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Recent advances and perspectives in MXene-based cathodes for aq.eous z.nc-ion batteries

International Journal of Minerals,Metallurgy and Materials 2024年第7期31卷 1752-1765页

作者： Aiduo Wu Tianhao Wang Long z.ang chen chen q.aomin Li Xuanhui q. Yongchang Liu Beijing Advanced Innovation Center for Materials Genome Engineering Institute for Advanced Materials and TechnologyState Key Laboratory for Advanced Metals and MaterialsUniversity of Science and Technology BeijingBeijing 100083China School of Materials Science and Engineering University of Science and Technology BeijingBeijing 100083China School of Economics and Management University of Science and Technology BeijingBeijing 100083China

Aq.eous z.nc-ion batteries(Az.Bs)show great potential for applications in grid-scale energy storage,given their intrinsic safety,cost effectiveness,environmental friendliness,and impressive electrochemical ***,strong electrostatic interactions exist between z.nc ions and host materials,and they hinder the development of advanced cathode materials for efficient,rapid,and stable z.-ion *** and their derivatives possess a large interlayer spacing,excellent hydrophilicity,outstanding electronic conductivity,and high redox *** materials are considered“rising star”cathode candidates for *** comprehensive review discusses recent advances in MXenes as Az.B cathodes from the perspectives of crystal structure,z.-storage mechanism,surface modification,interlayer engineering,and conductive network design to elucidate the correlations among their composition,structure,and electrochemical *** work also outlines the remaining challenges faced by MXenes for aq.eous z.-ion storage,such as the urgent need for improved toxic preparation methods,exploration of potential novel MXene cathodes,and suppression of layered MXene restacking upon cycling,and introduces the prospects of MXene-based cathode materials for high-performance Az.Bs.

关键词： aq.eous z.nc-ion batteries MXenes terminal groups interlayer engineering conductive network design

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The joint Laplace transforms for killed diffusion occupation times

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Applied Mathematics(A Journal of Chinese Universities) 2024年第3期39卷 398-415页

作者： LI Ying-q.u chen Ye School of Mathematics and Statistics Changsha University of Science and TechnologyChangsha 410114China College of Mathematics and Computational Science Hunan University of Arts and ScienceChangde 415000China

The approach of Li and z.ou(2014)is adopted to find the Laplace transform of occupation time over interval(0,a)and joint occupation times over semi-infinite intervals(-∞,a)and(b,∞)for a time-homogeneous diffusion process up to an independent exponential time e_(q.for 0q.ations associated with the diffusion *** these results,we obtain explicit expressions on the Laplace transform of occupation time and joint occupation time for Brownian motion with drift.

关键词： time-homogeneous diffusion process occupation time joint occupation time Laplace transform Brownian motion with drift

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Geometric phase-encoded stimuli-responsive cholesteric liq.id crystals for visualiz.ng real-time remote monitoring:humidity sensing as a proof of concept

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Light(Science & Applications) 2024年第2期13卷 283-293页

作者： Shi-Long Li z.ao-Yi chen Peng chen Wei Hu Chaohong Huang Sen-Sen Li Xuejia Hu Yan-q.ng Lu Lu-Jian chen Department of Electronic Engineering School of Electronic Science and EngineeringXiamen University361005 XiamenChina College of Engineering and Applied Sciences Nanjing University210093 NanjingChina Fujian Key Laboratory of Ultrafast Laser Technology and Applications Xiamen University361005 XiamenChina

Liq.id crystals are a vital component of modern photonics,and recent studies have demonstrated the exceptional sensing properties of stimuli-responsive cholesteric liq.id ***,existing cholesteric liq.id crystal-based sensors often rely on the naked eye perceptibility of structural color or the measurement of wavelength changes by spectrometric tools,which limits their practical ***,developing a platform that produces recogniz.ble sensing signals is *** this study,we present a visual sensing platform based on geometric phase encoding of stimuli-responsive cholesteric liq.id crystal polymers that generates real-time visual patterns,rather than freq.ency *** demonstrate this platform’s effectiveness,we used a humidity-responsive cholesteric liq.id crystal polymer film encoded with a q.plate pattern,which revealed that humidity causes a shape change in the vortex beam reflected from the encoded cholesteric liq.id crystal ***,we developed a prototype platform towards remote humidity monitoring benefiting from the high directionality and long-range transmission properties of laser beams carrying orbital angular *** approach provides a novel sensing platform for cholesteric liq.id crystals-based sensors that offers promising practical *** ability to generate recogniz.ble sensing signals through visual patterns offers a new level of practicality in the sensing field with stimuli-responsive cholesteric liq.id *** platform might have significant implications for a broad readership and will be of interest to researchers working in the field of photonics and sensing technology.

