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Wettability alteration analysis of smart water/novel functionalized nanocomposites for enhanced oil recovery

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Petroleum Science 2020年第5期17卷 1318-1328页

作者： Sara Habibi Arezou Jafari zahra F.akhroueian Chemical Engineering Faculty Tarbiat Modares UniversityTehranIran School of Chemical Engineering College of EngineeringInstitute of Petroleum EngineeringUniversity of TehranTehranIran

Smart water flooding,as a popular method to change the wettability of carbonate rocks,is one of the interesting and challenging issues in reservoir engineering.In addition,the recent studies show that nanoparticles have a great potential for application in EOR processes.However,little research has been conducted on the use of smart water with nanoparticles in enhanced oil recovery.In this study,stability,contact angle and IFT measurements and multi-step core flooding tests were designed to investigate the effect of the ionic composition of smart water containing SO4^2- and Ca^2+ ions in the presence of nanofluid on EOR processes.The amine/organosiloxane@Al2O3/SiO2(AOAS) nanocomposite previously synthesized using co-precipitation-hydrothermal method has been used here.However,for the first time the application of this nanocomposite along with smart water has been studied in this research.Results show that by increasing the concentrations of calcium and sulfate ions in smart water,oil recovery is improved by 9% and 10%,respectively,compared to seawater.In addition,the use of smart water and nanofluids simultaneously is very effective on increasing oil recovery.Finally,the best performance was observed in smart water containing two times of sulfate ions concentration(SW2 S) with nanofluids,showing increased efficiency of about 7.5%.

关键词： Smart water Nanofluid Wettability alteration Contact angle Stability Enhanced oil recovery

In Vivo Animal Model Evaluation of a Powerful Oral Nanomedicine for Treating Breast Cancer in BALB/c Mice Using 4T1 Cell Lines without Chemotherapy

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Advances in Nanoparticles 2022年第3期11卷 73-109页

作者： zahra fakhroueian Alireza Massiha Pegah Esmaeilzadeh Mehdi Assmar Afshin Zahedi Pouriya Esmaeilzadeh Sara Rezaei Shahab Rabiei Lalehdasht School of Chemical Engineering (Nanomedicine) College of Engineering University of Tehran Tehran Iran Department of Biotechnology Lahijan Branch Islamic Azad University Lahijan Iran Institute of Pharmacy Martin Luther University Halle Wittenberg Halle (Saale) Germany Department of Microbiology Lahijan Branch Islamic Azad University Lahijan Iran Department of Veterinary Pathology Islamic Azad University Rasht Branch Rasht Iran Department of Chemical Engineering Sharif University of Technology Tehran Iran Research Department Production and Laboratory Company ZFP Rasht Iran Department of Biology Faculty of Science Rasht Branch Islamic Azad University Guilan Iran

Nanopharmaceuticals containing quantum dot nanoparticles (Q-Dot NPs) for treating serious cancers such as breast cancer have made fantastic proposals. In this study, ZnO quantum dot NPs are formulated via ZnO@PVP nanopolymer as co-assistants coordinating with efficacious suitable wetting agents, PEG-binding compound, and W/O emulsifier for producing eco-friendly water-based nanodrug. Several characterization techniques containing SEM, TEM, FTIR, photoluminescence, zeta potential, and UV-Vis absorption were employed for ZnO Q-Dot NPs in nanodrug. This work aims to investigate the anti-tumor effects of such nanomedicine on the 4T1 breast cancer cell line in BALB/c mice, being elaborated through intraperitoneal, injection (IVP) and oral therapy. The impressive findings showed that ZnO nanodrug caused changes in blood factors, having the most effectiveness at 40 μg/ml concentration after two weeks of oral treatments. The significant increase in white blood cells (WBC) neutrophils and meaningful decreases in lymphocytes and especially cholesterol were powerful simultaneous impacts, successfully treating malignant breast cancer masses. In this significant animal model research for breast cancer, the sick mice recovered entirely and even had a safe space to mate. Histopathological results showed no evidence of breast tumor formation or metastasis in the group treated with nanodrug and their children. This nanomedicine has a therapeutic effect, and is ready to be applied for treating volunteer breast cancer patients. However, its prevention (inhibitory) effect can also be analyzed and added to current data in future studies.

