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Synthesis and Photophysical Properties of Novel Red Light-Emitting Cyclometalated Iridium(Ⅲ) Complexes

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有机化学 2004年第Z1期24卷 285-286页

作者： ZHANG,Xiao-Wei YANG,Chu-Luo LI,zhong-An huang,bing QIN,Jin-Gui Department of Chemistry Wuhan University Wuhan 430072 Department of Chemistry Wuhan University Wuhan 430072 Department of Chemistry Wuhan University Wuhan 430072 Department of Chemistry Wuhan University Wuhan 430072 Department of Chemistry Wuhan University Wuhan 430072

　　Considerable research is currently focused on the organic electrophosphorescent materials due to their high luminescent efficiency. Electrophosphorescent material based on heavy metal complexes is a hot topic in the research of organic light-emitting devices (OLEDs). We synthesized a series of novel cyclometalated heavy metal complexes by introducing pheny-quinoline moieties into ligands by means of a convenient method (Scheme 1), and investigated their photophysical properties which indicated that those compounds exhibited red light-emitting and high luminescent *** complexes have been characterized by 1H NMR, UV-vis and PL.……

关键词： luminescent efficiency metal complexes convenient method hot topic

Graphene oxide-composited chitosan scaffold contributes to functional recovery of injured spinal cord in rats

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Neural Regeneration Research 2021年第9期16卷 1829-1835页

作者： bing Yang Pang-Bo Wang Ning Mu Kang Ma Shi Wang Chuan-Yan Yang zhong-bing huang Ying Lai Hua Feng Guang-Fu Yin Tu-Nan Chen Chen-Shi Hu College of Biomedical Engineering Sichuan UniversityChengduSichuan ProvinceChina Department of Neurosurgery Southwest HospitalThird Military Medical University(Army Medical University)ChongqingChina

The study illustrates that graphene oxide nanosheets can endow materials with continuous electrical conductivity for up to 4 weeks. Conductive nerve scaffolds can bridge a sciatic nerve injury and guide the growth of neurons;however, whether the scaffolds can be used for the repair of spinal cord nerve injuries remains to be explored. In this study, a conductive graphene oxide composited chitosan scaffold was fabricated by genipin crosslinking and lyophilization. The prepared chitosan-graphene oxide scaffold presented a porous structure with an inner diameter of 18–87 μm, and a conductivity that reached 2.83 mS/cm because of good distribution of the graphene oxide nanosheets, which could be degraded by peroxidase. The chitosan-graphene oxide scaffold was transplanted into a T9 total resected rat spinal cord. The results show that the chitosan-graphene oxide scaffold induces nerve cells to grow into the pores between chitosan molecular chains, inducing angiogenesis in regenerated tissue, and promote neuron migration and neural tissue regeneration in the pores of the scaffold, thereby promoting the repair of damaged nerve tissue. The behavioral and electrophysiological results suggest that the chitosan-graphene oxide scaffold could significantly restore the neurological function of rats. Moreover, the functional recovery of rats treated with chitosangraphene oxide scaffold was better than that treated with chitosan scaffold. The results show that graphene oxide could have a positive role in the recovery of neurological function after spinal cord injury by promoting the degradation of the scaffold, adhesion, and migration of nerve cells to the scaffold. This study was approved by the Ethics Committee of Animal Research at the First Affiliated Hospital of Third Military Medical University(Army Medical University)(approval No. AMUWEC20191327) on August 30, 2019.

关键词： angiogenesis chitosan electrical conduction graphene oxide regeneration repair scaffold spinal cord injury

Electrophoretic deposition of Al_(2)O_(3)/ZrO_(2) layer with controllable thickness in ethanol medium

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中国化学前沿:英文版 2011年第2期6卷 76-83页

作者： Chun-mei YANG Xian-chun CHEN Xiaoming LIAO zhong-bing huang Ya-dong YAO Guang-fu YIN College of Materials Science and Engineering Sichuan UniversityChengdu 610064China

ZrO_(2) toughened Al_(2)O_(3)(Al_(2)O_(3)/ZrO_(2))ceramic layers with required thickness were prepared by electrophoretic deposition(EPD)method using ethanol suspensions with stabilizing agent of polyethyleneimine(PEI)under constant-voltage mode in this *** deposition of Al_(2)O_(3)/ZrO_(2) ceramic powders occurred on the titanium alloy cathode.A stable suspension with 1wt% PEI in ethanol at pH 5 was prepared in terms of the zeta potential and sedimentation of the *** effects of the suspension concentration,applied voltage,deposition time and processing method of titanium alloy cathode on the coating thickness and morphology were *** deposition layers on titanium alloys with smooth surfaces and thickness of 0.35–1.2 mm could be obtained by adjusting the aforementioned *** addition,after being sintered at 1500℃ for 3 h in air atmosphere,ZrO_(2) toughened Al_(2)O_(3) ceramic layers became smooth and dense.

