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Synthesis of atomically dispersed cationic nickel-confined mesoporous ZSM-48(ANMZ-48)directed by metal complexes in amphiphilic molecules

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Science China chemistry 2024年第1期67卷 343-350页

作者： yu chen Quanzheng Deng Yiru Mao yuxi Fang Zhihua Cao Honggen Peng Shunai che Lu Han School of chemical Science and Engineering Tongji UniversityShanghai 200092China School of chemistry and chemical Engineering Nanchang UniversityNanchang 330031China School of chemistry and chemical Engineering Shanghai Jiao Tong UniversityShanghai 200240China School of Resources and Environment Nanchang UniversityNanchang 330031China State Key Laboratory of Metal Matrix Composites Shanghai Key Laboratory for Molecular Engineering of Chiral DrugsShanghai Jiao Tong UniversityShanghai 200240China

The synthesis of mesoporous zeolite-anchored atomically dispersed metal catalysts(ADCs)is a considerable challenge in chemistry and materials *** we report the synthesis of atomically dispersed cationic nickel-confined mesoporous ZSM-48(ANMZ-48)by in situ hydrothermal reaction employing a designed tri-functional metal complex template,by which the triquaternary ammonium groups in the hydrophilic region direct the formation of ZSM-48 zeolite;the aromatic groups in the hydrophobic tail generate the mesopores through π-π stacking;and the complexes formed by nickel ions coordinated with terpyridyl groups generate atomically dispersed Ni2+confined in zeolite frameworks due to the strong sintering resistance generated by the strong coordination *** ANMZ-48 is consisting of stacking of sheet-like ZSM-48 domains connected by multiply crystal twinning sharing the common(011)plane,generating abundant of imbedded mesopores with the uniform thickness of~2.4 nm and with the width of 10-50 *** excellent catalytic activity and stability of ANMZ-48 were also reflected in the dry reforming of methane(DRM)reaction.

关键词： atomically dispersed catalyst mesoporous zeolite ZSM-48 in situ hydrothermal synthesis the dry reforming of methane reaction

A long-term daily gridded snow depth dataset for the Northern Hemisphere from 1980 to 2019 based on machine learning

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Big Earth Data 2024年第2期8卷 274-301页

作者： Yanxing Hu Tao che Liyun Dai yu Zhu Lin Xiao Jie Deng Xin Li Key Laboratory of Remote Sensing of Gansu Province Heihe Remote Sensing Experimental Research StationNorthwest Institute of Eco-Environment and ResourcesChinese Academy of SciencesLanzhouChina College of Resources and Environment University of Chinese Academy of SciencesBeijingChina State Key Laboratory of Tibetan Plateau Earth System Resources and Environment(TPESRE)Institute of Tibetan Plateau ResearchChinese Academy of SciencesBeijingChina yunnan Key Laboratory of International Rivers and Transboundary Eco-Security Institute of International Rivers and Eco-SecurityYunnan UniversityKunmingChina National Forestry and Grassland Administration Key Laboratory of Forest Resource Conservation and Ecological Safety on the Upper Reaches of the Yangtze River Sichuan Province Key Laboratory of Ecological Forestry Engineering on the Upper Reaches of the Yangtze RiverCollege of ForestrySichuan Agricultural UniversityChengduChina

A high-quality snow depth product is very import for cryospheric science and its related *** long time-series snow depth products covering the Northern Hemisphere can be divided into two categories:remote sensing snow depth products and reana-lysis snow depth ***,existing gridded snow depth products have some *** sensing-derived snow depth products are temporally and spatially discontinuous and tend to underestimate snow depth,while reanalysis snow depth products have coarse spatial resolutions and great *** overcome these problems,in our previous work we proposed a novel data fusion framework based on Random Forest Regression of snow products from Advanced Microwave Scanning Radiometer for the Earth Observing System(AMSR-E),Advanced Microwave Scanning Radiometer-2(AMSR2),Global Snow Monitoring for Climate Research(GlobSnow),the Northern Hemisphere Snow Depth(NHSD),ERA-Interim,and Modern-Era Retrospective Analysis for Research and Applications,ver-sion 2(MERRA-2),incorporating geolocation(latitude and longitude),and topographic data(elevation),which were used as input indepen-dent *** than 3.,000 ground observation sites were used as the dependent variable to train and validate the model in different time *** fusion framework resulted in a long time series of continuous daily snow depth product over the Northern Hemisphere with a spatial resolution of 0.25°.Here,we compared the fused snow depth and the original gridded snow depth products with 13.272 observation sites,showing an improved precision of our *** evaluation indices of the fused(best original)dataset yielded a coeffi-cient of determination R2 of 0.81(0.23.,Root Mean Squared Error(RMSE)of 7.69(15.86)cm,and Mean Absolute Error(MAE)of 2.74(6.14)*** of the bias(88.3.%)between the fused snow depth and in situ observations was in the range of−5 cm to 5 *** accuracy assessment of independent snow observation sites-Sodank