关键词： Nanomedicine Nanodrug ZnO Q-Dot NPs In Vivo Breast Cancer BALB/c Mice 4T1 Cell Lines Metastasis Oral Treatment

The Interesting of Antifungal Effects of Novel In Vitro Fabrics of Stabilized ZnO Nanofluids

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Advances in Nanoparticles 2016年第4期5卷 206-223页

作者： Fatemeh Katouzian zahra fakhroueian Soheila Moradi Bidhendi Department of Microbiology Faculty of Advanced Sciences and Technology Pharmaceutical Sciences (IAUPS) Tehran Iran School of Chemical Engineering College of Engineering and IPE University of Tehran Tehran Iran Microbiology Department Razi Vaccine and Serum Research Institute Karaj Iran

According to the extent of fungal infections, to be chronic these such diseases and recently the emerging issue of increased antibiotic resistance in fungal infections, most of scientists are going to find a proper way to replace antibacterial agent by significant semiconductor ZnO nanoparticles (NPs). They are well known to be one of the most important and special metal oxide nanoparticles in pharmaceutical against the most common fungi. ZnO nanoparticles were synthesized using sol-gel, hydrothermal and functionalized surface methods and formulated in water solutions as nanofluids. XRD, FTIR and SEM techniques and UV-Vis absorbance spectroscopy characterized their ZnO modified nanostructures. Also antimycotic potential according to generally tests such as: (MIC) minimum inhibitory concentration, (MFC) minimum fungicidal concentration and normally well diffusion method with standard strains fungi were performed. Among five common fungi strains using in this research, new various ZnO nanofluids showed noticeable results for dermatophyte fungi like Trichophyton mentagrophytes, Microsporum gypseum, Microsporum canis, Candida albicans and Candid tropicalis which had un growth zones in order 70, 40, 35, 30 and 30 mm in comparing with Clotrimazole reference reagent: 30, 25, 25, 18 and 20 mm by well method. The performance of MIC for ZnO nanofluids on fungi was determined to be equal to 0.35, 3.12, 6.25, 6.25 and 6.25 μgr/ml and MFC of nanoproducts showed the 1.5, 12.5, 25, 25 and 25 μgr/ml. Therefore, the designed ZnO nanofluids could reveal the most effect on fungi which cause dermal (ringworm), mucosal (thrush) and vaginal infections, so we are able to apply these surface high energetic ZnO water-based nanofluid formulations as in vitro nanomedicine and nanohygiene for the first time.

关键词： ZnO Nanofluids Potential Medical Applications Antifungal Activity Traditional Re-sistant Antibiotic Surface Modification Nanomedicine Nanohygiene MFC Nanoformulation Stabilized Water-Based Nanoparticle

Synthesis and Characterization of Various Protein <i>α</i>-Lactalbumin Nanotubes Structures by Chemical Hydrolysis Method

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Advances in Nanoparticles 2013年第2期2卷 154-164页

作者： Pegah Esmaeilzadeh zahra fakhroueian Pouriya Esmaeilzadeh Narges Mohammadi Biomedical Material Department Institute of Pharmacy Martin Luther University Halle-Wittenberg Germany College of Chemical Engineering University of Tehran Tehran Iran Department of Chemistry College of Science Alzahra University Tehran. Iran Process simulation and control Lab. Chemical Engineering Collage Iran University of Science and Technology (IUST) Tehran Iran