关键词： humidity visual liq.id

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Lewis Base Catalyz.d Selenofunctionaliz.tion of Alkynes with Acid-Controlled Divergent Chemoselectivity

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Chinese Journal of Chemistry 2024年第14期42卷 1623-1629页

作者： Ling-Ling chen Ren-Fei Cao Hua Ke z.i-Min chen School of Chemistry and Chemical Engineering Shanghai Key Laboratory for Molecular Engineering of Chiral DrugsShanghai Jiao Tong UniversityShanghai200240 China Engineering Technology Research Center for Environmental Protection Materials Pingxiang UniversityPingxiangJiangxi337055 China

Lewis base catalyz.d and Brønsted acid controlled chemodivergent electrophilic selenofunctionaliz.tions of alkynes were developed for the first *** selenium-containing tetrasubstituted alkenes were readily obtained in moderate to excellent yields with complete E/z.*** the substrates were 1-ethynyl naphthol derivatives,linear selenium-containing tetrasubstituted alkenes were produced via intermolecular oxygen nucleophilic attack in the absence of acid additive;in contrast,cyclic selenium-containing tetrasubstituted alkenes were generated through intramolecular carbon nucleophilic capture with the addition of Brønsted acid.

关键词： Alkynes Electrophilic addition Chemoselectivity Lewis base catalysis Selenofunctionaliz.tion

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Endogenous Security Formal Definition,Innovation Mechanisms,and Experiment Research in Industrial Internet

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Tsinghua Science and Technology 2024年第2期29卷 492-505页

作者： Hongsong chen Xintong Han Yiying z.ang School of Computer and Communication Engineering University of Science and Technology BeijingBeijing 100083China

With the rapid development of information technologies,industrial Internet has become more open,and security issues have become more *** endogenous security mechanism can achieve the autonomous immune mechanism without prior ***,endogenous security lacks a scientific and formal definition in industrial ***,firstly we give a formal definition of endogenous security in industrial Internet and propose a new industrial Internet endogenous security architecture with cost ***,the endogenous security innovation mechanism is clearly ***,an improved clone selection algorithm based on federated learning is ***,we analyz. the threat model of the industrial Internet identity authentication scenario,and propose cross-domain authentication mechanism based on endogenous key and z.ro-knowledge *** conduct identity authentication experiments based on two types of blockchains and compare their experimental *** on the experimental analysis,Ethereum alliance blockchain can be used to provide the identity resolution services on the industrial *** of Things Application(IOTA)public blockchain can be used for data aggregation analysis of Internet of Things(IoT)edge ***,we propose three core challenges and solutions of endogenous security in industrial Internet and give future development directions.

关键词： industrial Internet endogenous security architecture federated learning blockchain

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An Isolable Phosphinogermylyne as a Synthon of One-Coordinate GeⅠRadical

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Chinese Journal of Chemistry 2024年第7期42卷 736-742页

作者： Dongmin Wang Haonan chen Yuhao He Xiaodan chen Li z.ang Gengwen Tan Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education Guangdong Basic Research Center of Excellence for Functional Molecular EngineeringSchool of ChemistryIGCMESun Yat-Sen UniversityGuangzhouGuangdong 510275China School of Electronic Engineering Guangxi Universityof Science and TechnologyLiuzhouGuangxi 545000China College of Chemistry and Material Jinan UniversityGuangzhouGuangdong 510632China Innovation Center for Chemical Science College of ChemistryChemical Engineering and Materials ScienceSoochow UniversitySuzhouJiangsu 215123China Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education Hangzhou Normal UniversityHangzhouZhejiang 311121China

Reduction of chlorogermylene MsFluindtBu-GeCl 1 with potassium graphite(KC8)afforded putative germylyne radical MsFluindtBu-Ge 2 as confirmed by electron paramagnetic resonance(EPR)***,it slowly decayed via C—H bond activation at the fluorenyl moiety to yield a bis(germylene)3 at room *** using a Lewis base to stabiliz. the unoccupied p orbital at the GeⅠradical center,acyclic two-coordinate GeⅠradicals MsFluindtBu-Ge(IMe4)4(IMe4=1,3,4,5-tetramethyl-imidaz.lin-2-ylidene),MsFluindtBu-Ge(IiPr)5(IiPr=1,3-diisopropyl-4,5-dimethyl-imidaz.lin-2-ylidene),MsFluindtBu-Ge(PMe3)6 were isolated in crystalline *** unpaired electron in 4-6 mainly resides at the Ge 4p orbital as revealed by EPR spectroscopic studies and theoretical ***,facile ligand exchange of PMe3 in 6 with IMe4 and IiPr was observed to afford 4 and 5,***,phosphinogermylyne 6 reacted with PhEEPh(E=S,Se),4-tetrabutylphenylacetylene(Ar'CCH),[CpMo(CO)3]2 and nBu3SnH to furnish germylenes MsFluindtBu-GeEPh(E=S 7,Se 8),MsFluindtBu-GeCH=CHAr'9,a germylyne complex MsFluindtBu-Ge≡Mo(CO)2Cp 10 and a Ge(Ⅳ)compound MsFluindtBu-GeH2SnnBu311,*** reactivity studies demonstrate that 6 can act as a synthon of one-coordinate germylyne radical attributing to labile coordination of trimethylphosphine.

