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Additive-free synthesis of β-keto phosphorodithioates via geminal hydro-phosphorodithiolation of sulfoxonium ylides with P_(4)S_(10)and alcohols

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Chinese Chemical Letters 2024年第9期35卷 165-168页

作者： Jindong hao Yufen Lv Shuyue Tian chao Ma Wenxiu Cui Huilan Yue Wei Wei Dong Yi Key Laboratory of Catalytic Conversion and Clean Energy in Universities of Shandong Province School of Chemistry and Chemical EngineeringQufu Normal UniversityQufu 273165China Qinghai Provincial Key Laboratory of Tibetan Medicine Research and CAS Key Laboratory of Tibetan Medicine Research Northwest Institute of Plateau BiologyXining 810008China Green Pharmaceutical Technology Key Laboratory of Luzhou City School of PharmacySouthwest Medical UniversityLuzhou 646000China

A simple and additive-free protocol has been developed for the preparation ofβ-keto phosphorodithioates through the three-component reaction of easily available sulfoxonium ylides,P_(4)S_(10),and *** present geminal hydro-phosphorodithiolation reaction was performed at room temperature to construct a series ofβ-keto phosphorodithioates in the absence of any metal reagents,bases,or additives.

关键词： β-Keto phosphorodithioates Phosphorodithiolation Sulfoxonium ylides P_(4)S_(10) Alcohols

Solitons and Their Biperiodic Pulsation in Ultrafast Fiber Lasers Based on CB/GO

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Chinese Physics Letters 2024年第8期41卷 28-32页

作者： Zhen-Tao Ju Zhi-Zeng Si Xin yan chao-Qing Dai College of Optical Mechanical and Electrical EngineeringZhejiang A&F UniversityLin’an 311300China

The carbon black(CB)is introduced to manufacture CB/graphene oxide(GO)composite material to mitigate limitations of GO as a saturable absorber with the excellent performance in ultrafast fiber *** a central wavelength of 1555.5 nm,the stable mode-locked pulse with width of 656 fs,repetition rate of 20.16 MHz,and high signal-to-noise ratio of 82.07 dB is experimentally ***,experimental observations for pulsation phenomena of vector biperiodic solitons combining period-1 and period-17,period-2 and period-32,period-3 and period-36 are verified via simulations.

关键词： fiber periodic absorber

Patient satisfaction and follow-up adherence to glaucoma case management clinic in China

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International Journal of Ophthalmology(English edition) 2024年第1期17卷 73-81页

作者： hao Lin Hu-Jie Lu Wen-Zhe Zhou Shu-Shu Zuo yan-yan Chen Shao-Dan Zhang National Clinical Research Center for Ocular Diseases Eye HospitalWenzhou Medical UniversityWenzhou 325027Zhejiang ProvinceChina School of Ophthalmology and Optometry Biomedical EngineeringWenzhou Medical UniversityWenzhou 325027Zhejiang ProvinceChina

AIM:To assess glaucoma patient satisfaction and follow-up adherence in case management and identify associated predictors to improve healthcare quality and patient ***:In this cross-sectional study,a total of 119 patients completed a Patient Satisfaction Questionnaire-18 and a sociodemographic *** data was obtained from the case management ***-up adherence was defined as completing each follow-up within±30d of the scheduled time set by ophthalmologists during the study ***:Average satisfaction scored 78.65±7,with an average of 4.39±0.58 across the seven *** negatively correlated with satisfaction(P=0.008),whilst patients with follow-up duration of 2 or more years reported higher satisfaction(P=0.045).Multivariate logistics regression analysis revealed that longer follow-up durations were associated with lower follow-up adherence(OR=0.97,95%CI,0.95-1.00,P=0.044).Additionally,patients with suspected glaucoma(OR=2.72,95%CI,1.03-7.20,P=0.044)and those with an annual income over 100000 Chinese yuan demonstrated higher adherence(OR=5.57,95%CI,1.00-30.89,P=0.049).CONCLUSION:The case management model proves effective for glaucoma patients,with positive adherence *** implementation of this model can be optimized in the future based on the identified factors and extended to glaucoma patients in more hospitals.

