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Well-dispersed Sb particles embedded on N-doped carbon nanofibers toward high-performance li-ion battery

Rare Metals 2024年第7期43卷 2994-3006页

作者： ying li yi-Han Zhao Lu-Lu Zhao Peng-Fei Wang ying Xie Ting-Feng yi School of Materials Science and Engineering Northeastern UniversityShenyang 110819China Key Laboratory of Dielectric and Electrolyte Functional Material Hebei Province School of Resources and MaterialsNortheastern University at QinhuangdaoQinhuangdao 066004China Key Laboratory of Functional Inorganic Material Chemistry Ministry of EducationSchool of Chemistry and Materials ScienceHeilongjiang UniversityHarbin 150080China

The alloy-type material Sb is widely used in the anode materials of lithium-ion batteries(liBs)due to its high theoretical specific ***,its serious volume expansion problem during alloying/dealloying of li~+limits its practical *** this work,C-Sb composite was constructed as anode material of liBs by electrospinning route for the first time,Sb was introduced into the polyacrylonitrile-based hard carbon and coal tar pitch-based soft carbon composite amorphous carbon fiber with a diameter of 300-600 nm,which realized high cycling *** C-Sb-2(the mass ratio of polyacrylonitrile to Sb source is 1:2)electrode displayed charge capacities of 1098.5,930.3,841.7,753.5,643.9 and 545.8 mAh·g^(-1)at 0.1,0.2,0.3,0.5,1 and 2 A·g^(-1),*** when the current density returned to 0.1 A·g^(-1),the charge capacity was 939.3 mAh·g^(-1),revealing good stability and *** introduction of Sb into the amorphous carbon improved its conductivity and addressed the volume expansion issue of high specific capacity Sb during charge/***-situ XRD analysis confirmed the high reversibility of the C-Sb-2 during charging and *** functional theory(DFT)calculations revealed the gradual enhancement of the interface interaction between Sb_(x)li_(y) and amorphous carbon(AMC)with increasing lithium content,contributing to the anchoring of alloy nanoparticles on the AMC surface and buffering the volume change of the ***,the gradual lithiation of Sb facilitated the electron transfer from Sb_(x)li_(y) to *** findings hold promise for designing lithium storage materials with exceptional performance,highlighting the potential of C-Sb composites as anode materials for efficient next-generation lithium storage.

关键词： li-ion battery Metallic Sb Carbon Electrospinning Cycling stability

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Lead-free(Ba,Sr)TiO_(3)-based ceramics with superior tunable properties by the semi-solution method

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Journal of Advanced Ceramics 2024年第6期13卷 746-756页

作者： yi Zhao Wenfeng liu Dongsheng Ran yihang Jin Zhiyuan li Chengzhi zhong Fanyi Kong Shengtao li State Key Laboratory of Electrical Insulation and Power Equipment Xi’an Jiaotong UniversityXi’an 710049China Jiaxing Electric Power Company State Grid Zhejiang Electric Power Co. Ltd.Jiaxing 314000China

High-performance dielectric tunable materials with both high dielectric tunability and low dielectric loss are urgently needed for new-generation electronic tunable *** the present study,a new system,(Ba_(0.675)Sr_(0.325))_(1−x)La_(x)Ti_(1−x)MnxO_(3)(x=0.25%,0.5%,0.75%,and 1.0%),was *** acceptor dopant Mn was added to lower dielectric loss,while the donor dopant La was introduced to enhance dielectric *** samples were prepared using the conventional solid-state(CS)reaction method and the semi-solution(SS)*** experimental results showed that the morphology of the ceramics was optimized by further improving the processing *** microstructures,homogeneous grains,and uniform dopant distributions could be achieved successfully by the semi-solution ***,a significant enhancement in the tunable properties was realized owing to the improved microstructure mentioned *** optimum tunable properties occurred in the samples prepared by the semi-solution method at x=0.75%,with a high dielectric tunability of 85.0%,a low dielectric loss of 0.0011,and an excellent figure of merit(FOM)of *** tunable properties of(Ba,Sr)TiO_(3)(BST)ceramics were even superior to those of lead-based materials,with an FOM of approximately *** the results suggested that the semi-solution method rendered BST ceramics more promising for applications in tunable devices.

