检索结果-南通市图书馆

Transforming liquid flow fuel cells to controllable reactors for highlyefficient oxidation of 5-hydroxymethylfurfural to 2, 5-furandicarboxylic acid at low temperature

在线全文

学校读者我要写书评

暂无评论

Journal of Energy Chemistry 2024年第3期90卷 621-631,I0014页

作者： Ye Qiang Xi Liu Denghao Ouyang zhao Jiang Xuebing zhao Key Laboratory of Industrial Biocatalysis Ministry of EducationTsinghua UniversityBeijing 100084China Institute of Applied Chemistry Department of Chemical EngineeringTsinghua UniversityBeijing 100084China School of Chemical Engineering and Technology Xi'an Jiaotong UniversityXi'an 710049ShaanxiChina

Highly-efficient oxidation of 5-hydroxymethylfurtural(HMF) to 2,5-furandicarboxylic acid(FDCA) at low temperature with air as the oxidant is still ***,inspired by the respirato ry electron transport chain(ETC) of living cells mediated by electron carriers,we constructed artificial ETCs and transformed liquid flow fuel cells(LFFCs) to flexible reactors for efficient oxidation of HMF to produce FDCA under mild *** LFFC reactor employed an electrodeposition modified nickel foam as an anode to promote HMF oxidation and(VO_(2))_(2)SO_(4) as a cathode electron carrier to facilitate the electron transfer to *** reaction rate could be easily controlled by selecting the anode catalyst,adjusting the external loading and changing the cathodic electron carrier or oxidants.A maximal power density of 44.9 mW cm^(-2) at room temperature was achieved,while for FDCA production,short-circuit condition was preferred to achieve quick transfer of *** a single batch operation with 0.1 M initial HMF,FDCA yield reached 97.1%.By fed-batch operation,FDCA concentration reached 144.5 g L^(-1) with a total yield of 96%.Ni^(2+)/Ni^(3+) redox couple was the active species mediating the electron transfer,while both experimental and DFT calculation results indicated that HMFCA pathway was the preferred reaction mechanism.

关键词： 5-Hydroxymethylfurfural 2 5-Furandicarboxylic acid Electrodeposition Electron transport chain Liquid flow fuel cell

Cortical Organoid-on-a-Chip with Physiological Hypoxia for Investigating Tanshinone IIA-Induced Neural Differentiation

在线全文

学校读者我要写书评

暂无评论

Research 2024年第3期2023卷 457-468页

作者： Yue Zhi Yujuan Zhu Jinglin Wang Junqi zhao Yuanjin zhao Department of Rheumatology and Immunology Nanjing Drum Tower HospitalClinical Medical College of Traditional Chinese and Western MedicineNanjing University of Chinese MedicineNanjing210023China State Key Laboratory of Bioelectronics School of Biological Science and Medical EngineeringSoutheast UniversityNanjing210096China Shenzhen Research Institute Southeast UniversityShenzhen518038China

Cortical organoids represent cutting-edge models for mimic human brain development during the early and even middle stage of pregnancy, while they often fail to recreate the complex microenvironmental factors, such as physiological hypoxia. Herein, to recapitulate fetal brain development, we propose a novel cortical organoid-on-a-chip with physiological hypoxia and further explore the effects of tanshinone IIA (Tan IIA) in neural differentiation. The microfluidic chip was designed with a micropillar array for the controlled and efficient generation of cortical organoids. With low oxygen, the generated cortical organoids could recapitulate key aspects of early-gestational human brain development. Compared to organoids in normoxic culturing condition, the promoted neurogenesis, synaptogenesis and neuronal maturation were observed in the present microsystem, suggesting the significance of physiological hypoxia in cortical development. Based on this model, we have found that Chinese herbal drug Tan IIA could promote neural differentiation and maturation, indicating its potential therapeutic effects on neurodevelopmental disorders as well as congenital neuropsychiatric diseases. These results indicate that the proposed biomimetic cortical organoid-on-a-chip model with physiological hypoxia can offer a promising platform to simulate prenatal environment, explore brain development, and screen natural neuroactive components.

