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Science china(Technological {1.) 2005年第Z1期48卷 53-64页

作者： zhang.lei1,2. li shihai1, liAN Zhenzhong1,{2. WANG {2. 1. institute of mechanics, chinese academy of sciences, beijing 1.0080, china 2. Graduate School, chinese academy of sciences, beijing 100060, china institute of {1. Chinese Academy of Sciences Beijing 100080 China Graduate School Chinese Academy of Sciences Beijing 100060 China

This paper studies the effect of fissure water pressure in different fractures on the critical angle of landslide by laboratory investigation and numerical simulation in order to understand the mechanisms of fissure water pressure on landslide stability. Laboratory observations show that the effect of fissure water pressure on the critical angle of landslide is little when the distance between water-holding fracture and slope toe is three times greater than the depth of fissure water. These experimental results are also simulated by a three-dimensional face-to-face contact discrete element method. This method has included the fissure water pressure and can accurately calculate the critical angle of jointed slope when fissure water pressure in vertical sliding surface exists. Numerical results are in good agreement with experimental observations. It is revealed that the location of water-holding structural surface is important to landslide stability. The ratio of the distance between water-holding fissure and slope toe to the depth of fissure water is a key parameter to justify the effect of fissure water pressure on the critical angle of landslide.

关键词： jointed rock slope, discrete element method, fracture in vertical sliding surface, model experiment,fissure water pressure.

Effect of rock mass structure and block size on the slope stability——Physical modeling and discrete element simulation

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Science china(Technological {1.) 2005年第Z1期48卷 1-17页

作者： li shihai1, liAN Zhenzhong1,2.& J. G. Wang3 1. {2. of {2., chinese academy of sciences, beijing 1.0080, china 2. Graduate School, chinese academy of sciences, beijing 100060, china 3. Tropical Marine Science {2., National University of Singapore, Singapore 1192.0 institute of {1. Chinese Academy of Sciences Beijing 100080 China Graduate School Chinese Academy of Sciences Beijing 100060 China Tropical Marine Science institute National University of Singapore Singapore 119260 Singapore

This paper studies the stability of jointed rock slopes by using our improved three-dimensional discrete element methods (DEM) and physical modeling. Results show that the DEM can simulate all failure modes of rock slopes with different joint configurations. The stress in each rock block is not homogeneous and blocks rotate in failure development. Failure modes depend on the configuration of joints. Toppling failure is observed for the slope with straight joints and sliding failure is observed for the slope with staged joints. The DEM results are also compared with those of limit equilibrium method (LEM). Without considering the joints in rock masses, the LEM predicts much higher factor of safety than physical modeling and DEM. The failure mode and factor of safety predicted by the DEM are in good agreement with laboratory tests for any jointed rock slope.

关键词： rock masses, slope stability, DEM simulation, block size effect, joints configuration effect, limit equilibrium method.

Structures and physical properties of rigid polyurethane foams with water as the sole blowing agent

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Science china Chemistry 2006年第4期49卷 363-370页

作者： li Xiaobin1.{1. CAO Hongbin1.& zhang Yi1.1. institute of Process Engineering,{{1., beijing 1.0080, china {1. Graduate School of the{{1., beijing 1.0039, china institute of Process Engineering Chinese Academy of Sciences Beijing China Graduate School of the chinese academy of sciences Beijing China

Rigid polyurethane foams blown by varying water level were prepared in this study. The structures and physical properties of rigid polyurethane foams blown by water were measured with FT-IR, universal testing machine (Instron3365), scanning electron microscope (SEM) and differential scanning calorimeter (DSC). The results show that polyurea and polybiuret were the typical charac- teristics, and the cream time and gel time were shorter for the fully water blown rigid foams than that for the fully cyclopentane blown foams. The density of foam samples decreased from 45.0 kg/m3 to 2..4 kg/m3 with the increase of water level from 3 pph to 7 pph. Compressive strength exhibited the similar behavior with density. The average cell size of foam samples ranged from 2.1.μm to 356 μm with the increase of water level from 3 pph to 7 pph, respectively. At the same time, poorer dimen- sional stability was encountered with the increase of average cell size due to fast diffusion rate of CO2.out of the foam. The results of thermal analysis show that the glass transition temperature (Tg) shifted to a higher temperature with the increase of isocyanate level when more water was used as chemical blowing agent.