关键词： microstructure tunable properties (Ba,Sr)TiO_(3)(BST)ceramics semi-solution(SS)method

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Efficacy of exercise rehabilitation for managing patients with Alzheimer's disease

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Neural Regeneration Research 2024年第10期19卷 2175-2188页

作者： Dan li Jinning Jia Haibo Zeng Xiaoyan zhong Hui Chen Chenju yi Department of Pathology The First Affiliated Hospital of Gannan Medical UniversityGanzhouJiangxi ProvinceChina Department of Pathology Huichang County People’s HospitalGanzhouJiangxi ProvinceChina School of life Sciences Faculty of ScienceUniversity of Technology SydneyUltimoNSWAustralia Research Center The Seventh Affiliated Hospital of Sun Yat-sen UniversityShenzhenGuangdong ProvinceChina Shenzhen Key Laboratory of Chinese Medicine Active Substance Screening and Translational Research ShenzhenGuangdong ProvinceChina Guangdong Provincial Key Laboratory of Brain Function and Disease GuangzhouGuangdong ProvinceChina

Alzheimer's disease(AD) is a progressive and degenerative neurological disease characterized by the deterioration of cognitive functions. While a definitive cure and optimal medication to impede disease progression are currently unavailable, a plethora of studies have highlighted the potential advantages of exercise rehabilitation for managing this condition. Those studies show that exercise rehabilitation can enhance cognitive function and improve the quality of life for individuals affected by AD. Therefore, exercise rehabilitation has been regarded as one of the most important strategies for managing patients with AD. Herein, we provide a comprehensive analysis of the currently available findings on exercise rehabilitation in patients with AD, with a focus on the exercise types which have shown efficacy when implemented alone or combined with other treatment methods, as well as the potential mechanisms underlying these positive effects. Specifically, we explain how exercise may improve the brain microenvironment and neuronal plasticity. In conclusion, exercise is a cost-effective intervention to enhance cognitive performance and improve quality of life in patients with mild to moderate cognitive dysfunction. Therefore, it can potentially become both a physical activity and a tailored intervention. This review may aid the development of more effective and individualized treatment strategies to address the challenges imposed by this debilitating disease, especially in low-and middle-income countries.

关键词： Alzheimer's disease cerebrovascular function cognitive function epigenetic regulation exercise hippocampal neurogenesis mitochondria neuroinflammation neuronal plasticity

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Effect of Hyperconjugation on Photovoltaic Performance in Pseduo-2D Perylene Diimide Derivatives

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Chinese Journal of Chemistry 2024年第7期42卷 725-730页

作者： Zhilong He Yuwen Hong Guangyu li Tong Shan yi Zhang Hongliang zhong Schoolof Chemistry and Chemical Engineering Shanghai Key Lab of Electrical Insulation and Thermal AgingShanghai Jiao Tong UniversityShanghai200230China Shanghai Institute of Organic Chemistry Chinese Academy of SciencesShanghai 200032China Shenzhen Research Institute Shanghai Jiao Tong UniversityShenzhenGuangdong 518057China

Theπ-πinteraction is acknowledged as the predominant factor to determine the molecular packing in organic photovoltaic materials,while other non-covalent intermolecular interactions especially theσ-πhyperconjugation are often ***,a perylene diimide(PDI)derivative named FIDT-PDI is designed and synthesized to shed light into the effect of hyperconjugation on the molecular packing and further the photovoltaic *** NMR and 2D NOE NMR demonstrate the formation of intermolecularσ-πhyperconjugation between the C—H bond of the PDI moiety in one molecule and the phenyl sidechain in another molecule of *** from theσ-πhyperconjugation,FIDT-PDI with twisted backbone reversely exhibits more ordered packing and stronger crystallinity compared with another PDI derivative FIDTT-PDI which has better planarity,consequently achieving superior PCE and higher carrier *** contribution is the first paradigm to unravel the structure-property relationship betweenσ-πhyper-conjugation of conjugated materials and corresponding photovoltaic performance.

关键词： Hyperconjugation Weak intermolecular interactions Conformation Organic solar cells Nonfullerene acceptor Perylene diimide

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Structural Evolution of Ultra-High Molecular Weight Polyethylene Low-Entangled Films with Reserved Shish Crystals During Hot Stretching

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Chinese Journal of Polymer Science 2024年第8期42卷 1227-1242页

作者： Jia-Wei Gao li Chen Ye-Shun zhong Chao-Wei Xing yi-Guo li Zong-Bao Wang School of Materials Science and Chemical Engineering Ningbo UniversityNingbo 315211China