关键词： Snow depth datasets machine learning data fusion Northern Hemisphere

Effects of coal-fired power plants on soil microbial diversity and community structures

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Journal of Environmental Sciences 2024年第3期137卷 206-223页

作者： Bowen Sun Renbin Zhu yu Shi Wanying Zhang Zeming Zhou Dawei Ma Runfang Wang Haitao Dai chenshuai che Institute of Polar Environment&Anhui Key Laboratory of Polar Environment and Global Change School of Earth and Space SciencesUniversity of Science and Technology of ChinaHefei 230026China State Key Laboratory of Crop Stress Adaptation and Improvement School of Life SciencesHenan UniversityKaifeng 450046China State Grid Anhui Electric Power Research Institute Hefei 230601China

Long-term deposition of atmospheric pollutants emitted from coal combustion and their effects on the eco-environment have been extensively studied around coal-fired power ***,the effects of coal-fired power plants on soil microbial communities have received little attention through atmospheric pollutant deposition and ***,we collected the samples of power plant soils(PS),coal-stacking soils(CSS)and agricultural soils(AS)around three coal-fired power plants and background control soils(BG)in Huainan,a typical mineral resource-based city in East China,and investigated the microbial diversity and community structures through a high-throughput sequencing ***-stacking significantly increased(p<0.05)the contents of total carbon,total nitrogen,total sulfur and Mo in the soils,whereas the deposition of atmospheric pollutants enhanced the levels of V,Cu,Zn and ***,Actinobacteria,Thaumarchaeota,Thermoplasmata,Ascomycota and Basidiomycota were the dominant taxa in all *** bacterial community showed significant differences(p<0.05)among PS,CSS,AS and BG,whereas archaeal and fungal communities showed significant differences(p<0.01)according to soil samples around three coal-fired power *** predominant environmental variables affecting soil bacterial,archaeal and fungal communities were Mo-TN-TS,Cu-V-Mo,and organic matter(OM)-Mo,*** soil microbial genera were closely related to multiple key factors associated with stacking coal and heavy metal deposition from power *** study provided useful insight into better understanding of the relationships between soil microbial communities and long-term disturbances from coal-fired power plants.

关键词： Coal-fired power plants Soil microbial communities Coal-stacking Heavy metals Environmental variables

Implications for fault reactivation and seismicity induced by hydraulic fracturing

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Petroleum Science 2024年第2期21卷 1081-1098页

作者： Zi-Han Sun Ming-Guang che Li-Hong Zhu Shu-Juan Zhang Ji-yuan Lu Chang-yu Jin Key Laboratory of Ministry of Education on Safe Mining of Deep Metal Mines School of Resources and Civil Engineering and Key Laboratory of Liaoning Province on Deep Engineering and Intelligent TechnologyNortheastern UniversityShenyang110819LiaoningChina Research Institute of Petroleum Exploration&Development PetroChina Company LimitedBeijing100084China The Exploration and Development Research Institute of Daqing Oilfield Limited Company Daqing163458HeilongjiangChina