关键词： promoted herbal cutting

Editable semiconductor photo-electrodes for sustainable ammonia synthesis

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Nano Research 2024年第4期17卷 3107-3112页

作者： Ning Lan Kun Du Erling zhao Wei zhao Tao Ling Key Laboratory for Advanced Ceramics and Machining Technology of Ministry of Education Institute of New-EnergySchool of Materials Science and EngineeringTianjin UniversityTianjin 300072China School of Materials Science and Engineering Tianjin Chengjian UniversityTianjin 300384China

Powered by an inexhaustible supply of solar energy,photoelectrochemical(PEC)nitrogen reduction reaction(NRR)provides an ideal solution for the synthesis of green ammonia(NH_(3)).Although great efforts have been made in the past decades,there are still significant challenges in increasing the NH_(3) yields of the PEC-NRR *** addition to the issues of low activity and selectivity similar to electrochemical NRR,the progress of PEC-NRR is also impeded by the limited increase in NH_(3) yields as the electrode is ***,we propose an editable electrode design strategy that parallels unit photo-electrodes to achieve a linear increase in NH_(3) yields with electrode active *** demonstrate that the editable electrode design strategy minimizes the electrode charge transfer resistance,allowing more photo-generated carriers to reach the electrode surface and promote the catalytic *** believe that this editable electrode design strategy provides an avenue to achieve sustainable PEC NH_(3) production.

关键词： editable electrode photoelectrochemical nitrogen reduction reaction parallel electrode ZnSe

Intuitive Human-Robot-Environment Interaction With EMG Signals:A Review

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

IEEE/CAA Journal of Automatica Sinica 2024年第5期11卷 1075-1091页

作者： Dezhen Xiong Daohui Zhang Yaqi Chu Yiwen zhao Xingang zhao State Key Laboratory of Robotics Shenyang Institute of AutomationChinese Academy of SciencesShenyang 110016 Institutes for Robotics and Intelligent Manufacturing Chinese Academy of SciencesShenyang 110169 University of Chinese Academy of Sciences Beijing 100049China

A long history has passed since electromyography(EMG)signals have been explored in human-centered robots for intuitive ***,it still has a gap between scientific research and real-life *** studies mainly focused on EMG decoding algorithms,leaving a dynamic relationship between the human,robot,and uncertain environment in real-life scenarios seldomly *** fill this gap,this paper presents a comprehensive review of EMG-based techniques in human-robot-environment interaction(HREI)*** general processing framework is summarized,and three interaction paradigms,including direct control,sensory feedback,and partial autonomous control,are ***-based intention decoding is treated as a module of the proposed *** key issues involving precision,stability,user attention,compliance,and environmental awareness in this field are *** important directions,including EMG decomposition,robust algorithms,HREI dataset,proprioception feedback,reinforcement learning,and embodied intelligence,are proposed to pave the way for future *** the best of what we know,this is the first time that a review of EMG-based methods in the HREI system is *** provides a novel and broader perspective to improve the practicability of current myoelectric interaction systems,in which factors in human-robot interaction,robot-environment interaction,and state perception by human sensations are considered,which has never been done by previous studies.

关键词： robot summarized Robot

Application of ultrasonic fatigue technology in very-high-cycle fatigue testing of aviation gas turbine engine blade materials:A review

在线全文

学校读者我要写书评

暂无评论

Science China(Technological Sciences) 2024年第5期67卷 1317-1363页

作者： zhao JiuCheng WAN Jie ZHANG ShiZhong YAN ChuLiang zhao HongWei Key Laboratory of CNC Equipment Reliability Ministry of Education Jilin UniversityChangchun 130025China School of Mechanical&Aerospace Engineering Jilin UniversityChangchun 130025China Chongqing Research Institute of Jilin University Chongqing401120China School of Aeronautic Science and Engineering Beihang UniversityBeijing 102206China

