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Persistent radical anion of perylene dianhydride:an emerging metal-free photocatalyst for near-infrared photocontrolled RAFT polymerization

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Science China Chemistry 2024年第2期67卷 677-686页

作者： Haitao Zhao Guoqing Bian Xiang Xu Weiwei He Lifen Zhang zhenping cheng State and Local Joint Engineering Laboratory for Novel Functional Polymeric Materials Jiangsu Key Laboratory of Advanced Functional Polymer Design and ApplicationSuzhou Key Laboratory of Macromolecular Design and Precision SynthesisCollege of ChemistryChemical Engineering and Materials ScienceSoochow UniversitySuzhou215123China

Developing a new type of photocatalyst(PC) and catalytic mechanism for near-infrared(NIR) photocontrolled reversibledeactivation radical polymerization(RDRP) system is charming but ***,a novel PC of the persistent radical anion(PRA)(possessing the properties of both radical and anion) was developed for NIR photocontrolled reversible additionfragmentation chain transfer(RAFT) polymerization,enabling successful polymerization while gaining a deep insight into the mechanism of photo-induced electron transfer RAFT(PET-RAFT) *** from the conventional and wellaccepted reductive quenching(RQ) pathway,in which the radical anion intermediates of PCs(PCs^(·-)) must be generated in an excited state(ES),here,the PRA(3,4,9,10-perylenetetracarboxylic dianhydride radical anion(PTCDA^(·-))) could generate conveniently in situ in the ground state(GS) and subsequently serve as highly efficient PC in the NIR region(740–850 nm).The successful implementation of this strategy elucidates the peculiar role played by light and the real way of electron transfer *** fact,the transfer of a single electron from PRA to chain transfer agent(CTA) and cleavage of the C–S bonds is a process from ES to GS,rather than always from GS(PCs^(·-)) to GS(CTA) in the RQ pathway as is well known to *** addition,the excellent spatial-temporal control and powerful penetration ability of the NIR light were also confirmed by this PRAcatalyzed polymerization system.

关键词： photocatalyst persistent radical anion(PRA) near-infrared(NIR)light reversible-deactivation radical polymerization(RDRP) photo-induced electron transfer RAFT(PET-RAFT)polymerization

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Recent advances in “living”/controlled radical polymerization of phosphorus-containing monomers and their potential applications

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Science China Chemistry 2015年第11期58卷 1633-1640页

作者： Tianchi Xu Lifen Zhang zhenping cheng Xiulin Zhu Suzhou Key Laboratory of Macromolecular Design and Precision Synthesis Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application Department of Polymer Science and Engineering College of Chemistry Chemical Engineering and Materials ScienceSoochow University

Special research attention has been paid to phosphorus-containing materials and their corresponding applications. This mini review considers recent publications devoted to the "living"/controlled radical(co)polymerization of phosphorus-containing monomers. In addition, different properties of the polymers involved in the phosphonate group in various chemical environments are demonstrated, and their potential applications are briefly discussed.

关键词：可控自由基聚合应用含磷单体生命化学环境出版物聚合物

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A novel reversible-deactivation radical polymerization strategy via near-infrared light-controlled photothermal conversion dividing wall-type heat exchanger

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Science China Chemistry 2021年第7期64卷 1242-1250页

作者： Qun Gao Kai Tu Haihui Li Lifen Zhang zhenping cheng State and Local Joint Engineering Laboratory for Novel Functional Polymeric Materials Suzhou Key Laboratory of Macromolecular Design and Precision SynthesisCollege of ChemistryChemical Engineering and Materials ScienceSoochow UniversitySuzhou 215123China

As an effective means of utilizing light energy,photothermal conversion has excellent application in the field of ***,a dividing wall-type heat exchanger with the aid of photothermal conversion was designed to conduct polymerization under irradiation with near-infrared(NIR)light by utilizing the ketocyanine-type dye solution as the highly efficient activator(>83.2%photothermal conversion efficiency).Various types of reversible-deactivation radical polymerization(RDRP)methods,including reversible addition-fragmentation chain transfer,atom transfer radical polymerization,and bromine-iodine transformation RDRP,are suitable for this ***-defined polymers with excellent control over molar mass and molar mass dispersity(D<1.28)were thus synthesized within a few hours under NIR(λ_(max)=810 nm,850 nm)irradiation at room ***,in addition to conventional heating methods(such as electrical heating jackets),the designed dividing wall-type heat exchanger via NIR light activation has another unique advantage:it can enhance the polymerization by the synergistic effect of both heating and NIR light irradiation due to the deeper penetration of NIR light.

