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Universal design of three-dimensional porous graphene-iron based promotors for kinetically rationalized lithium-sulfur chemistry

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Journal of Energy Chemistry 2025年第1期100卷 192-200页

作者： Hua gao Yunfeng Zhang Menglei Wang Ruoxuan Yang Shuai feng Xuan Cao Yaping Zhang Zhongyuan Lu Yingze Song State Key Laboratory of Environment-Friendly Energy Materials School of Materials and Chemistry Southwest University of Science and Technology School of Material Science and Engineering Henan University of Technology College of Chemistry and Chemical Engineering Taishan University

Lithium-sulfur （Li-S） batteries are widely deemed to be one of the most potential candidates for future secondary batteries because of their remarkable energy ***,notorious polysulfide shuttling and retarded sulfur reaction kinetics pose significant obstacles to the further application of Li-S *** rationally designed highly active electrocatalysts can facilitate polysulfide conversion,the universal and scalable synthesis strategies need to be ***,a universal synthetic strategy to construct a series of three-dimensional （3D） porous graphene-iron （3Dgr-Fe） based electrocatalysts involving 3Dgr-FeP,3Dgr-Fe3C,and 3Dgr-Fe3Se4is exploited for manipulating the Li-S redox *** has been observed that the implementation of a 3D porous gr architecture leads to the well-designed conductive networks,while the uniformly dispersed iron nanoparticles introduce an abundance of active sites,fostering the lithium polysulfide conversion,thereby bolstering the overall electrochemical *** Li-S battery with the 3Dgr-Fe based electrocatalyst exhibits remarkable capacity retention of 94.8%upon 100 times at 0.2 ***,the soft-packaged Li-S pouch cell based on such a 3Dgr-Fe electrocatalyst delivers superior capacity of 1060.71 mA h g-1and guarantees for the continuous 30 min work of fan *** investigation gives comprehensive insights into the design,synthesis,and mechanism of 3Dgr-Fe based electrocatalysts with high activity toward efficient and durable Li-S batteries.

关键词： Redox reactions

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Alkaline leaching mechanism of MSWI bottom ash: the pivotal role of Si(Al) chemical bonding environments

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Science China Technological Sciences 2025年

作者： Ningning SHAO Zekun JIAO Weipeng feng Yu JIN Fanlong KONg Zhijun DONg Zuotai ZHANg Institute of Technology for Marine Civil Engineering Shenzhen Institute of Information Technology (SZIIT) guizhou NASH Ecological Technology Co. LTD School of Environmental Science and Engineering Key Laboratory of Municipal Solid Waste Recycling Technology and Management of Shenzhen City Southern University of Science and Technology (SUSTech)

Municipal solid waste incineration bottom ash(MSWIBA) is a complex assemblage of aluminosilicate materials encompassing diverse solid wastes. Thus, its complexity poses great challenges to their resource utilization. For the sake of the alkali activation use of MSWIBA, this work focused on the characterizations and alkaline leaching experiments of various classified MSWIBA after sorting. Among the different categories of MSWIBA, waste glass(BA-g) and other unidentified slags(BA-O) were identified as potential precursors for alkali activation use. The alkaline leaching experiments proved that alkaline concentration, reaction temperature, reaction time, and raw material classification influenced the leaching process and results. Among these, the Si/Al chemical bonding environments from the material type played a pivotal role. When the materials had Qn(n>2) as the primary bonding structure, steric hindrance by the chain frameworks affected the alkali dissolution process, resulting in gradual disintegration from the outer layers inward. For the materials dominated by Q1frameworks, OH-could penetrate the frameworks, leading to their rapid depolymerization and outward dissolution. Overall, the Si/Al bonding environment played a crucial role in alkaline dissolution, providing theoretical guidance for classifying the alkali-activation utilization of MSWIBA and other aluminosilicate solid wastes.

