(2)displayed strong antibacterial,good antifungal and antialgal ***(3R)-5-hydroxymellein(3)and emodin(4)showed good antifungal,antibacterial and algicidal ***:Antimicrobial activities of the ethyl acetate fraction of the endophytic fungus Phoma *** isolated compounds clearly demonstrate that Phoma *** its active compounds represent a great potential for the food,cosmetic and pharmaceutical industries.

关键词： Natural product Endrophytic fungi Phoma sp

Seimatoric acid and colletonoic acid:Two new compounds from the endophytic fungi,Seimatosporium *** Colletotrichum sp.

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Chinese Chemical Letters 2014年第12期25卷 1577-1579页

作者： Hidayat Hussain Natalia Root Farah Jabeen Ahmed Al-Harrasi Ahmed Al-Rawahi Manzoor Ahmad Zahid Hassan Ghulam Abbas Fazal Mabood Afzal Shah amin badshah Amjad Khan Riaz Ahmad Ivan R.Green Siegfried Draeger Barbara Schulz Karsten Krohn Department of Chemistry University of PaderbornWarburger Strasse 100Paderborn 33098Germany UoN Chair of Oman's Medicinal Plants and Marine Natural Products University of NizwaP.O.Box 33Postal Code 616Birkat Al MauzNizwaOman Department of Chemistry University of MalakandChakdaraDir(L)Pakistan Department of Chemistry CIITAbbottabad CampusAbbottabad 22060Pakistan Department of Chemistry Quaid-i-Azam UniversityIslamabad 45320Pakistan Department of Biotechnology Quaid-i-Azam UniversityIslamabad 45320Pakistan Department of Chemistry and Polymer Science University of StellenboschP/Bag X1Matieland 7602South Africa Institute of Microbiology University of BraunschweigSpielmannstraβe 7Braunschweig 38106Germany

A new metabolite,named seimatoric acid（1）,representing a new oxobutanoic acid derivative has been isolated from Seimatosporium sp., in addition to four known compounds viz.,2-hydroxymethyl-4β,5α,6β-trihydroxycyclohex-2-enone（2）,（-）-phyllostine（3）,（＋）-epiepoxydon（4） and（＋）-epoxydon monoacetate（5）.Similarly one new benzoic acid derivative,named colletonoic acid（6） was isolated from the ethyl acetate fraction of Colletotrichum *** structures of the new compounds were elucidated by detailed ^1 H NMR,^13C NMR,COSY,*** spectroscopic analysis,and *** acid（1）was also isolated from another taxonomical unidentified fungal strain 4295 in *** structures of the known compounds were elucidated by their spectral data comparison to literature *** studies showed that colletonoic acid（6） showed good antibacterial,antifungal,and antialgal activities.

关键词： Seimatosporium sp. Colletotrichum sp. Activity Natural product

Electrochemical Characterization, Detoxification and Anticancer activity of Didodecyldimethylammonium Bromide

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International Journal of Organic Chemistry 2011年第4期1卷 183-190页

作者： Afzal Shah Erum Nosheen Rumana Qureshi Muhammad Masoom Yasinzai Suzanne K. Lunsford Dionysios D. Dionysiou Zia ur-Rehman Muhammad Siddiq amin badshah Saqib Ali 不详

Quaternaryammonium compounds (QACs) are cationic surfactants with broad range applications. They enter into aquatic environment through the discharge of sewage effluents and adversely affect the ecosystem due to toxicity. Modern electrochemical methods have been used for characterization and detoxification of an extensively used QAC, didodecyldimethylammonium bromide (DDAB) in a wide pH range. The diffusion coefficient of DAAB was determined by Randles-Sevcik equation. In acidic conditions the electrochemical reduction of DAAB occurred by two electrons and two protons process. However, in neutral medium the overall reduction of DAAB followed electronation-protonation mechanism involving 3e– and 3H+. Although DDAB is toxic yet it is bestowed with cancer preventing ability. Hence, for getting insights into the under-standing of DAAB anticancer effect, its DNA binding parameters has been evaluated.

