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A New Scheme and Microstructural Model for 3D Full 5-directional Braided Composites

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Chinese Journal of Aeronautics 2010年第1期23卷 61-67页

作者： Zhang Fan,Liu zhenguo,wu Zhe,Tao Guoquan School of Aeronautic Science and Engineering,Beijing University of Aeronautics and Astronautics,Beijing 100191,China [a] School of Aeronautic Science Engineering Beijing University of Aeronautics Astronautics Beijing 100191 China

Three-dimensional（3 D）braided composites are a kind of advanced ones and are used in the aeronautical and astronautical fields more widely. The advantages, usages, shortages and disadvantages of 3D braided composites are analyzed, and the possible approach of improving the properties of the materials is presented, that is, a new type of 3D full 5-directional braided composites is developed. The methods of making this type of preform are proposed. It is pointed out that the four-step braiding which is the most possible to realize industrialized production almost has no effect on the composites＇ properties. By analyzing the simulation model,the advantages of the material compared with the 3D 4-directional and 5-directional materials are presented. Finally, a microstructural model is analyzed to lay the foundation for the future theoretical analysis of these composites.

关键词： 3D braided fabrics four-step braiding 3D full 5-directional braided composites preform microstructure

The chance of sodium titanate anode for the practical sodium-ion batteries

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Chinese Journal of Chemical Engineering 2024年第8期72卷 226-244页

作者： Feng Chen Haoyu Li Xianyan Qiao Ruoyang Wang Changyan Hu Ting Chen Yifan Niu Benhe Zhong zhenguo wu Xiaodong Guo School of Chemical Engineering Sichuan UniversityChengdu 610065China Institute for Advanced Study Chengdu UniversityChengdu 610106China Chengdu No.7 High School Chengdu 6100412China

Supporting sustainable green energy systems,there is a big demand gap for grid energy *** storage,especially sodium-ion batteries(SIBs),have advanced significantly and are now emerging as a feasible alternative to the lithium-ion batteries equivalent in large-scale energy storage due to their natural abundance and prospective inexpensive *** various anode materials of SIBs,beneficial properties,such as outstanding stability,great abundance,and environmental friendliness,make sodium titanates(NTOs),one of the most promising anode materials for the rechargeable ***,there are still enormous challenges in application of NTO,owing to its low intrinsic electronic conductivity and collapse of *** research on NTOs is still in its infancy;there are few conclusive reviews about the specific function of various modification ***,we summarize the typical strategies of optimization and analysis the fine structures and fabrication methods of NTO anodes combined with the application of in situ characterization *** work provides effective guidance for promoting the continuous development,equipping NTOs in safety-critical systems,and lays a foundation for the development of NTO-anode materials in SIBs.

关键词： Sodium titanates Sodium-ion batteries Modification methods Electronic materials Electrochemistry Synthesis

Efficient Chemical Prelithiation with Modificatory Li^(+) Solvation Structure Enabling Spatially Homogeneous SEI toward High Performance SiO_(x) Anode

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Chinese Journal of Chemistry 2024年第17期42卷 2056-2065页

作者： Ruoyang Wang Yuqing wu Yifan Niu Qing Yang Haoyu Li Yang Song Benhe Zhong Liwen Yang Ting Chen zhenguo wu Xiaodong Guo School of Chemical Engineering Sichuan UniversityChengduSichuan 610065China Chengdu No.7 High School ChengduSichuan 6100412China Institute for Applied Materials(IAM) Karlsruhe Institute of Technology(KIT)Hermann-von-Helmholtz-Platz1D-76344 Eggenstein-LeopoldshafenGermany Institute for Advanced Study Chengdu UniversityChengduSichuan 610106China

Chemical prelithiation is widely proven to be an effective strategy to address the low initial coulombic efficiency(ICE)of promising SiO_(x) *** the reagent composition has been widely explored,the Li^(+) solvation structure,which practically plays the cornerstone role in the prelithiation ability,rate,uniformility,has rarely been explored.A novel environmentally-friendly reagent with weak solvent cyclopentyl methyl ether(CPME)is proposed that enables both improved ICE and spatial homogeneous solid electrolyte interphase(SEl).And the prelithiation behavior and mechanism were explored focused on the Li^(+) solvation *** theoretical investigation and spectroscopic results suggest that weak solvent feature of CPME reduces the solvent coordination number and decreases the Li^(+) desolvation energy.

