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Toeless and reversible DNA strand displacement based on Hoogsteen-bond triplex

Chinese Chemical Letters 2024年第5期35卷 330-337页

作者： Yang Qin Jiangtian Li Xuehao Zhang Kaixuan Wan Heao Zhang Feiyang Huang Limei Wang Hongxun Wang Longjie Li Xianjin Xiao Institute of Reproductive Health Tongji Medical CollegeHuazhong University of Science and TechnologyWuhan 430030China Department of Pancreatic Surgery Union HospitalTongji Medical CollegeHuazhong University of Science and TechnologyWuhan 430022China Wuhan Polytechnic University Wuhan 430023China

Strand displacement reaction is a crucial component in the assembly of diverse DNA-based nanodevices,with the toehold-mediated strand displacement reaction representing the prevailing strategy.However,the single-stranded Watson-Crick sticky region that serves as the trigger for strand displacement can also cause leakage reactions by introducing crosstalk in complex DNA circuits.Here,we proposed the toeless and reversible DNA strand displacement reaction based on the Hoogsteen-bond triplex,which is compatible with most of the existing DNA circuits.We demonstrated that our proposed reaction can occur at pH 5 and can be reversed at pH 9.We also observed an approximately linear relationship between the degree of reaction and pH within the range of pH 5-6,providing the potential for precise regulation of the reaction.Meanwhile,by altering the sequence orientation,we have demonstrated that our proposed reaction can be initiated or regulated through the same toeless mechanism without the requirement for protonation in low pH conditions.Based on the proposed reaction principle,we further constructed a variety of DNA nanodevices,including two types of DNA logic gates that rely on pH 5/pH 9 changes for initiating and reversing:the AND gate and the OR gate.We also successfully constructed a DNA Walker based on our proposed reaction modes,which can move along a given track after the introduction of a programmable DNA sequence and complete a cycle after 4 steps.Our findings suggest that this innovative approach will have broad utility in the development of DNA circuits,molecular sensors,and other complex biological systems.

关键词： DNA strand displacement Toeless Triplex DNA strands reversible DNA circuit DNA walker

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Amphiphilic amino-acid derivatives promote gram-scale single-crystal COFs synthesis

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Science China Chemistry 2024年第2期67卷 415-416页

作者： Yijia Yuan Kian Ping Loh Department of Chemistry National University of SingaporeSingapore117543Singapore

Covalent organic frameworks(COFs) are crystalline organic compounds synthesized from covalently linked building blocks that extend in space to form a framework structure with periodic pores. The covalent linkages used... 详细信息

关键词： synthesis correction reversible

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Insight into role of Ni/Fe existing forms in reversible oxygen catalysis based on Ni-Fe single-atom/nanoparticles and N-doped carbon

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Rare Metals 2022年第12期41卷 4034-4040页

作者： Hong-Yu Gong Xiu Liang Guan-Liang Sun Dong-Wei Li Xiang-Jun Zheng Huan Shi Kai Zeng Guan-Chen Xu Yong Li Rui-Zhi Yang Chang-Zhou Yuan Advanced Materials Institute Qilu University of Technology(Shandong Academy of Sciences)Jinan 250014China Shandong Saikesaisi Hydrogen Energy Co. LtdJinan 250100China School of Environmental and Chemical Engineering Jiangsu University of Science and TechnologyZhenjiang 212003China School of Materials Science&Engineering University of JinanJinan 250014China College of Energy Soochow Institute for Energy and Materials InnovationsSoochow UniversitySuzhou 215006China

Oxygen catalysis reactions play essential roles in metal-air batteries,fuel cells,water electrolysis and artificial photosynthesis,with their development receiving significant attention in recent years.Understanding the structure-activity relationship plays an important role in the construction and performance optimization of reversible oxygen catalyst.

关键词： catalyst catalysis reversible

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Amino acid promoted hydrogen battery system using Mn-pincer complex for reversible CO_(2) hydrogenation to formic acid

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Frontiers in Energy 2022年第5期16卷 697-699页

作者： Zupeng CHEN Henrik JUNGE Matthias BELLER Jiangsu Co-Innovation Center of Efficient Processing and Utilization of Forest Resources College of Chemical EngineeringNanjing Forestry UniversityNanjing 210037China Leibniz-Institute for Catalysis University of RostockRostock 18059Germany Leibniz-Institute for Catalysis Rostock 18059Germany

The worldwide energy system developed in the past century is highly dependent on non-renewable fossil feedstocks.Hence,the concentration of carbon dioxide(CO_(2))in the atmosphere has continuously increased from 280 ppm(parts per million)to>420 ppm since the industrial revolution[1–5].This excessive emission of CO_(2) causes global warming and ocean acidification.In this context,the Paris Agreement on Climate Change adopted in 2015 recognized the necessity of holding the increase of global average temperature below 2℃,preferably 1.5℃,above pre-industrial levels,and reaching a CO_(2)-neutral process by 2050.