关键词： Didodecyldimethylammonium Bromide Detoxification Anticancer Effect DNA Binding Parameters

Geometrically Nonlinear Bending Analysis of Metal-Ceramic Composite Beams under Thermomechanical Loading

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Chinese Journal of Mechanical Engineering 2013年第4期26卷 701-713页

作者： TORABIZADEH Mohammad amin Department of Industrial Design Engineering University of Applied Science and Technology

A new method is developed to derive equilibrium equations of Metal-Ceramic beams based on first order shear deformation plate theory which is named first order shear deformation beam theory2(FSDBT2). Equilibrium equations obtained from conventional method (FSDBT1) is compared with FSDBT2 and the case of cylindrical bending of Metal-Ceramic composite plates for non-linear thermomechanical deformations and various loadings and boundary conditions. These equations are solved by using three different methods (analytical, perturbation technique and finite element solution). The through-thickness variation of the volume fraction of the ceramic phase in a Metal-Ceramic beam is assumed to be given by a power-law type function. The non-linear strain-displacement relations in the von-Kármán sense are used to study the effect of geometric non-linearity. Also, four other representative averaging estimation methods, the linear rule, Mori-Tanaka, Self-Consistent and Wakashima-Tsukamoto schemes, by comparing with the power-law type function are also investigated. Temperature distribution through the thickness of the beams in thermal loadings is obtained by solving the one-dimensional heat transfer equation. Finally it is concluded that for Metal-Ceramic composites, these two theories result in identical static responses. Also the displacement field and equilibrium equations in the case of cylindrical bending of Metal-Ceramic plates are the same as those supposed in FSDBT2.

关键词： thermomechanical loading functionally graded beams monlinear analysis analytical solution

Effect of the spectral shape of ground motion records on the collapse fragility assessment of degrading SDOF systems

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Earthquake Engineering and Engineering Vibration 2021年第4期20卷 925-941页

作者： amin Norouzi Mehdi Poursha Department of Civil Engineering Sahand University of TechnologyTabriz 51335-1996Iran Earthquake Engineering Research Center Sahand University of TechnologyTabriz 51335-1996Iran

The main purpose of this paper is to study the collapse capacity of single degree of freedom(SDOF)systems and to produce fragility curves as well as collapse capacity spectra while considering a broad range of structural parameters,including system degradation,the P-Δeffect,ductility capacity and the post-capping stiffness *** modified Ibarra-Krawinkler deterioration model was used to consider hysteretic behavior.A comprehensive study was conducted to extract the collapse capacity spectrum of SDOF systems with a wide range of periods,varying from 0.05 to 4 s,to cover short,intermediate and long *** dynamic analysis(IDA)was performed for SDOF systems to identify the condition in which the collapse capacity of the system is *** IDAs were performed using different sets of seismic ground *** ground motion records were categorized into different sets based on three spectral shape parameters,including the epsilon,SaRatio and N_(p).The collapse fragility curves of SDOF systems with different periods were extracted to illustrate the collapse capacity at different probability *** results show that structural degradation and ductility as well as the spectral shape parameters significantly affect the collapse capacity of SDOF *** the other hand,the post-capping stiffness ratio and small levels of the P-Δeffect do not remarkably change collapse ***,the collapse capacity of SDOF systems is more sensitive to the records categorized based on SaRatio and N_(p)than those classified based on epsilon.

关键词： collapse capacity fragility analysis degrading SDOF system IDA curve Epsilon,N_(p) SaRatio P-Δeffect

Crack detection of the cantilever beam using new triple hybrid algorithms based on Particle Swarm Optimization

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Frontiers of Structural and Civil Engineering 2022年第9期16卷 1127-1140页

作者： amin GHANNADIASL Saeedeh GHAEMIFARD Department of Civil Engineering University of Mohaghegh ArdabiliArdabil 56199-11367Iran

The presence of cracks in a concrete structure reduces its performance and increases in the size of cracks result in the failure of the ***,the accurate determination of crack characteristics,such as location and depth,is one of the key engineering issues for assessment of the reliability of *** paper deals with the inverse analysis of the crack detection problems using triple hybrid algorithms based on Particle Swarm Optimization(PSO);these hybrids are Particle Swarm Optimization-Genetic Algorithm-Firefly Algorithm(PSO-GA-FA),Particle Swarm Optimization-Grey Wolf Optimization-Firefly Algorithm(PSO-GWO-FA),and Particle Swarm Optimization-Genetic Algorithm-Grey Wolf Optimization(PSO-GA-GWO).A strong correlation exists between the changes in the natural frequency of a concrete beam and the crack ***,the location and depth of a crack in a beam can be predicted by measuring its natural ***,the measured natural frequency can be used as the input parameter of the *** this paper,this is applied to identify crack location and depth in a cantilever beam using the new hybrid *** results show that among the proposed triple hybrid algorithms,the PSO-GA-FA and PSO-GWO-FA algorithms are much more effective than PSO-GA-GWO algorithm for the crack detection.

关键词： crack cantilever beam triple hybrid algorithms Particle Swarm Optimization