检索结果-南通市图书馆

An in-depth understanding of improvement strategies and corresponding characterizations towards Zn anode in aqueous Zn-ions batteries

引用

Green Energy & Environment 2023年第4期8卷 1006-1042页

作者： Yuzhu Chu Lingxiao Ren Zhenglin Hu Chengde Huang Jiayan Luo Key Laboratory for Green Chemical Technology of Ministry of Education School of Chemical Engineering and TechnologyTianjin UniversityTianjin300072China Key Laboratory of Materials Processing and Mold(Zhengzhou University) Ministry of EducationZhengzhou450002China Shanghai Key Lab of Advanced High-Temperature Materials and Precision Forming School of Materials Science and EngineeringShanghai Jiao Tong UniversityShanghai200240China

Combining the unique advantages of aqueous electrolytes and metallic Zn anode, rechargeable aqueous Zn-ion batteries(ZIBs) are of great promise for large-scale energy storage applications due to their inherent high safety, low cost, and environmental friendliness. As the essential component of ZIBs, Zn metal anode suffers from severe dendrite formation and inevitable side reactions(e.g. corrosion and hydrogen evolution)in aqueous electrolytes, which leads to low Coulombic efficiency and inferior cycling stability, impeding their large-scale applications. To be compatible with satisfactory aqueous ZIBs, Zn anode has been modified from various perspectives and focus areas. Herein, based on their intrinsic characteristics, we review the related improvement strategies for Zn anode, including interphase, substrate, and bulk design, so as to achieve an in-depth understanding of Zn anode optimization. Furthermore, the timely summary of characterization methods for Zn anodes are also performed for the first time, from both thermodynamic and kinetics perspectives, which is particularly helpful for beginners to understand the complicated characterizations and employ suitable methods. Finally, certain noteworthy points are put forward for subsequent investigation of aqueous ZIBs. It is expected that this review will enlighten researchers to explore more efficient optimization strategies for Zn anode in aqueous electrolytes.

关键词： Zn anodes Corrosion Dendrite Batteries Electrolyte

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Highly Efficient Aligned Ion‑Conducting Network and Interface Chemistries for Depolarized All‑Solid‑State Lithium Metal Batteries

引用

Nano-Micro Letters 2024年第5期16卷 102-119页

作者： Yongbiao Mu Shixiang Yu yuzhu Chen Youqi chu Buke Wu Qing Zhang Binbin Guo Lingfeng Zou Ruijie Zhang Fenghua Yu Meisheng Han Meng Lin Jinglei Yang Jiaming Bai Lin Zeng Shenzhen Key Laboratory of Advanced Energy Storage Southern University of Science and TechnologyShenzhen 518055People’s Republic of China Department of Mechanical and Energy Engineering Southern University of Science and TechnologyShenzhen 518055People’s Republic of China SUSTech Energy Institute for Carbon Neutrality Southern University of Science and TechnologyShenzhen 518055People’s Republic of China Department of Mechanical and Aerospace Engineering Hong Kong University of Science and TechnologyKowloon 997077Hong Kong Special Administrative Region of ChinaPeople’s Republic of China HKUST Shenzhen-Hong Kong Collaborative Innovation Research Institute FutianShenzhenPeople’s Republic of China

Improving the long-term cycling stability and energy density of all-solid-state lithium(Li)-metal batteries(ASSLMBs)at room temperature is a severe challenge because of the notorious solid–solid interfacial contact loss and sluggish ion transport.Solid electrolytes are generally studied as two-dimensional(2D)structures with planar interfaces,showing limited interfacial contact and further resulting in unstable Li/electrolyte and cathode/electrolyte interfaces.Herein,three-dimensional(3D)architecturally designed composite solid electrolytes are developed with independently controlled structural factors using 3D printing processing and post-curing treatment.Multiple-type electrolyte films with vertical-aligned micro-pillar(p-3DSE)and spiral(s-3DSE)structures are rationally designed and developed,which can be employed for both Li metal anode and cathode in terms of accelerating the Li+transport within electrodes and reinforcing the interfacial adhesion.The printed p-3DSE delivers robust long-term cycle life of up to 2600 cycles and a high critical current density of 1.92 mA cm^(−2).The optimized electrolyte structure could lead to ASSLMBs with a superior full-cell areal capacity of 2.75 mAh cm^(−2)(LFP)and 3.92 mAh cm^(−2)(NCM811).This unique design provides enhancements for both anode and cathode electrodes,thereby alleviating interfacial degradation induced by dendrite growth and contact loss.The approach in this study opens a new design strategy for advanced composite solid polymer electrolytes in ASSLMBs operating under high rates/capacities and room temperature.