关键词： near-infrared light photothermal conversion ketocyanine dye reversible-deactivation radical polymerization dividing wall-type heat exchange

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Low-dose immune tolerance induction for severe hemophilia A inhibitor patients: Immunosuppressants are generally not necessary for inhibitor-titer below 200 BU/mL

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儿科学研究(英文) 2024年第2期08卷 91-100页

作者： Li Zhengping Sun Jie Li Zekun Chen zhenping Liu Guoqing Yao Wanru cheng Xiaoling Li Gang Zhen Yingzi Ai Di Zhou Yaohan Mao Qianqian Poon Man-Chiu Wu Runhui Hemophilia Comprehensive Care Center Hematology Department Hematology Center Beijing Key Laboratory of Pediatric Hematology-Oncology Key Laboratory of Major Diseases in Children National Key Discipline of Pediatrics (Capital Medical University) Ministry of Education Beijing Children’s Hospital Capital Medical University National Center for Children’s Health Beijing China Hematologic Disease Laboratory Hematology Department Hematology Center Beijing Key Laboratory of Pediatric Hematology-Oncology Key Laboratory of Major Diseases in Children National Key Discipline of Pediatrics (Capital Medical University) Ministry of Education Beijing Pediatric Research Institute Beijing Children’s Hospital Capital Medical University National Center for Children’s Health Beijing China Department of Pharmacy Beijing Children’s Hospital Capital Medical University National Center for Children’s Health Beijing China Departments of Medicine Pediatrics and Oncology University of Calgary Cumming School of Medicine Calgary Canada

Importance: It remained unclear that the efficacy comparison between low-dose immune tolerance induction (LD-ITI) incorporating immunosuppressants (IS) when severe hemophilia A (SHA) patients had inhibitor-titer ≥200 Bethesda Units (BU)/mL (LD-ITI-IS200 regimen) and LD-ITI combining with IS when SHA patients had inhibitor-titer ≥40 BU/mL (LD-ITI-IS40 regimen).Objective: To compare the efficacy of the LD-ITI-IS200 regimen with that of the LD-ITI-IS40 regimen for SHA patients with high-titer ***: A prospective cohort study on patients receiving LD-ITI-IS200 compared to those receiving LD-ITI-IS40 from January 2021 to December 2023. Both received LD-ITI [FVIII 50 IU/kg every other day]. IS (rituximab+ prednisone) was added when peak inhibitor tier ≥200 BU/mL in the LD-ITI-IS200 regimen and ≥40 BU/mL in the LD-ITI-IS40 regimen. Success is defined as a negative inhibitor plus FVIII recovery ≥66% of the ***: We enrolled 30 patients on LD-ITI-IS200 and 64 patients on LD-ITI-IS40, with similar baseline clinical characteristics. A lower IS-use rate was discovered in the LD-ITI-IS200 regimen compared to the LD-ITI-IS40 regimen (30.0% vs. 62.5%). The two regimens (LD-ITI-IS200 vs. LD-ITI-IS40) had similar success rate (70.0% vs. 79.7%), median time to success (9.4 vs. 10.6 months), and annualized bleeding rate during ITI (3.7 vs. 2.8). The cost to success was lower for LD-ITI-IS200 than for LD-ITI-IS40 (2107 vs. 3256 US Dollar/kg). Among patients with peak inhibitor-titer 40-199 BU/mL, 10 non-IS-using (on LD-ITI-IS200 regimen) and 28 IS-using (on LD-ITI-IS40 regimen) had similar success rates (70.0% vs. 78.6%) and time to success (9.0 vs. 8.8 months).Interpretation: In LD-ITI, IS are not necessary for inhibitor titer <200 BU/mL.