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Metal-organic frameworks with dinuclear metal centers for synergistically boosting CO2 photoreduction

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Science China Chemistry 2025年第01期 201-208页

作者： Hui-feng Wang Wen-Jie Shi Yu-Xin Yang Bao-Xia Dong Tong-Bu Lu Di-Chang Zhong School of Chemistry and Chemical Engineering Yangzhou University Institute for New Energy Materials and Low Carbon Technologies School of Materials Science and Engineering Tianjin University of Technology

Dinuclear metal synergistic catalysis （DMSC） has been proved powerful in boosting CO2reduction,while this has not been achieved in heterogeneous catalysts with long-range order *** this study,we,by introduction of metal catalytic centers into an indium-based metal-organic framework （MOF）,obtained a series of isostructural In-MOFs,including three MOFs with mononuclear metal catalytic center （M-In）,three MOFs with dinuclear homometallic catalytic centers （MM-In）,and three MOFs with dinuclear heterometallic catalytic centers (MM’-In,M/M’=Co（II）,Ni（II）,Zn（II）).It was found that all these MOFs can serve as catalysts for photochemical CO2reduction to *** with M-In,the catalytic activities of MM-In were obviously enhanced,and that of MM’-In was further significantly *** example,the CO yield of Co Zn-In reaches a record value of 12,700μmol g-1h-1,which is 4.0,8.1,9.4,and 18.6-fold higher than that of Co Co-In,Zn Zn-In,Co-In,and Zn-In,***,the catalytic activities of Co Ni-In and Ni Zn-In also show different fold increase than those of corresponding dinuclear homometallic and mononuclear metallic *** results of control experiments and theoretical calculation reveal that the higher catalytic activities of MM-In over M-In can be ascribed to the DMSC effect,and the higher catalytic activity of MM’-In over MM-In can be ascribed to the strengthened DMSC *** work reveals the relationship between DMSC effect and bimetal centers in CO2reduction,which provides new insights into the DMSC and paves a new way to design highly active catalysts for photochemical CO2reduction.

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Engineering N3C vacancies in hierarchical porous carbon nitride nanosheets for room temperature ultradeep photocatalytic aerobic oxidative desulfurization

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Science China Chemistry 2025年

作者： Yina Nie Weijie Yang Xin Wang Xiang Li Lele Wei Xiaolin Bai Lin Liu feng Fu Jun Wan College of Chemistry & Chemical Engineering Research Institute of Comprehensive Energy Industrial Technology Shaanxi Key Laboratory of Chemical Reaction Engineering Yan'an University Anhui Engineering Research Center of Carbon Neutrality College of Chemistry and Materials Science Anhui Normal University

The production of ultra-low sulfur clean fuels holds global significance for improving energy efficiency and reducing environmental pollution. Photocatalytic aerobic oxidative desulfurization（PODS） offers an attractive approach to efficiently remove refractory heterocyclic aromatic sulfur compounds under mild conditions. However, the sluggish charge dynamics,insufficient molecule activation, and slow mass transfer within photocatalysts restrict the overall desulfurization efficiency,hindering the widespread application of this technology. Herein, we developed a defective g-C3N4（M1U3CN） photocatalyst with bridged N3Cvacancies and hierarchical porous structures to address these limitations. This catalyst not only demonstrates outstanding dibenzothiophene（DBT） removal efficiency of 99.6% for model oil with high conversion and selectivity but also achieves complete sulfur removal from gasoline as well as 96.7% sulfur removal for distilled diesel at room temperature,successfully achieving ultradeep aerobic oxidative desulfurization. The introduction of rich N3Cvacancies and abundant micromeso-macroporous distribution in M1U3CN enhances kinetic efficiencies by promoting charge carrier separation, mass transfer,and molecular activation simultaneously; resulting in exceptional PODS performance. This work provides a collaborative strategy to overcome kinetic challenges in aerobic oxidative desulfurization via defect and structural engineering of the catalyst.