Evaluating the physical mechanisms that link hydraulic fracturing(HF) operations to induced earthquakes and the anticipated form of the resulting events is significant in informing subsurface fluid injection operations. Current understanding supports the overriding role of the effective stress magnitude in triggering earthquakes, while the impact of change rate of effective stress has not been systematically addressed. In this work, a modified critical stiffness was brought up to investigate the likelihood, impact,and mitigation of induced seismicity during and after hydraulic fracturing by developing a poroelastic model based on rate-and-state fraction law and linear stability analysis. In the new criterion, the change rate of effective stress was considered a key variable to explore the evolution of this criterion and hence the likelihood of instability slip of fault. A coupled fluid flow-deformation model was used to represent the entire hydraulic fracturing process in COMSOL Multiphysics. The possibility of triggering an earthquake throughout the entire hydraulic fracturing process, from fracturing to cessation, was investigated considering different fault locations, orientations, and positions along the fault. The competition between the effects of the magnitude and change rate of effective stress was notable at each fracturing stage. The effective stress magnitude is a significant controlling factor during fracturing events, with the change rate dominating when fracturing is suddenly started or stopped. Instability dominates when the magnitude of the effective stress increases(constant injection at each fracturing stage) and the change rate of effective stress decreases(the injection process is suddenly stopped). Fracturing with a high injection rate, a fault adjacent to the hydraulic fracturing location and the position of the junction between the reservoir and fault are important to reduce the Coulomb failure stress(CFS) and enhance the critical stiffness as

关键词： Hydraulic fracturing Coulomb failure stress Rate-and-state fraction model Linear stability analysis Critical stiffness Seismically induced fault

Precision design of Ti sites for unprecedented catalytic performance

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National Science Review 2024年第7期11卷 67-68页

作者： Haoquan Zheng Shunai che Key Laboratory of Applied Surface and Colloid chemistry Ministry of Education School of Chemistry and Chemical Engineering Shaanxi Normal University School of chemistry and chemical Engineering Shanghai Jiao Tong University

In 1983. Taramasso et al. incorporated titanium(Ti) into porous silica frameworks to endow Ti sites with catalytic oxidation ability [1]. Nowadays, catalytic oxidation reactions using titanium silicate materials have ...

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Evaluation on the state of sand filling layer and the influence on segment deformation of immersed tunnels

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Underground Space 2024年第3期16卷 224-238页

作者： Ziyao Xu Ailan che Chao Su School of Naval Architecture Ocean and Civil EngineeringShanghai Jiao Tong UniversityShanghai 200240China CCCC Second Harbor Engineering Company Ltd. Wuhan 430040China

The immersed tunnel is considered an effective solution for traffic problems across rivers and *** sand filling layer,as an important part of immersed tunnel foundation treatments,directly affects segment attitude *** to difficulties in quality control of concealed construction and the complex hydrodynamic environment,the sand filling layer is prone to compaction defects,further leading to changes in segment ***,limited by structural concealment and state complexity,most studies consider the sand filling layer part of the foundation to study its impact on settlement while neglecting its influence on segment *** research proposes an evaluation method for the sand filling layer state based on elastic wave testing and the elastic wave characteristic parameters selected come from analysis of the time domain,frequency domain and time–frequency *** classifying the elastic wave characteristic parameters through the K-means clustering method,the relationship between the state of the sand filling layer and the elastic wave characteristic parameters is *** state of the sand filling layer is divided into dense,incompact,and void.A numerical model is established based on the Guangzhou BI-UT immersed tunnel with incompact and void sand filling layer states to simulate deformation and *** results indicate that the settlement of the tunnel segment is low in the eastern region and high in the western region due to the presence of a less dense sand filling layer,with a maximum differential settlement of 0.04 *** evaluation method plays a crucial role in guiding the construction of immersed tube tunnels.

关键词： Sand filling layer state Immersed tunnel Elastic wave test Clustering algorithm

Cell replacement with stem cell-derived retinal ganglion cells from different protocols

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Neural Regeneration Research 2024年第4期19卷 807-810页

作者： Ziming Luo Kun-che Chang Spencer Center for Vision Research Byers Eye InstituteStanford University School of Medicine Department of Ophthalmology Louis J.Fox Center for Vision RestorationUniversity of Pittsburgh School of Medicine Department of Neurobiology Center of NeuroscienceUniversity of Pittsburgh School of Medicine

Glaucoma,characterized by a degenerative loss of retinal ganglion cells,is the second leading cause of blindness *** is currently no cure for vision loss in glaucoma because retinal ganglion cells do not regenerate and are not replaced after *** stem cell-derived retinal ganglion cell transplant is a potential therapeutic strategy for retinal ganglion cell degenerative *** this review,we first discuss a 2D protocol for retinal ganglion cell differentiation from human stem cell culture,including a rapid protocol that can generate retinal ganglion cells in less than two weeks and focus on their transplantation ***,we discuss using 3. retinal organoids for retinal ganglion cell transplantation,comparing cell suspensions and *** review provides insight into current knowledge on human stem cell-derived retinal ganglion cell differentiation and transplantation,with an impact on the field of regenerative medicine and especially retinal ganglion cell degenerative diseases such as glaucoma and other optic neuropathies.

