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Hollow Gradient-Structured Iron-Anchored Carbon Nanospheres for Enhanced Electromagnetic Wave Absorption

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Nano-Micro Letters 2023年第1期15卷 144-160页

作者： Cao Wu Jing Wang Xiaohang zhang Lixing Kang Xun Cao yongyi zhang Yutao Niu Yingying Yu Huili Fu Zongjie Shen Kunjie Wu Zhenzhong Yong Jingyun Zou Bin Wang Zhou Chen Zhengpeng Yang Qingwen Li Key Laboratory of Multifunctional Nanomaterials and Smart Systems Advanced Materials DivisionSuzhou Institute of Nano-Tech and Nano-BionicsChinese Academy of SciencesSuzhou 215123JiangsuPeople’s Republic of China School of Science Nanchang Institute of TechnologyNanchang 330099JiangxiPeople’s Republic of China Division of Nanomaterials and Jiangxi Key Lab of Carbonene Materials Jiangxi Institute of NanotechnologyNanchang 330200JiangxiPeople’s Republic of China School of Nano-Tech and Nano-Bionics University of Science and Technology of ChinaHefei 230026AnhuiPeople’s Republic of China School of Materials Science and Engineering Nanyang Technological University50 Nanyang AvenueSingapore 639798Singapore Jiangsu Key Laboratory of Micro and Nano Heat Fluid Flow Technology and Energy Application School of Physical Science and TechnologySuzhou University of Science and TechnologySuzhou 215009People’s Republic of China School of Mechanical and Power Engineering Nanjing Tech UniversityNanjing 211800People’s Republic of China Henan Key Laboratory of Materials On Deep-Earth Engineering School of Materials Science and EngineeringHenan Polytechnic UniversityJiaozuo 454003People’s Republic of China College of Safety Science and Engineering Xi’an University of Science and TechnologyXi’an 710054People’s Republic of China

In the present paper,a microwave absorber with nanoscale gradient structure was proposed for enhancing the electromagnetic absorption performance.The inorganic-organic competitive coating strategy was employed,which can effectively adjust the thermodynamic and kinetic reactions of iron ions during the solvothermal process.As a result,Fe nanoparticles can be gradually decreased from the inner side to the surface across the hollow carbon shell.The results reveal that it offers an outstanding reflection loss value in combination with broadband wave absorption and flexible adjustment ability,which is superior to other relative graded distribution structures and satisfied with the requirements of lightweight equipment.In addition,this work elucidates the intrinsic microwave regulation mechanism of the multiscale hybrid electromagnetic wave absorber.The excellent impedance matching and moderate dielectric parameters are exhibited to be the dominative factors for the promotion of microwave absorption performance of the optimized materials.This strategy to prepare gradient-distributed microwave absorbing materials initiates a new way for designing and fabricating wave absorber with excellent impedance matching property in practical applications.

关键词： Gradient structures Carbon nanospheres Electromagnetic wave absorption Impedance matching

Carbon nanotube fibers with excellent mechanical and electrical properties by structural realigning and densification

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Nano Research 2023年第11期16卷 12762-12771页

作者： Kunjie Wu Bin Wang Yutao Niu Wenjing Wang Cao Wu Tao Zhou Li Chen Xianghe Zhan Ziyao Wan Shan Wang Zhengpeng Yang Yichi zhang Liwen zhang yongyi zhang Zhenzhong Yong Muqiang Jian Qingwen Li Key Laboratory of Multifunctional Nanomaterials and Smart Systems Suzhou Institute of Nano-Tech and Nano-BionicsChinese Academy of SciencesSuzhou 215123China Division of Nanomaterials and Jiangxi Key Lab of Carbonene Materials Jiangxi Institute of NanotechnologyNanchang 330200China School of Nano-Tech and Nano-Bionics University of Science and Technology of ChinaHefei 230026China Henan Key Laboratory of Materials on Deep-Earth Engineering School of Materials Science and EngineeringHenan Polytechnic UniversityJiaozuo 454003China Beijing Graphene Institute(BGI) Beijing 100095China

