检索结果-南通市图书馆

Photoredox-catalyzed C-glycosylation of peptides with glycosyl bromides

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

Chinese Chemical Letters 2024年第6期35卷 263-267页

作者： Chen li Ziyuan zhao Shouyun Yu State Key Laboratory of Analytical Chemistry for life Science Jiangsu Key Laboratory of Advanced Organic MaterialsChemistry and Biomedicine Innovation Center(ChemBIC)School of Chemistry and Chemical EngineeringNanjing UniversityNanjing 210023China

Glycosyl radicals,produced under mild photoredox conditions,show unique utility in the preparation of C-linked *** herein report the construction of C-glycosidic bonds on α,β-dehydroalanine(DHA)of peptides with easily available glycosyl bromides as glycosyl radical precursors under highly anomeric control,leading to C-glycosylation modifications of *** method not only has outstanding functional group compatibility,but also is feasible in near-physiological conditions(pH~7 and temperature T≤37℃ in aqueous media).

关键词： Glycosylation C-Glycosides Glycopeptides Dehydroalanine Photoredox catalysis

维普期刊数据库

Learning Scalable Task Assignment with Imperative-Priori Conflict Resolution in Multi-UAV Adversarial Swarm Defense Problem

在线全文

学校读者我要写书评

暂无评论

Journal of Systems Science & Complexity 2024年第1期37卷 369-388页

作者： zhao Zhixin CHEN Jie XIN Bin li li JIAO Keming ZHENG Yifan School of Electronics and Information Engineering Tongji UniversityShanghai 201804China Shanghai Institute of Intelligent Science and Technology Tongji UniversityShanghai 201804China School of Automation Beijing Institute of TechnologyBeijing 100081China National Key Laboratory of Autonomous Intelligent Unmanned Systems Beijing 100081China Shanghai Institute of Intelligent Science and Technology Tongji UniversityShanghai 201804China.

The multi-UAV adversary swarm defense(MUASD)problem is to defend a static base against an adversary UAV swarm by a defensive UAV *** the problem into task assignment and low-level interception strategies is a widely used ***-based approaches for task assignment are a promising *** studies on learning-based methods generally assume decentralized decision-making architecture,which is not beneficial for conflict *** contrast,centralized decision-making architecture is beneficial for conflict resolution while it is often detrimental to *** achieve scalability and conflict resolution simultaneously,inspired by a self-attention-based task assignment method for sensor target coverage problem,a scalable centralized assignment method based on self-attention mechanism together with a defender-attacker pairwise observation preprocessing(DAP-SelfAtt)is ***,an imperative-priori conflict resolution(IPCR)mechanism is proposed to achieve conflict-free ***,the IPCR mechanism is parallelized to enable efficient *** validate the algorithm,a variant of proximal policy optimization algorithm(PPO)is employed for training in scenarios of various *** experimental results show that the proposed algorithm not only achieves conflict-free task assignment but also maintains scalability,and significantly improve the success rate of defense.

关键词： Conflict resolution reinforcement learning scalability task assignment.

维普期刊数据库

Single-atom catalysts supported on graphene/electride heterostructures for the enhanced sulfur reduction reaction in lithium-sulfur batteries

在线全文

学校读者我要写书评

暂无评论

Journal of Energy Chemistry 2024年第10期97卷 738-746页

作者： Siyun Qi Chuanchuan li Gang Chen Mingwen zhao School of Physics and Electronics Shandong Normal University Qingdao Industrial Energy Storage Research Institute Qingdao Institute of Bioenergy and Bioprocess Technology Chinese Academy of Sciences School of Physics & State Key Laboratory of Crystal Materials Shandong University

Single-atom catalysts（SACs） hold great promise in addressing the sluggish kinetics of the sulfur reduction reaction（SRR） in lithium-sulfur（li-S） batteries for their unique catalytic activity and maximum atom *** these SACs must be dispersed on solid substrates,the underlying support is usually limited to carbon materials that have a poor ability to modulate the coordination environment and electronic structures of single atoms,and consequently their catalytic activity toward the SRR is *** we propose two-dimensional（2D） graphene/electride heterostructu res as substrates to enhance the catalytic activities of SACs for li-S batteries.2D electrides featuring the anionic electron gas on their surface enable efficient electron transfer to SACs,which alters their electronic structures,resulting in the shifts of the d orbital and Fermi *** unique electronic structure decreases the filling of antibonding states such that the bonding with adsorbates at active sites is *** demonstrate the enhanced catalytic performance of SACs in terms of the Gibbs free energy of SRR and li2S *** addition,a universal descriptor for the rapid screening of SACs is established by a linear regression fitting *** work provides a new design strategy to modulate SAC activity through electrides for li-S batteries.