关键词： All-solid-state lithium metal batteries Composite solid electrolyte 3D printing Areal capacity Interfacial degradation

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Support induced phase engineering toward superior electrocatalyst

引用

Nano Research 2022年第3期15卷 1831-1837页

作者： Beibei Sheng Dengfeng Cao Hongwei Shou Oyawale Adetunji Moses Wenjie Xu Yujian Xia yuzhu Zhou Huijuan Wang Ping Wan Shuang Zhu Wangsheng chu Xiaojun Wu Shuangming Chen Li Song National Synchrotron Radiation Laboratory CAS Center for Excellence in NanoscienceUniversity of Science and Technology of ChinaHefei 230026China Hefei National Laboratory for Physical Sciences at the Microscales Department of Materials Sciences and EngineeringUniversity of Science and Technology of ChinaHefei 230026China Experimental Center of Engineering and Material Science University of Science and Technology of ChinaHefei 230026China Materials Interfaces Center Shenzhen Institutes of Advanced TechnologyChinese Academy of SciencesShenzhen 440305China Institute of Energy Hefei Comprehensive Nation Science CenterHefei 230031China

The phase transformation of catalysts has been extensively observed in heterogeneous catalytic reactions that hinder the long cycling catalysis,and it remains a big challenge to precisely control the active phase during the complex conditions in electrochemical catalysis.Here,we theoretically predict that carbon-based support could achieve the phase engineering regulation of catalysts by suppressing specific phase transformation.Taken single-walled carbon nanotube(SWCNT)as typical support,combined with calculated E-pH(Pourbaix)diagram and advanced synchrotron-based characterizations technologies prove there are two different active phases source from cobalt selenide which demonstrate that the feasibility of using support effect regulating the potential advantageous catalysts.Moreover,it is worth noting that the phase engineering derived Co_(3)O_(4)-SWCNT exhibits a low overpotential of 201 mV for delivering the current density of 10 mA/cm^(2)in electrocatalytic oxygen evolution reaction(OER).Also,it reaches a record current density of 529 mA/cm^(2)at 1.63 V(vs.RHE)in the electrocatalytic urea oxidation reaction(UOR),overwhelming most previously reported catalysts.

关键词： phase engineering support synchrotron radiation characterization oxygen evolution reaction(OER) urea oxidation reaction(UOR)

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Qualitative Analyses of Correlations between Strong Ground Motions of the Three Large Earthquakes and Landslide Distributions

引用

Journal of Earth Science 2023年第2期34卷 369-380页

作者： yuzhu Bai Chong Xu Institute of Geology China Earthquake AdministrationBeijing 100029China National Institute of Natural Hazards Ministry of Emergency Management of ChinaBeijing 100085China Key Laboratory of Compound and Chained Natural Hazards Dynamics Ministry of Emergency Management of ChinaBeijing 100085China

