检索结果-南通市图书馆

Effect of solvent on the initiation mechanism of living anionic polymerization of styrene:A computational study

在线全文

学校读者我要写书评

暂无评论

Chinese Journal of Chemical Engineering 2024年第5期69卷 135-142页

作者： Shen Li Yin-ning zhou Zhong-Xin Liu Zheng-Hong Luo School of Chemical Engineering and Technology Hainan UniversityHaikou 570228China Department of Chemical Engineering School of Chemistry and Chemical EngineeringState Key Laboratory of Metal Matrix CompositesShanghai Jiao Tong UniversityShanghai 200240China

For living anionic polymerization(LAP),solvent has a great influence on both reaction mechanism and *** this work,by using the classical butyl lithium-styrene polymerization as a model system,the effect of solvent on the mechanism and kinetics of LAP was revealed through a strategy combining density functional theory(DFT)calculations and kinetic *** terms of mechanism,it is found that the stronger the solvent polarity,the more electrons transfer from initiator to solvent through detailed energy decomposition analysis of electrostatic interactions between initiator and solvent ***,we also found that the stronger the solvent polarity,the higher the monomer initiation energy barrier and the smaller the initiation rate ***,initiation is more favorable at lower temperatures based on the calculated results ofΔG_(TS).Finally,the kinetic characteristics in different solvents were further examined by kinetic *** is found that in benzene and n-pentane,the polymerization rate exhibits first-order ***,slow initiation and fast propagation were observed in tetrahydrofuran(THF)due to the slow free ion formation rate,leading to a deviation from first-order kinetics.

关键词： Living anionic polymerization Solvent effect Reaction kinetics Computational chemistry Mathematical modeling Kinetic modeling

Gut microbiome and serum metabolome analyses identify Bacteroides fragilis as regulators of serotonin content and PRL secretion in broody geese

在线全文

学校读者我要写书评

暂无评论

Journal of Integrative Agriculture 2024年第6期23卷 2033-2051页

作者： Yu Zhang ning zhou Jia Wu Lina Song Qiang Bao Kaiqi Weng Yang Zhang Wanwipa Vongsangnak Guohong Chen Qi Xu College of Animal Science and Technology Yangzhou UniversityYangzhou 225009China Joint International Research Laboratory of Agriculture&Agri-Product Safety of Ministry of Education Yangzhou UniversityYangzhou 225009China Department of Zoology Faculty of ScienceKasetsart UniversityBangkok 10900Thailand

Broody behavior is regulated by hypothalamic prolactin secretion,which seriously affects egg production in poulty *** studies have provided evidence that animal behavior is governed by dynamic bidirectional communication between specific gut bacteria and their host via the brain-gut-microbiome ***,little research focused on how the gut microbiota influence broody behavior in *** this study,Zhedong white geese in laying and brooding phases were *** differentially abundant bacteria in cecum were detected between brooding and laying geese through metagenomic analyses and 16S rRNA sequencing(P<0.05),and Bacteroides fragilis was specifically identified as a key driver species in the brooding ***,the serum metabolites were quantified,and the 313 differentially abundant metabolites were found between the two groups of different physiological *** were primarily enriched in the tryptophan metabolism *** correlation analyses revealed there was a significant positive correlation between *** abundance and the context of 11 tryptophan metabolism-related metabolites(such as serotonin,etc.)in broody geese,which hinted that those tryptophan metabolites might be produced or driven by ***,the serum hormone levels were also *** found there was a positive correlation between *** abundance and content of ***,prolactin secreted by the pituitary gland was greater in brooding geese than that in laying geese,which was also highly correlated with *** *** result implied that *** could promote the secretion of prolactin by the pituitary ***,the current study findings provided the information on gut microbiota influencing broody behavior,*** produced or driven more serum serotonin,and stimulated the pituitary gland to secret more prolactin,which potentially offered a new enlightenment for the intervention of broody behavior in pou

关键词： geese broody behavior gut microbiota serotonin prolactin

Reversible Mn^(2+)/Mn^(4+)double-electron redox in P3-type layer-structured sodium-ion cathode

