检索结果-南通市图书馆

A high-entropy spinel ceramic oxide as the cathode for proton-conducting solid oxide fuel cells

Journal of Advanced Ceramics 2022年第5期11卷 794-804页

作者： yangsen xu Xi xu Lei BI School of Resource Environment and Safety Engineering University of South ChinaHengyang 421001China Department of Materials Imperial College London SW72BPUK

A high-entropy ceramic oxide is used as the cathode for the first time for proton-conducting solid oxide fuel cells(H-SOFCs).The Fe_(0.6)Mn_(0.6)Co_(0.6)Ni_(0.6)Cr_(0.6)O_(4)(FMCNC)high-entropy spinel oxide has been successfully prepared,and the in situ chemical stability test demonstrates that the FMCNC material has good stability against CO_(2).The first-principles calculation indicates that the high-entropy structure enhances the properties of the FMCNC material that surpasses their individual components,leading to lower O_(2)adsorption energy for FMCNC than that for the individual components.The HSOFC using the FMCNC cathode reaches an encouraging peak power density(PPD)of 1052 mW·cm^(-2)at 700℃,which is higher than those of the H-SOFCs reported recently.Additional comparison was made between the high-entropy FMCNC cathode and the traditional Mn_(1.6)Cu_(1.4)O_(4)(MCO)spinel cathode without the high-entropy structure,revealing that the formation of the high-entropy material allows the enhanced protonation ability as well as the movement of the O p-band center closer to the Fermi level,thus improving the cathode catalytic activity.As a result,the high-entropy FMCNC has a much-decreased polarization resistance of 0.057Ω·cm^(2)at 700℃,which is half of that for the traditional MCO spinel cathode without the high-entropy design.The excellent performance of the FMCNC cell indicates that the high-entropy design makes a new life for the spinel oxide as the cathode for HSOFCs,offering a novel and promising route for the development of high-performance materials for H-SOFCs.

关键词： proton-conducting oxides high-entropy oxides cathode solid oxide fuel cells(SOFCs)

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Taking advantage of Li-evaporation in LiCoO_(2) as cathode for proton-conducting solid oxide fuel cells

引用

Journal of Advanced Ceramics 2022年第12期11卷 1849-1859页

作者： yangsen xu Shoufu YU Yanru YIN Lei BI School of Resource Environment and Safety Engineering University of South ChinaHengyang 421001China

LiCoO_(2),a widely used electrode material for Li-ion batteries,was found to be suitable as a cathode material for proton-conducting solid oxide fuel cells(H-SOFCs).Although the evaporation of Li in LiCoO_(2) was detrimental to the Li-ion battery performance,the Li-evaporation was found to be beneficial for the H-SOFCs.The partial evaporation of Li in the LiCoO_(2) material preparation procedure led to the in-situ formation of the LiCoO_(2)+Co_(3)O_(4) composite.Compared to the cell using the pure phase LiCoO_(2) cathode that only generated moderate fuel cell performance,the H-SOFCs using the LiCoO_(2)+Co_(3)O_(4) cathode showed a high fuel cell performance of 1160 mW·cm^(-2) at 700℃,suggesting that the formation of Co_(3)O_(4) was critical for enhancing the performance of the LiCoO_(2) cathode.The first-principles calculation gave insights into the performance improvements,indicating that the in-situ formation of Co_(3)O_(4) due to the Li-evaporation in LiCoO_(2) could dramatically decrease the formation energy of oxygen vacancies that is essential for the high cathode performance.The evaporation of Li in LiCoO_(2),which is regarded as a drawback for the Li-ion batteries,is demonstrated to be advantageous for the H-SOFCs,offering new selections of cathode candidates for the H-SOFCs.

关键词： cathode composite proton conductor solid oxide fuel cells(SOFCs)

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Visiting the roles of Sr-or Ca-doping on the oxygen reduction reaction activity and stability of a perovskite cathode for proton conducting solid oxide fuel cells

引用

SusMat 2023年第1期3卷 91-101页

作者： Tong Hu yangsen xu Kang xu Feng Zhu Yu Chen School of Environment and Energy South China University of TechnologyGuangzhouChina