In this work,the correlations between spatial distributions of landslide point density(LPD)and strong ground motions of the three strong earthquakes are qualitatively investigated.Meanwhile the qualitative relationship between the distribution of LPD and the fault rupture process is also characterized.Three strong events are the Lushan,Wenchuan,and Jiuzhaigou earthquakes.In order to reconstruct the near filed strong ground motions and the fault processes of these earthquakes,the broadband ground simulation method of University of California Santa Barbara(UCSB)and the simplified crustal layer structures are applied.To show the rationality of the UCSB method,the fault slip distributions of the three earthquakes reconstructed by the kinematic rupture generator model in the UCSB method are compared with those by inversed.Furthermore,the validation of the UCSB method for the three earthquakes is also carried according to the validation exercise of the Southern California Earthquake Center(SCEC)Broadband Platform(BBP).Lastly,the fields of peak ground acceleration(PGA)and peak ground velocity(PGV)in three mutually perpendicular directions of the three earthquakes are achieved.Generally,the landslide distribution length of large LPD values along the fault strike is less than the fault strike length.Therefore,the slip modes of earthquake faults affect the distributions of landslides.For the strike slip earthquakes,the distributions of large LPD values relate well to PGA and PGV components of the parallel and normal to the fault strike.For the reverse slip earthquakes,distributions of LPD relate to ground motion components in all directions.Moreover,distributions of landslides in near fields of earthquakes are significantly affected by the focus parameters and fault scales.

关键词： Lushan earthquake Wenchuan earthquake Jiuzhaigou earthquake landslide ground motions engineering geology

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Decoupled δ^(13)Ccarb and δ^(13)Corg records at Triassic–Jurassic boundary interval in eastern Tethys: Environmental implications for spatially different global response

引用

Geoscience Frontiers 2021年第4期12卷 175-184页

作者： yuzhu Ge Department of Earth Sciences Khalifa University of Science and TechnologyPO Box 127788Abu DhabiUnited Arab Emirates Institute of Geology Mineralogy and GeophysicsRuhr-University Bochum44780 BochumGermany

Althoughδ^(13)C data(eitherδ^(13)Ccarb orδ^(13)Corg)ofmany Triassic–Jurassic(T-J)sections have been acquired,pairedδ^(13)Ccarb andδ^(13)Corg from continuous T-J carbonate sections,especially in eastern Tethys,have been scarcely reported.This study presents paired and decoupledδ^(13)Ccarb andδ^(13)Corg data from a continuous T-J carbonate section in Wadi Naqab.The T-J Wadi Naqab carbonate section,located in United Arab Emirates,Middle East,represents tropical and shallow marine sedimentation in eastern Tethys.At the T-J boundary interval,an initial carbon isotope excursion(CIE)is observed with different magnitude of isotope excursion and timing inδ^(13)Ccarb andδ^(13)Corg,while subsequently a positive CIE is only distinct inδ^(13)Ccarb.Based on petrological,carbon isotope,Rock-Eval and elemental analyses,theδ^(13)Ccarb is thought to record marine inorganic carbon,and theδ^(13)Corg to record terrigenous organic carbon.Therefore,the pairedδ^(13)Ccarb andδ^(13)Corg herein potentially document simultaneous changes in T-J atmospheric and marine settings of eastern Tethys.Their decoupled behavior may likely be caused by different changes or evolution of carbon pool between marine and atmospheric settings.The initial CIE present in bothδ^(13)Ccarb andδ^(13)Corg may indicate influence of isotopically light carbon release related to CAMP activity in both atmospheric and marine settings.The following positive CIE only inδ^(13)Ccarb suggests relatively steady carbon isotope composition in atmosphere,but enhanced burial of isotopically light carbon in marine settings.Furthermore,the T-J carbonates in the studied section were possibly deposited in normal and oxic shallow marine conditions.Global correlation based on the Wadi Naqab section and other T-J sections suggests spatially different T-J environmental parameters:in eastern Tethys and western Panthalassa,oxic condition,lacking organic-rich sediment,weaker ocean acidification and less influence of isotopically light carbon are more prevalent;in western Tethys and eastern P

关键词： Triassic–Jurassic δ^(13)C records Eastern Tethys Global difference

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Simultaneous quantification of ginsenoside Rg1 and its metabolites by HPLC–MS/MS:Rg1 excretion in rat bile, urine and feces

引用

Acta Pharmaceutica Sinica B 2016年第6期6卷 593-599页

作者： Chiyu He Ru Feng Yupeng Sun Shifeng chu Ji Chen Chao Ma Jie Fu Zhenxiong Zhao Min Huang Jiawen Shou Xiaoyang Li yuzhu Wang Jinfeng Hu Yan Wang Juntian Zhang State Key Laboratory of Bioactive Substances and Functions of Natural Medicines Institute of Materia MedicaChinese Academy of Medical Sciences Beijing Analytical Application Center Shimadzu (China) Co. Ltd.