New water-based nanofluids including unparalleled milk protein α-lactalbumin hollow nano-bio-tubes using low cost, available and advanced partial chemical hydrolysis strategy in bottom-up nano-assembly have been employed in this work. The aqueous sol-gel chemistry in nanotechnology which we selected for this goal offers new fabrication as interesting smart protein nanotubes. The kinds of nanometer sized tubular structures such as waved, helically coiled, bent, bamboo-shaped, bead-like and branched single-walled protein nanotubes (SWPNTs) with a range of 3 - 8 nm in outer diameters were produced by this method. Complete characterization for natural produced nanotubes including SEM, TEM images, G bond and D bond in Raman spectroscopy, XRD patterns, DLS (Dynamic Light Scattering) and FTIR analysis were evaluated which they are most significant experiments in synthesized protein nanotubes soluble in clear water nanofluids and stabilization of transparent nanofluids was proved within more than one year after preparation. Various necessary ligand ion salts such as Mn2+, Zn2+ and Ca2+ or mixtures as bridge makers and producing biological self-assembly hollow SWPNTs were performed and we focused on new chemical technology under specific acidic hydrolysis method not conventional enzymatic proteolysis and applying surfactants, pH reagent, Tris-HCl buffer, polar solvent which could be produced by β-sheet stacked hydrolysed protein α-lactalbumin mechanism under appropriate conditions to achieving high efficiency new protein nanotubes skeleton. They can be promising materials applied in food science, diet nutrition, nanomedicine, nano-biotechnology and surgery.

关键词： Nanobiotechnology Milk Protein Nanotubes Helical Self-Assembly Water-Based Nanofluids Chemical Hydrolysis Nanomedicine

Influence of Modified ZnO Quantum Dots and Nanostructures as New Antibacterials

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Advances in Nanoparticles 2013年第3期2卷 247-258页

作者： zahra fakhroueian Faraz M. Harsini Firoozeh Chalabian Fatemeh Katouzian Azizollah Shafiekhani Pegah Esmaeilzadeh Biomedical Material Department Institute of Pharmacy Martin Luther University Halle-Wittenberg Germany Department of Biology Azad University Tehran Iran Department of Biotechnology School of Chemical Engineering University of Tehran Iran Department of Microbiology Azad University Tehran Iran Physics Department Alzahra University Tehran Iran School of Physics IPM Tehran Iran School of Chemical Engineering College of Engineering University of Tehran Tehran Iran

Antibacterial activities of various spherical zinc oxide nanoparticles and nano special morphological structures including quantum dots, nanorod arrays, nanoporous shapes and needle-like crystals had been investigated as new nanomedicine compounds. Also antibacterial activity based on minimal inhibitory concentration and the growth inhibitory zone (well method) was evaluated. ZnO nanostructures were fabricated by novel hydrolysis sol-gel-hydrothermal process followed with rapid quenching as new technique using glycerine, vegetable fatty esters such as coconut, sunflower and Lauric alcohol ethoxylated as organic templates soluble in eco-friendly nanofluids. The results showed that Bacillus anthracis and Pseudomonas aerogenes were extremely sensitive to treatment with unique ZnO nanostructured. Their growth inhibitory zone presented 30 mm and 25 mm inhibition zone with better inhibitory effect compared to the Gentamicin antibiotic standard. ZnO nanostructures had also been indicated to have a wide range of antibacterial activities against both Gram-positive and Gram-negative bacteria especially more effective on (gr+) species using the growth inhibitory zone. We could design and make significant formulations of fatty acids and esters-capped ZnO quantum dots nanofluids which created high promising agents for controlling Anthrax, Staphylococcus epidermidis and their influences in antimicrobial properties with low cost for future.