关键词： polyether polyol, polyurethane rigid foam, compressive strength, dimensional stability, cell size, glass transition temperature.

Application of three-dimensional discrete element face-to-face contact model with fissure water pressure to stability analysis of landslide in Panluo iron mine

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Science china(Technological {1.) 2005年第Z1期48卷 146-156页

作者： zhang.lei1,2. WEI Zuoan1, liU Xiaoyu1 & li shihai1 1.{2. of mechanics, chinese academy of sciences, beijing 1.0080, china 2.Graduate School, chinese academy of sciences, beijing 100060, china institute of {1. Chinese Academy of Sciences Beijing China Graduate School Chinese Academy of Sciences Beijing China

Three-dimensional discrete element face-to-face contact model with fissure water pressure is established in this paper and the model is used to simulate three-stage process of landslide under fissure water pressure in the opencast mine, according to the actual state of landslide in Panluo iron mine where landslide happened in 1.90 and was fathered in 1.99. The calculation results show that fissure water pressure on the sliding surface is the main reason causing landslide and the local soft interlayer weakens the stability of slope. If the discrete element method adopts the same assumption as the limit equilibrium method, the results of two methods are in good agreement; while if the assumption is not adopted in the discrete element method, the critical φ numerically calculated is less than the one calculated by use of the limit equilibrium method for the sameC. Thus, from an engineering point of view, the result from the discrete element model simulation is safer and has more widely application since the discrete element model takes into account the effect of rock mass structures.

关键词： face-to-facecontactmodel, fissure water pressure, three-dimensional discrete element method,landslide.

Stochastic structural model of rock and soil aggregates by continuum-based discrete element method

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Science china(Technological {1.) 2005年第Z1期48卷 95-106页

作者： WANG yuannian1, ZHAO Manhong1. {1. shihai1 & J.G. Wang2.. {2. of mechanics, chinese academy of sciences, beijing 1.0080, china 2. Tropical Marine Science {2., National University of Singapore, 1. Kent Ridge Crescent, Singapore 1.92.0 institute of {1. Chinese Academy of Sciences Beijing China Tröpical Marine Science institute National University of Singapore Singapore

This paper first presents a stochastic structural model to describe the random geometrical features of rock and soil aggregates. The stochastic structural model uses mixture ratio, rock size and rock shape to construct the microstructures of aggregates, and introduces two types of structural elements (block element and jointed element) and three types of material elements (rock element, soil element, and weaker jointed element) for this microstructure. Then, continuum-based discrete element method is used to study the deformation and failure mechanism of rock and soil aggregate through a series of loading tests. It is found that the stress-strain curve of rock and soil aggregates is nonlinear, and the failure is usually initialized from weaker jointed elements. Finally, some factors such as mixture ratio, rock size and rock shape are studied in detail. The numerical results are in good agreement with in situ test. Therefore, current model is effective for simulating the mechanical behaviors of rock and soil aggregates.

关键词： CDEM, rock and soil aggregate, mixture ratio.

