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Rare Metals 2022年第2期41卷 639-649页

作者： Rui Lv yan-qin liang Zhao-yang Li Sheng-Li Zhu Zhen-Duo Cui Shui-LinWu School of Materials Science&Engineering the Key Laboratory of Advanced Ceramics and Machining Technology by the Ministry of Education of ChinaTianjin UniversityTianjin 300072China The Key Laboratory of Advanced Ceramics and Machining Technology by the Ministry of Education of China Tianjin UniversityTianjin 300072China

Pathogenic bacteria have been threatening the daily life of human *** effective methods without causing drug-resistance of bacteria need to be developed to fight against these ***,flower-like CuS/-graphene oxide(GO)hybrids have been successfully synthesized via simple one-pot hydrothermal *** worked as an excellent electron acceptor to transport the photogenerated electrons from CuS,which can suppress the recombination of hole–electron pairs efficiently,thus enhancing the photocatalytic *** addition,the morphology of CuS and GO with high specific surface area and the increased defect in GO also improved photocatalytic performance of the *** to the synergy of photothermal,enhanced photocatalytic effect and released Cu ions,CuS/GO exhibited outstanding antibacterial efficacy under visible light irradiation for 15 ***,the hybrid showed great biocompatibility to L929 ***,the synthesized CuS/GO would be a promising antibacterial material for daily life including rapid water disinfection and wounds sterilization.

关键词： Antibacterial Photocatalytic CuS Graphene oxide Photoresponsive

Preparation of hydroxyapatite layer on Ti-based bulk metallic glasses by acid and alkali pre-treatment

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Rare Metals 2015年第1期34卷 22-27页

作者： Hao Hu Zhen-Duo Cui Sheng-Li Zhu Zhao-yang Li yan-qin liang Xian-Jin yang School of Materials Science and Engineering Tianjin University Tianjin Key Laboratory of Composite and Functional Materials

In this paper, a thin calcium phosphate layer was prepared on the surface of Ti4oZr10Cu36Pd14 bulk metallic glasses （BMGs）. All samples were dipped in HNO3 aqueous solution and boiled in 1.2 mol-L-I NaOH aqueous solution. After the two preliminary treatment steps, they were soaked in simulated body fluid （SBF） to form an apatite layer on the surface. After immersion for 12 days, a coating composed mainly of Ca-P particles was rapidly deposited on the surface of Ti40Zr10Cu36Pd14 bulk metallic glasses. The surfaces of chemically treated sam- ples and the samples after immersion in SBF were char- acterized by X-ray diffraction （XRD）, X-ray photoemission spectroscopy （XPS）, field emission scanning electron microscopy （FESEM）, and energy dispersive spectroscopy （EDS）. Analysis results indicate that this apatite coating consists of Ca-P particles with different diameters. In addition, the Ca/P ratio of the apatite coatings immersed for 14 days is 1.62, which is close to that of hydroxyapatite （HA）.

关键词： Metallic glass Titanium alloy Hydroxyapatite Thin film

Zr_(55)Al_(10)Ni_(5)Cu_(30)amorphous alloy film prepared by magnetron sputtering method

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Rare Metals 2021年第8期40卷 2237-2243页

作者： Dong-Mei Mi Sheng-Li Zhu yan-qin liang Zhao-yang Li Zhen-Duo Cui Xian-Jin yang Akihisa Inoue School of Materials Science and Engineering Tianjin UniversityTianjin300072China Tianjin Key Laboratory of Composite and Functional Materials Tianjin300072China Key Laboratory of Advanced Ceramics and Machining Technology Ministry of EducationTianjin300072China Department of Physics Kings Abudulaziz UniversityJeddah22254Saudi Arabia

In this work,amorphous Zr_(55)Al_(10)Ni_(5)Cu_(30)alloy thin film was prepared on D36 steel substrate by magnetron sputtering *** film was characterized by scanning electron microscopy(SEM),X-ray diffraction(XRD),atomic force microscopy(AFM),hardness tester and nano *** behavior of the film was investigated in 3.5%NaCl aqueous solutions by an electrochemical *** room temperature,the amorphous alloy film was formed completely after sputtering for 5 *** surface morphology of the amorphous alloy film was uniform and *** of the amorphous alloy film improved the microhardness and corrosion resistance of the D36 *** amorphous alloy film(prepared at room temperature for 5 h)exhibited good adhesion strength with the *** as-sputtered sample exhibited a crevice corrosion trend when the sputtering time was too short(1 h)or too long(10 h).