Floating catalysis chemical vapor deposition(FCCVD)direct spinning process is an attractive method for fabrication of carbon nanotube fibers(CNTFs).However,the intrinsic structural defects,such as entanglement of the constituent carbon nanotubes(CNTs)and inter-tube gaps within the FCCVD CNTFs,hinder the enhancement of mechanical/electrical properties and the realization of practical applications of CNTFs.Therefore,achieving a comprehensive reassembly of CNTFs with both high alignment and dense packing is particularly crucial.Herein,an efficient reinforcing strategy for FCCVD CNTFs was developed,involving chlorosulfonic acid-assisted wet stretching for CNT realigning and mechanical rolling for densification.To reveal the intrinsic relationship between the microstructure and the mechanical/electrical properties of CNTFs,the microstructure evolution of the CNTFs was characterized by cross-sectional scanning electron microscopy(SEM),wide angle X-ray scattering(WAXS),polarized Raman spectroscopy and Brunauer–Emmett–Teller(BET)analysis.The results demonstrate that this strategy can improve the CNT alignment and eliminate the inter-tube voids in the CNTFs,which will lead to the decrease of mean distance between CNTs and increase of inter-tube contact area,resulting in the enhanced inter-tube van der Waals interactions.These microstructural evolutions are beneficial to the load transfer and electron transport between CNTs,and are the main cause of the significant enhancement of mechanical and electrical properties of the CNTFs.Specifically,the tensile strength,elastic modulus and electrical conductivity of the high-performance CNTFs are 7.67 GPa,230 GPa and 4.36×10^(6)S/m,respectively.It paves the way for further applications of CNTFs in high-end functional composites.

关键词： carbon nanotube fibers mechanical property electrical property alignment packing density

One-step wet-spinning assembly of twisting-structured graphene/carbon nanotube fiber supercapacitor

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Journal of Energy Chemistry 2020年第12期29卷 434-441页

作者： Zhengpeng Yang Yuanheng Jia Yutao Niu yongyi zhang Chunjing zhang Ping Li Meng Zhu Qingwen Li Henan Key Laboratory of Materials on Deep-Earth Engineering School of Materials Science and EngineeringHenan Polytechnic UniversityJiaozuo 454003HenanChina Key Laboratory of Multifunctional Nanomaterials and Smart Systems Advanced Materials DivisionSuzhou Institute of Nano-Tech and Nano-BionicsChinese Academy of SciencesSuzhou 215123JiangsuChina School of Nano-Tech and Nano-Bionics University of Science and Technology of ChinaHefei 230026AnhuiChina Division of Nanomaterials and Jiangxi Key Lab of Carbonene Materials Suzhou Institute of Nano-Tech and Nano-BionicsNanchangChinese Academy of SciencesNanchang 330200JiangxiChina

Graphene fiber-based supercapacitors hold great promise as flexible energy-storage devices. However, simultaneously achieving high ion-transport ability in electrode and electrolyte layer, which is crucial for realizing the high electrochemical performance, still remains challenging. Here, a facile and effective strategy to solve the problem was proposed by developing a twisting-structured graphene/carbon nanotube(CNT) fiber supercapacitor via one-step wet-spinning process with customized multi-channel spinneret.The remarkable structure features of the resulting fiber supercapacitor with wrinkled and thin electrolyte layer, and well-developed porosity of fiber electrode favored the rapid infiltration and transport of electrolyte ions inside the electrode, as well as between electrode and electrolyte, thus boosting high specific capacitance of 187.6 mF cm^(-2) and energy density of 30.2 μWh cm^(-2), and featuring long cycling life(93%capacitance retention after 10,000 cycles) and excellent flexibility. Moreover, the specific capacitance and energy density could be further improved to 267.2 m F cm^(-2) and 66.8 μWh cm^(-2), respectively, when Mn O2 was incorporated into the fiber.