关键词： electrophoretic deposition suspension Al_(2)O_(3) ZrO_(2)

A simple photochemical method for surface fluorination using perfluoroketones

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Chinese Chemical Letters 2024年第5期35卷 254-258页

作者： Zhiwei zhong Yanbin huang Wantai Yang Department of Chemical Engineering Tsinghua UniversityBeijing 100084China

Surface fluorination of conventional polymers can give them desirable surface properties similar to the expensive and difficult-to-process ***,traditional surface fluorination techniques often require toxic reagents and special ***,we report a simple and effective polymer surface fluorination method by using safe and inexpensive perfluoro-2-methyl-3-pentanone(PFMP,C_(2)F_(5)C(=O)CF(CF_(3))_(2))and UV *** method is applicable to various polymer materials,and generates nanometer-thick fluorinated layer on the outermost surface,significantly changing their surface properties without changing the surface morphology.

关键词： Surface fluorination Perfluoroketone UV irradiation Photochemistry Surface free energy

Optimal SOC Headroom of Pump Storage Hydropower for Maximizing Joint Revenue from Day-ahead and Real-time Markets Under Regional Transmission Organization Dispatch

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Journal of Modern Power Systems and Clean Energy 2024年第1期12卷 238-250页

作者： Yikui Liu bing huang Yang Lin Yonghong Chen Lei Wu Electrical and Computer Engineering Department Stevens Institute of TechnologyHobokenNJ 07030USA Midcontinent Independent System Operator Inc.CarmelIN 46032USA

In response to the increasing penetration of volatile and uncertain renewable energy,the regional transmission organizations(RTOs)have been recently focusing on enhancing the models of pump storage hydropower(PSH)plants,which are one of the key flexibility assets in the day-ahead(DA)and real-time(RT)markets,to further boost their flexibility provision *** by the recent research works that explored the potential benefits of excluding PSHs’cost-related terms from the objective functions of the DA market clearing model,this paper completes a rolling RT market scheme that is compatible with the DA ***,with the vision that PSHs could be permitted to submit state-of-charge(SOC)headrooms in the DA market and to release them in the RT market,this paper uncovers that PSHs could increase the total revenues from the two markets by optimizing their SOC headrooms,assisted by the proposed tri-level optimal SOC headroom ***,in the proposed tri-level model,the middle and lower levels respectively mimic the DA and RT scheduling processes of PSHs,and the upper level determines the optimal headrooms to be submitted to the RTO for maximizing the total revenue from the two *** case studies quantify the profitability of the optimal SOC headroom submissions as well as the associated financial risks.

关键词： Pump storage hydropower energy market state-of-charge(SOC) headroom market revenue tri-level problem

Revisiting the Mg isotopic systematics of siliciclastic components of sediments and sedimentary rocks:A new geochemical proxy of continental weathering in Earth's history

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Science China Earth Sciences 2024年第2期67卷 620-633页

作者： Tianzheng huang bing SHEN Kangjun huang Meng NING Chao LI Jinzhuang XUE Yuanlin SUN Baoqi huang Key Laboratory of Orogenic Belt and Crustal Evolution MOESchool of Earth and Space SciencesPeking UniversityBeijing100871China State Key Laboratory of Continental Dynamics Shaanxi Key Laboratory of Early Life and EnvironmentsDepartment of GeologyNorthwest UniversityXi’an710069China Institute of Sedimentary Geology Chengdu University of TechnologyChengdu610059China Key Laboratory of Rhenium-Osmium Isotopic Geochemistry Chinese Academy of Geological SciencesBeijing100037China