在线全文

学校读者我要写书评

暂无评论

Journal of Energy Chemistry 2024年第2期89卷 79-88,I0004页

作者： Jie Zeng Jian Bao Ya Zhang Xun-Lu Li Cui Ma Rui-Jie Luo Chong-Yu Du Xuan Xu Zhe Mei Zhe Qian Yong-ning zhou Department of Materials Science Fudan UniversityShanghai 200433China Shanghai Xuanyi New Energy Development Co. LtdShanghai 201800China Global Institute of Future Technology Shanghai Jiao Tong UniversityShanghai 200240China

The balance between cationic redox and oxygen redox in layer-structured cathode materials is an important issue for sodium batteries to obtain high energy density and considerable cycle *** redox can contribute extra capacity to increase energy density,but results in lattice instability and capacity fading caused by lattice oxygen gliding and oxygen *** this work,reversible Mn^(2+)/Mn^(4+)redox is realized in a P3-Na_(0.65)Li_(0.2)Co_(0.05)Mn_(0.75)O_(2)cathode material with high specific capacity and structure stability via Co *** contribution of oxygen redox is suppressed significantly by reversible Mn^(2+)/Mn^(4+)redox without sacrificing capacity,thus reducing lattice oxygen release and improving the structure *** X-ray techniques reveal that P3 phase is well maintained in a wide voltage window of 1.5-4.5 V ***^(+)/Na even at 10 C and after long-term *** is disclosed that charge compensation from Co/Mn-ions contributes to the voltage region below 4.2 V and O-ions contribute to the whole voltage *** synergistic contributions of Mn^(2+)/Mn^(4+),Co^(2+)/Co^(3+),and O^(2-)/(O_n)^(2-)redox in P3-Na_(0.65)Li_(0.2)Co_(0.05)Mn_(0.75)O_(2)lead to a high reversible capacity of 215.0 m A h g^(-1)at 0.1 C with considerable cycle *** strategy opens up new opportunities for the design of high capacity cathode materials for rechargeable batteries.

关键词： Sodium batteries Cathode materials Layered structure Co substitution

Dual-symmetry-perturbed all-dielectric resonant metasurfaces for high-Q perfect light absorption

在线全文

学校读者我要写书评

暂无评论

Chinese Optics Letters 2024年第2期22卷 200-206页

作者：葛俊洋高一骁徐雷周宁沈祥 Laboratory of Infrared Materials and Devices Research Institute of Advanced TechnologiesNingbo UniversityNingbo 315211China Key Laboratory of Photoelectric Detection Materials and Devices of Zhejiang Province Ningbo 315211China Advanced Optics&Photonics Laboratory Department of EngineeringSchool of Science and TechnologyNottingham Trent UniversityNottingham NG118NSUK School of Physics and Optoelectronic Engineering Hangzhou Institute for Advanced StudyUniversity of Chinese Academy of SciencesHangzhou 310024China ningbo Institute of Oceanography Ningbo 315832China

We demonstrate a high-Q perfect light absorber based on all-dielectric doubly-resonant *** bound states in the continuum(BICs)protected by different symmetries,we manage to independently manipulate the Q factors of the two degenerate quasi-BICs through dual-symmetry perturbations,achieving precise matching of the radiative and nonradiative Q factors for degenerate critical *** achieve a narrowband light absorption with a>600 Q factor and a>99%absorptance atλ_(0)=1550 nm on an asymmetric germanium metasurface with a 0.2λ_(0)*** work provides a new strategy for engineering multiresonant metasurfaces for narrowband light absorption and nonlinear applications.

关键词： resonant metasurface perfect light absorption bound states in the continuum

在线全文

学校读者我要写书评

暂无评论

神经网络增强的成对双线性因子分解机

计算机工程与科学 2024年第9期46卷 1648-1659页

作者：周祺周宁宁南京邮电大学计算机学院江苏南京210023

基于神经网络增强的因子分解机模型因可以捕捉更多高阶特征的交互,使预测结果愈加精准而成为了当前推荐算法的研究热点。针对现有模型在对用户与物品交互特征进行建模时,并没有综合考虑高阶交互特征和原始低阶特征的问题,同时为了提高... 详细信息

