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The Synthesis of Diaminoanthraquinone Coloured Cross Linked Epoxy Resins and Their Application in Paint and Selected Polymers

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Open Journal of Applied Sciences 2014年第1期4卷 13-21页

作者： zwahruddeen muhammad salisu Mohammed Kabir Yakubu Peter Obinna Nkeonye Hamza Abba Department of Chemistry Ahmad Bello University Zaria Nigeria Department of Textile Science and Technology Ahmadu Bello University Zaria Nigeria National Research Institute for Chemical Technology (NARICT) Zaria Nigeria

Novel polymeric pigments were synthesized in xylene by cross linked epoxy resin with 1,4 and 1,5-diaminoanthraquinones, by varying weight fractions from 5% to 20% of the diaminoanthraquinone derivatives. FTIR, UV and solubility tests were carried out. The pigments were then used to colour PLA, PMMA, PE and also in emulsion paints using polyvinyl alcohol as binder. Their light fastness, surface drying time and surface hardening time were assessed. It was found that λmax of the 1,4-diaminoanthraquinone shifted towards longer wavelength after the cross linkage, in contrast to the 1,5-diaminoanthraquinone which suffered a blue shift. However in all the cases, the λmax was not affected by the weight fractions of the anthraquinones, but the absorptivity coefficients was significantly increased as the weight fractions of the anthraquinones increased. The light fastness properties of the coloured plastics varied from 4 to 7, indicating a trend of increase with the weight fractions of the anthraquinones. Similar observations were seen with the emulsion paints produced. In all the cases, the 1,4-diaminoanthraqunione produced better result.

关键词： Epoxy Resin Diaminoanthraquinone Derivatives Chromophore Pigments

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Optimisation of Crude Oil Adsorbent Developed from a Modified Styrene Kenaf Shive

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Journal of Materials Science and Chemical Engineering 2019年第2期7卷 38-51页

作者： zwahruddeen muhammad salisu Ishiaku S. Umaru Danladi Abdullahi Mohammed Kabir Yakubu Diya’uddeen Bashir Hasan National Research Institute for Chemical Technology (NARICT) Zaria Nigeria Department of Polymer and Textile Engineering Ahmadu Bello University (ABU) Zaria Nigeria Center for Energy Research and Training (CERT) Ahmadu Bello University (ABU) Zaria Nigeria

A new kind of hydrophobic crude oil sorbent was successfully developed by grafting kenaf shive with styrene monomer. In this paper, crude oil sorbents were developed through regeneration method by varying the initiator concentration, monomer ratio and particle sizes in the range of 0.5 - 2.5 wt%, 0.5 - 2.0 wt % and 125 - 1000 μm respectively. This research approach for the development of crude oil sorbent from graft modified kenaf shive/core and the aforementioned variable optimization has not been reported. The effect studies of the individual and combine factors were carried out using a statistical experimental design matrix using five-level central composite design (CCD). Respond surface methodology (RSM) was used to optimise and develop equations of the aforementioned variables (initiator concentration, monomer ratio and particle sizes). The optimal swelling capacity of 616% and 267% lower retention were achieved at initiator concentration, monomer ratio and particle size of 12.5 wt%, 1.50 wt% and 562 μm respectively. TGA-DTA, XRD and BET analysis were carried out on optimised sample and, FTIR was carried on both unmodified (UG) and optimized sorbent. Further computations were done for grafting efficiency (GE), homopolymers and density. The findings display the effect of the three variables and navigation equations were generated for further investigations on them. However, the results show the feasibility and robustness of facile oil sorption.

关键词： Sorbent Initiator Crude Oil Kenaf Shive Respond Surface Methodology (RSM)

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