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MDCFS: few-shot object detection with multilevel decoupled classifiers

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Optoelectronics Letters 2025年

作者： LI Chuanhui ZHOU Mian feng Zhikun SUI Zezhou gAO Zhan School of Computer Science and Engineering， Tianjin University of Technology

Few-shot object detection poses unique challenges as it requires effectively learning novel classes with limited labeled data. Current approaches often suffer from biases towards base classes during fine-tuning， leading to suboptimal performance on detecting novel classes. Additionally， in complex scenes， the confusion between foreground and background objects further affects the accuracy and robustness of the model. To address these issues， we propose the Multilevel Decoupling Classification Few-Shot Algorithm (MDCFS). we decouple the standard classifier into a parallel foreground classifier and a background classifier in the Few-Shot Object Detection (FSOD) setting. This decoupling enables the independent separation of positive samples from noisy negative samples， alleviating the foreground-background confusion problem commonly encountered in few-shot detectors. For generalized Few-Shot Object Detection (g-FSOD)， where the few-shot dataset contains base classes， we further decouple the foreground classification head into a base class classification head and a novel class classification head. To ensure balance， we assign more weight to the novel class classification head， effectively addressing the bias towards base classes. Furthermore， we optimize the initial weights of the few-shot fine-tuning stage， significantly reducing training time and mitigating catastrophic forgetting in g-FSOD. Additionally， we incorporate metric learning into our model with minimal cost. Experimental results demonstrate the effectiveness of our approach. Compared to state-of-the-art few-shot object detection methods based on fine-tuning， MDCFS achieves performance improvements of up to 6.3% on the PASCAL VOC dataset and 1.5% on the COCO dataset.

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Peri-centrosomal localization of small interfering RNAs in C. elegans

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Science China Life Sciences 2025年

作者： Qile Jin Xuezhu feng Minjie Hong Ke Wang Xiangyang Chen Jiewei Cheng Yan Kuang Xiaoyue Si Mingjing Xu Xinya Huang Shouhong guang Chengming Zhu Department of Obstetrics and gynecology The First Affiliated Hospital of USTC The USTC RNA Institute Hefei National Research Center for Physical Sciences at the Microscale School of Life Sciences Division of Life Sciences and Medicine Biomedical Sciences and Health Laboratory of Anhui Province University of Science and Technology of China School of Basic Medicine Anhui Medical University

The centrosome is the microtubule-organizing center and a crucial part of cell division. Centrosomal RNAs(cnRNAs) have been reported to enable precise spatiotemporal control of gene expression during cell division in many species. Whether and how cnRNAs exist in C. elegans are unclear. Here, using the nuclear RNAi Argonaute protein NRDE-3 as a reporter, we observed potential peri-centrosome localized small interfering(si)RNAs in C. elegans. NRDE-3 was previously shown to associate with pre-mRNAs and pre-rRNAs via a process involving the presence of complementary siRNAs. We generated a gFP-NRDE-3 knock-in transgene through CRISPR/Cas9 technology and observed that NRDE-3 formed peri-centrosomal foci neighboring the tubulin protein TBB-2, other centriole proteins and pericentriolar material(PCM)components in C. elegans embryos. The peri-centrosomal accumulation of NRDE-3 depends on RNA-dependent RNA polymerase(RdRP)-synthesized 22g siRNAs and the PAZ domain of NRDE-3, which is essential for siRNA binding. Mutation of eri-1, ergo-1, or drh-3 significantly increased the percentage of pericentrosome-enriched NRDE-3. At the metaphase of the cell cycle, NRDE-3 was enriched in both the peri-centrosomal region and the spindle. Moreover, the integrity of centriole proteins and pericentriolar material(PCM) components is also required for the peri-centrosomal accumulation of NRDE-3. Therefore, we concluded that siRNAs could accumulate in the pericentrosomal region in C. elegans and suggested that the peri-centrosomal region may also be a platform for RNAi-mediated gene regulation.

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Permutation orbifolds of vertex operator superalgebras and associative algebras

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Science China Mathematics 2025年第1期 19-38页

作者： Chongying Dong feng Xu Nina Yu Department of Mathematics University of California at Santa Cruz Department of Mathematics Huzhou University Department of Mathematics University of California at Riverside School of Mathematical Sciences Xiamen University

Let V be a vertex operator superalgebra and g =（1 2 ···k） be a k-cycle which is viewed as an automorphism of the tensor product vertex operator superalgebra V■*** this paper,we construct an explicit isomorphism from Ag(V■k) to A（V） if k is odd and to Aσ（V） if k is even where σ is the canonical automorphism of V of order 2 determined by the superspace structure of *** recover previous results by Barron（2016）and Barron and Vander Werf（2014） that there is a one-to-one correspondence between irreducible g-twisted V■k-modules and irreducible V-modules（*** σ-twisted V-modules） when k is odd（***）.This explicit isomorphism is expected to be useful in our further study on the Zhu algebra of the fixed point subalgebra.