While double perovskites of PrBaCo_(2)O_(6)(PBC)have been extensively developed as the cathodes for proton-conducting solid oxide fuel cells(H-SOFCs),the effects of Sr-or Ca-doping at the A site on the activity and stability of the oxygen reduction reaction are yet to be fully studied.Here,the effect of A-site doping on the oxygen reduction reaction activity and stability has been studied by evaluating the performance of both symmetrical and single cells.It is shown that Ca-doped PBC(PrBa_(0.8)Ca_(0.2)Co_(2)O_(6),PBCC)shows a slightly smaller polarization resistance(0.076Ωcm^(2))than that(0.085Ωcm^(2))of Sr-doped PBC(PrBa0.8Sr0.2Co2O6,PBSC)at 700◦C in wet air.Moreover,the degradation rate of PBCC is 0.0003Ωcm^(2)h^(−1)(0.3%h−1)in 100 h,about 1/10 of that of PBSC at 700◦C in wet air.In addition,it is also confirmed that single cells with PBCC cathode show higher peak power density(1.22Wcm^(−2)vs.1.08Wcm^(−2)at 650◦C)and better durability(degradation rate of 0.1%h^(−1)vs.0.13%h^(−1))than those with PBSC cathode.The distribution of relaxation time analyses suggests that the better stability of the PBCC electrode may come from the fast and stable surface oxygen exchange process in the medium frequency range of the electrochemical impedance spectrum.

关键词： activity and stability cathode oxygen reduction reaction proton-conducting solid oxide fuel cells

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Entropy engineering design of high-performing lithiated oxide cathodes for proton-conducting solid oxide fuel cells

引用

Journal of Advanced Ceramics 2023年第11期12卷 2017-2031页

作者： Yufeng Li yangsen xu Yanru Yin Hailu Dai Yueyuan Gu Lei Bi School of Resource Environment and Safety Engineering University of South ChinaHengyang 421001China School of Materials Science and Engineering Yancheng Institute of TechnologyYancheng 224051China

A new medium entropy material LiCo_(0.25)Fe_(0.25)Mn_(0.2)5Ni_(0.2)5O_(2)(LCFMN)is proposed as a cathode for proton-conducting solid oxide fuel cells(H-SOFCs).Unlike traditional LiXO_(2)(X=Co,Fe,Mn,Ni)lithiated oxides,which have issues like phase impurity,poor chemical compatibility,or poor fuel cell performance,the new LCFMN material mitigates these problems,allowing for the successful preparation of pure phase LCFMN with good chemical and thermal compatibility to the electrolyte.Furthermore,the entropy engineering strategy is found to weaken the covalence bond between the metal and oxygen in the LCFMN lattice,favoring the creation of oxygen vacancies and increasing cathode activity.As a result,the H-SOFC with the LCFMN cathode achieves an unprecedented fuel cell output of 1803 mW·cm^(−2)at 700℃,the highest ever reported for H-SOFCs with lithiated oxide cathodes.In addition to high fuel cell performance,the LCFMN cathode permits stable fuel cell operation for more than 450 h without visible degradation,demonstrating that LCFMN is a suitable cathode choice for H-SOFCs that combining high performance and good stability.

关键词： entropy design LiCo_(0.25)Fe_(0.25)Mn_(0.25)Ni_(0.25)O_(2)(LCFMN) cathode proton conductor solid oxide fuel cells(SOFCs)

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Riverine sulfate sources and behaviors in arid environment,Northwest China:Constraints from sulfur and oxygen isotopes

引用

Journal of Environmental Sciences 2024年第3期137卷 716-731页

作者： Yifu xu Wenjing Liu Bing xu Zhifang xu Key Laboratory of Cenozoic Geology and Environment Institute of Geology and GeophysicsChinese Academy of SciencesBeijing 100029China Innovation Academy for Earth Science Chinese Academy of SciencesBeijing 100029China University of Chinese Academy of Sciences Beijing 100049China