关键词： glaucoma patient satisfaction follow-up adherence case management

LKPNR: Large Language Models and Knowledge Graph for Personalized News Recommendation Framework

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Computers, Materials & Continua 2024年第6期79卷 4283-4296页

作者： hao Chen Runfeng Xie Xiangyang Cui Zhou yan Xin Wang Zhanwei Xuan Kai Zhang State Key Laboratory of Communication Content Cognition People’s Daily OnlineBeijing100733China

Accurately recommending candidate news to users is a basic challenge of personalized news recommendation *** methods are usually difficult to learn and acquire complex semantic information in news texts,resulting in unsatisfactory recommendation ***,these traditional methods are more friendly to active users with rich historical ***,they can not effectively solve the long tail problem of inactive *** address these issues,this research presents a novel general framework that combines Large Language Models(LLM)and Knowledge Graphs(KG)into traditional *** learn the contextual information of news text,we use LLMs’powerful text understanding ability to generate news representations with rich semantic information,and then,the generated news representations are used to enhance the news encoding in traditional *** addition,multi-hops relationship of news entities is mined and the structural information of news is encoded using KG,thus alleviating the challenge of long-tail *** results demonstrate that compared with various traditional models,on evaluation indicators such as AUC,MRR,nDCG@5 and nDCG@10,the framework significantly improves the recommendation *** successful integration of LLM and KG in our framework has established a feasible way for achieving more accurate personalized news *** code is available at https://***/Xuan-ZW/LKPNR.

关键词： Large language models news recommendation knowledge graphs(KG)

FAST Observations of Four Comets to Search for the Molecular Line Emissions between 1.0 and 1.5 GHz Frequencies

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Research in Astronomy and Astrophysics 2024年第10期24卷 130-140页

作者： Long-Fei Chen chao-Wei Tsai Jian-yang Li Bin yang Di Li yan Duan Chih-hao Hsia Zhichen Pan Lei Qian Donghui Quan Xue-Jian Jiang Xiaohu Li Ruining Zhao Pei Zuo School of Physics and Electronic Science Guizhou Normal UniversityGuiyang 550025China Guizhou Provincial Key Laboratory of Radio Astronomy and Data Processing Guiyang 550025China Research Center for Astronomical Computing Zhejiang LaboratoryHangzhou 311100China National Astronomical Observatories Chinese Academy of SciencesBeijing 100101China Institute for Frontiers in Astronomy and Astrophysics Beijing Normal UniversityBeijing 102206China Key Laboratory of Radio Astronomy and Technology Chinese Academy of SciencesBeijing 100101China School of Atmospheric Sciences Sun Yat-sen UniversityZhuhai 519082China Núcleo de Astronomía Facultad de Ingenieríay CienciasUniversidad Diego PortalesChile Department of Astronomy College of Physics and Electronic EngineeringQilu Normal UniversityJinan 250200China Department of Electronic and Optical Engineering Space Engineering UniversityBeijing 101416China Laboratory for Space Research Faculty of ScienceThe University of Hong KongHong Kong(SAR)China Xinjiang Astronomical Observatory Chinese Academy of SciencesUrumqi 830011China CAS Key Laboratory of Optical Astronomy National Astronomical ObservatoriesChinese Academy of SciencesBeijing 100101China School of Astronomy and Space Sciences University of Chinese Academy of SciencesBeijing 100049China