关键词： Magnetron sputtering Amorphous alloy Thin film Corrosion resistance Zr_(55)Al_(10)Ni_(5)Cu_(30)

Highly efficient nanoporous CoBP electrocatalyst for hydrogen evolution reaction

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Rare Metals 2021年第5期40卷 1031-1039页

作者： Hui-Lan Guang Sheng-Li Zhu yan-qin liang Shui-Lin Wu Zhao-yang Li Shui-Yuan Luo Zhen-Duo Cui Akihisa Inoue School of Materials Science and Engineering Tianjin UniversityTianjin 300350China School of Materials Science and Engineering Lanzhou Jiaotong UniversityLanzhou 730070China College of Chemistry Engineering and Materials Science Quanzhou Normal UniversityQuanzhou 362000China International Institute of Green Materials Josai International UniversityTogane 283-8555Japan Department of Physics King Abdulaziz UniversityJeddah 22254Saudi Arabia

Water splitting is an environment friendly and efficient way to produce *** efficient and low-cost non-noble metal catalysts play an important role in hydrogen evolution reaction(HER).Dealloying is a simple method to prepare three-dimensional self-supporting nanoporous materials without conductive supports and *** this work,we prepared self-supporting nanoporous CoBP electrocatalyst by dealloying *** influence of the synergistic effect of nonmetallic elements on catalytic activity was *** synergistic electronic effect of Co,B and P atoms on the surface optimizes the H atoms desorption and results in superior HER *** bi-continuous structure of nanoporous CoBP provides more active area and favors of electron and electrolyte *** nanoporous CoBP with the B/P atomic ratio of 1/3 exhibits low overpotential of 42 mV at 10 mA·cm^(-2),small Tafel slope of 39.8 mV·dec-1 and good long-term stability with no performance decrease for 20 h in alkaline solution.

关键词： Hydrogen evolution reaction Nanoporous Self-supporting electrocatalyst Co-B-P alloy Dealloying

Electrodeposition of self-supported NiMo amorphous coating as an efficient and stable catalyst for hydrogen evolution reaction

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Rare Metals 2022年第8期41卷 2624-2632页

作者： Fu-Hang Yuan Mohammad-Reza Mohammadi Li-Li Ma Zhen-Duo Cui Sheng-Li Zhu Zhao-yang Li Shui-Lin Wu Hui Jiang yan-qin liang School of Materials Science and Engineering Tianjin UniversityTianjin300072China Department of Physics University of Sistan and BaluchestanZahedan98167-45845Iran

NiMo-based materials have been identified as potential candidates of Pt/C electrocatalysts for hydrogen evolution reaction(HER)due to appropriate binding energy to hydrogen,and good resistance to corrosive ***,little work has been carried out to enhance the catalytic performance in large-scale water-alkali *** NoMo amorphous coating,as a highefficient and cost-effective catalyst toward HER,was synthesized by a facile electrodeposition strategy in this *** effects of the pH value of electrolyte on the structure and HER activity of NiMo coating were *** as-prepared NiMo_((pH10))exhibited the highest HER activity with overpotentials of 63.9 and 157.1 mV(***,with 80%potential drop due to electrical resistance(iR)compensation)at the current density of-10 mA·cm^(-2)and-100 mA·cm^(-2).This NiMo_((pH10))coating also had excellent long-term durability of up to100 h stable operation under the constant current density of-100 mA·cm^(-2).The rapid HER kinetics and outstanding endurance can be ascribed to the NiMo compact coating with amorphous structures as well as good contact between NiMo coating and Ni foam substrate,endowing it grand feasibility in practical industrial applications.

关键词： Electrodeposition NiMo coating Hydrogen evolution reaction(HER) Alkaline water electrolysis

Application of carbon materials for Zn anode protection in aqueous Zn metal batteries

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Rare Metals 2024年第10期43卷 4807-4843页

作者： Cui-qin Chao yan-Nan Li yan Zhao College of Energy Materials and Chemistry Inner Mongolia University School of Physical Science and Technology Inner Mongolia University

Aqueous Zn metal batteries (AZMBs) have gained widespread attention due to their high theoretica specific capacity,good safety,and low *** Zn anodes suffer from serious problems of dendrites and side reactions,which should be solved by modifying the Zn anode (Zn host,protective layer),electrolyte,and *** materials with structurally tunable and physicochemical stability properties have been widely used in the study of Zn anode protection and have also been reviewed in the past ***,review reports on carbon-based Zn anodes for Zn anode protection from new perspectives are still urgently ***,the timeliness of the review reports is very valuable for researchers to timely and accurately understand the dynamics of the research ***,this review firs reports the significance of AZMBs and summarizes the current main challenges that should be solved for practical ***,the ways to construct long-life Zn anodes using carbon materials from the perspectives of modified carbon materials with gradient properties (gradient zincophilicity,gradient electrical conductivity,and multigradient deposition) as protective layers/hosts to guide Zn ions toward bottom-up gradient Zn deposition are *** addition,the recent advances of carbon materials for electrolyte and separator modifications are ***,the remaining challenges and future perspectives of carbon materials in AZMBs Zn anode protection are briefly outlined.