Discovery of immune related factors in Fenneropenaeus chinensis by annotation of ESTs

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Progress in Natural Science:Materials International 2004年第1期14卷 48-55页

作者： SHEN Yaoqing 1,2. , XIANG Jianhai 1*, WANG Bing 1,2. , li Fuhua 1 and TONG Wei 3(1. Experimental Marine Biology Laboratory, institute of Oceanology, chinese academy of sciences, Qingdao 2.6071,{2. 2. Graduate School of the chinese academy of sciences, beijing 100039, china 3. Genomics & Bioinformatics institute, chinese academy of sciences, beijing 101300, china) chinese Acad Sci Inst Oceanol Expt Marine Biol Lab Qingdao 266071 Peoples R China chinese Acad Sci Grad Sch Beijing 100039 Peoples R China chinese Acad Sci Geonom & Bioinformat Inst Beijing 101300 Peoples R China

A total of 1.446 expressed sequence tags (ESTs) are obtained by a large scale sequencing of a cDNA library from cephalothorax of adult Fenneropenaeus chinensis . An EST analysis platform was built up based on local computers and bioinformatic techniques were used to annotate these ESTs in order to promptly find possible functional genes, especially for immune related factors. About 4% of the ESTs show similarity to the coding sequences of such factors, including lectin, serine protease, serpin, lysozyme, etc. These ESTs provide a partial profile of the immune system in F. chinensis and useful information for further study on these genes.

关键词： Fenneropenaeus chinensis bioinformatics ESTs immune factors

Bio-regeneration of p-complexation desulfurization adsorbents

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Science china Chemistry 2005年第6期48卷 538-544页

作者： li Wangliang1,2. XING Jianmin1, XIONG Xiaochao1,2. SHAN Guobin1,2.& liU Huizhou1 1. Laboratory of Separation Science and Engineering, institute of Process Engineering,{2.,{2., china 2. Graduate School of the{2.,beijing 100039, china Laboratory of Separation Science and Engineering Institute of Process Engineering Chinese Academy of Sciences Beijing China Graduate School of the chinese academy of sciences Beijing China

The coupling of adsorption desulfurization and biodesulfurization is a new approach to produce clean fuels. Sulfur compounds are firstly adsorbed on adsorbents, and then the ad-sorbents are regenerated by microbial conversion. p-Complexation adsorbent, Cu(I)-Y, was ob-tained by ion exchanging Y-type zeolite with Cu2. and then by auto-reduction in helium at 450℃ for 3 h. Dibenzothiophene (DBT) was used as a model compound. The effects of cell concentra-tion, volume of oil phase, the ratio of aqueous phase to adsorbent on DBT desorption by a bac-terium were studied. The amounts of DBT desorbed and 2.HBP produced can be apparently increased with addition of n-octane. BDS activity can be improved by increasing cell concentra-tion and the ratio of water-to-adsorbent. 89% of DBT desorbed from the adsorbents can be converted to 2.HBP within 6 h and almost 1.0% within 2. h, when the volume ratio of oil-to-water was 1.5 mL/mL, the cell concentration was 60 g·L?1. and the ratio of adsorbent-to-oil was 0.03 g·mL?1. The amount of 2.HBP produced was strongly dependent on the volume ratio of oil-to- water, cell concentration and amount of adsorbent. Adsorption capacity of the regenerated ad-sorbent is 95% that of the fresh one after being desorbed with Pseudomonas delafieldii R-8, washed with n-octane, dried at 1.0℃ for 2. h and auto-reduced in He.

关键词： adsorption desulfurization p-complexation adsorbents bio-regeneration Pseudomonas delafieldii desorption.

Effect of concentration on surfactant micelle shapes——A molecular dynamics study

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Science china Chemistry 2005年第5期48卷 470-475页

作者： GAO Jian1.2. GE Wei1.& {1. Jinghai1.1. Multiphase Reaction Laboratory, institute of Process Engineering, chinese academy of sciences,{2., china 2. Graduate School of The chinese academy of sciences, beijing 1.0085, china Multiphase Reaction Laboratory Institute of Process Engineering Chinese Academy of Sciences Beijing China Graduate School of The chinese academy of sciences Beijing China

Many aspects of the behavior of surfactants have not been well understood due to the coupling of many different mechanisms. Computer simulation is, therefore, attractive in the sense that it can explore the effect of different mechanisms separately. In this paper, the shapes, structures and sizes of sodium dodecylbenzenesulfonate (SDBS) micelles under different con-centrations in an oil/water mixture were studied via molecular dynamics (MD) simulations using a simplified atomistic model which basically maintains the hydrophile and lipophile properties of the surfactant molecules. Above the critical micellar concentration (cmc), surfactant molecules ag-gregate spontaneously to form a wide variety of assemblies, from spherical to rodlike, wormlike and bilayer micelles. Changes in their ratios of the principle moments of inertia (g1.g3, g2.g3) in-dicated the transition of micelle shapes at different concentrations. The aggregation number of micelle is found to have a power-law dependence on surfactant concentration.

