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Boosting Oxygen Evolution Reaction Performance on NiFe‑Based Catalysts Through d‑Orbital Hybridization

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Nano-Micro Letters 2025年第1期17卷 281-292页

作者： Xing Wang wei Pi Sheng Hu Haifeng Bao Na Yao wei Luo State Key Laboratory of New Textile Materials and Advanced Processing Technology Key Laboratory of New Textile Materials and Applications of Hubei ProvinceSchool of Materials Science and EngineeringWuhan Textile UniversityWuhan 430200People’s Republic of China College of Chemistry and Molecular Sciences Wuhan UniversityWuhan 430072People’s Republic of China

Anion-exchange membrane water electrolyzers(AEMWEs)for green hydrogen production have received intensive attention due to their feasibility of using earth-abundant NiFe-based *** introducing a third metal into NiFe-based catalysts to construct asymmetrical M-NiFe units,the d-orbital and electronic structures can be adjusted,which is an important strategy to achieve sufficient oxygen evolution reaction(OER)performance in ***,the ternary NiFeM(M:La,Mo)catalysts featured with distinct M-NiFe units and varying d-orbitals are reported in this *** and theoretical calculation results reveal that the doping of La leads to optimized hybridization between d orbital in NiFeM and 2p in oxygen,resulting in enhanced adsorption strength of oxygen intermediates,and reduced rate-determining step energy barrier,which is responsible for the enhanced OER *** critically,the obtained NiFeLa catalyst only requires 1.58 V to reach 1 A cm^(−2) in an anion exchange membrane electrolyzer and demonstrates excellent long-term stability of up to 600 h.

关键词： NiFe-based catalysts d-orbital coupling Oxygen evolution reaction Anion exchange membrane electrolyzer

Discovery of a new family member of arsenic–vanadium polyoxometalates with high catalytic performance for one-pot coupling of CO2, epoxides and amines

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Tungsten 2025年第1期7卷 80-87页

作者： Fang-Qian Wang Yin Zhang wei-wei Wang Mei-Qian Fu Hong-Bing Mo wei-Dong Yu Chao Liu Jun Yan College of Chemistry and Chemical Engineering Central South University Junior Education Department Changsha Normal University School of Science Hunan University of Technology and Business

Arsenic-vanadium polyoxometalates（POMs） represent a family of tremendous potential catalysts owing to their peculiar physical and chemical *** in CO2conversion,using POMs to catalyze the conversion of CO2and epoxide into chemical intermediates is the research ***,A new family number of arsenic-vanadium POMs,[N（CH3）4]4[As8V12O38（H2O）]·2H2O({As8V12O38}),was reported and characterized by single-crystal X-ray diffraction,fourier transform infrared spectroscopy,X-ray photoelectron spectroscopy,*** from other allotropicity,{As8V12O38}shows a different structure pattern with an I-43d *** obtained {As8V12O38} was employed as a catalyst for the *** initial catalytic reaction confirmed that {As8V12O38} can catalyze the formation of epoxy carbonate by using 1.01 kPa CO2and epoxide at 70℃.Furtherly,when added amine in the catalytic system,oxazolidinone could be obtained by high yields,which provides an efficient way to convert CO2into profitable ***,a possible catalytic reaction mechanism was proposed by using different characterization analyses.{As8V12O38} first catalyzes the epoxide and CO2to form an epoxy carbonate and then catalyzes epoxy carbonate and benzylamine into oxazolidinone.

关键词： Arsenic CO2 conversion Oxazolidinone Polyoxometalates Vanadium

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岩土锚固安全评价指标体系研究

公路交通技术 2023年第3期39卷 27-34页

作者：潘荣建胡居义韦勇克许明广西新发展交通集团有限公司南宁530025 招商局重庆交通科研设计院有限公司重庆400067 重庆大学土木工程学院重庆400074

加强锚杆(索)施工质量控制和工程可靠性检测是岩土支护结构时效性分析的一项重要内容。首先,通过理论研究、模型试验和现场测试等方法,将单锚失效模式归纳为粘结失效、筋材断裂失效、预应力松弛失效和锚具失效,并提出了岩土锚固安全评... 详细信息