关键词： Phosphinogermylyne Germanium Radicals Donor-acceptor systems Radical reactions

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A Reverse Path Planning Approach for Enhanced Performance of Multi-Degree-of-Freedom Industrial Manipulators

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Computer Modeling in Engineering & Sciences 2024年第5期139卷 1357-1379页

作者： z.iwei Lin Hui Wang Tianding chen Yingtao Jiang Jianmei Jiang Yingpin chen Key Laboratory of Light Field Manipulation and System Integration Applications in Fujian Province School of Physics and Information EngineeringMinnan Normal UniversityZhangzhou363000China Department of Electrical and Computer Engineering University of NevadaLas Vegas89154USA College of Material Engineering Fujian Agriculture and Forestry UniversityFuzhou350000China

In the domain of autonomous industrial manipulators,precise positioning and appropriate posture selection in path planning are pivotal for tasks involving obstacle avoidance,such as handling,heat sealing,and *** Multi-Degree-of-Freedom(MDOF)manipulators offer kinematic redundancy,aiding in the derivation of optimal inverse kinematic solutions to meet position and posture req.isites,their path planning entails intricate multiobjective optimiz.tion,encompassing path,posture,and joint motion *** satisfactory results in practical scenarios remains *** response,this study introduces a novel Reverse Path Planning(RPP)methodology tailored for industrial *** approach commences by conceptualiz.ng the manipulator’s end-effector as an agent within a reinforcement learning(RL)framework,wherein the state space,action set,and reward function are precisely defined to expedite the search for an initial collision-free *** enhance convergence speed,the q.learning algorithm in RL is augmented with ***,we formulate the cylindrical bounding box of the manipulator based on its Denavit-Hartenberg(DH)parameters and propose a swift collision detection ***,the motion performance of the end-effector is refined through a bidirectional search,and joint weighting coefficients are introduced to mitigate motion in high-power *** efficacy of the proposed RPP methodology is rigorously examined through extensive simulations conducted on a six-degree-of-freedom(6-DOF)manipulator encountering two distinct obstacle configurations and target *** results substantiate that the RPP method adeptly orchestrates the computation of the shortest collision-free path while adhering to specific posture constraints at the target ***,itminimiz.s both posture angle deviations and joint motion,showcasing its prowess in enhancing the operational performance of MDOF industrial manipulators.

关键词： Reverse path planning Dyna-q bidirectional search posture angle joint motion

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KINETIC STUDY OF SPINEL LiMn_2O_4 SYNTHESIz.D BY SOLID REACTION WITH SOFT-CHEMICAL METHOD

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Acta Metallurgica Sinica(English Letters) 2005年第4期18卷 512-518页

作者： C.q. Xu Y. W. Tian Y. C. z.ai z.J. Guo z. q. Huang School of Materials and Metallurgy Northeastern University Shenyang 110004 China

The differential thermal analysis （DTA） curves were measured at different heating rates in flowing air for studying the synthesis of the spinel LiMn2O3 with Li2CO3 and MnO2, The reaction began at about 503K, and finished at about 873K. The apparent activation energy of Kissinger method was about ***^-1, the reaction orderwas 1.67, the freq.ency factor was 7.81×10^9, and therefore the dinetic epuation was dδ/dt=A·exp（- E/RT）·（1-δ）^n=7.81×10^9, exp（-122770/RT）·（l-δ）^1.67 . Coats-Redfem integral method was used to analyz. the DTA curves of the samples at different heating rates, and the calculated apparent activation energy and freq.ency factor were 112. 13kJ· mol^-1 and 1.18 × 10^9, respectively, rather close to that of Kissinger method. X-ray diffraction （XRD） and scanning electron microscope （SEM） results shown that the synthesiz.d LiMn2O3 possesses pure phase, regular shape and normal particle distribution.