Shish crystals are crucial to achieving high performance low-dimensional ultra-high molecular weight polyethylene(UHMWPE)***,high stretch and shear flow fields are necessary for the formation of shish *** this study,UHMWPE gel films with reserved shish crystals were prepared by gel molding,the structural evolution and properties of UHMWPE films stretched at temperatu res of 100,110,120and 130℃were investigated by in situ small-angle X-ray scattering(SAXS)/ultra-small-angle X-ray scattering(USAXS)/wide-angle X-ray diffraction(WAXD)measu rements as well as scanning electron microscopy(SEM)and differential scanning calorimetry(DSC)*** findings showed that the reserved shish crystals can facilitate the formation and structural evolution of shish-kebab crystals during the hot ***,the reserved shish crystals promote the structu ral evolution of UHMWPE films to a greater extent when stretched at 120 and 130℃,compared to 100 and 110℃,resulting in higher crystallinity,orientation,thermal properties,breaking strength and Young's *** pared to UHMWPE high-entangled films with reserved shish crystals prepared by compression molding,UHMWPE low-entangled films with reserved shish crystals prepared by gel molding are more effective in inducing the formation and evolution of shish-kebab crystals during the hot stretching,resulting in increased breaking strength and Young's modulus.

关键词： UHMWPE low-entangled films Reserved shish crystals Structural evolution Hot stretching

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C_(Ar)-Br bond cleavage via cooperative EnT/NHC catalysis: mild access to indolines

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Science China Chemistry 2024年第3期67卷 922-927页

作者： yi-Xiong Dong Cao-Bo li Ming-Lei Jin zhong-Hua Gao Song Ye Beijing National Laboratory for Molecular Sciences CAS Key Laboratory of Molecular Recognition and FunctionCAS Research/Education Center for Excellence in Molecular SciencesInstitute of ChemistryChinese Academy of SciencesBeijing 100190China University of Chinese Academy of Sciences Beijing 100049China

The cooperative visible-light mediated and NHC-catalyzed dearomative arylation-acylation of N-(2-bromobenzoyl)indoles with aldehydes was developed, affording the corresponding highly functionalized polycyclic indolines in moderate to good yields with exclusive diastereoselectivities. Mechanism investigations support the activation of CAr-Br bond via visible-light mediated energy transfer(EnT) and the following single-electron-transfer(SET) with Breslow intermediate under NHC catalysis to give key aryl radical and ketyl radical. This protocol demonstrates the cleavage of CAr-Br bond under mild cooperative EnT/NHC catalysis.

关键词： energy transfer N-heterocyclic carbenes photocatalysis aryl radicals indolines

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Geoeffectiveness of the coronal mass ejections associated with solar proton events

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Research in Astronomy and Astrophysics 2016年第1期16卷 117-128页

作者： Gui-Ming Le Chuan li Yu-Hua Tang liu-Guan Ding Zhi-Qiang yin Yu-lin Chen Yang-Ping Lu Min-Hao Chen zhong-yi li Key Laboratory of Space Weather National Center for Space Weather China Meteorological Administration Beijing 100081 China School of Astronomy and Space Science Nanjing University Xianlin Campus Nanjing 210046 China National Astronomical Observatories Chinese Academy of-Sciences Beijing 100012 China School of Mathematics and Statistics Nanjing University of Information Science and Technology Nanjing 210044China

The intensity-time profiles of solar proton events（SPEs） are grouped into three types in the present study. The Type-I means that the intensity-time profile of an SPE has one peak, which occurs shortly after the associated solar flare and coronal mass ejection（CME）. The Type-II means that the SPE profile has two peaks： the first peak occurs shortly after the solar eruption, the second peak occurs at the time when the CME-driven shock reaches the Earth, and the intensity of the second peak is lower than the first *** the intensity of the second peak is higher than the first one, or the SPE intensity increases continuously until the CME-driven shock reaches the Earth, this kind of intensity-time profile is defined as Type-III. It is found that most CMEs associated with Type-I SPEs have no geoeffectiveness and only a small part of CMEs associated with Type-I SPEs can produce minor（–50 n T ≤ Dst ≤–30 n T） or moderate geomagnetic storms（–100 n T≤ Dst ≤–50 n T）, but never an intense geomagnetic storm（–200 n T ≤ Dst 〈-100 n T）. However,most of the CMEs associated with Type-II and Type-III SPEs can produce intense or great geomagnetic storms（Dst ≤-200 n T）. The solar wind structures responsible for the geomagnetic storms associated with SPEs with different intensity-time profiles have also been investigated and discussed.