加强锚杆(索)施工质量控制和工程可靠性检测是岩土支护结构时效性分析的一项重要内容。首先,通过理论研究、模型试验和现场测试等方法,将单锚失效模式归纳为粘结失效、筋材断裂失效、预应力松弛失效和锚具失效,并提出了岩土锚固安全评价指标体系。其次,针对各指标参数的特点,在动力学理论和结构探伤理论基础上,利用现代信号处理技术、神经网络和优化算法等数学手段,建立了锚杆(索)质量检测的力学和数学模型,并研究了不同损伤锚杆在声波和应力波激励下的动力响应规律,确定了单锚安全等级划分方法及其对应的失效阈值。最后,通过确定单锚的锚固力取值,重新计算正常工况下的锚固边坡稳定安全系数,并将其与容许安全系数进行比较,对运营期内的锚固边坡稳定性进行评价,对锚失效后不稳定的边坡提出了原锚补强和增设新锚等处治方法。锚固安全评价与处治技术具有在线、动态、实时的特点,可弥补传统的锚杆(索)拉拔试验的不足,对提高锚杆(索)加固技术和岩土工程的稳定性和可靠性具有促进作用。

关键词：锚杆(索) 安全评价指标体系动力响应承载力损伤探测

Solar cycles during the seventeenth century revealed by equatorial aurora records

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Earth and Planetary Physics 2025年第1期9卷 182-187页

作者： Yong wei LiMei Yan Key Laboratory of Earth and Planetary Physics Institute of Geology and GeophysicsChinese Academy of SciencesBeijing 100029China College of Earth and Planetary Sciences University of Chinese Academy of SciencesBeijing 100049China

Solar cycles are fundamental to astrophysics,space exploration,technological infrastructure,and Earth's climate.A better understanding of these cycles and their history can aid in risk mitigation on Earth,while also deepening our knowledge of stellar physics and solar system *** the solar cycles between 1600 and 1700-especially the post-1645 Maunder Minimum,characterized by significantly reduced solar activity-poses challenges to existing solar activity *** study utilizes a new red equatorial auroral catalog from ancient Korean texts to establish solar cycle patterns from 1623 to ***,a further reevaluation of the solar cycles between 1610 and 1755 identified a total of 13 cycles,diverging from the widely accepted record of 12 cycles during that *** research enhances our understanding of historical solar activity,and underscores the importance of integrating diverse historical sources into modern analyses.

关键词： solar cycle Maunder Minimum solar activity red equatorial aurora West Pacific geomagnetic anomaly

From text to image:challenges in integrating vision into ChatGPT for medical image interpretation

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Neural Regeneration Research 2025年第2期20卷 487-488页

作者： Shunsuke Koga wei Du Department of Pathology and Laboratory Medicine Hospital of the University of PennsylvaniaPhiladelphiaPAUSA

Large language models(LLMs),such as ChatGPT developed by OpenAI,represent a significant advancement in artificial intelligence(AI),designed to understand,generate,and interpret human language by analyzing extensive text *** potential integration into clinical settings offers a promising avenue that could transform clinical diagnosis and decision-making processes in the future(Thirunavukarasu et al.,2023).This article aims to provide an in-depth analysis of LLMs’current and potential impact on clinical *** ability to generate differential diagnosis lists underscores their potential as invaluable tools in medical practice and education(Hirosawa et al.,2023;Koga et al.,2023).

关键词： image diagnosis text

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加热和冻藏对鸡爪胶原纤维超微结构的影响

肉类研究 2015年第8期29卷 13-16页

作者：高伟伟霍香如李桂霞韦永可朱杰西北农林科技大学理学院生物物理研究所生物力学与工程研究室陕西杨凌712100 西北农林科技大学中美食品安全联合研究中心陕西杨凌712100

研究不同温度和时间条件处理对鸡爪筋胶原纤维超微结构的影响。加热组将新鲜鸡爪筋剪碎匀浆后分别在50、60、70℃条件下水浴加热10、20、30 min;冻藏组将新鲜鸡爪筋分别在-20、-80℃条件下冻藏5、10、15 d,通过对处理后的样品采用原子... 详细信息