关键词： One-step wet-spinning Graphene fiber-based supercapacitor Twisting-structured fiber Ion transport

FeCo alloy catalysts promoting polysulfide conversion for advanced lithium-sulfur batteries

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Journal of Energy Chemistry 2020年第10期29卷 339-347页

作者： Hongyi Li Linfeng Fei Rong zhang Shenglan Yu yongyi zhang Longlong Shu Yong Li Yu Wang School of Materials Science and Engineering Nanchang UniversityNanchang 330031JiangxiChina Division of Nanomaterials and Jiangxi Key Lab of Carbonene Materials Suzhou Institute of Nano-Tech and Nano-BionicsChinese Academy of SciencesNanchang 330200JiangxiChina College of Chemistry Biology and Material ScienceEast China University of TechnologyNanchang 330013JiangxiChina

Lithium sulfur batteries(LSBs)draw extensive interest because of the ultra-high capacity and low material cost.However,the sluggish lithium polysulfides(LIPSs)conversion processes are detrimental to cycle stability and rate capability,inhibiting the commercial application of LSBs.Here we present the well-designed Fe Co alloy catalysts anchored on porous carbon(FeCo-C)as sulfur host to improve the electrochemical performance by accelerating the conversion reactions.The FeCo alloy demonstrates high catalytic effect and strong adsorption capability of LIPSs,in which potential polarization can be greatly decreased and"shuttle effects"can be largely avoided.As a result,the obtained S/Fe Co-C composites show an initial specific capacity of 791.9 m Ah g^-1 at a large current density of 2 C and maintain 502.5 mAh g^-1 even after 500 cycles.Moreover,720 m Ah g^-1(corresponding to 70%retention)can be achieved after 100 cycles at 0.2 C with a high sulfur content of 80 wt%,enabling high sulfur utilization.This work not only provides a new insight to investigate the conversion kinetics of Li PSs,but also opens up a new avenue for advanced lithium sulfur batteries.

关键词： Lithium sulfur batteries FeCo alloys Catalysts Adsorption Porous carbon

High-loading Co-doped NiO nanosheets on carbon-welded carbon nanotube framework enabling rapid charge kinetic for enhanced supercapacitor performance

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Journal of Energy Chemistry 2020年第11期29卷 240-247页

作者： Hao Xu Yufang Cao Yong Li Pei Cao Dandan Liu yongyi zhang Qing wen Li School of Nano-Tech and Nano-Bionics University of Science and Technology of ChinaHefei 230026AnhuiChina Key Laboratory of Multifunctional Nanomaterials and Smart Systems Advanced Materials DivisionSuzhou Institute of Nano-Tech and Nano-BionicsChinese Academy of SciencesSuzhou 215123JiangsuChina Division of Nanomaterials and Jiangxi Key Lab of Carbonene Materials Suzhou Institute of Nano-Tech and Nano-BionicsNanchangChinese Academy of SciencesNanchang 330200JiangxiChina School of Materials Science and Engineering Nanchang UniversityNanchang 330031JiangxiChina

Developing high power and energy supercapacitors(SCs)is a long-pursued goal for the application in transportation and energy storage station.Herein,a rationally-designed Co-doped nickel oxide nanosheets@carbon-welded carbon nanotube foam(Co-doped NiO@WCNTF)as freestanding electrode is successfully prepared for high power and energy SCs.The WCNTF framework with high specific surface area provides three dimensional highly conductive network for fast charge transport and ensures high loading of active materials(9.2 mg/cm2).Moreover,porous Co-doped NiO nanosheets uniformly anchored on the WCNTF framework enable rapid charge kinetics due to the high intrinsic conductivity of Co-doped Ni O nanosheets and their good contact with conductive WCNTF substrate.As a result,the unique integrated electrode with 3D architecture exhibits an ultrahigh specific capacitance of 11.45 F/cm2 at 5 mA/cm2,outstanding rate capability(11.45 F/cm2 at 5 mA/cm2 and a capacitance retention of 86.2%at 30 mA/cm2)and good cycling stability,suggesting great potential for high performance supercapacitor.