关键词： Anode protection Aqueous Zn battery Carbon Gradient deposition

Bilayer Compounded Polytetrafluoroethylene Membrane for Enhanced Oil-Water Emulsion Separation

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Chinese Journal of Polymer Science 2024年第6期42卷 838-850页

作者： Yu-liang yang Tai-Ran Zhang yan-Ting Han Shao-Yun Guo qin-Gong Rong Jia-Bin Shen State Key Laboratory of Polymer Materials Engineering Polymer Research Institute of Sichuan UniversitySichuan Provincial Engineering Laboratory of Plastic/Rubber Complex Processing TechnologyChengdu610065China West China Hospital/West China School of Nursing Sichuan UniversityChengdu610041China Shandong Senrong New Materials Co. Ltd.Zibo256401China

In order to achieve efficient and durable oil-water emulsion separation,the membranes possessing high separation efficiency and mechanical strength attract extensive attention and are in great *** present study,a kind of polytetrafluoroethylene(PTFE)-based bilayer membrane was fabricated by electrospinning fibrous PTFE(fPTFE)on an expanded PTFE(ePTFE)*** morphological observation revealed that the fibrous structure of the fPTFE layer could be tailored by controlling the formulation of spinning *** addition of appropriate polyoxyethylene(PEO)would make the fibers in the fPTFE layer finer and more *** a result,the compounded membrane exhibited a small pore size of approximately 1.25µm and a substantial porosity nearing 80%.This led to super-hydrophobicity,characterized by a high water contact angle(WCA)of 149.8°,and facilitated rapid oil *** water-in-oil emulsion separation experiment further confirmed that the compounded membrane not only had a high separation efficiency closing 100%,but such an outstanding separation capacity could be largely retained,either through multiple cycles of use or through strong acid(pH=1),strong alkali(pH=12),or high-temperature(100°C)***,the mechanical behavior of the bilayer membrane was basically contributed by that of each layer in terms of their volume *** significantly,the poor creep resistance of fPTFE layer was suppressed by compounding with ePTFE ***,this study has laid the groundwork for a novel approach to create PTFE-based compounded membranes with exceptional overall characteristics,showing promise for applications in the realm of emulsion separation.

关键词： ePTFE Electrospinning membrane Bilayer compounding Emulsion separation

Control of chiral-optical activities by magnetic field based on the transformation of achiral binary crystals into chiral ternary crystals

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Science China Chemistry 2024年第7期67卷 2300-2305页

作者： Zhiyan Chen yan Lv Wei qin College of Physics Qingdao UniversityQingdao 266071China School of Physics State Key Laboratory of Crystal MaterialsShandong UniversityJinan 250100China Shandong Linuo Photovoltaic Hi-Tech Co. Ltd.Jinan 250100China

Multicomponent self-assembled chiral systems have attracted great attention due to their promising application in the area of spin-photonics and *** this work,through introducing an achiral third component into an achiral binary crystal,a chiral organic ternary crystal is fabricated,where both pronounced chiral-optical coupling and magnetic field dependence of chiral-optical activities are *** transformation of achiral structure into chiral structure generates a significant effect on the polarized state of light and the electron spin resonance ***,the coupling between circularly polarized photon and spin is observed in chiral ternary crystal with pronounced chiral orbit,where obvious magnetic field-transmissivity loop is ***,temperature could increase the magnitude of lattice parameters to lead to a larger helix radius to increase the chiral orbit ***,this work indicates that the further exploration of photon-chiral orbit-spin interactions in organic chiral ternary crystals is promising.