关键词： Hemophilia A High-titer inhibitor Immune tolerance induction Immunosuppressant Low-dose

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Mechanism study and molecular design in controlled/“living” radical polymerization

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Science China Chemistry 2010年第8期53卷 1605-1619页

作者： TU YingFeng,cheng zhenping,ZHANG ZhengBiao,ZHU Jian,ZHANG Wei,ZHOU NianChen,NI PeiHong & ZHU XiuLin College of Chemistry,Chemical Engineering and Materials Science,Soochow University,Suzhou 215123,China College of Chemistry Chemical Engineering and Materials Science Soochow University Suzhou China

This tutorial review summarizes recent progress in the research field of controlled/"living" radical polymerization (CLRP) from Soochow *** present paper gives a broad overview of the mechanism study and molecular design in *** mechanism study in CLRP aided by microwave,initiated by γ-radiation at low temperature,mediated by iron,in reversible addition-fragmentation chain transfer (RAFT) polymerization and the mechanism transfer between different CLRP processes are reviewed and *** molecular design in CLRP,especially in RAFT polymerization for mechanism study,and in achieving tailor-made functional polymers is studied and discussed in the later part.

关键词： controlled/"living" radical polymerization atom transfer radical polymerization reversible addition-fragmentation chain transfer polymerization molecule design mechanism study

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有序排布砂轮磨削加工BK7玻璃试验研究

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湖南大学学报（自然科学版） 2024年第4期51卷 54-63页

作者：卜颖滨万珍平成雨华南理工大学机械与汽车工程学院广东广州510641

考虑磨削过程中任意相邻磨粒之间的相互作用,针对单颗磨粒进行有序排布研究,提出一种能够控制任意两颗磨粒间距的有序排布策略.经过排布后的每颗磨粒作为单独切削刃,在工件表面先后切除材料后形成沟痕.根据排布策略设计3种排布方式,任... 详细信息

考虑磨削过程中任意相邻磨粒之间的相互作用,针对单颗磨粒进行有序排布研究,提出一种能够控制任意两颗磨粒间距的有序排布策略.经过排布后的每颗磨粒作为单独切削刃,在工件表面先后切除材料后形成沟痕.根据排布策略设计3种排布方式,任意相邻磨粒间距分别为-50µm、0µm、50µm,利用电化学阳极溶解在砂轮基体表面制备排布模板,上砂电镀加厚制备相应的有序排布砂轮.采用磨削运动学方法,分析磨削中的磨削力和磨削温度变化情况,通过磨削试验测量实际磨削中磨削力和磨削温度并进行分析.结果表明,磨削力与进给速度呈正相关,磨削温度与进给速度呈负相关.磨削深度和磨粒排布间距综合影响温度和磨削力的变化,当磨粒间距较小时,随磨削深度的增加,磨削温度和磨削力稳步升高;当磨粒间距较大时,随磨削深度增加,两者先稳步升高,后缓慢升高.

关键词：磨削加工砂轮磨粒有序排布磨削性能 BK7玻璃

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基于改进拉普拉斯金字塔的HDR图像色调映射算法

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激光与光电子学进展 2024年第4期61卷 558-566页

作者：张博文夏振平张跃渊程成刘宇杰苏州科技大学电子与信息工程学院江苏苏州215009

为进一步提升高动态范围图像在普通显示器上的呈现效果,提出了一种基于改进拉普拉斯金字塔的高动态范围图像色调映射算法。该算法将预处理后的图像分解为高频层和低频层,分别输入2个特征提取子网络,将2个包含不同特征的输出图像融合后... 详细信息

为进一步提升高动态范围图像在普通显示器上的呈现效果,提出了一种基于改进拉普拉斯金字塔的高动态范围图像色调映射算法。该算法将预处理后的图像分解为高频层和低频层,分别输入2个特征提取子网络,将2个包含不同特征的输出图像融合后再输入微调网络,最终得到感知效果优越的低动态范围图像。此外,该算法设计了自适应分组卷积模块以增强子网络提取局部和全局特征的能力。测试结果表明:与现有的先进算法相比,所提算法可以更好地压缩高动态范围图像的亮度,保留更多图像细节,拥有更加优越的客观质量指标和主观感知效果。

关键词：图像处理高动态范围图像色调映射拉普拉斯金字塔深度学习

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SYNTHESIS OF HYPERBRANCHED POLY（ε-CAPROLACTON） CONTAINING TERMINAL AZOBENZENE VIA COMBINED RING-OPENING POLYMERIZATION AND CLICK CHEMISTRY

SYNTHESIS OF HYPERBRANCHED POLY（ε-CAPROLACTON） CONTAINING...