Ginsenoside Rg1(Rg1), the major effective component of ginseng, has been shown to have multiple bioactivities, but low oral bioavailability. The aim of this study was to develop a simple, sensitive and rapid high performance liquid chromatography–tandem mass spectrometry(LC–MS/MS) method, which could be used to validate and quantify the concentrations of Rg1 and its metabolites in Sprague-Dawley rat bile,urine, and feces after oral administration(25 mg/kg). Calibration curves offered satisfactory linearity(r40.995)within the determined ranges. Both intra-day and inter-day variances were less than 15%, and the accuracy was within 80–120%. The excretion recoveries of Rg1, ginsenoside Rh1(Rh1), and protopanaxatriol(Ppt) in bile,urine, and feces combined were all greater than 70%. The fecal excretion recoveries of Rg1, Rh1, and Ppt were40.11%, 22.19%, and 22.88%, respectively, whereas 6.88% of Rg1 and 0.09% of Rh1 were excreted in bile.Urinary excretion accounted for only 0.04% of Rg1. In conclusion, the observed excretion profiles for Rg1 and its metabolites after oral administration are helpful for understanding the poor oral bioavailability of Rg1 and will aid further investigations of Rg1 as a pharmacologically active component.

关键词： Ginsenoside Rg1 Ginsenoside Rh1 Protopanaxatriol Excretion LC–MS/MS

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

基于增益连续扩张状态观测器的永磁同步电机电流解耦控制

引用

中国电机工程学报 2020年第6期40卷 1985-1996页

作者：杨淑英王玉柱储昭晗谢震合肥工业大学电气与自动化工程学院安徽省合肥市230009

为解决传统电流解耦控制方法在电感参数失配时解耦效果不佳的问题,提出一种基于增益连续扩张状态观测器(extended state observer,ESO)的电流解耦控制方法。该方法通过ESO获得了电阻压降、交叉耦合、以及其他确定和不确定因素所引起扰... 详细信息

为解决传统电流解耦控制方法在电感参数失配时解耦效果不佳的问题,提出一种基于增益连续扩张状态观测器(extended state observer,ESO)的电流解耦控制方法。该方法通过ESO获得了电阻压降、交叉耦合、以及其他确定和不确定因素所引起扰动的综合观测和补偿。扰动补偿控制不仅实现了励磁和转矩控制回路间的解耦,而且将各子系统控制对象简化为一阶积分环节,从而使得调节器无需积分项,简化了设计,克服积分饱和所带来的不利影响。与基于fal()函数的常规ESO不同,文中提出了一种具有连续可微特性的非线性函数,在优化fal()函数"大误差小增益,小误差大增益"特性的同时,克服其增益在切换点处的突变问题,且所提非线性函数具有统一表达式,避免切换点判断。论文对ESO参数选择、系统稳定性等进行了讨论。最后,通过实验进行验证。

关键词：永磁同步电机解耦控制增益连续扩张状态观测器鲁棒性

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Endomembrane-biased dimerization of ABCG16 and ABCG25 transporters determines their substrate selectivity in ABA-regulated plant growth and stress responses

引用

Molecular Plant 2024年第3期17卷 478-495页

作者： Yeling Zhou yuzhu Wang Dong Zhang Jiansheng Liang institute of Plant and Food Science Department of BiologySchool of Life SciencesSouthern University of Science and Technology(SUSTech)Shenzhen 518055China Key Laboratory of Molecular Design for Plant Cell Factory of Guangdong Higher Education Institutes Southern University of Science and Technology(SUSTech)Shenzhen 518055China jiangsu Key Laboratory of Crop Genetics and Physiology/Co-lnnovation Center for Modern Production Technology of Grain Crops Key Laboratory of Plant Functional Genomics of the Ministry of EducationYangzhou UniversityYangzhou 225009China