关键词： Lithium-ion battery SiO_(x)anode Prelithiation Weak solvent Homogeneous SEI Energy conversion Desolvation energy

Self-Adaptive and Electric Field-Driven Protective Layer with Anchored Lithium Deposition Enable Stable Lithium Metal Anode

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Energy & Environmental Materials 2024年第3期7卷 32-40页

作者： Ting Chen Luchao Yue Guoqiang Shu Qing Yang Dong Wang Ruoyang Wang Xianyan Qiao Yan Sun Benhe Zhong zhenguo wu Xiaodong Guo Department of Chemical Engineering Sichuan UniversityChengdu 610065China School of Mechanical Engineering Chengdu UniversityChengdu 610106China

Lithium metal battery has great development potential because of its lowest electrochemical potential and highest theoretical ***,the uneven deposition of Li^(+)flux in the process of deposition and stripping induces the vigorous growth of lithium dendrites,which results in severely battery performance degradation and serious safety ***,the tetragonal BaTiO3 polarized by high voltage corona was used to build an artificial protective layer with uniform positive polarization direction,which enables uniform Li^(+)*** contrast to traditional strategies of using protective layer,which can guide the uniform deposition of lithium *** ferroelectric protective layer can accurately anchor the Li^(+)and achieve bottom deposition of lithium due to the automatic adjustment of the electric ***,the huge volume changes caused by Li^(+)migration change of the lithium metal anode during charging and discharging is functioned to excite the piezoelectric effect of the protective layer,and achieve seamless dynamic tuning of lithium deposition/*** dynamic effect can accurately anchor and capture Li^(+).Finally,the layer-modified Li anode enables reversible Li plating/stripping over 1500 h at 1 mA cm^(-2)and 50℃in symmetric *** addition,the assembled Li-S full cell exhibits over 300 cycles with N/P≈*** work provides a new perspective on the uniform Li^(+)flux at the Li-anode interface of the artificial protective layer.

关键词： dense plating/stripping process electric field ferroelectric materials lithium metal batteries solid electrolyte interphase

Nonlinear optical microscopy for skin in vivo:Basics,development and applications

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Journal of Innovative Optical Health Sciences 2023年第1期16卷 95-113页

作者： Jianhua Zhao Yuan Zhao zhenguo wu Yunxian Tian Haishan Zeng Integrative Oncology Department–Imaging Unit BC Cancer Research Institute VancouverBCCanada Department of Dermatology and Skin Science University of British Columbia and Vancouver Coastal Health Research Institute VancouverBCCanada

Multi-photon microscopy(MPM)and coherent anti-Stokes Raman scattering(CARS)are two advanced nonlinear optical imaging techniques,which provide complementary information and have great potential in combination for noninvasive in vrito biomedical *** paper provides a detailed discussion of the basics,development and applications of these technologies for in vrivo skin research,covering the following topics:The principle and advantage of MPM and CARS,instrumentation development for in vino applications,MPM and CARS of normal skin,application of MPM and CARS in skin cancer and disease diagnosis;application of MPM in skin disease intervention,ie.,imaging guided two-photon photothermolysis.

关键词： Nonlinear microscopy multiphoton microscopy coherent anti-Stokes Raman scattering microscopy skin skin cancer multiphoton therapy

Limit　Monopoly　and　Promote　Productivity　Studying　Problems　about　Our　country＇s　Counter－monopoly　Law

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生产力研究 1994年第3期 80-80页

作者： wu zhenguo

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Improving the intrinsic electronic conductivity of NiMo0_(4) anodes by phosphorous doping for high lithium storage

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Nano Research 2022年第1期15卷 186-194页

作者： Luchao Yue Chaoqun Ma Shihai Yan zhenguo wu Wenxi Zhao Qian Liu(ISl) Yonglan Luo Benhe Zhong Fang Zhang Yang Liu Abdulmohsen AN Alshehri Khalid Ahmed Alzahrani Xiaodong Guo Xuping Sun School of Chemical Engineering Sichuan UniversityChengdu 610065China Institute of Fundamental and Frontier Sciences University of Electronic Science and Technology of ChinaChengdu 610054China College of Chemistry and Pharmaceutical Sciences Qingdao Agricultural UniversityQingdao 266109China National Engineering Research Center for Nanotechnology No.28 East Jiang Chuan RoadShanghai 200241China School of Materials Science and Engineering Henan Normal UniversityXinxiang 453007China Chemistry Department Faculty of ScienceKing Abdulaziz UniversityP.O.Box 80203Jeddah 21589Saudi Arabia

Heteroatom doping is one of the most promising strategies toward regulating intrinsically sluggish electronic conductivity and kinetic reaction of transition metal oxides for enhancing their lithium ***,we designed phosphorus-doped NiMo0_(4) nanorods(P-NiMo0_(4))by using a facile hydrothermal method and subsequent low-temperature phosphorization *** doping played an indispensable role in significantly improving electronic conductivity and the Li+diffusion kinetics of NiMo0_(4) *** investigation and density functional theory calculation demonstrated that phosphorus doping can expand the interplanar spacing and alter electronic structures of NiMo0_(4) ***,the introduced phosphorus dopant can generate some oxygen vacancies on the surface of NiMo0_(4),which can accelerate Li+diffusion kinetics and provide more active site for lithium *** excepted,P-NiMo0_(4) electrode delivered a high specific capacity(1,130 mA·g^(-1) at 100 mA·g^(-1) after 100 cycles),outstanding cycling durability(945 mA·g^(-1) at 500 mA·g^(-1) over 200 cycles),and impressive rate performance(640 mA·g^(-1)at 2,000mA·g^(-1))for lithium ion batteries(LIBs).This work could provide a potential strategy for improving intrinsic conductivity of transition metal oxides as high-performance anodes for LIBs.