关键词： lithium manganese oxides synthesiz.d kinetics Kissinger method,Coats-Redfern integral method

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Numerical Simulation of the Settling Flux of Biodeposition in a Bay with Cage Culture Through Similarity Theory and a Simplified Pollution Source

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Journal of Ocean University of China 2024年第1期23卷 247-254页

作者： LIU Yao chen Yifan GE Changz. Marine College Shandong UniversityWeihai 264209China

The settling flux of biodeposition affects the environmental q.ality of cage culture areas and determines their environmental carrying *** and effective simulation of the settling flux of biodeposition is extremely important for determining the spatial distribution of ***,biodeposition in cage culture areas without specific emission rules can be simplified as point source *** is a fluid simulation software that can simulate the dispersion of particulate matter simply and *** on the simplification of pollution sources and bays,the settling flux of biodeposition can be easily and effectively simulated by Fluent fluid *** the present work,the feasibility of this method was evaluated by simulation of the settling flux of biodeposition in Maniao Bay,Hainan Province,China,and 20 sampling sites were selected for determining the settling *** sampling sites P1,P2,P3,P4,P5,z.,z.,z.,z.,A1,A2,A3,A4,B1,B2,C1,C2,C3 and C4,the measured settling fluxes of biodeposition were 26.02,15.78,10.77,58.16,6.57,72.17,12.37,12.11,106.64,150.96,22.59,11.41,18.03,7.90,19.23,7.06,11.84,5.19 and 2.57 g d^(−1)m^(−2),*** simulated settling fluxes of biodeposition at the corresponding sites were 16.03,23.98,8.87,46.90,4.52,104.77,16.03,8.35,180.83,213.06,39.10,17.47,20.98,9.78,23.25,7.84,15.90,6.06 and 1.65 g d^(−1)m^(−2),*** was a positive correlation between the simulated settling fluxes and measured ones(R=0.94,P=2.22×10^(−9)<0.05),which implies that the spatial differentiation of biodeposition flux was well ***,the posterior difference ratio of the simulation was 0.38,and the small error probability was 0.94,which means that the simulated results reached an acceptable level from the perspective of relative ***,if nonpoint source pollution is simplified to point source pollution and open waters are simplified based on similarity theory,the setting flux of biodeposition i

关键词： fluent fluid simulation software pollution source simplification posterior difference ratio similarity theory Spear-man correlation

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q.antitative prediction model for the depth limit of oil accumulation in the deep carbonate rocks:A case study of Lower Ordovician in Taz.ong area of Tarim Basin

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Petroleum Science 2024年第1期21卷 115-124页

作者： Wen-Yang Wang Xiong-q. Pang Ya-Ping Wang z.ang-Xin chen Fu-Jie Jiang Ying chen State Key Laboratory of Lithospheric Evolution Institute of Geology and GeophysicsChinese Academy of SciencesBeijing100029China State Key Laboratory of Petroleum Resources and Prospecting China University of Petroleum(Beijing)Beijing102249China College of Geosciences China University of Petroleum(Beijing)Beijing102249China Research Institute of Exploration and Development PetroChina Southwest Oil&Gas Field CompanyChengdu610041SichuanChina Chemical and Petroleum Engineering Schulich School of EngineeringUniversity of CalgaryCalgaryT2N 1N4Canada

With continuous hydrocarbon exploration extending to deeper basins,the deepest industrial oil accumulation was discovered below 8,200 m,revealing a new exploration ***,the extent to which oil exploration can be extended,and the prediction of the depth limit of oil accumulation(DLOA),are issues that have attracted significant attention in petroleum *** it is difficult to characteriz. the evolution of the physical properties of the marine carbonate reservoir with burial depth,and the deepest drilling still cannot reach the ***,the DLOA cannot be predicted by directly establishing the relationship between the ratio of drilling to the dry layer and the *** this study,by establishing the relationships between the porosity and the depth and dry layer ratio of the carbonate reservoir,the relationships between the depth and dry layer ratio were obtained *** depth corresponding to a dry layer ratio of 100%is the *** on this,a q.antitative prediction model for the DLOA was finally *** results indicate that the porosity of the carbonate reservoir,Lower Ordovician in Taz.ong area of Tarim Basin,tends to decrease with burial depth,and manifests as an overall low porosity reservoir in deep *** critical porosity of the DLOA was 1.8%,which is the critical geological condition corresponding to a 100%dry layer ratio encountered in the *** depth of the DLOA was 9,000 *** study provides a new method for DLOA prediction that is beneficial for a deeper understanding of oil accumulation,and is of great importance for scientific guidance on deep oil drilling.

关键词： Deep layer Tarim Basin Hydrocarbon accumulation Depth limit of oil accumulation Prediction model

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