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Nano energy for miniaturized systems

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Nano Materials Science 2021年第2期3卷 107-112页

作者： Minshen Zhu feng Zhu Oliver g.Schmidt Institute for Integrative Nanosciences Leibniz IFW Dresden01069DresdenGermany State Key Laboratory of Polymer Physics and Chemistry Changchun Institute of Applied ChemistryChinese Academy of Sciences130022ChangchunChina Material Systems for Nanoelectronics Chemnitz University of Technology09107ChemnitzGermany Center for Materials Architectures and Integration of Nanomembranes(MAIN)Chemnitz University of Technology09126ChemnitzGermany School of Science Dresden University of TechnologyGermany

Skin mountable electronic devices are in a high-speed development at the crossroads of materials science,electronics,and computer *** functions,such as sensing,actuating,and computing,are integrated into a soft electronic device that can be firmly mounted to any place of human *** advanced electronic devices are capable of yielding abilities for us whenever they are needed and even expanding our abilities beyond their natural *** the great promise of skin mounted electronic devices,they still lack satisfactory power supplies that are safe and *** Perspective discusses the prospects of the development of energy storage devices for the next generation skin mountable electronic devices based on their unique requirements on flexibility and miniaturized size.

关键词： Micro-energy-storage devices Wearability Flexibility Electronics

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Cooperation and Contract Design in Project Management with Outsourcing

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Journal of Systems Science and Systems Engineering 2023年第1期32卷 34-70页

作者： Xiaoqiang Cai Nicholas g.Hall Siyi Wang feng Zhang School of Data Science The Chinese University of Hong KongShenzhen518172China Shenzhen Research Institute of Big Data Shenzhen518172China Department of Operations&Business Analytics Fisher College of BusinessOhio State UniversityColumbusOhioUSA School of Science and Engineering The Chinese University of Hong KongShenzhen518172China Suning Bank Nanjing210019China

We study a project management problem where the prime contractor needs to outsource tasks to subcontractors with the required *** execution of the project requires proper coordination among the subcontractors,as well as contract design by the prime contractor to incentivize the *** modeling the subcontractors’coordination problem as a cooperative game,we develop a profit sharing scheme to facilitate the subcontractors’*** consider two contract designs for the prime contractor:a uniform contract across all subcontractors,and a nonuniform one that customizes incentives for each *** propose efficient algorithms to solve the implicit optimization problems for optimal contract *** experiments show that the pooling effect of subcontractors’cooperation mitigates the negative impact of poor estimates about the crashing cost and resource *** observe three unexpected results through the randomized computation experiments:(i)the subcontractors’profits may decrease if they provide false information;(ii)it is safer for the prime contractor to overestimate subcontractors’crashing costs than underestimate them;and(iii)uniform contracts deliver more project profit for the subcontractors in the coalitions.

关键词： Project management with outsourcing subcontracting cooperative game contract design

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Editorial for a special issue“Nano energy materials and devices for miniaturized electronics and smart systems”

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Nano Materials Science 2021年第2期3卷 105-106页

作者： feng Zhu Oliver g.Schmidt Changchun Institute of Applied Chemistry China Leibniz IFW DresdenGermany Chemnitz Chemnitz University of Technology Germany

The Smart Era urgently demands small-size, low-energy consuming and multi-functional devices which can satisfy versatile application scenarios, including autonomous systems, wireless sensor networks,biomedical equipment, wearable gadgets, and the Internet of *** overwhelming trend has drawn much attention and stimulates intensive collaborative efforts spanning diverse fundamental and applied research related to energy generation-harvesting-storage-managementapplications at the small scale. For instance, on one hand.

关键词： energy smart versatile

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