关键词： Charge transfers DFT calculations Electrides Kinetics Universal descriptors

Construction technology for deep tunnels crossing superhigh-temperature fault zones with high water surges

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

Frontiers of Structural and Civil Engineering 2024年第8期18卷 1267-1280页

作者： Yong zhao Tingyu ZHU li YU Ming LU Sichuan–Xizang Railway Co. Ltd.Linzhi 860000China School of Civil Engineering Southwest Jiaotong UniversityChengdu 610036China

The harsh environment in tunnels with high geothermal temperatures and humidity can adversely impact machinery,personnel,and *** main causes of specific problems are the unknown mechanisms of local geothermal formation,inappropriate temperature control measures,and insufficient systematic *** this study,three work sections relating to a high geothermal tunnel are:the tunnel face,middle-of-tunnel section,and outside-oftunnel section.A cooling strategy is proposed to offer technical support in achieving comprehensive cooling,overall as well as for each of the ***,a comprehensive geological survey explores the mechanism and exact location of the heat ***,grouting and centralized drainage measures are used to control the heat release of hot *** ventilation,ice chillers and other applicable measures are used to control the ambient ***,a monitoring and early warning system is established to prevent *** cooling strategy has been applied in the field with good results.

关键词： high geothermal tunnels cooling strategy comprehensive cooling measures safety and security

IQABC-Based Hybrid Deployment Algorithm for Mobile Robotic Agents Providing Network Coverage

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Tsinghua Science and Technology 2024年第2期29卷 589-604页

作者： Shuang Xu Xiaojie liu Dengao li Jumin zhao College of Computer Science and Technology(College of Data Science) Taiyuan University of TechnologyTaiyuan 030024China Pengcheng Laboratory Shenzhen 518055China College of Information and Computer Taiyuan University of TechnologyTaiyuan 030024China

Working as aerial base stations,mobile robotic agents can be formed as a wireless robotic network to provide network services for on-ground mobile devices in a target ***,a challenging issue is how to deploy these mobile robotic agents to provide network services with good quality for more users,while considering the mobility of on-ground *** this paper,to solve this issue,we decouple the coverage problem into the vertical dimension and the horizontal dimension without any loss of optimization and introduce the network coverage model with maximum coverage ***,we propose a hybrid deployment algorithm based on the improved quick artificial bee *** algorithm is composed of a centralized deployment algorithm and a distributed *** proposed deployment algorithm deploy a given number of mobile robotic agents to provide network services for the on-ground devices that are independent and identically *** results have demonstrated that the proposed algorithm deploys agents appropriately to cover more ground area and provide better coverage uniformity.

关键词： wireless robotic networks network coverage deployment algorithm improved quick artificial bee colony

Image format pipeline and instrument diagram recognition method based on deep learning

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Biomimetic Intelligence & Robotics 2024年第1期4卷 36-44页

作者： Guanqun Su Shuai zhao Tao li Shengyong liu Yaqi li Guanglong zhao Zhongtao li Shandong Qingniao IIoT Co. ltd.Jinan 250014China Jinan Housing and Urban-Rural Development Bureau Jinan 250012China State Grid Shandong Electric Extrahigh Voltage Company Jinan 250018China School of Information Science and Engineering University of JinanJinan 250022China

In this study,we proposed a recognition method based on deep artificial neural networks to identify various elements in pipelines and instrumentation diagrams(P&ID)in image formats,such as symbols,texts,and ***,the P&ID image format is recognized manually,and there is a problem with a high recognition error rate;therefore,automation of the above process is an important issue in the processing plant *** China National Offshore Petrochemical Engineering *** the image set used in this study,which contains 51 P&ID drawings in the *** converted the PDF P&ID drawings to PNG P&IDs with an image size of 8410×*** addition,we used labeling software to annotate the images,divided the dataset into training and test sets in a 3:1 ratio,and deployed a deep neural network for *** method proposed in this study is divided into three *** first step segments the images and recognizes symbols using YOLOv5+*** second step determines text regions using character region awareness for text detection,and performs character recognition within the text region using the optical character recognition *** third step is pipeline recognition using YOLOv5+*** symbol recognition accuracy was 94.52%,and the recall rate was 93.27%.The recognition accuracy in the text positioning stage was 97.26%and the recall rate was 90.27%.The recognition accuracy in the character recognition stage was 90.03%and the recall rate was 91.87%.The pipeline identification accuracy was 92.9%,and the recall rate was 90.36%.

