Mechanism study and molecular design in controlled/“living” radical polymerization
Mechanism study and molecular design in controlled/"living" radical polymerization作者机构:College of Chemistry Chemical Engineering and Materials Science Soochow University Suzhou China
出 版 物:《Science China Chemistry》 (中国科学(化学英文版))
年 卷 期:2010年第53卷第8期
页 面:1605-1619页
核心收录:
学科分类:081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070305[理学-高分子化学与物理] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程(可授工学、理学学位)] 0703[理学-化学]
基 金:supported by the National Natural Science Foundation of China (20874069, 50803044, 20974071, 20904036) the Specialized Research Fund for the Doctoral Program of Higher Education (200802850005) the Qing Lan Project the Program of Innovative Research Team of Soochow University
主 题:controlled/"living" radical polymerization atom transfer radical polymerization reversible addition-fragmentation chain transfer polymerization molecule design mechanism study
摘 要:This tutorial review summarizes recent progress in the research field of controlled/living radical polymerization (CLRP) from Soochow *** present paper gives a broad overview of the mechanism study and molecular design in *** mechanism study in CLRP aided by microwave,initiated by γ-radiation at low temperature,mediated by iron,in reversible addition-fragmentation chain transfer (RAFT) polymerization and the mechanism transfer between different CLRP processes are reviewed and *** molecular design in CLRP,especially in RAFT polymerization for mechanism study,and in achieving tailor-made functional polymers is studied and discussed in the later part.