The need for very-high-cycle fatigue(VHCF)testing up to 1010cycles of aviation gas turbine engine blade materials under combined mechanical loads and complex environments has encouraged the development of VHCF testing instrumentation and *** article begins with a comprehensive review of the existing available techniques that enable VHCF *** advances in ultrasonic fatigue testing(UFT)techniques are highlighted,containing their new capabilities and methods for single load,multiaxial load,variable amplitude fatigue,and combined cycle *** techniques for conducting UFT in high-temperature,humid environments,and corrosive environments are *** developments in mechanical loading and environmental building techniques provide the possibility of laboratory construction for real service conditions of blade *** techniques that can be used for in situ monitoring of VHCF damage are *** issues in the UFT field are presented,and countermeasures are ***,the existing problems and future trends in the field are briefly described.

关键词： aviation gas turbine engine blade materials ultrasonic fatigue very-high-cycle fatigue high-temperature complex stress in situ testing

金沙江干热河谷冲沟系统优先流影响下的土壤可蚀性

在线全文

学校读者我要写书评

暂无评论

北京林业大学学报 2023年第4期45卷 101-113页

作者：徐贵迁赵洋毅王克勤段旭李志成西南林业大学生态与环境学院云南昆明650224 国家林业和草原局云南玉溪森林生态系统国家定位观测研究站云南昆明650224

【目的】为探究金沙江干热河谷冲沟系统优先流影响下的土壤可蚀性差异规律,揭示冲沟发育区土、水相互作用机理,为干热河谷地区水土流失治理及生态恢复提供理论依据。【方法】在干热河谷典型冲沟发育区选择完整冲沟作为研究对象,基于染... 详细信息

【目的】为探究金沙江干热河谷冲沟系统优先流影响下的土壤可蚀性差异规律,揭示冲沟发育区土、水相互作用机理,为干热河谷地区水土流失治理及生态恢复提供理论依据。【方法】在干热河谷典型冲沟发育区选择完整冲沟作为研究对象,基于染色示踪、土壤抗冲抗蚀及土壤理化试验,利用主成分分析等统计分析方法获取土壤优先流、土壤可蚀性指标及其相关关系,明晰集水区、沟壁、沟床、沟底完整冲沟系统土壤优先流特征,探究优先流和土壤可蚀性之间的关系。【结果】干热河谷冲沟优先流类型以“大孔隙流”为主,伴随“指流”和“漏斗流”,优先流百分数呈集水区>沟壁>沟床>沟底,说明冲沟上游优先流发育程度高于下游。冲沟内优先流区有机质含量、土壤含水率均高于基质流区,机械组成黏粒、粉粒、砂粒配比优先流区优于基质流区,土壤密度优先流区低于基质流区。冲沟内优先流区土壤抗冲系数小于基质流区,表明优先流会使土壤稳定性降低,抗蚀指数呈优先流区大于基质流区,说明土壤水分溶质运移会使局部土壤抗蚀性提高。冲沟系统土壤可蚀性因子(K)与优先流百分数、优先流区染色面积比、最大染色深度均呈正相关关系,同时主成分分析显示以上3个因子是影响土壤可蚀性的主要因子。【结论】优先流发育程度高的土层中优先流区K值总是大于基质流区,在优先流发育不足土层中则相反,优先流发育一定程度上会提高土壤可蚀性。

关键词：干热河谷冲沟优先流区基质流区土壤可蚀性

Insight into the Inhibition of the Poisonous Sulfide Production from Sulfate-Reducing Microbiota in Mariculture Habitat

在线全文

学校读者我要写书评

暂无评论

Journal of Ocean University of China 2024年第2期23卷 447-454页

作者： zhao Xuning ZHANG Zhiming zhao Yangguo MUPINDU Progress Shandong Provincial Key Laboratory of Marine Environment and Geological Engineering(MEGE) College of Environmental Science and EngineeringOcean University of ChinaQingdao 266100China Key Laboratory of Marine Environmental Science and Ecology(Ocean University of China) Ministry of EducationQingdao 266100China