关键词： NiMo0_(4) phosphorus doping anode lithium ion batteries

Effect of Panax notoginseng saponins on the expression of beta-amyloid protein in the cortex of the parietal lobe and hippocampus, and spatial learning and memory in a mouse model of senile dementia

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Neural Regeneration Research 2008年第12期3卷 1297-1303页

作者： zhenguo Zhong Dengpan wu Liang Lu Jinsheng Wang Wenyan Zhang Zeqiang Qu Center of Research ＆ Development of New Drugs Guangxi College of Traditional Chinese Medicine Nanning 530001 Guangxi ZhuangAutonomous Region China

BACKGROUND： The pharmacological actions of Panax notoginseng saponins （PNS） lie in removing free radicals, anti-inflammation and anti-oxygenation. It can also improve memory and behavior in rat models of Alzheimer＇s disease. OBJECTIVE： Using the Morris water maze, immunohistochemistry, real-time PCR and RT-PCR, this study aimed to measure improvement in spatial learning, memory, expression of amyloid precursor protein （App） and β -amyloid （A β ）, to investigate the mechanism of action of PNS in the treatment of AD in the senescence accelerated mouse-prone 8 （SAMP8） and compare the effects with huperzine A. DESIGN, TIME AND SETTING： A completely randomized grouping design, controlled animal experiment was performed in the Center for Research ＆ Development of New Drugs, Guangxi Traditional Chinese Medical University from July 2005 to April 2007. MATERIALS： Sixty male SAMP8 mice, aged 3 months, purchased from Tianjin Chinese Traditional Medical University of China, were divided into four groups： PNS high-dosage group, PNS low-dosage group, huperzine A group and control group. PNS was provided by Weihe Pharmaceutical Co., Ltd. （batch No.： Z53021485, Yuxi, Yunan Province, China）. Huperzine A was provided by Zhenyuan Pharmaceutical Co., Ltd. （batch No.： 20040801, Zhejiang, China）. METHODS： The high-dosage group and low-dosage group were treated with 93.50 and 23.38 mg/kg PNS respectively per day and the huperzine A group was treated with 0.038 6 mg/kg huperzine A per day, all by intragastric administration, for 8 consecutive weeks. The same volume of double distilled water was given to the control group. MAIN OUTCOME MEASURES： After drug administration, learning and memory abilities were assessed by place navigation and spatial probe tests. The recording indices consisted of escape latency （time-to-platform）, and the percentage of swimming time spent in each quadrant. The number of A β 1-40, A β 1-42 and App immunopositive neurons in the brains of SAMP8 mice was ana

关键词： Alzheimer's disease Panax notoginseng saponins learning and memory β -amyloid precursor protein 1-40 β -amyloid precursor protein 1-42 amyloid β -peptide synaptophysin senescence accelerated mouse-prone 8

Deciphering the degradation discrepancy in Ni-rich cathodes with a diverse proportion of[003]crystallographic textures

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Carbon Energy 2023年第7期5卷 15-26页

作者： Lang Qiu Mengke Zhang Yang Song zhenguo wu Yan-Fang Zhu Jun Zhang Dong Wang Hai-Yan Hu Hong-Wei Li Hang-Rui Liu Xin-Bei Jia Jian Peng Shuangqiang Chen Zuguang Yang Yao Xiao Xiaodong Guo Department of Chemical Engineering College of Chemical EngineeringSichuan UniversityChengduChina Institute for Carbon Neutralization College of Chemistry and Materials EngineeringWenzhou UniversityWenzhouZhejiangChina Ruyuan Dongyang Guangcixing Material Limited CompanyShaoguanGuangdongChina Department of Chemical Engineering School of Environmental and Chemical EngineeringShanghai UniversityShanghaiChina Department of Aerospace Engineering College of Aerospace EngineeringChongqing UniversityChongqingChina State Key Laboratory of Electrical Insulation and Power Equipment School of Electrical EngineeringXi'an Jiaotong UniversityXi'anShaanxiChina

The crystal plane plays a very important role in the properties of Ni-rich cathodes.[003]crystallographic texture regulation has been proven to improve structural stability,and yet,the discrepancy of particles with different exposed ratios of[003]in structural attenuation has not been ***,we have unraveled comprehensively the structural decay difference for Ni-rich cathodes’primary particles with the different percentages of exposed[003]by regulating the precursor coprecipitation *** findings based on structural characterization,first-principles calculations,finite element analysis,and electrochemical test reveal that the length and width of particles represent[110]and[003]directions,respectively,and show that cathode particles with a higher[110]/[003]ratio can effectively inhibit structure degradation and intergranular/intragranular crack formation owing to the low oxygen vacancy formation energy on(003)planes and the small local stress on secondary/primary *** study may provide guidance for the structural design of layered cathodes.

关键词： cracks crystal plane Ni-rich cathodes oxygen vacancy structure degradation