关键词： Sun: coronal mass ejections (CMEs) -- Sun: particle emission -- Sun: solar-terrestrial rela- tions

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Recent advancements in hydrometallurgical recycling technologies of spent lithium-ion battery cathode materials

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Rare Metals 2024年第3期43卷 879-899页

作者： Juan Wu li Xiao li Shen Jian-Jun Ran Hui zhong yi-Rong Zhu Han Chen College of Materials and Advanced Manufacturing Hunan University of TechnologyZhuzhou412007China School of Resources Processing and Bioengineering Central South UniversityChangsha410083China Guangdong JiaNa Energy Technology Company Qingyuan513000China

The rapidly increasing production of lithium-ion batteries(liBs)and their limited service time increases the number of spent liBs,eventually causing serious environmental issues and resource *** the perspectives of clean production and the development of the liB industry,the effective recovery and recycling of spent liBs require urgent *** study provides an overview of the current hydrometallurgical processes employed in the recycling of spent cathode materials,focusing on the leaching of valuable metals and their *** particular,this research reviews the various leaching systems(inorganic acid,organic acid,and ammonia)and the separation of valuable metals,and then,recommendations for subsequent study are offered in an attempt to contribute to the development of highly efficient methods for recycling spent cathode *** addition,a range of existing technologies,such as solvent extraction,chemical precipitation,electrochemical deposition,and regeneration,for the postprocessing of leaching solutions are ***,the promising technologies,existing challenges and suggestions with respect to the development of effective and environmentally friendly recycling methods for handling spent cathode materials are identified.

关键词： Spent lithium-ion batteries(liBs) Cathode material Hydrometallurgy Leaching Recycling

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Cooperative enhancement of mechanical and tribological properties through tailoring TiN transition interface in boron nitride nanosheets reinforced copper composites

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Rare Metals 2024年第10期43卷 5202-5215页

作者： zhong-Hua li liang liu Xin You Jian-Hong yi Rui Bao Ming-yi Zhu Song Lu Jun-Jun Pai Faculty of Materials Science and Engineering Kunming University of Science and Technology Key Laboratory of Advanced Materials of Yunnan Province Kunming University of Science and Technology

Strengthening interface bonding between boron nitride nanosheets(BNNS) and copper matrix is an essential prerequisite for exploiting a new generation of copper matrix composites(CMCs) with high strength and wear resistance. Herein, BNNS/Cu composites were fabricated by the powder metallurgy route, matrix-alloying(adding 1.0 wt% Ti) strategy was adopted to improve the interfacial wettability and strengthen interface adhesion. A typical "sandwich"-like multiply interface structure involving TiN transition layers, BNNS and Cu matrix had been well constructed through the rational heat treatment(900℃for 120 min). Additionally, nano-sized TiB whisker was in situ formed in the vicinity of the interface, it had linked the BNNS-Cu-TiN multiply interface, which played a role of "threading the needle" and significantly strengthened the multi-interfaces bonding. This specific interface structure was finely characterized, and the formation mechanism of solid-state interfacial reaction feature was proposed. The results demonstrated that the ultimate tensile strength(UTS) of BNNS/Cu-(Ti)-900℃ increased from 248 to 530 MPa(increased by 114%), and the coefficient of friction(COF) decreased from 0.51 to 0.28 than pure Cu. This work highlights the importance of interface configuration design, which contributes to the development of CMCs with prominent comprehensive properties.

关键词： Boron nitride nanosheets Copper matrix composites Interface structure Mechanical and frictional properties

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High-Efficiency Dynamic Scanning Strategy for Powder Bed Fusion by Controlling Temperature Field of the Heat-Affected Zone

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Chinese Journal of Mechanical Engineering 2024年第1期37卷 203-214页

作者： Xiaokang Huang Xiaoyong Tian Qi zhong Shunwen He Cunbao Huo yi Cao Zhiqiang Tong Dichen li State Key Laboratory of Manufacturing Systems Engineering Xi’an Jiaotong UniversityXian 710049China

Improvement of fabrication efficiency and part performance was the main challenge for the large-scale powder bed fusion(PBF)*** this study,a dynamic monitoring and feedback system of powder bed temperature field using an infrared thermal imager has been established and integrated into a four-laser PBF equipment with a working area of 2000 mm×2000 *** heat-affected zone(HAZ)temperature field has been controlled by adjusting the scanning speed ***,the relationship among spot size,HAZ temperature,and part performance has been *** fluctuation of the HAZ temperature in four-laser scanning areas was decreased from 30.85℃to 17.41℃.Thus,the consistency of the sintering performance of the produced large component has been *** on the controllable temperature field,a dynamically adjusting strategy for laser spot size was proposed,by which the fabrication efficiency was improved up to 65.38%.The current research results were of great significance to the further industrial applications of large-scale PBF equipment.

关键词： Powder bed fusion Efficiency Large-scale Spot size Heat-affected zone(HAZ)

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