基于神经网络增强的因子分解机模型因可以捕捉更多高阶特征的交互,使预测结果愈加精准而成为了当前推荐算法的研究热点。针对现有模型在对用户与物品交互特征进行建模时,并没有综合考虑高阶交互特征和原始低阶特征的问题,同时为了提高模型对用户偏好的建模能力,采用深度神经网络,并且结合成对学习提出了新的深度神经网络增强的成对双线性因子分解机模型DeepPRBFM。该模型采用一对分别包含正样本和负样本输入的双线性结构,利用多层ResNet保留低阶特征,利用DNN增强高阶特征的交互,并采用了基于Pairwise Ranking的损失函数。此外,双线性结构中,通过增加负样本的比例,不仅能大大减缓推荐系统的冷启动问题,而且还能提升模型的预测效果。在2个真实数据集上的实验结果表明,所提出的模型获得了更高的推荐准确率,在HR和NDCG等客观指标上都优于其他对比模型。

关键词：隐式反馈成对学习因子分解机神经网络冷启动

维普期刊数据库博看期刊

Quantifying the Temperature Effects on the Morbidity of Digestive Diseases In an Inland Plateau-Valley City

在线全文

学校读者我要写书评

暂无评论

Biomedical and Environmental Sciences 2024年第9期37卷 1101-1105页

作者： Pan Ma Yang Yang ning zhou Xinzi Wang Yulu Wang Wenjuan Feng Zhaoqin Bai Shigong Wang Plateau Atmosphere and Environment Key Laboratory of Sichuan Province College of Atmospheric ScienceChengdu University of Information TechnologyChengdu 610225SichuanChina Chengdu Plain Urban Meteorology and Environment Observation and Research Station of Sichuan Province Chengdu 610225SichuanChina The Infectious Disease Department The First People’s Hospital of LanzhouLanzhou 730050GansuChina Meteorological Bureau of Jinnan District Tianjin 300350China Gansu University of Chinese Medicine Lanzhou 730000GansuChina

Extreme air temperature and increased weather oscillations caused by climate change have been threatening global *** conditions are external inducers that may trigger the onset of gastrointestinal diseases,in addition... 详细信息

关键词： Plateau weather consumption

Wearable and interactive multicolored photochromic fiber display

在线全文

学校读者我要写书评

暂无评论

Light(Science & Applications) 2024年第3期13卷 454-465页

作者： Pan Li Yuwei Wang Xiaoxian He Yuyang Cui Jingyu Ouyang Ju Ouyang Zicheng He Jiayu Hu Xiaojuan Liu Hang Wei Yu Wang Xiaoling Lu Qian Ji Xinyuan Cai Li Liu Chong Hou ning zhou Shaowu Pan Xiangru Wang Huamin zhou Cheng-Wei Qiu Yan-Qing Lu Guangming Tao State Key Laboratory of Material Processing and Die&Mould Technology School of Materials Science and Engineering and Wuhan National Laboratory for OptoelectronicsHuazhong University of Science and TechnologyWuhan 430074China Key Laboratory of Vascular Aging(HUST) Ministry of EducationWuhan 430030China School of Optoelectronic Science and Engineering University of Electronic Science and Technology of ChinaChengdu 611731China Department of Electrical and Computer Engineering National University of SingaporeSingapore 117583Singapore National Laboratory of Solid State Microstructures Key Laboratory of Intelligent Optical Sensing and ManipulationCollege of Engineering and Applied Sciencesand Collaborative Innovation Center of Advanced MicrostructuresNanjing UniversityNanjing 210023China School of Performing Arts Wuhan Conservatory of MusicWuhan 430060China School of Mechanical Science and Engineering Huazhong University of Science and TechnologyWuhan 430074China School of Architecture and Urban Planning Huazhong University of Science and TechnologyWuhan 430074China School of Fashion Beijing Institute of Fashion TechnologyBeijing 100029China School of Optical and Electronic Information Huazhong University of Science and TechnologyWuhan 430074China Tongji Medical College Huazhong University of Science and TechnologyWuhan 430074China State Key Laboratory for Modification of Chemical Fibers and Polymer Materials College of Materials Science and EngineeringDonghua UniversityShanghai 201620China