关键词： Carbon nanotube foam Pseudocapacitors Co-doped NiO nanosheets Freestanding electrode

混合式学习人际互动质量量表的汉化及信效度检验

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护理研究 2024年第4期38卷 583-589页

作者：周丽荣张永怡曹莫然赵贞贞南京卫生高等职业技术学校、江苏联合职业技术学院南京卫生分院江苏210038

目的:汉化混合式学习人际互动质量量表,并检验其信效度。方法:按照Brislin翻译模式进行翻译、回译、检译与文化调适,形成中文版在线学习人际互动质量量表(Online Learning Interaction Quality Scale,OLIQS)和传统面对面学习人际互动质... 详细信息

目的:汉化混合式学习人际互动质量量表,并检验其信效度。方法:按照Brislin翻译模式进行翻译、回译、检译与文化调适,形成中文版在线学习人际互动质量量表(Online Learning Interaction Quality Scale,OLIQS)和传统面对面学习人际互动质量量表(Traditonal Learning Interaction Quality Scale,TLIQS)。选取某职业院校的1433名在校护理专业学生进行调查,测定量表信度和效度。结果:中文版OLIQS包括在线师生互动和在线生生互动2个维度,共10个条目;中文版TLIQS包括情感支持、课堂组织、教学支持3个维度,共10个条目。Cronbach’sα系数分别为0.901和0.888,条目水平的内容效度指数为0.84~1.00。验证性因子分析结果显示2个分量表拟合良好,有良好的收敛效度和区别效度。结论:中文版OLIQS和TLIQS可以用于评价我国职业院校护理专业学生混合式学习人际互动质量,具有较好的信效度。

关键词：混合式学习人际互动护理教育量表信度效度质量评价

ZnS nanolayer coated hollow carbon spheres with enhanced rate and cycling performance for Li-S batteries

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Science China(Technological Sciences) 2022年第2期65卷 272-281页

作者： MENG FanCheng XU Bin LONG Tao CHENG Sheng LI Yong zhang yongyi LIU JieHua School of Materials Science and Engineering Engineering Research Centre of High-Performance Copper Alloy Materials and ProcessingMinistry of EducationHefei University of TechnologyHefei 230009China Division of Nanomaterials and Jiangxi Key Lab of Carbonene Materials Suzhou Institute of Nano-Tech and Nano-BionicsNanchangChinese Academy of SciencesNanchang 330200China Instrumental Analysis Centre Hefei University of TechnologyHefei 230009China School of Instrument Science and Opto-electronics Engineering Hefei University of TechnologyHefei 230009China Key Laboratory of Multifunctional Nanomaterials and Smart Systems Advanced Materials DivisionSuzhou Institute of Nano-Tech and Nano-BionicsChinese Academy of SciencesSuzhou 215123China School of Nano-Tech and Nano-Bionics University of Science and Technology of ChinaHefei 230026China

Conductive carbon structure has been considered as a promising sulfur-hosting material as the cathode of lithium-sulfur batteries.However, the issue of polysulfide shuttling requires an additional component to help restrict and convert sulfur substances.Herein, in this work, hollow and porous carbon nanospheres(HCS) are synthesized by a template method and a high-temperature carbonization treatment. A thin layer of ZnS coating is then deposited on the HCS-based sulfur(ZnS@HCS/S) cathode with controlled thickness, and the overall electrochemical properties are systematically evaluated. Results show that with 30 nm-thick ZnS coating, the cathode reveals an improved capacity of 1411 m A h g^(-1), and higher capacities from 0.2 to 3 C rate compared with bare HCS/S cathode. Moreover, the ZnS coating also enhances the cycling stability of ZnS@HCS/S cathode over 280 cycles at 0.5 C, with only 0.2% capacity decay per cycle. This work demonstrates potential applications for high-performance lithiumsulfur batteries.