关键词： system hydrogenation reversible

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reversible and irreversible heat generation of NCA/Si–C pouch cell during electrochemical energy-storage process

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Journal of Energy Chemistry 2019年第2期28卷 95-102页

作者： Ying Bai Limin Li Yu Li Guanghai Chen Huichun Zhao Zhaohua Wang Chuan Wu Hongyun Ma Xinquan Wang Hongyue Cui Jiang Zhou School of Materials Science and Engineering Beijing Institute of Technology Collaborative Innovation Center of Electric Vehicles in Beijing Lishen Research Institute Tianjin Lishen Battery Joint-stock Co.Ltd.

To meet the requirements of electronic vehicles(EVs) and hybrid electric vehicles(HEVs),the high energy density Li Ni_(0.8) Co_(0.15) Al_(0.05) O_2(NCA) cathode and Si–C anode have attracted more attention.Here we report the thermal behaviors of NCA/Si–C pouch cell during the charge/discharge processes at different current densities.The total heat generations are derived from the surface temperature change during electrochemical Li+insertion/extraction in adiabatic surrounding.The reversible heat is determined by the entropic coefficients,which are related with open-circuit voltage at different temperatures; while the irreversible heat is determined by the internal resistance,which can be obtained via V–I characteristic,electrochemical impedance spectroscopy and hybrid pulse power characterization(HPPC).During the electrochemical process,the reversible heat contributes less than 10% to total heat generation; and the heat generated in charge process is less than that in discharge process.The results of thermal behaviors analyses are conducive to understanding the safety management and paving the way for building a reliable thermal model of high energy density lithium ion battery.

关键词： Heat generation Internal resistance reversible heat Irreversible heat Pouch cell

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reversible self-assembly of gold nanorods mediated by photoswitchable molecular adsorption

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Nano Research 2019年第7期12卷 1563-1569页

作者： Qian Wang Di Li Junyan Xiao Fucheng Guo Limin Qi Beijing National Laboratory for Molecular Sciences (BNLMS) College of ChemistryPeking UniversityBeijing 100871China

Stimuli-responsive self-assembly of nanoparticles represents a powerful strategy to achieve reconfigurable materials with novel functionalities and promising applications.In this regard,light-induced reversible self-assembly (LIRSA) of nanoparticles is most attractive but it is usually limited by the prerequisite yet cumbersome chemical functionalizations of the particle surface.Here we describe an innovative method to realize LIRSA of gold nanorods (GNRs) without surface functionalization through photoswitchable adsorption of an anionic azobenzene derivate AzoNa.The LIRSA of GNRs is caused by the reversible change between a nearly neutral state and a highly charged state of the GNRs arising from the photoswichable adsorption of AzoNa triggered by photoisomerization.The LIRSA behavior can be readily adjusted by changing the concentration of AzoNa and the aspect ratio of the GNRs.This new LIRSA strategy may provide a convenient and efficient route toward light-triggered reversibly reconfigurable nanomaterials.

关键词： self-assembly of nanoparticles gold nanorods reversible self-assembly photoswichable adsorption reconfigurable nanomaterials

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reversible folding/unfolding of small α-helix in explicit solvent investigated by ABEEMσπ/MM

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Science China Chemistry 2009年第11期52卷 1917-1924页

作者： LIU Cui & YANG ZhongZhi Chemistry and Chemical Engineering Faculty,Liaoning Normal University,Dalian 116029,China Chemistry and Chemical Engineering Faculty Liaoning Normal University Dalian China

We have performed molecular dynamics simulations on the reversible folding/unfolding of small α-helix(short Ala based peptide Ala5) in explicit water solvent in terms of ABEEMσπ/MM.A dynamics analysis shows that the α-helical turn can be preserved up to a period of about 2 ns at 300 K,which supports the conclusions of Margulis et al.The time trajectory of the root mean square deviation between the heavy atoms of the backbone and the helical reference structure indicate that "helix melting and formation occurs rapidly on a time scale of 0.1 ns at 300 K" is not a felicitous conclusion.We first quantificationally concluded that the helix nucleation can maintain 2 ns,1―1.5 ns and 0.8 ns for Ala5 at 300 K,400 K and 500 K,respectively.Furthermore,increasing temperature dose not alter the pathway of folding/unfolding,but change the rate.An analysis of structures in a "transition-state ensemble" shows that helix-to-coil transitions occurs predominantly through breaking of hydrogen bonds at the helix ends(92%),particularly at the C-terminus(50%).Hydrogen bonds' breaking and formation occurs on a time scale of 0.1 ns.