The fate of riverine sulfate ion (SO_(4)^(2-)) and its environmental effects in arid environment are difficult to evaluate due to its complicated sources and strongly coupled behaviors with water cycle which is significantly modified by humans.To understand the sulfur cycle in aquatic systems in arid environment,the chemical and sulfur and oxygen isotopic compositions (δ^(34)S_(SO4)and δ^(18)O_(SO4)) of major rivers around the Badain Jaran Desert,northwestern China,were investigated.These rivers had averaged SO_(4)^(2-)content at 1336μmol/L,over 10times higher than the global average.The δ^(34)S_(SO4)and δ^(18)O_(SO4)values ranged from-5.3‰to+11.8‰and+1.6‰to+12.8‰,respectively.The end-member analysis and the inverse model showed that riverine sulfate was mainly derived from evaporites dissolution (0-87%),sulfide oxidation (13%-100%) and precipitation (0-33%),indicating heterogeneity in sulfur sources and behaviors along the river drainage with the lithology variations and climate gradients.Multiple isotopic tools combining with hydro-chemistry compositions could be applied to reveal sulfur cycle in arid environment.Based on the calculation,sulfide oxidation plays the primary role in the headwater and upstream in the Qilian-Mountains area,where sulfide is widely exposed.While the proportion of evaporites dissolution contributing to riverine sulfate is much higher in downstream in a drier environment.Besides,less precipitation and higher temperature can lead to more intensive evaporation,affecting the process of sulfide oxidation and enhancing the rates of evaporites dissolution and sulfate precipitation in the basin.

关键词： Sulfur and oxygen isotopes Source apportionment Inverse model Arid environment Inland rivers Northwestern China

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Biohythane production from two-stage anaerobic digestion of food waste:A review

引用

Journal of Environmental Sciences 2024年第5期139卷 334-349页

作者： Xiaona An Ying xu Xiaohu Dai State Key Laboratory of Pollution Control and Resource Reuse School of Environmental Science and EngineeringTongji UniversityShanghai 200092China Shanghai Institute of Pollution Control and Ecological Security Shanghai 200092China

The biotransformation of food waste(FW)to bioenergy has attracted considerable research attention as a means to address the energy crisis and waste disposal problems.To this end,a promising technique is two-stage anaerobic digestion(TSAD),in which the FW is transformed to biohythane,a gaseous mixture of biomethane and biohydrogen.This review summarises the main characteristics of FW and describes the basic principle of TSAD.Moreover,the factors influencing the TSAD performance are identified,and an overview of the research status;economic aspects;and strategies such as pre-treatment,co-digestion,and regulation of microbial consortia to increase the biohythane yield from TSAD is provided.Additionally,the challenges and future considerations associated with the treatment of FW by TSAD are highlighted.This paper can provide valuable reference for the improvement and widespread implementation of TSAD-based FW treatment.

关键词： Two-stage anaerobic digestion(TSAD) Food waste(FW) Methane production Hydrogen production

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Identification of high oxygen-consuming substances in stormwater drainage systems illicitly connected with sewage system

引用

Journal of Environmental Sciences 2024年第4期138卷 132-140页

作者： Chen xu Zuxin xu Wenhai Chu Shanshan Wu Rong Xiao Lei Su State Key Laboratory of Pollution Control and Resource Reuse College of Environmental Science and EngineeringTongji UniversityShanghai 200092China Ministry of Education Key Laboratory of Yangtze River Water Environment Tongji UniversityShanghai 200092China Guangzhou Resource Environmental Protection Technology Co. Ltd.Guangzhou 510030China

The dissolved oxygen content in water is an important indicator for assessing the quality of the water environment,and maintaining a certain amount of dissolved oxygen is essential for the healthy development of the ecological environment.When a water body is anoxic,the activity of anaerobic microorganisms increases and organic matter is decomposed to produce a large number of blackening and odorizing substances,resulting in black and odorous water bodies,which is a very common and typical phenomenon in China.Presently,there is still a relatively universal occurrence of illicitly connected stormwater and sewage pipes in the urban drainage pipe network in China,which makes oxygen-consuming substances be directly discharged into rivers through stormwater pipes and consume the dissolved oxygen in the water bodies,resulting in an oxygen deficiency of the water.This induces seasonal or year-round black and stink phenomena in urban rivers.Hence,identifying high oxygen-consuming substances,which lays the foundation for the subsequent removal of oxygen-consuming substances,is essential.Through a series of comparisons of water quality indicators and analysis of organic characteristics,it was found that the oxygen consumption capacity of domestic sewage was higher than that of industrial wastewater in the selected area of this study,and the oxygen-consuming substances of domestic sewage were small molecular amino acids.By comparing 20 conventional free amino acids,it was found that seven of them consumed oxygen easily,and compared with chemical oxygen consumption,biological oxygen consumption was in a leading position.