We used the Five-hundred-meter Aperture Spherical radio Telescope(FAST)to search for the molecular emissions in the L-band between 1.0 and 1.5 GHz toward four comets,C/2020 F3(NEOWISE),C/2020 R4(ATLAS),C/2021 A1(Leonard),and 67P/Churyumov-Gerasimenko during or after their perihelion *** of molecular transition lines fall in this low-frequency range,many attributed to complex organic or prebiotic *** conducted a blind search for the possible molecular lines in this frequency range in those comets and could not identify clear signals of molecular emissions in the *** several molecules have been detected at high frequencies of greater than100 GHz in comets,our results confirm that it is challenging to detect molecular transitions in the L-band frequency *** non-detection of L-band molecular lines in the cometary environment could rule out the possibility of unusually strong lines,which could be caused by the masers or non-LTE *** the line strengths are predicted to be weak,for FAST,using the ultra-wide bandwidth receiver and improving the radio frequency interference environments would enhance the detectability of those molecular transitions at low frequencies in the future.

关键词： astrochemistry ISM:molecules comets:general line:identification

Plutonium utilization in a small modular molten-salt reactor based on a batch fuel reprocessing scheme

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Nuclear Science and Techniques 2024年第4期35卷 15-28页

作者： Xue-chao Zhao Rui yan Gui-Feng Zhu Ya-Fen Liu Jian Guo Xiang-Zhou Cai yang Zou Shanghai Institute of Applied Physics Chinese Academy of SciencesShanghai 201800China CAS Innovative Academies in TMSR Energy System Chinese Academy of SciencesShanghai 201800China University of Chinese Academy of Sciences Beijing 100049China

A molten salt reactor(MSR)has outstanding features considering the application of thorium fuel,inherent safety,sustainability,and resistance to ***,fissile material^(233)U is significantly rare at the current stage,thus it is difficult for MSR to achieve a pure thorium-uranium fuel ***,using plutonium or enriched uranium as the initial fuel for MSR is more *** this study,we aim to verify the feasibility of a small modular MSR that utilizes plutonium as the starting fuel(SM-MSR-Pu),and highlight its advantages and ***,the structural design and fuel management scheme of the SM-MSR-Pu were ***,the neutronic characteristics,such as the graphite-irradiation lifetime,burn-up performance,and coefficient of temperature reactivity were calculated to analyze the physical characteristics of the *** results indicate that plutonium is a feasible and advantageous starting fuel for a SM-MSR;however,there are certain shortcomings that need to be *** a 250 MWth SM-MSR-Pu,approximately 288.64 kg^(233)U of plutonium with a purity of greater than 90% is produced while 978.00 kg is burned every ten *** temperature reactivity coefficient decreases from -4.0 to -6.5 pcm K^(-1) over the 50-year operating time,which ensures a long-term safe ***,the amount of plutonium and accumulation of minor actinides(MAs)would increase as the burn-up time increases,and the annual production and purity of^(233)U will *** achieve an optimal burn-up performance,setting the entire operation time to 30 years is ***,more than 3600 kg of plutonium eventually accumulate in the *** research is required to effectively utilize this accumulated plutonium.

关键词： Molten salt fuel Plutonium utilization ^(233)U TRUs mole fraction Temperature feedback coefficient

A general climatology of categorized Martian ionospheric irregularities

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Science China Earth Sciences 2024年第10期67卷 3302-3325页

作者： Xin WAN Jiahao ZHONG Yongqiang hao chao XIONG Hui WANG Yutian CAO Jun CUI Yiwen LIU Qiaoling LI Jiawei KUAI Planetary Environmental and Astrobiological Research Laboratory(PEARL) School of Atmospheric SciencesSun Yat-sen UniversityZhuhai 519082China Key Laboratory of Tropical Atmosphere-Ocean System Ministry of EducationZhuhai 519082China Department of Space Physics College of Electronic InformationLuojia LaboratoryWuhan UniversityWuhan 430079China School of Physics and Electronic Information Shangrao Normal UniversityShangrao 334001China School of Petroleum China University of Petroleum-Beijing at KaramayKaramay 834000China College of Astronautics Nanjing University of Aeronautics and AstronauticsNanjing 210016China