The Mg isotopic compositions of siliciclastic components(δ^(26)Mg_(sili))of sediments and sedimentary rocks have been commonly used to constrain the intensity of continental weathering,based on observations of,(1)an upward enrichment of26Mg in modern weathering profiles,(2)preferential uptake of26Mg in soil clays,and(3)general positive correlations between weathering intensities andδ^(26)Mg_(sili)***,not all weathering profiles display an upward increase ofδ^(26)Mg_(sili),and not all soil clays enrich in26Mg,complicating the interpretations ofδ^(26)Mg_(sili)data of sediments and sedimentary *** further explore the controls ofδ^(26)Mg_(sili)of sediments and sedimentary rocks,here we measuredδ^(26)Mg_(sili),mineralogical compositions and major element compositions of deep sea sediments from South China Sea(SCS)and carbonate rock samples from two late Paleozoic sections in South *** samples show decreasing trends of both normalized Mg concentration(Mgnorm)andδ^(26)Mg_(sili)values with the increase of weathering intensity,while SCS sediments samples do not show any correlation between Mgnormorδ^(26)Mg_(sili)values and weathering intensity.A three-stages weathering model is developed to explain the observed Mgnorm andδ^(26)Mg_(sili)*** the new model,weathering can be divided into three stages,(1)the preliminary weathering stage characterized by dissolution of primary minerals and formation of secondary clay minerals in saprolite,(2)the transitional stage with massive vermiculite and chlorite formation on the bottom of soil,and(3)the advanced stage showing dissolution of vermiculite and chlorite in the top of *** new model explains anδ^(26)Mg_(sili)increase and Mgnormdecrease with an increase weathering intensity in preliminary weathering stage and decrease of Mgnormandδ^(26)Mg_(sili)with increase weathering intensity in advanced weathering *** revised weathering model warrants the application of Mg isotope in the study of contin

关键词： Clay mineral Chemical weathering CIA Soil Weathering model

Chemical, carbon and sulfur isotopic compositions constrain the origin of Upper Carboniferous-Lower Triassic gases in eastern Sichuan Basin, SW China

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Science China Earth Sciences 2024年第10期67卷 3169-3185页

作者： Chunfang CAI Ilya KUTUZOV Wenhua MEI Daowei WANG bing LUO Shipeng huang bing HE Alon AMRANI China University of Petroleum National Key Lab Petroleum Resource&EngineeringBeijing 102249China State Key Laboratory of Lithospheric and Environmental Coevolution Institute of Geology and GeophysicsChinese Academy of SciencesBeijing 100029China Institute of Earth Sciences The Hebrew UniversityJerusalem 91904Israel College of Earth and Planetary Sciences University of Chinese Academy of SciencesBeijing 100049China Yulin University Yulin 719000China Research Institute of Exploration and Development Southwest Oil&Gas Field CompanyPetroChinaChengdu 610051China PetroChina Research Institute of Petroleum Exploration and DevelopmentBeijing 100083China

Methane dominated gas is one of the cleanest energy resources;however, there is no direct method to determine its source rock. Natural gases produced from the eastern Sichuan Basin together with seismic data were studied for their sources and secondary alteration by thermochemical sulfate reduction(TSR). Our results demonstrate that Upper Permian to Lower Triassic(P_(3)ch-T_(1)f) gases in the surrounding of the Kaijiang-Liangping area show volatile organic sulfur compounds(VOSCs) δ^(34)S values close to those of the associated H_(2)S, and may have been altered by methane-dominated TSR, resulting in positive shift in methane δ^(13)C_(1)values with increasing TSR extents. Other(or group 2) gases produced from the P_(3)ch-T_(1)f reservoirs from the southern area and the Upper Carboniferous to Middle Permian(C_(2)h-P_(2)q) from the eastern Sichuan Basin are not significantly changed by TSR, show similar δ^(34)S values between the kerogens and some VOSCs, and may have been derived from the Lower Silurian and Middle Permian source rocks. This study demonstrates a case for the first time showing the δ^(34)S values of VOSCs can be used as a tool for direct correlation between non-TSR altered gas and source rocks. Methane-dominated gas pools can be found using gas and source rock geochemistry combined with seismic data.