关键词： surfactant, MD simulation, sodium dodecylbenzenesulfonate, micelle shape.

Experimental and discrete element numerical analysis of side slope instability induced by fissure water underlying impervious bed

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Science china(Technological {1.) 2005年第Z1期48卷 65-80页

作者： liU Bingshan1, li shihai1, zhang.lei1,{2. WANG Jianguo31. {2. of mechanics, chinese academy of sciences, beijing 1.0080, china 2. Graduate School, chinese academy of sciences, beijing 100060, china 3. Tropical Marine Science {2., National University of Singapore, 10 Kent Ridge Crescent, Singapore 1192.0 institute of {1. Chinese Academy of Sciences Beijing 100080 China Graduate School Chinese Academy of Sciences Beijing 100060 China Tropical Marine Science institute National University of Singapore 10 Kent Ridge Crescent Singapore 119260 Singapore

When the sliding mass contains impervious bed, rainfall can infiltrate into mountain via crevices and form higher artesian aquifer at impervious bed inferior. This will decrease slip resistance and increase sliding forces of the sliding mass, thus lowering the safety factor, and inducing landslide disasters. In this paper, a landslide experimental apparatus is designed for experimental studies on the mechanism of this type of landslides. Meanwhile, the non-dimensional parameters in the model experiment are taken into account using dimensional analysis. The experimental results show that (1. the ratio of the cleft water pressure to the overlying pressure is a crucial parameter affecting the stability of the slope; (2. when the shut-in pressure reaches 80% of the normal component of the pressure on the slip surface made up of rock and soil, landslide will occur; (3) the whole slope will start to slide when the shut-in pressure is equal to the normal component of the pressure formed by the overlying rock and soil on the upper 30% area. In this article, a discrete element method simulation is used to investigate the influence of cleft water pressure and shearing strength on the landslide stability. It can be concluded that the critical value of Ccr, ?cr, which determines the slide mass stability, increases with the increase of the water pressure; if the water pressure reaches a high level, the stability of the slide mass depends mainly on C, while the influence of ? becomes smaller than C.

关键词： impervious bed, rainfall infiltration, pore water pressure, landslide experiment, displacement monitor, discrete element method.

Properties and applications of cold supersonic gas jet

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Science china(Physics,{1. & Astronomy) 2006年第6期49卷 709-715页

作者： zhang Shaofeng1,2.MA Xinwen1,2.liU Huiping2.li Bin1,2.& ZHU Xiaolong1,2.1. {2. of Modern Physics,{2. academy of sciences,Lanzhou 730000,china 2. Graduate University of chinese academy of sciences,beijing 100049,china institute of Modern Physics Chinese Academy of Sciences Lanzhou China Graduate University of chinese academy of sciences Beijing China

By analyzing the formation mechanism of a supersonic gas jet,a set of equations which describe the atomic beam properties were established. The influence of initial temperature,initial pressure,background gas pressure and pumping speed was discussed in detail. A simulation program was developed based on the equations,and the results under different initial conditions were obtained. The results are in good agreement with the experimental data,and suggest that,in order to get much smaller transverse momentum in collision experiments,it is necessary to lower the initial temperature and the initial pressure of the supersonic gas jet,together with increasing the pumping speed. These results are very instructive for construction of a new generation of cold supersonic gas jets.

关键词： cold supersonic gas jet,zone of silence,nozzle,skimmer.