A climatological survey of Martian ionospheric plasma density irregularities was conducted by exploring the in-situ measurements of the Mars Atmosphere and Volatile EvolutioN(MAVEN) spacecraft. The irregularities were first classified as enhancement, depletion, and oscillation. By checking the simultaneous magnetic field fluctuation, the irregularities have been classified into two types: with or without magnetic signatures. The classified irregularities exhibit diverse global occurrence patterns, as those with magnetic signatures tend to appear near the periphery of the crustal magnetic anomaly(MA), and those without magnetic signatures prefer to appear either inside of the MA or outside of the MA, depending on the type and solar zenith angle. Under most circumstances, the irregularities have a considerable occurrence rate at altitudes above the ionospheric dynamo height(above 200 km), and the magnetization state of the ions seems irrelevant to their occurrence. In addition, the irregularities do not show dependence on magnetic field geometry, except that the enhancement without magnetic signatures favors the vertical field line, implying its equivalence to the localized bulge. Other similarities and discrepancies exist in reference to previous studies. We believe this global survey complements previous research and provides crucial research clues for future efforts to clarify the nature of the Martian ionospheric irregularities.

关键词： Mars MAVEN Ionosphere Ionospheric irregularities Crustal magnetic anomaly Plasma

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Establishment of an Iron Deficiency Model by Iron Depletion in Pregnant Rats

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Biomedical and Environmental Sciences 2024年第2期37卷 210-215页

作者： CHEN Xi HAN chao Zhao Jin Peng SHEN Shi WANG Li Yuan REN Shou WANG Tong Lei MA yan XU Ze chao HUO Jun Sheng Key Laboratory of Trace Element Nutrition National Health Commission of the People’s Republic of ChinaNational Institute for Nutrition and HealthChinese Center for Disease Control and PreventionBeijing 100050China

Anemia,a global public health problem,has significant adverse consequences on the cognitive development of children and the work capacity of adults;affecting social and economic ***,roughly 43%of children under five years of age,38%of pregnant women,and 29%of nonpregnant women had *** during pregnancy significantly increases the risk of low birth weight and preterm birth.A 10 g/L increase in hemoglobin has been estimated to decrease the risk of maternal and perinatal mortality by 29%and 28%.

关键词： mortality pregnancy anemia

New recessive compound heterozygous variants of RP1L1 in RP1L1 maculopathy

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International Journal of Ophthalmology(English edition) 2024年第1期17卷 107-112页

作者： Wen-chao Cao Qing-Shan Chen Run Gan Tao Huang Xiao-He yan The Second Clinical Medical College Jinan UniversityShenzhen 518040Guangdong ProvinceChina Shenzhen Eye Hospital Jinan UniversityShenzhen Eye InstituteShenzhen 518040Guangdong ProvinceChin

AIM:To identify a maculopathy patient caused by new recessive compound heterozygous variants in ***:Comprehensive retinal morphological and functional examinations were evaluated for the patient with RP1L1 *** sequence capture array technique was used to screen potential pathologic *** chain reaction and Sanger sequencing were used to confirm the screening ***:Fundus examination showed round macular lesions appeared in both *** coherence tomography showed that the inner segment/outer segment continuity was disorganized and disruptive in the left eye,but it was uneven and slightly elevated in the right *** autofluorescence showed patchy hyper-autofluorescence in the *** field examination indicates central defects in both ***(ERG)and multifocal ERG showed no obvious *** fluorescein angiography in the macula showed obviously irregular hyper-fluorescence in the right eye and slightly hyper-fluorescence in the left *** found that the proband carried a missense variant(c.1972C>T)and a deletion variant(c.4717_4718del)of RP1L1,which were originated from the parents and formed compound heterozygous *** variants are likely pathogenic according to the ACMG *** imaging,ERG and detailed medical history are important diagnostic tools for differentiating between acquired and inherited retinal ***:A maculopathy case with detailed retinal phenotype and new recessive compound heterozygous variants of RP1L1 is identified in a Chinese family,which expands the understanding of phenotype and genotype in RP1L1 maculopathy.

关键词： maculopathy recessive compound heterozygous variants RP1L1