关键词： organic chiral ternary crystals chiral orbit chiral-optical activities magnetic field

Photothermal-controlled sustainable degradation of protective coating modified Mg alloy using near-infrared light

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Rare Metals 2021年第9期40卷 2538-2551页

作者： Zhi-Xin Han Xiang-Mei Liu Lei Tan Zhao-yang Li Yu-Feng Zheng Kelvin Wai-Kwok Yeung Zhen-Duo Cui yan-qin liang Sheng-Li Zhu Shui-Lin Wu Hubei Key Laboratory of Polymer Materials Ministry-of-Education Key Laboratory for the Green Preparation and Application of Functional MaterialsSchool of Materials Science&EngineeringHubei UniversityWuhan 430062China The Key Laboratory of Advanced Ceramics and Machining Technology by the Ministry of Education of China School of Materials Science&EngineeringTianjin UniversityTianjin 300072China State Key Laboratory for Turbulence and Complex System Department of Materials Science and EngineeringCollege of EngineeringPeking UniversityBeijing 100871China Department of Orthopaedics and Traumatology Li Ka Shing Faculty of MedicineThe University of Hong KongPokfulam 999077Hong KongChina

Controlling the corrosion rate is critical for practical applications of Mg-based alloys. In this work, we constructed a protective coating of hybrid polycaprolactone(H-PCL)/indocyanine green(ICG) on AZ31 Mg alloy,whose degradation rate was controlled by 808-nm nearinfrared(NIR) light irradiation. The corrosion behaviors of H-PCL/ICG coated Mg alloys were systematically investigated by potentiodynamic polarization tests, electrochemical impedance spectroscopy(EIS) and hydrogen evolution experiments. The results disclosed that the H-PCL/ICG composite coating could effectively protect Mg alloy from corroding without NIR light irradiation. In contrast, under 808-nm NIR light irradiation, the corrosion resistance of this composite coating was decreased significantly, i.e., the corrosion current density(i_(corr))increasedfrom(8.81 ± 1.068) 9 10^(-8) to(1.22 ± 0.545) 9 10^(-6) A·cm^(-2). This is because the component of ICG in the coating was excited to produce heat locally, which triggered the glass transition temperature(T_(g)) of H-PCL in the coating, resulting in the motion of the molecular chain segment. Consequently, the electrolytes penetrated the coating and corroded the Mg substrate. In vitro biological experiment indicated that the synthesized coating exhibited good ***, these findings will provide a new strategy for designing novel photoresponsive coatings to remotely adjust the degradation rate of biodegradable metals for biomedical applications.

关键词： Magnesium Corrosion Coating Photoresponsive Surface modification

ALD-induced TiO_(2)/Ag nanofilm for rapid surface photodynamic ion sterilization

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Rare Metals 2022年第12期41卷 4138-4148页

作者： Peng-Fei Cai Jun Li Xin-Bao Wu Zhao-yang Li Jie Shen Jing-Jun Nie Zhen-Duo Cui Da-Fu Chen yan-qin liang Sheng-Li Zhu Shui-Lin Wu School of Materials Science&Engineering The Key Laboratory of Advanced Ceramics and Machining Technology by the Ministry of Education of ChinaTianjin UniversityTianjin 300072China Department of Orthopedic Trauma Beijing Jishuitan HospitalBeijing 100035China Shenzhen Key Laboratory of Spine Surgery Department of Spine SurgeryPeking University Shenzhen HospitalShenzhen 518041China Laboratory of Bone Tissue Engineering Beijing Laboratory of Biomedical MaterialsBeijing Research Institute of Orthopaedics and TraumatologyBeijing Jishuitan HospitalBeijing 100035China

The daily life of people in the intelligent age is inseparable from electronic device,and a number of bacteria on touch screens are increasingly threatening the health of ***,a photocatalytic TiO_(2)/Ag thin film was synthesized on a glass by atomic layer deposition and subsequent in situ ***-visible(UV-Vis)spectra showed that this film can harvest the simulated solar light more efficiently than that of pristine TiO_(2).The antibacterial tests in vitro showed that the antibacterial efficiency of the TiO_(2)/Ag film against *** and *** was 98.2%and 98.6%,under visible light irradiation for 5 *** underlying mechanism was that the in-situ reduction of Ag on the surface of TiO_(2)reduced the bandgap of TiO_(2)from 3.44 to 2.61 eV due to the formation of Schottky heterojunction at the interface between TiO_(2)and ***,TiO_(2)/Ag can generate more reactive oxygen species for bacterial inactivation on the surface of electronic *** importantly,the TiO_(2)/Ag film had great biocompatibility with/without light *** platform not only provides a more convenient choice for the traditional antibacterial mode but also has limitless possibilities for application in the field of billions of touch screens.

关键词： Antibacterial Photoresponsive Photodynamic Surface sterilization Atomic layer deposition(ALD)