The production of toxic sulfides is a common environmental problem in ***,the effective inhibition of sulfidogens is the key to prevent sulfides *** this study,the possibility and mechanism of nitrate(NO_(3)^(−))inhibiting the activity of the sulfate-reducing microbiota(SRM)from mariculture sediments was *** results showed that 1,3,and 5 mmol L^(−1)NO_(3)^(−)continuously inhibited sulfide production for 1-3 *** NO_(3)^(−) dosage increased to 7 mmol L^(−1),the duration of inhibition increased to 6 *** product NO_(2)^(−)heavily inhibited the activity of dissimilar sulfate reductase gene(dsrB)by 3 orders,which was the main reason that the sulfate-reducing activity was *** SRM structure changed significantly with the dosage of NO_(3)^(−),while the abundance of sulfidogens Desulfovibrio species increased due to their capability of detoxifying nitrite through nitrite ***,sulfidogens Desulfovibrio species are more adaptable to a high nitrate/nitrite environment,and the traditional control strategies by dosing nitrate/nitrite should be paid more attention *** findings will serve as helpful guidelines for sulfate-reducing microbiota in the habitat of mariculture to reduce their generation of poisonous sulfide.

关键词： sulfate-reducing microbiota sulfide nitrate Desulfovibrio mariculture

THE EXISTENCE OF PSEUDOHARMONIC MAPS FOR SMALL HORIZONTAL ENERGY

在线全文

学校读者我要写书评

暂无评论

Acta Mathematica Scientia 2024年第5期44卷 1955-1964页

作者： Biqiang zhao Shanghai Center for Mathematical Sciences Fudan UniversityShanghai200433China

In this paper,we consider pseudoharmonic heat flow with small initial horizontal energy and give the existence of pseudoharmonic maps from closed pseudo-Hermitian manifolds into closed Riemannian manifolds.

关键词： pseudoharmonic map pseudoharmonic heat flow small horizontal energy

滇东喀斯特石漠化地区不同植被模式土壤酶活性与有机碳

在线全文

学校读者我要写书评

暂无评论

东北林业大学学报 2015年第11期43卷 79-83,97页

作者：曹向文赵洋毅熊好琴段旭舒树淼西南林业大学昆明650224

为探讨喀斯特石漠化地区植被对土壤质量的改良作用,以裸地为对照,利用冗余分析法,对滇东喀斯特石漠化地区4种不同植被模式、不同层次的土壤酶活性以及有机碳质量分数的关系。结果表明:(1)各植被模式下土壤有机碳质量分数及酶活性均表现... 详细信息

为探讨喀斯特石漠化地区植被对土壤质量的改良作用,以裸地为对照,利用冗余分析法,对滇东喀斯特石漠化地区4种不同植被模式、不同层次的土壤酶活性以及有机碳质量分数的关系。结果表明:(1)各植被模式下土壤有机碳质量分数及酶活性均表现为土壤表层最高,针阔混交林模式和灌草模式对提高土壤有机碳质量分数及酶活性的作用较显著;(2)研究区土壤有机碳与过氧化氢酶、蔗糖酶、脲酶、多酚氧化酶呈极显著的正相关关系,与淀粉酶存在显著的正相关关系,相关系数与其在RDA(冗余分析)排序图中的夹角变化规律一致;(3)在RDA排序图中,生境由有机碳质量分数较低的针叶林模式过渡到有机碳质量分数较高的灌草模式和针阔混交林模式时,在有机碳质量分数较高的生境中,过氧化氢酶、脲酶、蔗糖酶、多酚氧化酶活性也较高。RDA排序图直观展示了土壤中各种酶活性对土壤有机碳的敏感强度,因此,可作为探索土壤环境因子与酶活性内在关系的新视角。

关键词：喀斯特土壤酶活性土壤有机碳