Endowing flexible and adaptable fiber devices with light-emitting capabilities has the potential to revolutionize the current design philosophy of intelligent,wearable interactive ***,significant challenges remain in developing fiber devices when it comes to achieving uniform and customizable light effects while utilizing lightweight ***,we introduce a mass-produced,wearable,and interactive photochromic fiber that provides uniform multicolored light *** designed independent waveguides inside the fiber to maintain total internal reflection of light as it traverses the *** impact of excessive light leakage on the overall illuminance can be reduced by utilizing the saturable absorption effect of fluorescent materials to ensure light emission uniformity along the transmission *** addition,we coupled various fluorescent composite materials inside the fiber to achieve artificially controllable spectral radiation of multiple color systems in a single *** prepared fibers on mass-produced kilometer-long using the thermal drawing *** fibers can be directly integrated into daily wearable devices or clothing in various patterns and combined with other signal input components to control and display patterns as *** work provides a new perspective and inspiration to the existing field of fiber display interaction,paving the way for future human–machine integration.

关键词： fiber interactive colored

Concise Synthesis of Lactococcus garvieae Lipoteichoic Acids Through an Additive-Modulated Preactivation Protocol and the Immunological Studies

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

CCS Chemistry 2024年第2期6卷 403-414页

作者： Tianlu Li Tong Li Yue Yang Haoru Zhuang Jianwu Lv ning zhou Miaomiao Zhang Fengshan Wang Yiqun Geng Richard R.Schmidt Peng Peng National Glycoengineering Research Center Shandong Key Laboratory of Carbohydrate Chemistry and GlycobiologyNMPA Key Laboratory for Quality Research and Evaluation of Carbohydrate Based MedicineShandong UniversityQingdao 266237 State Key Laboratory of Bioactive Substance and Function of Natural Medicines Institute of Materia MedicaChinese Academy of Medical Sciences and Peking Union Medical CollegeBeijing 100050 Department of Chemistry University of KonstanzD-78457 Konstanz

Lipoteichoic acids(LTAs)are macroamphiphiles composed of alditol,lipid,phosphate,and carbohydrate *** to their inherent complexity,it is a severe challenge to access LTAs with structural integrity from natural sources for biological or immunological ***,we describe the first total synthesis of Lactococcus garvieae LTA(type II LTA),containing five distinct 1,2-cis gluco/galactopyranosidic linkages,via a novel additive-modulated O-glycosyl trichloroacetimidate preactivation glycosidation *** strategy features(1)high glycosidation yields and excellent 1,2-cis stereoselectivities independent of the donor anomeric configuration,(2)common and inexpensive reagents as promoters and additives,(3)application to standard glycosyl imidate donors without resorting to participating protection,and(4)general application to reactive and less reactive glycosyl ***,via the precise stereocontrolled construction of three galactopyranosidic and two glucopyranosidic bonds on a multigram scale,a series of structurally well-defined LTA molecules were successfully *** evaluation of these type II synthetic LTAs showed a structure–activity relationship in the stimulation of a proinflammatory response.

关键词： 1,2-cis glycosidation stereoselectivity lipoteichoic acid total synthesis additive-modulated trichloroacetimidate glycosidation immune response

Sora文生影像模式下中国风格产品系统参数化建构策略研究

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

新疆师范大学学报（哲学社会科学版） 2024年第6期45卷 138-144页

作者：周敏宁江南大学设计学院江南大学中国轻工业工业设计重点实验室江苏无锡214122

Sora文生影像模式的出现,标志着人工智能正式进入千亿级参数量的大数据、大模型时代。AI智能既初步具备了机器知觉能够“识万物”,又能通过输入文字、参数使“万物生”。伴随新质生产力的壮大,中国应深刻理解科技不仅是生产力,而且是意... 详细信息

Sora文生影像模式的出现,标志着人工智能正式进入千亿级参数量的大数据、大模型时代。AI智能既初步具备了机器知觉能够“识万物”,又能通过输入文字、参数使“万物生”。伴随新质生产力的壮大,中国应深刻理解科技不仅是生产力,而且是意识形态,应努力建构符合中国美学风格、满足中国用户需求的智能化系统;推动中国语境下的科学与人文相结合,形成能够在未来国际虚拟社区传播、具有中国风格的自创生AI体系,全面推进新时代中国智造与世界智能新业态的紧密融合。

关键词： Sora 文生影像中国风格人工智能自创生隐私让渡