ATP-binding cassette(ABC)transporters are integral membrane proteins that have evolved diverse func-tions fulfilled via the transport of various substrates.In Arabidopsis,the G subfamily of ABC proteins is particularly abundant and participates in multiple signaling pathways during plant development and stress responses.In this study,we revealed that two Arabidopsis ABCG transporters,ABCG16 and ABCG25,engage in ABA-mediated stress responses and early plant growth through endomembrane-specific dimerization-coupled transport of ABA and ABA-glucosyl ester(ABA-GE),respectively.We first revealed that ABCG16 contributes to osmotic stress tolerance via ABA signaling.More specifically,ABCG16 induces cellular ABA efflux in both yeast and plant cells.Using FRET analysis,we showed that ABCG16 forms oblig-atory homodimers for ABA export activity and that the plasma membrane-resident ABCG16 homodimers specifically respond to ABA,undergoing notable conformational changes.Furthermore,we demonstrated that ABCG16 heterodimerizes with ABCG25 at the endoplasmic reticulum(ER)membrane and facilitates the ER entry of ABA-GE in both Arabidopsis and tobacco cells.The specific responsiveness of the ABCG16-ABCG25 heterodimer to ABA-GE and the superior growth of their double mutant support an inhib-itory role of these twoABCGs in early seedling establishment via regulation of ABA-GE translocation across the ER membrane.Our endomembrane-specific analysis of the FRET signals derived from the homo-or heterodimerized ABcG complexes allowed us to link endomembrane-biased dimerization to the transloca-tion of distinct substrates by ABcG transporters,providing a prototypic framework for understanding the omnipotence of ABcG transporters in plant development and stress responses.

关键词： abscisic acid ABCG transporter dimerization endomembrane substrate selectivity

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

基于沙因组织文化模型探究公立医院廉洁文化建设路径

引用

现代医院 2023年第7期23卷 1000-1003页

作者：潘禹竹褚美娟刘朝阁天津市儿童医院//天津大学儿童医院天津300134 天津市口腔医院天津300041

近年来,我国反腐败斗争不断深入,医疗领域不断发展,公立医院廉洁文化建设面临越来越大的挑战和压力。如何建立和发展一种符合医疗领域特点的廉洁文化,成为了当前需要思考和解决的问题。而在探究公立医院廉洁文化建设路径时,沙因组织文... 详细信息

近年来,我国反腐败斗争不断深入,医疗领域不断发展,公立医院廉洁文化建设面临越来越大的挑战和压力。如何建立和发展一种符合医疗领域特点的廉洁文化,成为了当前需要思考和解决的问题。而在探究公立医院廉洁文化建设路径时,沙因组织文化模型可能是一个值得借鉴的工具和思路。基于此,笔者应用沙因组织文化模型对公立医院廉洁文化建设的关键路径进行深入探究,从物质层面、制度层面、假设层面三个方面探究加强公立医院廉洁文化建设的关键路径,为公立医院廉洁文化建设提供新的发展思路。

关键词：沙因组织文化模型公立医院廉洁文化

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Global Existence and Time-decay Rates of Solutions to 2D Magneto-micropolar Fluid Equations with Partial Viscosity

引用

Journal of Partial Differential Equations 2022年第2期35卷 173-198页

作者： LU Cheng WANG yuzhu School of Mathematics and Statistics North China University of Water Resources and Electric PowerZhengzhou 450011China

In this paper,we investigate the initial value problem for the two-dimensiona magneto-micropolar fluid equations with partial viscosity.We prove that global existence of smooth large solutions by the energy method.Furthermore,with aid of the Fourier splitting methods,optimal time-decay rates of global smooth large solutions are also established.

关键词： Magneto-micropolar fluid equations with partial viscosity global smooth large solutions time-decay rates

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

欢迎您,

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

请选择保存的检索档案：

请选择收藏分类：

通借通还

欢迎您,

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：