研究不同温度和时间条件处理对鸡爪筋胶原纤维超微结构的影响。加热组将新鲜鸡爪筋剪碎匀浆后分别在50、60、70℃条件下水浴加热10、20、30 min;冻藏组将新鲜鸡爪筋分别在-20、-80℃条件下冻藏5、10、15 d,通过对处理后的样品采用原子力显微镜扫描成像的方法研究鸡爪筋在不同温度及时间处理后的胶原纤维周期长度和粗糙度的变化。结果表明:胶原纤维周期长度随加热温度升高、加热时间增长而变短,随冻藏温度降低,冻藏时间的延长而变长,其中760、-20℃变化最典型。60℃时,当加热时间由10min增至30min,周期长度由(72.20±2.58)nm减至(71.00±1.78)nm;-20℃时,当冻藏时长由5 d增至15 d,周期长度由(69.70±2.60)nm增至(73.00±2.90)nm。冻藏时间增加,鸡爪筋胶原纤维表面的粗糙度增加;加热时间增加,50℃加热时,鸡爪筋胶原纤维的粗糙度先增后减;60℃加热则与之相反。

关键词：原子力显微镜加热冻藏鸡爪胶原纤维超微结构

Record-breaking bifunctional oxygen electrocatalyst accomplished by a data-driven approach for zinc-air batteries

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Journal of Energy Chemistry 2025年第1期100卷 144-145页

作者： Deviprasath Chinnadurai Zhi wei Seh Institute of Materials Research and Engineering (IMRE) Agency for Science Technology and Research (A*STAR)

Rechargeable zinc-air batteries(ZABs) have recently drawn great attention in energy research due to their high theoretical capacity,low costs, and inherently safe nature [1–3]. However, the sluggish cathode reactions necessitate the development of bifunctional oxygen electrocatalysts with lower ΔE indicator values. The ΔE indicator is commonly employed to quantitatively evaluate the electrocatalytic activity of a bifunctional oxygen electrocatalyst,representing the overall overpotential from oxygen reduction reaction(ORR) to oxygen evolution reaction(OER).

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Fabrication and Mechano-sensing Characteristics of Bending Polypyrrole Actuator

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Journal of Wuhan University of Technology(Materials Science) 2025年第1期40卷 240-245页

作者： CHEN Jinyou HU wei School of Automotive Engineering Hunan Financial&Industrial Vocational-technical CollegeHengyang 421002China College of Mechanical and Electrical Engineering Hunan Agricultural UniversityChangsha 410128China

To prepare a conductive polymer actuator with decent performance,a self-built experimental platform for the preparation of polypyrrole film is *** of the essential goals is to examine the mechanical characteristics of the actuator in the presence of various combinations of process parameters,combined with the orthogonal test method of"four factors and three levels".The bending and sensing characteristics of actuators of various sizes are methodically examined using a self-made bending polypyrrole *** functional relationship between the bending displacement and the output voltage signal is established by studying the characteristics of the actuator sensor subjected to various degrees of *** experimental results reveal that the bending displacement of the actuator tip almost exhibits a linear variation as a function of length and *** the voltage reaches 0.8 V,the bending speed of the actuator tends to be ***,the mechanical properties of the self-assembled polypyrrole actuator are verified by the design and fabrication of the microgripper.

关键词： conductive polymer polypyrrole mechanical characteristics actuators sensing characteristics

Dative B–N bonds weaven toward two-dimensional purely organic materials for single crystals

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Science China Chemistry 2025年第1期68卷 12-14页

作者： wei-Lei Zhou Siwei Wang Yong Chen College of Chemistry and Materials Science Inner Mongolia Key Laboratory of Chemistry for Nature Products and Synthesis for Functional Molecules Innovation Team of Optical Functional Molecular Devices Inner Mongolia Minzu University College of Chemistry Nankai University

Molecular topology is one of the important topics to study and understand the relationship between molecular structure and properties [1]. Particularly, two-dimensional (2D) materials with extremely high surface area and ultra-thin morphology have attracted considerable attention due to their unexpected properties in materials and chemistry [2,3].

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