关键词： cell clumps cell suspension cell transplantation differentiation direct-induced protocol glaucoma optic neuropathy regenerative medicine retinal ganglion cell retinal organoids stem cells

Hollow FeCoNiAl microspheres with stabilized magnetic properties for microwave absorption

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Nano Research 2024年第3期17卷 2079-2087页

作者： Linhe yu Gangjie Lian Guozhen Zhu Sue Ren Yanfang Du Xuhui Xiong Rui chen Jincang Zhang Wenbin You Renchao che Institute of Advanced Materials College of Chemistry and Chemical EngineeringJiangxi Normal UniversityNanchang 330022China Laboratory of Advanced Materials Shanghai Key Lab of Molecular Catalysis and Innovative MaterialsAcademy for Engineering&TechnologyFudan UniversityShanghai 200438China Zhejiang Laboratory Hangzhou 311100China Capital Aerospace Machinery Corporation Limited Beijing 100000China AECC Beijing Institute of Aeronautical Materials Beijing 100095China International Center for Quantum and Molecular Structures Materials Genome InstitutePhysics DepartmentShanghai UniversityShanghai 200444China

Development of high-performance microwave absorption materials(MAM)with stabilized magnetic properties at high temperatures is specifically essential but remains ***,the Snoke's limitation restrains the microwave absorption(MA)property of magnetic *** alloy components is considered an effective way to solve the aforementioned ***,a hollow medium-entropy FeCoNiAl alloy with a stable magnetic property is prepared via simple spray-drying and two-step annealing for efficient *** exhibited an ultrabroad effective absorption band(EAB)of 5.84 GHz(12.16–18 GHz)at a thickness of just 1.6 mm,revealing an excellent absorption ***,the MA mechanism of FeCoNiAl is comprehensively investigated via off-axis ***,the electromagnetic properties,antioxidant properties,and residual magnetism at high temperatures of FeCoNiAl alloys are summarized in detail,providing new insights into the preparation of MAM operating at elevated temperatures.

关键词： microwave absorption hollow structure magnetic stability multiple microwave absorption mechanism

Numerical investigation of transient gas–solid heat transfer in a packed bed:Impact of intra-particle thermal diffusion

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Particuology 2024年第7期90卷 404-411页

作者： Hanqiao che yuanhe yue Zhaohua Jiang Duan Li School of Mechanical Engineering Guangxi UniversityNanningGuangxi530004China School of chemical Engineering University of BirminghamBirminghamB152TTUK Hebei Engineering Research Center of Advanced Energy Storage Technology and Equipment School of Energy and Environmental EngineeringHebei University of TechnologyTianjin300401China Hebei Key Laboratory of Thermal Science and Energy Clean Utilization School of Energy and Environmental EngineeringHebei University of TechnologyTianjin300401China School of Mechatronics and Vehicle Engineering Chongqing Jiaotong UniversityChongqing400074China School of Instrumentation and Opto-Electronic Engineering Beihang UniversityBeijing 100191China

The transient heat transfer behaviours in a packed bed have been studied using coupled computational fluid dynamics(CFD)and discrete element method(DEM).Intra-particle thermal diffusion,which is a crucial but rarely explored issue,is considered by introducing a one-dimensional diffusion equation in the DEM *** achieve a sufficiently long physical time of simulations,we further reduce the computational cost by applying periodic boundary condition to a small segment of the packed *** study demonstrates a shifting peak heat flow rate from the bottom to the top of the packed bed during the initial warming *** affirm that the influence of thermal diffusion within a particle is noteworthy only for particles exhibiting a high Biot number(e.g.,Bi=1.2).This insight enriches our understanding of heat transfer mechanisms in packed beds and their practical engineering applications.

关键词： Packed bed Intra-particle heat transfer CFD–DEM