关键词： Sulfur isotopes Volatile organic sulfur compounds Thermochemical sulfate reduction Sichuan Basin Gas-source rock correlation

In situ anchoring in carbon matrix of Bi_(2)O_(2)CO_(3) as a high-performance anode material for Li-ion batteries

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Rare Metals 2024年第8期43卷 3634-3646页

作者： Pu-Qiang He Jun Guo Hui huang zhong-Cheng Guo Faculty of Metallurgy and Energy Engineering Kunming University of Science and TechnologyKunming 650093China Research Center of Metallurgical Electrode Materials Engineering Technology Kunming 650106China Kunming Hendera Science and Technology Co. Ltd.Kunming 650106China

Bismuth-based anode materials have been regarded as promising Li-ion batteries due to their high theoretical ***,their low conductivity and associated volume expansion inhabited their *** this work,Bi_(2)O_(2)CO_(3)@C composites were successfully synthesized by in situ anchoring of flower-like Bi_(2)O_(2)CO_(3) nanosheets on a carbon-based substrate via *** unique composited structure of Bi_2O_(2)-CO_(3)@C leads to a stable specific capacity of 547 mAh·g^(-1)after 100 cycles at a current density of 0.1 A·g^(-1).Notably,it demonstrates excellent rate capability with a specific capacity of 210 mAh·g^(-1)at 5 A·g^(-1).After 550 cycles at a current density of 0.5 A·g^(-1),a high reversible capacity of nearly 400 mAh·g^(-1)was ***,in situ X-ray diffraction measurements clearly demonstrate the conversion between Bi and Li_(3)Bi during alloying/dealloying,confirming the good electrochemical reversibility of the materials for Li *** reaction kinetics of Bi_(2)O_(2)CO_(3)@C were further investigated using galvanostatic intermittent titration ***,Bi_2O_(2)-CO_(3)@C exhibited excellent long-term stability,maintaining its high reversible capacity for over 200 cycles at a current density of 0.5 A·g^(-1)in a full cell configuration using Li_(1.20)Mn_(0.54)Ni_(0.13)Co_(0.13)O_(2) as the cathode *** result further underscores its promising potential for lithium-ion *** work may provide inspiration for the design of alloy-type negative electrode materials for high-performance rechargeable batteries.

关键词： Bi_(2)O_(2)CO_(3) Composite materials Anode materials Full batteries

Superior comprehensive properties of LaFe_(11.8)Si_(1.2)/Ce_(60)Co_(40) magnetocaloric composites

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Journal of Rare Earths 2024年第6期42卷 1073-1086,I0003页

作者： Xichun zhong Yuanxin Li Yucai Wu Jiaohong huang Cuilan Liu Jian Liu zhongwu Liu Minglong zhong Zhenchen zhong R.V.Ramanujan School of Materials Science and Engineering South China University of TechnologyGuangzhou510640China Baotou Research Institute of Rare Earths Baotou014030China Center for Advanced Solidification Technology School of Materials Science and EngineeringShanghai UniversityShanghai200444China Jiangxi KeyLaboratory for Rare Earth Magnetic Materials and Devices&Institute for Rare Earth Magnetic Materials and Devices(IREMMD) Jiangxi University of Science and TechnologyGanzhou341000China School of Materials Science and Engineering Nanyang Technological University639798Singapore Singapore-HUJ Alliance for Research and Enterprise(SHARE) The Smart Grippers for Soft Robotics(SGSR)ProgrammeCampus for Research Excellence and Technological Enterprise(CREATE)138602Singapor

LaFe_(11.8)Si_(1.2)/10 wt%Ce_(60)Co_(40) composites were prepared by spark plasma sintering and subsequent diffusion annealing.A novel core-shell structure is observed with the LaFe11.8Si1.2 particles as the core and the(La,Ce)_(2)(Fe,Co,Si)_(17)(2:17)phase as the *** diffusion annealing time(t_(a))increases,this core-shell structure is replaced by the formation of the(La,Ce)_(1)(Fe,Co,Si)_(13) *** at 1323 K for 12 h results in samples with(-ΔSM)^(max) of 9.30 J/(kg·K)(Δμ0H=2 T),good mechanical properties((σbc)^(max)=402 MPa,ε=4.21%)and thermal conductivity of 8.7 W/(m·K).Thus,bulk composites with excellent comprehensive properties for magnetic refrigeration are obtained in this work.

关键词： LaFe_(11.8)Si_(1.2)/Ce_(60)Co_(40)composites Spark plasma sintering Diffusion annealing Microstructure evolution Magnetocaloric effect Rareearths