关键词： reversible folding/unfolding of protein Ala5 temperature hydrogen bond

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Sign-reversible valley-dependent Berry phase effects in 2D valley-half-semiconductors

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npj Computational Materials 2021年第1期7卷 1435-1441页

作者： Xiaodong Zhou Run-Wu Zhang Zeying Zhang Wanxiang Feng Yuriy Mokrousov Yugui Yao Centre for Quantum Physics Key Laboratory of Advanced Optoelectronic Quantum Architecture and Measurement(MOE)School of PhysicsBeijing Institute of Technology100081 BeijingChina Beijing Key Lab of Nanophotonics&Ultrafine Optoelectronic Systems School of PhysicsBeijing Institute of Technology100081 BeijingChina College of Mathematics and Physics Beijing University of Chemical Technology100029 BeijingChina Peter Grünberg Institut and Institute for Advanced Simulation Forschungszentrum Jülich and JARA52425 JülichGermany Institute of Physics Johannes Gutenberg University Mainz55099 MainzGermany

Manipulating valley-dependent Berry phase effects provides remarkable opportunities for both fundamental research and practical applications.Here,by referring to effective model analysis,we propose a general scheme for realizing topological magneto-valley phase transitions.More importantly,by using valley-half-semiconducting VSi2N4 as an outstanding example,we investigate sign change of valley-dependent Berry phase effects which drive the change-in-sign valley anomalous transport characteristics via external means such as biaxial strain,electric field,and correlation effects.As a result,this gives rise to quantized versions of valley anomalous transport phenomena.Our findings not only uncover a general framework to control valley degree of freedom,but also motivate further research in the direction of multifunctional quantum devices in valleytronics and spintronics.

关键词： Berry phase reversible

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reversible electrochemistry of DNA on multi-walled carbon nanotube modified electrode

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Chinese Chemical Letters 2007年第7期18卷 861-864页

作者： Hong Xia Luo Zhi Xin Guo Nan He Department of Chemistry Renmin University of China Beijing 100872 China

Calf thymus DNA was electrochemically oxidized at a multi-walled carbon nanotube modified electrode. The potentials for DNA oxidation at pH 7.0 were 0.71 and 0.81 V versus SCE, corresponding to the oxidation of guanine and adenine residues,respectively. The initial 6e-oxidation of adenine, observed in the first scan, resulted a quasi-reversible 2e-redox process of the oxidation product in the following scans.

关键词： Carbon nanotube DNA Cyclic voltammetry reversible

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reversible dysphagia due to gabapentin-induced jaw myoclonus

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Chinese Medical Journal 2019年第12期132卷 1485-1486页

作者： Chun-Him Hui Jackson Ka-Chun Leung Richard Shek-Kwan Chang Yat-Fung Shea Respiratory Division Department of MedicineQueen Mary HospitalThe University of Hong KongHong KongChina Medical Oncology Division Department of MedicineQueen Mary HospitalThe University of Hong KongHong KongChina Neurology Division Department of MedicineQueen Mary HospitalThe University of Hong KongHong KongChina Geriatrics Division Department of MedicineQueen Mary HospitalThe University of Hong KongHong KongChina

An 89-year-old woman was admitted with a 3-day history of dysphagia and lower jaw twitching. She had a history of hypertension, diabetes mellitus, surgically corrected left proximal humeral fracture, and right C5 dermatome postherpetic neuralgia. The jaw twitching had caused dysphagia with an inability to drink liquids. Physical examination confirmed the persistent lower jaw myoclonus (Supplementary Video;http://***/CM9/A48). The patient was fully conscious and had no twitching or nystagmus in any of her other extremities. The results of neurological examination and biochemical analysis (including complete blood profile, electrolyte level, random glucose concentration, renal function test, and liver function test) were all within the normal range. Computed tomography of the brain was unremarkable and an electroencephalogram showed no evidence of seizure. A careful review of her prescribed medications revealed the following: the patient complained of allodynia over the right C5 dermatome around 3 months prior and was prescribed gabapentin. The dosage of gabapentin was increased to 300 mg total dissolved solids (TDS) around 2 months prior. Creatinine levels were normal but her glomerular filtration rate, as estimated by the Cockcroft-Gault equation, was 36 mL/min.[1] Since the patient’s relatives supervised her medication intake, overdosage was not possible. Gabapentin was discontinued and replaced with pregabalin 50 mg BD and the patient was prescribed valium 2 mg TDS transiently. The jaw myoclonus subsided on the second day. After a consultation with a speech therapist, the patient resumed oral intake and remained tolerant of a normal diet. Upon review after 1 month, the patient remained free from jaw myoclonus.

关键词： reversible dysphagia jaw myoclonus woman

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