关键词： lithium-sulfur battery ZnS nanolayer hollow carbon sphere rate performance cycling stability

基于有限元分析的单榀变截面门式刚架稳定性研究

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甘肃科学学报 2024年第3期36卷 146-152页

作者：李静薇卫杰雄滕振超张永益刘欣东北石油大学土木建筑工程学院黑龙江大庆163000

某门式钢结构厂房进行建筑改造,需对原结构进行稳定性分析。应用ABAQUS软件对某单榀变截面H型钢门式刚架进行了线性屈曲、非线性屈曲以及粘钢加固的分析研究。对改造前结构进行屈曲分析,得到屈曲模态以及荷载-位移曲线。结果表明:刚梁... 详细信息

某门式钢结构厂房进行建筑改造,需对原结构进行稳定性分析。应用ABAQUS软件对某单榀变截面H型钢门式刚架进行了线性屈曲、非线性屈曲以及粘钢加固的分析研究。对改造前结构进行屈曲分析,得到屈曲模态以及荷载-位移曲线。结果表明:刚梁易发生Y轴方向的扭转破坏;结构施加几种微初始缺陷对承载能力影响不大;在结构材料应力达到屈服应力时,荷载系数均小于1.0,结构发生失稳破坏。对梁上下翼缘粘贴钢板以及梁柱节点处全焊接加劲板进行加固补强,将加固前后的荷载-位移曲线、结构应力云图进行对比得到:当结构材料的应力达到屈服应力时,所施加初始缺陷为0 mm时,结构加固后的荷载系数相比加固前提升了61%;当初始缺陷为50 mm时,加固后结构的荷载系数相比加固前提升了52%,且加固后结构荷载系数均大于1.0,梁的应力情况得到明显改善,并且结构的跨中挠度满足规范要求。

关键词：门式刚架屈曲分析微初始缺陷粘钢加固

猪链球菌2型核糖核酸酶Ⅲ的克隆表达及催化特性分析

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畜牧与兽医 2024年第1期56卷 46-55页

作者：孙文张永毅陆畅朱德文尹媛媛徐泉明陈叶福建农林大学动物科学学院(蜂学学院) 闽台动物病原生物学福建省高校重点实验室福建福州350002 福建警察学院福建福州350007

为了研究猪链球菌2型(SS2)核糖核酸酶Ⅲ(RNaseⅢ)的催化特性,利用大肠杆菌BL21(DE3)异源表达猪链球菌2型RNaseⅢ(SS-RNaseⅢ)并通过镍柱亲和层析的方法分离纯化。异源表达研究显示,重组蛋白RNaseⅢ大部分为可溶性表达;催化特性研究显示,... 详细信息

为了研究猪链球菌2型(SS2)核糖核酸酶Ⅲ(RNaseⅢ)的催化特性,利用大肠杆菌BL21(DE3)异源表达猪链球菌2型RNaseⅢ(SS-RNaseⅢ)并通过镍柱亲和层析的方法分离纯化。异源表达研究显示,重组蛋白RNaseⅢ大部分为可溶性表达;催化特性研究显示,RNaseⅢ主要依赖Mg^(2+)或Mn^(2+)发挥催化功能,并在不同离子浓度和pH值环境下具有不同的催化活性;底物特异性研究显示,RNaseⅢ特异性切割长度为30 bp的双链RNA,同时对内源性的rnc mRNA和5S rRNA具有良好的特异性。上述结果表明,相较于其他细菌RNaseⅢ,SS-RNaseⅢ具有独特的催化特性,为深入理解RNaseⅢ如何介导SS2致病机制奠定了基础。

关键词：猪链球菌2型核糖核酸酶Ⅲ 原核表达催化特性