关键词： Deep learning Image processing Piping and instrumentation Object recognition Pipeline recognition

Adaptive 5G-and-beyond network-enabled interpretable federated learning enhanced by neuroevolution

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Science China(Information Sciences) 2024年第7期67卷 107-132页

作者： Bin CAO Jianwei zhao Xin liU Yun li State Key Laboratory of Reliability and Intelligence of Electrical Equipment Hebei University of Technology School of Artificial Intelligence Hebei University of Technology School of Economics and Management Hebei University of Technology Industrial Artificial Intelligence Centre Shenzhen Institute for Advanced StudyUniversity of Electronic Science and Technology of China

Mobile telemedicine systems based on the next-generation communication will significantly enhance deep fusion of network automation and federated learning(FL), but data privacy is a paramount issue in sectors like healthcare. This work hence considers FL augments 5G-and-beyond networks by training deep learning(DL) models without the need to exchange raw data. The substantial communication loads imposed on by extensive parameters involved in DL models are managed through adaptive scheduling mechanisms effectively. To address the opaque nature of DL models and to improve the interpretability of FL models, we introduce a convolutional fuzzy rough neural network specifically designed for medical image processing. We also develop a multiobjective memetic evolutionary algorithm to streamline and optimize the neural network architectures. Our comprehensive FL framework integrates smart scheduling, interpretable fuzzy rough logic,and neuroevolution. This framework is shown to improve communication efficiency, increase interpretability of diagnosis with protected privacy, and generate low-complexity neural architectures.

关键词： 5G-and-beyond network interpretable federated learning mobile telemedicine system fuzzy rough set theory neuroevolution

Spatially Coupled Codes via Bidirectional Block Markov Superposition Transmission

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

Tsinghua Science and Technology 2024年第3期29卷 656-670页

作者： Gaoyan li Shancheng zhao Haiqiang Chen Jinming Wen College of Information Science and Technology Jinan UniversityGuangzhou 510632China Guangxi Key Laboratory of Multimedia Communications and Network Technology Guangxi UniversityNanning 530004China

In this paper,we present a new class of spatially coupled codes obtained by using both non-recursive and recursive block-oriented *** resulting codes are termed as bidirectional block Markov superposition transmission(BiBMST)***,we perform an iterative decoding threshold analysis according to protograph-based extrinsic information transfer(PEXIT)charts for the BiBMST codes over the binary erasure channels(BECs).Secondly,we derive the generator and parity-check matrices of the BiBMST ***,extensive numerical results are presented to show the advantages of the proposed BiBMST ***,our numerical results show that,under the constraint of an equal decoding latency,the BiBMST codes perform better than the recursive BMST(rBMST)***,the simulation results show that,in finite-length regime,negligible performance gain is obtained by increasing the encoding *** solve this limitation by introducing partial superposition,and the resulting codes are termed as partially-connected BiBMST(PC-BiBMST)*** results have confirmed the advantages of the PC-BiBMST codes over the original BiBMST *** also present extensive simulation results to show the performance advantages of the PC-BiBMST codes over the spatially coupled low-density parity-check(SC-LDPC)codes,spatially coupled generalized LDPC(SC-GLDPC)codes,and the original BiBMST codes in the finite-length regime.

关键词： block Markov superposition transmission(BMST) protograph-based extrinsic information transfer(PEXIT) capacity-approaching codes spatial coupling

The suitability assessment on site selection for bottom seeding scallop culture based on analytic hierarchy process

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Journal of Oceanology and limnology 2024年第2期42卷 647-663页

作者： Ziniu ZHANG Zhenyan WANG Guihua li Meihan zhao Wenjian li School of Earth Sciences and Engineering Shandong University of Science and TechnologyQingdao 266590China Key Laboratory of Marine Geology and Environment Institute of OceanologyChinese Academy of SciencesQingdao 266071China Laboratory for Marine Mineral Resources National Laboratory for Marine Science and TechnologyQingdao 266237China University of Chinese Academy of Sciences Beijing 100049China

Scallop culture is an important way of bottom-seeding marine ranching,which is of great significance to improve the current situation of fishery ***,there are some problems in site-selection evaluation of marine ranching,such as imperfect criteria system,complex structure,untargeted criteria quantification,*** addition,no site-selection evaluation method of bottom-seeding culture areas for scallops is ***,we established a hierarchy structure model according to the analytic hierarchy process(AHP)theory,in which social,physical,chemical,and biological environments are used as main criteria,and marine functional zonation,water depth,current,water temperature,salinity,substrate type,water quality,sediment quality,red tide,phytoplankton,and zooplankton are used as sub-criteria,on which a multi-parameter evaluation system is set ***,the dualism method,assignment method,and membership function method were used to quantify sub-criteria,and a quantitative evaluation for the entire criteria was added,including the evaluation and analysis of two types of unsuitable environmental *** overall consideration in scallop yield,quality,and marine ranching construction objectives,the weight of the main criteria could be *** grades in the suitability corresponding to the evaluation result were divided,and the Python language was used to create an evaluation system for efficient calculation and intuitive presentation of the evaluation *** marine cases were simulated based on existing survey data,and the results prove that the method is feasible for evaluating and analyzing the site selection of bottom-seeding culture areas for scallops under various environmental *** proposed evaluation method can be promoted for the site selection of bottom-seeding marine *** study provided theoretical and methodological references for the site selection evaluation of other types of marine ranching.

关键词： marine ranching bottom-seeding scallops site selection evaluation analytic hierarchy process evaluation system

维普期刊数据库