关键词： Nanobiotechnology Antibacterial Activity Hydrolysis Sol-Gel-Hydrothermal ZnO Quantum Dots MIC and Well Method Complex Defects

Seismic performance evaluation of hybrid coupled shear wall system with shear and flexural fuse-type steel coupling beams

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Earthquake Engineering and Engineering Vibration 2024年第3期23卷 691-712页

作者： zahra Ramezandoust Abbas Tajaddini Panam Zarfam Department of Civil Engineering Science and Research branchIslamic Azad UniversityTehran 14778-93855Iran Department of Civil Engineering Karaj BranchIslamic Azad UniversityKaraj 31485-313Iran

Replaceable flexural and shear fuse-type coupling beams are used in hybrid coupled shear wall(HCSW)systems,enabling concrete buildings to be promptly recovered after severe earthquakes.This study aimed to analytically evaluate the seismic behavior of flexural and shear fuse beams situated in short-,medium-and high-rise RC buildings that have HCSWs.Three building groups hypothetically located in a high seismic hazard zone were studied.A series of 2D nonlinear time history analyses was accomplished in OpenSees,using the ground motion records scaled at the design basis earthquake level.It was found that the effectiveness of fuses in HCSWs depends on various factors such as size and scale of the building,allowable rotation value,inter-story drift ratio,residual drift quantity,energy dissipation value of the fuses,etc.The results show that shear fuses better meet the requirements of rotations and drifts.In contrast,flexural fuses dissipate more energy,but their sectional stiffness should increase to meet other requirements.It was concluded that adoption of proper fuses depends on the overall scale of the building and on how associated factors are considered.

关键词： hybrid coupled shear wall steel fuse coupling beam shear and flexural fuse nonlinear dynamic analysis seismic performance

Safety of tranexamic acid in surgically treated isolated spine trauma

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World Journal of Orthopedics 2024年第4期15卷 346-354页

作者： Wajiha zahra Sandeep Krishan Nayar Ashwin Bhadresha Vinay Jasani Syed Aftab Trauma and Orthopedics Department University Hospital of North Midlands NHS TrustStoke-on-Trent ST46QGUnited Kingdom Trauma and Orthopedics Department Royal London HospitalBarts Health InstituteLondon E11BBUnited Kingdom Craniospinal Services University Hospital of North Midlands NHS TrustStokeon-Trent ST46QGUnited Kingdom Spine Department Royal London HospitalBarts Health InstituteLondon E11BBUnited Kingdom

BACKGROUND Tranexamic acid(TXA),a synthetic antifibrinolytic drug,effectively reduces blood loss by inhibiting plasmin-induced fibrin breakdown.This is the first study in the United Kingdom to investigate the effectiveness of TXA in the surgical management of isolated spine trauma.AIM To assess the safety of TXA in isolated spine trauma.The primary and secondary outcomes are to assess the rate of thromboembolic events and to evaluate blood loss and the incidence of blood transfusion,respectively.METHODS This prospective observational study included patients aged≥17 years with isolated spine trauma requiring surgical intervention over a 6-month period at two major trauma centers in the United Kingdom.RESULTS We identified 67 patients:26(39%)and 41(61%)received and did not receive TXA,respectively.Both groups were matched in terms of age,gender,American Society of Anesthesiologists grade,and mechanism of injury.A higher proportion of patients who received TXA had a subaxial cervical spine injury classification or thoracolumbar injury classification score>4(74%vs 56%).All patients in the TXA group underwent an open approach with a mean of 5 spinal levels involved and an average operative time of 203 min,compared with 24 patients(58%)in the non TXA group who underwent an open approach with an average of 3 spinal levels involved and a mean operative time of 159 min.Among patients who received TXA,blood loss was<150 and 150–300 mL in 8(31%)and 15(58%)patients,respectively.There were no cases of thromboembolic events in any patient who received TXA.CONCLUSION Our study demonstrated that TXA is safe for isolated spine trauma.It is challenging to determine whether TXA effectively reduces blood loss because most surgeons prefer TXA for open or multilevel cases.Further,larger studies are necessary to explore the rate,dosage,and mode of administration of TXA.