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第四届国际高分子化学学术讨论会

作者： Xiaoqiang Xue Jian Zhu Zhengbiao Zhang zhenping cheng Xiulin Zhu Key Laboratory of Organic Synthesis of Jiangsu Province College of Chemistry Chemical Engineering and Materials Science of Soochow University

＜正＞In recent years,biodegradable aliphatic polyesters have been attracted considerable research *** materials can be widely applied in the specialty biomedical areas of drug delivery materials,environmental and marine fields.[1]Poly（-caprolactone）（PCL）as aliphatic polyesters via ring opening polymerization is also considered as the perfect biodegradable materials with flexibility and good

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基于Transformer-CNN的轻量级图像超分辨率重建网络

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计算机应用 2024年第1期44卷 292-299页

作者：陈豪夏振平程成林李兴张博文苏州科技大学电子与信息工程学院江苏苏州215009 苏州科技大学物理科学与技术学院江苏苏州215009

针对现有超分辨率重建网络具有较高的计算复杂度和存在大量内存消耗的问题,提出了一种基于Transformer-CNN的轻量级图像超分辨率重建网络,使超分辨率重建网络更适合应用于移动平台等嵌入式终端。首先,提出了一个基于Transformer-CNN的... 详细信息

针对现有超分辨率重建网络具有较高的计算复杂度和存在大量内存消耗的问题,提出了一种基于Transformer-CNN的轻量级图像超分辨率重建网络,使超分辨率重建网络更适合应用于移动平台等嵌入式终端。首先,提出了一个基于Transformer-CNN的混合模块,从而增强网络捕获局部−全局深度特征的能力;其次,提出了一个改进的倒置残差块来特别关注高频区域的特征,以提升特征提取能力和减少推理时间;最后,在探索激活函数的最佳选择后,采用GELU(Gaussian Error Linear Unit)激活函数来进一步提高网络性能。实验结果表明,所提网络可以在图像超分辨率性能和网络复杂度之间取得很好的平衡,而且在基准数据集Urban100上4倍超分辨率的推理速度达到91 frame/s,比优秀网络SwinIR(Image Restoration using Swin transformer)快11倍,表明所提网络能够高效地重建图像的纹理和细节,并减少大量的推理时间。

关键词：图像超分辨率深度学习 Transformer 卷积神经网络轻量级

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中文纠错任务为例的数据集增强质量评价方法

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计算机工程与应用 2024年第3期60卷 331-339页

作者：宋程谢振平江南大学人工智能与计算机学院江苏无锡214000 江南大学江苏省媒体设计与软件技术重点实验室江苏无锡214000

数据增强被认为是一种有效提升模型效果的方案。但是在选取生成的数据时,需考虑固有的数据特征和相应的任务关联性。针对这一问题,以中文纠错任务场景为例,提出了一种可用于数据集增强质量的评价方法。该方法使用对比学习优化后的预训... 详细信息

数据增强被认为是一种有效提升模型效果的方案。但是在选取生成的数据时,需考虑固有的数据特征和相应的任务关联性。针对这一问题,以中文纠错任务场景为例,提出了一种可用于数据集增强质量的评价方法。该方法使用对比学习优化后的预训练模型提取数据集的特征向量,提出互覆盖度、总分散度、自支撑度等三个基本评价指标,并给出一个综合性的数据集质量融合指标。在四种数据增强方法、两个中文纠错数据集和三个中文纠错模型上的实验分析结果表明,上述评价方法能够独立于测试集性能检验方法,为不同增强数据集的选用提供重要依据。

关键词：数据集增强机器学习质量评价中文纠错深度学习

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