关键词： Urban drainage system Oxygen-consuming substances Domestic sewage Amino acid

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Aldehyde oxidase mediated enantioselective metabolic health risk of dinotefuran

引用

Science China Chemistry 2024年第6期67卷 2079-2091页

作者： Liwei xu Xinxin xu Hua Kuang Chuanlai xu Xiaoling Wu State Key Laboratory of Food Science and Resources Jiangnan UniversityWuxi214122China International Joint Research Laboratory for Biointerface and Biodetection and School of Food Science and Technology Jiangnan UniversityWuxi214122China Collaborative Innovation center of Food Safety and Quality Control in Jiangsu Province Jiangnan UniversityWuxi214122China

Chiral pollutants often pose significant differential environmental health risks.In this study,the biotransformation of chiral dinotefuran(DIN)and its enantioselective metabolic toxicity mechanisms have been systemically investigated.Firstly,reversedphase chromatography-high resolution mass spectrometry was developed to quantify the content of DIN R/S chiral enantiomer with pg level sensitivity,revealing a lower elimination rate constant(K_(e))of S-DIN(0.730 h^(-1))than R-DIN(0.746 h^(-1)).Secondly,the interaction mechanism between DIN metabolism and important endogenous bioactive molecules,such as aldehyde oxidase(AOX)and neurotransmitters,was revealed.The DIN nitro-group was converted into a guanidine group by the reducing site of nearby flavin adenine dinucleotide(FAD)in AOX with the preferred higher affinity of S-configuration.Meanwhile,the endogenous tryptophan(Trp)aldehyde metabolic intermediate,5-hydroxyindoleacetaldehyde(5-HIAL),provides a persistent electron donor for DIN reduction via the oxidation-catalyzed site in AOX,resulting in remarkable up-regulation of monoamine neurotransmitters such as serotonin and dopamine.Thirdly,the higher level of neurotransmitters further mediated dysregulation of oxylipin homeostasis via the serotonergic pathway,where S-DIN exhibited more pronounced liver lipid damage and environmental health risk with the accumulated lipid biomarkers,oxidized triglyceride(OxTG)and oxidized sphingomyelin(OxSM).This study elucidates the AOX-mediated enantioselectivity metabolic pathway of DIN,providing a new analytical method for chiral pollutants and paves the way for their health risk assessments.

关键词： neonicotinoid dinotefuran enantiomer aldehyde oxidase metabolomics health risk

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Mapping super-resolution image quality

引用

Light(Science & Applications) 2024年第2期13卷 178-180页

作者： Megan A.Steves Ke xu Department of Chemistry University of CaliforniaBerkeleyCA94720USA

The local quality of super-resolution microscopy images can be assessed and mapped by rolling Fourier ring correlation,even when image quality varies within a single image.

关键词： image resolution Mapping

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Controllable chemical redox reactions to couple microbial degradation for organic contaminated sites remediation:A review

引用

Journal of Environmental Sciences 2024年第5期139卷 428-445页

作者： Bin Chen Jiang xu Lizhong Zhu College of Environmental and Resource Sciences Zhejiang UniversityHangzhou 310058China Zhejiang Provincial Key Laboratory of Organic Pollution Process and Control Zhejiang UniversityHangzhou 310058China Zhejiang Agriculture&Forest University Lin'an 311300China

Global environmental concern over organic contaminated sites has been progressively conspicuous during the process of urbanization and industrial restructuring.While traditional physical or chemical remediation technologies may significantly destroy the soil structure and function,coupling moderate chemical degradation with microbial remediation becomes a potential way for the green,economic,and efficient remediation of contaminated sites.Hence,this work systematically elucidates why and how to couple chemical technology with microbial remediation,mainly focused on the controllable redox reactions of organic contaminants.The rational design of materials structure,selective generation of reactive oxygen species,and estimation of degradation pathway are described for chemical oxidation.Meanwhile,current progress on efficient and selective reductions of organic contaminants(i.e.,dechlorination,defluorination,-NO_(2) reduction)is introduced.Combined with the microbial remediation of contaminated sites,several consideration factors of how to couple chemical and microbial remediation are proposed based on both fundamental and practical points of view.This review will advance the understanding and development of chemical-microbial coupled remediation for organic contaminated sites.

关键词： Soil remediation Groundwater remediation Rational design Reactive species Environmental nanotechnology

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

欢迎您,

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

请选择保存的检索档案：

请选择收藏分类：

通借通还

欢迎您,

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：