关键词： Tranexamic acid Infection Trauma Thromboembolic disease Minimally invasive Percutaneous

Application of Plant-Based Coagulants and Their Mechanisms in Water Treatment:A Review

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Journal of Renewable Materials 2024年第4期12卷 667-698页

作者： Abderrezzaq Benalia Kerroum Derbal zahra Amrouci Ouiem Baatache Amel Khalfaoui Antonio Pizzi Higher Normal School of Constantine Ali Mendjeli Nouvelle VilleConstantine25000Algeria Laboratory of Process Engineering for Sustainable Development and Health Products(GPDDPS) Department of Process EngineeringNational Polytechnic School of ConstantineConstantine25000Algeria Department of Environmental Engineering Laboratoire de Recherche sur le Médicament et le Développement Durable(ReMeDD)University of Salah Boubnider Constantine 3El Khroub25012Algeria Laboratory LIPE Faculty Process EngineeringUniversity of Constantine 3Ali Mendjeli Nouvelle VilleConstantine25000Algeria Laboratoire d’Etude et Recherche sur le Matériau Bois(LERMAB).Ecole Nationale Supérieure des Technologies et Industries du Bois(ENSTIB)—University of Lorraine Epinal88000France

This review describes the mechanisms of natural coagulants.It provides a good understanding of the two key processes of coagulation-flocculation:adsorption and charge neutralization,as well as adsorption and bridging.Various factors have influence the coagulation/flocculation process,including the effect of pH,coagulant dosage,coagulant type,temperature,initial turbidity,coagulation speed,flocculation speed,coagulation and flocculation time,settling time,colloidal particles,zeta potential,the effects of humic acids,and extraction density are explained.The bio-coagulants derived from plants are outlined.The impact of organic coagulants on water quality,focusing on their effects on the physicochemical parameters of water,heavy metals removal,and bacteriological water quality,is examined.The methods of extraction and purification of plant-based coagulants,highlighting techniques such as solvent extraction and ultrasonic extraction,are discussed.It also examines the parameters that influence these processes.The methods and principles of purification of coagulating agents,including dialysis,freeze-drying,ion exchange,electrophoresis,filtration,and centrifugation,are listed.Finally,it evaluates the sustainability of natural coagulants,focusing on the environmental,technical,and economic aspects of their use.At the end of this review,the readers should have a comprehensive understanding of the mechanisms,selection,extraction,purification,and sustainability of plant-based natural coagulants in water treatment.

关键词： Bio-coagulants coagulating agents extraction water treatment

利用标准化降雨指数对伊朗法尔斯省干旱危害的GIS分析

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Journal of Resources and Ecology 2024年第2期15卷 439-447页

作者： MASOUDI Masoud TAHERI zahra 伊朗设拉子大学农业学院自然资源与环境工程系伊朗设拉子13131-71441 伊朗德黑兰大学自然资源学院环境科学系伊朗德黑兰31587-77871

干旱是广泛影响经济和环境的主要自然灾害之一。因此,有必要采用诸如标准化降雨指数(SPI)等指标来研究干旱的影响,以辨析决策和规划的现实条件。本研究的目的是利用SPI指数分析伊朗南部法尔斯省的干旱空间格局。本文根据法尔斯省42个站... 详细信息

干旱是广泛影响经济和环境的主要自然灾害之一。因此,有必要采用诸如标准化降雨指数(SPI)等指标来研究干旱的影响,以辨析决策和规划的现实条件。本研究的目的是利用SPI指数分析伊朗南部法尔斯省的干旱空间格局。本文根据法尔斯省42个站点的数据,对1990-2019年间的干旱灾害格局进行了评价。评价模型中使用的干旱危害标准包括:该时期的最严重干旱程度、干旱趋势和连续干旱年的最大数量,最终的干旱灾害图是通过计算干旱强度、连续性和趋势三个指标的算术平均值获得的。三个指标的灾害图和最终灾害脆弱图采用反距离加权法(IDW)插值制图,分为无、轻度、中度、重度和极重度5个危害等级。最终的干旱脆弱性图显示,在研究区南部观察到的中度灾害区域占研究区36%,比在北部和中部观察到的严重和非常严重灾害区(占研究区64%)分布范围更小。

关键词：干旱标准化降雨指数 GIS 灾害地图反距离加权法法尔斯省